Thermodynamic Properties from Cubic Equations of State

Phillip Savage - University of Michigan

SOAVE-REDLICH-KWONG

Enter data into outlined cells only

Phase(s)
T=
P=
ompound =
Tc =
Pc =

Cpa=
Cpb=
Cpc=
Cpd=

200.000 K
10.000 MPa
Nitrogen
126.200 K
3.394 MPa
0.040
2.72E+01 J/mol-K
4.20E-03 J/mol-K^2
0.00E+00 J/mol-K^3
0.00E+00 J/mol-K^4

Z
f
H
S
G
A
U

SCF

=
=
=
=
=
=
=

0.86879
8.39E+00
-3.45E+03
-9.08E+01
1.47E+04
1.33E+04
-4.89E+03

V =

1.44E-04

PENG-ROBINSON
Phase(s)

SCF

MPa
J/mol
J/mol-K
J/mol
J/mol
J/mol

Z
f
H
S
G
A
U

=
=
=
=
=
=
=

0.82490
7.93E+00
-3.54E+03
-9.08E+01
1.46E+04
1.33E+04
-4.91E+03

m^3/mol

V =

1.37E-04

Calculate Parameters in SRK Equation of State

a=
1.39E-07 m^6 MPa/mol^2
Reference state: ideal gas at Tref & Pref
b=
2.68E-05 m^3/mol
T ref =
273. K
m=
0.547

P ref =
0.001 MPa
0.737
R=
8.314E-06 m^3 MPa/mol K
A=
0.370
B=
0.161

MPa
J/mol
J/mol-K
J/mol
J/mol
J/mol
m^3/mol

Calculate Parameters in Peng-Robinson EOS

a=
1.17E-07 m^6 MPa/mol^2
b=
2.41E-05 m^3/mol

0.436

0.787
A=
0.422
B=
0.145

Solve Soave-Redlich-Kwong EOS for Z

a1 = -1.00E+00
Q = 5.0E-02
a2 =
1.83E-01
R = -3.6E-02
a3 = -5.95E-02 Q^3-R^2 = -1.2E-03

Solve Peng-Robinson EOS for Z

a1 =
-8.55E-01
Q=
a2 =
7.01E-02
R=
a3 =
-3.71E-02 Q^3-R^2 =

Single Phase: Only One Real Root Exists

Z=
0.8688

Single Phase: Only One Real Root Exists

Z=
0.8249

5.79E-02
-3.17E-02
-8.13E-04