()/

(
( )

A TEMPERATU

PARAMETROS DE ANTOINE P(KPa), T(C)

i
A
B
C
1
16.0692
3448.660
204.090
2
16.2620
3799.890
226.350
PARAMETROS DE NRTL
b12(cal/mol) b21(cal/mol)
1-propanol(1)
500.4
1636.57
Agua(2)

12
0.5081

Psat 1
Psat 2
20.298474863 19.9237193312
12
0.75592658

21
G12
G21
2.4722757053 0.6810726513 0.284744416

12 12

1
_(1=1
)
2
_(1=0)
^ ]
19.828427202
4.3055000323
20.201390335
0.236629778
^ ]
_(1=0)
_(1=1)

A TEMPERATURA CONSTAN

x1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

A PRESION CONSTANTE
P(kpa)

101.33

1.987

x1
x2

1
0

n
t(C)
T(K)
12
21
G12
G21
1
2
psat1
psat2
t(C)

0
100
373.15
0.6748946539
2.2072588804
0.7096992618
0.3257880582
1
4.0309143602
101.33
91.2251173341
97.0815107029

1
97.081510703
370.2315107
0.6802147652
2.2246584297
0.7077834298
0.3229205542
1
4.0495375859
101.33
91.225117334
97.081510703

2
97.0815107
370.2315107
0.680214765
2.22465843
0.70778343
0.322920554
1
4.049537586
101.33
91.22511733
97.0815107

X1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

T(X1)
99.999608
88.368494
87.667009
87.436609
87.279619
87.279861
87.544602
88.21184
89.52808
92.028438
97.081511

1
14.676297
5.2816464
2.8892519
2.0076017
1.5855304
1.3488327
1.202617
1.1078119
1.0467929
1.011711
1

2
1
1.0539011
1.169284
1.3180073
1.4950755
1.7052077
1.9604626
2.2812675
2.6998035
3.2656002
4.0495376

A TEMPERATURA CONSTANTE

_
_
_ _ _

Tsat
97.0815107029
99.9996079031

T(C)
60

T (K)
333.15

ii
0

Gii
1

R (cal/mol-K)
1.987

A TEMPERATURA CONSTANTE

x2
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

1
19.8284272022
5.6076768338
2.9356261193
2.0186510815
1.5919453143
1.3547583905
1.2079237927
1.1118694121
1.0492089286
1.0125313971
1

2
1
1.0609906396
1.1851471868
1.3400495482
1.5209836819
1.7342538342
1.9943181141
2.325509137
2.7676345764
3.3878536359
4.3055000323

P (KPa)
19.92371933
30.40772047
30.80777853
30.98180123
31.10781597
31.02615789
30.60510019
29.69831472
28.06618775
25.2474233
20.29847486

y1
0
0.374336798
0.386842128
0.396770394
0.41551052
0.443166847
0.480684799
0.531965449
0.60706046
0.732651351
1

To

97.0815107029

Psat1
Psat2

101.33
91.22511733

3
97.081510703
370.2315107
0.6802147652
2.2246584297
0.7077834298
0.3229205542
1
4.0495375859
101.33
91.225117334
97.081510703

4
97.0815107029
370.2315107029
0.6802147652
2.2246584297
0.7077834298
0.3229205542
1
4.0495375859
101.33
91.2251173341
97.0815107029

5
97.081510703
370.2315107
0.6802147652
2.2246584297
0.7077834298
0.3229205542
1
4.0495375859
101.33
91.225117334
97.081510703

6
97.0815107
370.2315107
0.680214765
2.22465843
0.70778343
0.322920554
1
4.049537586
101.33
91.22511733
97.0815107

P1(T)
113.09934294
72.04105119
70.02722833
69.376089923
68.935305337
68.935983011
69.680662028
71.587209341
75.475350509
83.344415313
101.33000114

P2(T)
101.3300003505
65.8952943538
64.1417181772
63.5743322656
63.1901319322
63.1907226815
63.839753213
65.5002611658
68.8816867509
75.7064881079
91.2251183185

Y1
0
0.3755011928
0.3993413649
0.4123543553
0.4314577016
0.4588133233
0.4961954923
0.5478497353
0.623760474
0.7489234736
1.0000000113

___
_
__

TEMPERATURA

CONSTANTE

P -X

33
31
29
27
25
23
21
19

0.2

0.4

0.6
P,X

0.8
P,Y

PRESIN

CONSTANTE

T-X-Y
105
100
95
90
85
80

0.2

0.4

0.6
T,X

0.8
T,Y

1.2

1.2

1.2

 ((
GRUPO
1
1
5
7

1
2
3
4

k
CH3
CH2
OH
H2O

n
t(C)
T(K)
x1
x2
L1
L2
J1
J2
1
2
3
4
s11
s21
s31
s41
s12
s22
s32
s42
1
2
3
4
Ganma 1
Ganma 2
Psat1
Psat2
t (C)

Frecuencia
vk1
1
2
1
0

Rk
0.9011
0.6744
1
0.92

Qk
0.848
0.54
1.2
1.4

0
60
333.15
1
0
1.0000
0.4476
1.0000
0.2831
0.8480
1.0800
1.2000
0.0000
2.6784
2.6784
1.2998
0.4522
0.5689
0.5689
2.7847
1.4000
2.6784
2.6784
1.2998
0.4522
1.00000
3.37424
101.330
98.853
99.3075

1
99.308
372.458
1
0
1.0000
0.4476
1.0000
0.2831
0.8480
1.0800
1.2000
0.0000
2.7165
2.7165
1.3364
0.5205
0.6256
0.6256
2.5898
1.4000
2.7165
2.7165
1.3364
0.5205
1.00000
3.42165
101.330
98.853
99.3075

2
99.308
372.458
1
0
1.0000
0.4476
1.0000
0.2831
0.8480
1.0800
1.2000
0.0000
2.7165
2.7165
1.3364
0.5205
0.6256
0.6256
2.5898
1.4000
2.7165
2.7165
1.3364
0.5205
1.00000
3.42165
101.330
98.853
99.3075

P=

101.33
A
16.0692
16.2620

1-propanol
Agua

Para P =
x1
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

101.33 Kpa
T(x1)
100.00
89.59
89.20
89.06
88.98
89.11
89.60
90.55
92.15
94.77
99.48

T(K)
373.15
362.74
362.35
362.21
362.13
362.26
362.75
363.70
365.30
367.92
372.63

Ganma 1
16.13149
5.05989
2.68047
1.84898
1.47013
1.27
1.15275
1.08113
1.04
1.00968
1

Para T=60C
x1
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00

Ganma 1
17.92727
5.15174
2.67188
1.8306
1.45426
1.26
1.14543
1.07736
1.04
1.00968
1

Ganma2
1.000
1.061
1.187
1.343
1.518
1.708
1.913
2.143
2.416
2.783
3.374

P
21.84
32.39
32.71
32.84
32.93
32.74
32.11
30.93
29.10
26.43
22.39

 ()/
(
( )
Frecuencia
vk2
0
0
0
1
3
99.308
372.458
1
0
1.0000
0.4476
1.0000
0.2831
0.8480
1.0800
1.2000
0.0000
2.7165
2.7165
1.3364
0.5205
0.6256
0.6256
2.5898
1.4000
2.7165
2.7165
1.3364
0.5205
1.00000
3.42165
101.330
98.853
99.3075
KPa
B
3448.660
3799.890

Gk1=vk1*Qk
Gk2 =vk2*Qk
r1=vk1*Rk
r2=vk2*Rk
0.848
0
0.9011
0
1.08
0
1.3488
0
1.2
0
1
0
0
1.4
0
0.92
_2
_1
_1=
_2
3.128
1.4 =
0.92
3.2499 =
=
4
5
99.308
99.308
372.458
372.458
1
1
0
0
1.0000
1.0000
0.4476
0.4476
1.0000
1.0000
_^=1_+_5_ [1_/_
0.2831
0.2831
+(_/_ )]
0.8480
0.8480
1.0800
1.0800
1.2000
1.2000
0.0000
0.0000
_^=_ (1 _ )[
_
2.7165
2.7165

_
(,
)
/_

_
(,
)

_
(,
)
/_

)]
2.7165
2.7165
1.3364
1.3364
0.5205
0.5205
0.6256
0.6256
0.6256
0.6256
2.5898
2.5898
1.4000
1.4000
2.7165
2.7165
2.7165
2.7165
1.3364
1.3364
0.5205
0.5205
1.00000
1.00000
3.42165
3.42165
101.330
101.330
98.853
98.853
99.3075
99.3075

C
204.090
226.350

Tsat
T(C)
97.0815107029 97.0815107029
99.9996079031

Presin
Psat
103.236
70.592
69.296
68.930
68.720
69.079
70.364
72.957
77.488
85.412
101.330

y1
0.000
0.356
0.366
0.374
0.396
0.430
0.479
0.546
0.637
0.770
1.000

y1
0.000
0.352
0.367
0.377
0.399
0.433
0.480
0.545
0.634
0.766
1.000

T -X-Y
105.00
100.00
95.00
90.00
85.00
80.00
0.00

0.20

0.40

0.60
T,X

TEMPERATURA

CONSTANTE

P-X-Y.
33.00
31.00
29.00
27.00
25.00
23.00
21.00
19.00
0.00

0.20

0.40

0.60
P.X

0.80
P,Y

Parmetros de interaccin
1
1
5
1
2
3
0
0
986.5
0
0
986.5
156.4
156.4
0
300
300
-229.1

_ _ _

1_+_5_ [1_/_

_ (1 _ )[
_

_(,) _(,)/_ )]

Psati(KPa)
22.392
21.845

T(C)
62

7
4
1318
1318
353.5
0

CONSTANTE

T -X-Y

1.20
1.00
0.80
0.60
0.40

0.40

0.60
T,X

0.80

1.00

T,Y

P.X

0.80
P,Y

0.20
0.00
0.00

P-X-Y.

0.60

1.20

1.00

1.20

0.20

0.40

x-y

0.20

0.40

0.60

0.80

1.00

1.20