Informe B - Ensayo de Aptitud in-RDA-02-16-CZN

__________________________________________________________________
INFORME B
1er. ENSAYO DE APTITUD EN CONCENTRADO DE ZINC
IN-RDA-02-16-CZN
JULIO 2016
__________________________________________________________________
INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

Pedro Aguirre Cerda #8366, Antofagasta
Fono: 55-2893408, correo: ventas@intem.cl, sitio web: www.intem.cl

---------------------------------------------------------------------------------------------------------------------------------------------------
INDICE
1.
Introduccin ................................................................................................................................. 3
2.
Antecedentes Generales ............................................................................................................. 3
3.
Laboratorios Participantes ........................................................................................................... 4
4.
Descripcin de las Muestras ....................................................................................................... 4
5.
Identificacin de las Muestras ..................................................................................................... 4
6.
Preparacin de las Muestras ....................................................................................................... 5
7.
Test de Homogeneidad ............................................................................................................... 5
8.
Declaracin de la Confidencialidad ............................................................................................. 5
9.
Requerimientos de Anlisis ......................................................................................................... 5
10.
Resultados de anlisis ......................................................................................................... 5-7
11.
Anlisis Estadstico para el Ensayo de Aptitud ....................................................................... 8
11.1
Evaluacin del desempeo de los laboratorios ................................................................... 8
11.1.1
Valores Asignados ........................................................................................................... 9
11.1.2
Resultado del desempeo de los laboratorios ......................................................... 10-21
12.
Comentarios ..................................................................................................................... 22-23
13.
Recomendaciones ................................................................................................................. 23
14.
Anexos ................................................................................................................................... 24
15.
Referencias ........................................................................................................................... 24
16.
Responsables ........................................................................................................................ 24
Pgina 2 de 110

--------------------------------------------------------------------------------------------------------------------------------------------------1. Introduccin
Para que un laboratorio sea considerado competente, es necesario demostrar su capacidad
tcnica y asegurar la confiabilidad de sus resultados. Un determinado laboratorio debe demostrar
con evidencia objetiva que los resultados analticos que informa, son aceptables para los
requerimientos a los cuales estn destinadas dichas mediciones. Mediante la participacin en
Ensayos de Aptitud, es posible verificar estas competencias y tener pruebas objetivas del
desempeo del laboratorio.
La Norma ISO 17043 proporciona los requisitos generales para el desarrollo y la operacin de los
programas de ensayos de aptitud. La mayora de estos programas, tambin conocidos como
Ensayo de Intercomparacin o Round Robin, comparten como caracterstica comn, la
comparacin de los resultados de ensayos o medicin obtenidos por dos o ms laboratorios y
permite evaluar la habilidad de los laboratorios para efectuar ensayos en forma competente. Esto
puede incluir evaluaciones por los mismos laboratorios, por sus clientes o por otras partes, tales
como los organismos de acreditacin o fiscalizadores. Por lo tanto, complementa los
procedimientos internos de control de la calidad de los laboratorios, al proporcionar una medida
externa de su capacidad de ensayo. Tener la confianza que un laboratorio de ensayo o la
calibracin obtiene resultados confiables en forma consistente es de importancia primordial para
los usuarios de los servicios del laboratorio.
Adicionalmente, la participacin en un ensayo de aptitud permite a los laboratorios obtener otros
beneficios tales como:
Evaluar y comparar el desempeo individual del laboratorio respecto de otros laboratorios
participantes.
Permite identificar deficiencias o tendencias de los sistemas de medicin e introducir mejoras
cuando los resultados as lo requieran, siendo corregidos con el fin de garantizar el funcionamiento
analtico en un alto nivel y constante en el tiempo.
Cumplir con los requerimientos de las normativas internacionales (ISO 17025).
El examen de los resultados de la participacin de un laboratorio en ensayos de aptitud, slo
puede considerarse como informacin proporcionada sobre la competencia tcnica del laboratorio
de ensayo en un momento dado bajo las condiciones especficas del ensayo (o ensayos)
involucrados en un programa particular de ensayos de aptitud.
2. Antecedentes Generales
El presente informe contiene los resultados del 1er. Ensayo de Aptitud en Concentrado de Zinc, INRDA-02-16-CZN, ao 2016, efectuado por el Instituto Nacional de Tecnologa, Estandarizacin y
Metrologa (INTEM).
Algunas muestras consideradas en este ensayo, han sido proporcionadas por Minera San Cristbal
(Bolivia), uno de los principales productores de Pb, Zn y Ag en Sudamrica.
3. Laboratorios Participantes
El ensayo de aptitud cont con la participacin de 22 laboratorios.
Pgina 3 de 110

--------------------------------------------------------------------------------------------------------------------------------------------------ALFRED H. KNIGHT DEL PER S.A.C.

Av. Guillermo Dansey N1890, Lima-Per.
LABORATORIO QUMICO CASTRO

Millares esquina Periodista N 147, Potos-Bolivia.
ALEXSTEWART ASSAYERS ARGENTINA S.A.

Rodriguez Pea 1140, Luzuriaga-Maip-Mendoza.
LAMBOL S.A.
Carretera a Oruro Km 8.5, Potos-Bolivia.
BACHELET LABORATORIES
Avenue Pr Aily 26, Angleur-Belgium.
LABORATORIOS ANALITICOS DEL SUR EIRL.

Parque Industrial de Rio Seco C-1, Arequipa-Per.
CERTIMIN S.A.
Av. Las Vegas 845, Lima-Per.
LABORATORY SERVICES INTERNATIONAL

ROTTERDAM BV
Pittsburghstraat 9 3047 BL, Rotterdam- Netherlands.
COMINESA S.A.
Km. 3 Carretera Vinto Sepulturas Planta POLYMET
(Bolivia) S.A., Oruro-Bolivia.
MINERA CENTINELA AMSA

Av. Apoquindo 4001 piso 18, Santiago-Chile.
LABORATORIO QUMICO CONDE MORALES

Av. al Aeropuerto Nro s/n, Urbanizacin Pedro Ferrari,
Oruro-Bolivia.
MINERA SAN CRISTOBAL S. A.

Calacoto Calle 15 Edificio Torre Ketal Piso 5, La PazBolivia.
ERSA GLOBAL MEX, S.A. DE C.V.

Calz.Cuauhtemoc1177 Sur, Torren COAH.-Mxico.
NYRSTAR MINERA EL TOQUI

12 de Octubre # 737, Coyhaique-Chile.
INSPECTORATE CHILE LTDA..

Avda. Ruta del Cobre 320-Galpn 16 Sector La Negra,
Antofagasta-Chile.
SGS DEL PER S.A.C.

Av. Elmer Faucett N 3348, Callao-Per
INSPECTORATE SERVICES PERUS.A.C.

AV. Elmer Faucett 444 (Zona Industrial) Prov. Const. Del
Callao Per.
EMPRESA MINERA SINCHI WAYRA S. A.

Calle Lanza N 58, Potos-Bolivia
LABANNCY CIA. LTDA.

Gonzalo Benitez N54-45 y San Lorenzo, Quito-Ecuador.
SPECTROLAB
Ciudadela Universitaria Edif. Metalurgia,Oruro-Bolivia
LABPERU E.I.R.L.
Av. Panamericana Sur s/n Mz A-2Vista Alegre - Nasca
Ica-Per.
STEWART BLAITT Y CIA. LTDA.

Avenida Quilin N2910; Macul, Santiago
4. Descripcin de las Muestras

Las muestras consisten en Concentrado de Zinc los cuales poseen dentro de sus constituyentes:
Antimonio, Arsnico, Cadmio, Cobalto, Cobre, Hierro, Manganeso, Nquel, Plata, Plomo, Slice y
Zinc.
5. Identificacin de las Muestras
Todos los laboratorios recibieron las mismas muestras codificadas individualmente, las cuales
fueron identificadas como se indica a continuacin:
1. IN-200-XX
2. IN-201-XX
XX: Corresponde al nmero de sobre enviado a un determinado laboratorio.
Pgina 4 de 110

--------------------------------------------------------------------------------------------------------------------------------------------------6. Preparacin de las Muestras

Se seleccionaron 50 kg de cada material concentrado, proporcionado por diferentes productores,
para representar una matriz definida y con niveles de concentracin de los elementos de inters
adecuados al propsito del ensayo de aptitud. La muestra fue secada a 105C5 hasta peso
constante, chancada y pulverizada con granulometra tal que se encuentre 100% <200# ASTM y
95% <325# ASTM, homogeneizada y envasada en sobres de polietileno aluminizados sellados al
vaco en atmsfera de gas inerte.
7. Test de Homogeneidad
La evaluacin de homogeneidad se realiz utilizando un nmero de 15 unidades, seleccionadas
aleatoriamente. El test de homogeneidad aplicado est de acuerdo a norma ASTM E 826-81;
Testing Homogeneity Of Materials For The Development Of Reference Materials, lo cual permite
determinar la homogeneidad del material de referencia mediante test estadstico para determinar
las posibles diferencias dentro de cada uno de los frascos y entre cada uno de ellos.
El estudio de homogeneidad se realiz en base a la determinacin de Cobre, mediante tcnica de
espectroscopia de absorcin atmica de llama. De los resultados finales obtenidos se establece lo
siguiente:
Concentrado IN-200: El valor absoluto de la diferencia de los valores extremos de las medias de
resultados (t`) es igual a 0.003 y es menor a w cuyo valor es 0.007, por lo tanto a un nivel de
confianza del 95%, se puede concluir que existe una distribucin homognea de los especmenes
de Cobre presentes en el material.
Concentrado IN-201: El valor absoluto de la diferencia de los valores extremos de las medias de
resultados (t`) es igual a 0.004 y es menor a w cuyo valor es 0.008, por lo tanto a un nivel de
confianza del 95%, se puede concluir que existe una distribucin homognea de los especmenes
de Cobre presentes en el material.
8. Declaracin de la Confidencialidad
Los resultados obtenidos por los participantes y la informacin entregada por los mismos, sern
mantenidos bajo confidencialidad. INTEM, entreg a cada laboratorio participante un cdigo, con el
que hicieron llegar sus resultados (ej. IN-RDA02-16-XXX).
9. Requerimientos de Anlisis
Cada Laboratorio recibi las instrucciones para la realizacin de los anlisis requeridos para cada
material, de acuerdo a solicitud de anlisis presentada en Anexo N 1. Los mtodos usados
corresponden a los propios de cada laboratorio los cuales se describen en Anexo N2.
10. Resultados de anlisis

A continuacin, en tablas identificadas como; N1 y 2, se sealan los resultados provenientes de
los distintos laboratorios participantes. Existen laboratorios que no entregan toda la informacin por
no tener implementadas las metodologas o bien, no forma parte de su rutina.
Pgina 5 de 110

--------------------------------------------------------------------------------------------------------------------------------------------------Concentrado de Zn IN-200
Laboratorio
Pb (%)
Zn (%)
IN-RDA02-16-001
3.02
3.02
3.05
3.06
54.51
54.53
54.49
54.51
54.14
54.11
54.15
54.12
54.01
54.02
54.00
54.01
35.66
35.02
54.27
35.23
53.6
53.7
53.6
53.6
54.6
54.7
54.7
54.6
47.58
47.36
47.47
47.58
54.05
53.94
54.04
54.04
54.05
54.14
54.13
54.04
54.46
54.69
54.30
54.33
59.7
59.7
59.8
59.9
54.26
54.27
54.23
54.30
53.92
54.38
54.09
54.57
53.68
53.73
53.68
53.73
54.06
54.06
N.I
N.I
54.13
54.12
54.14
54.14
54.18
54.18
54.08
54.18
54.16
54.11
54.20
54.13
54.26
54.29
54.23
54.35
43.30
43.80
43.70
43.80
54.63
54.90
54.63
54.89
54.50
53.15
53.96
54.36
IN-RDA02-16-002
IN-RDA02-16-003
IN-RDA02-16-004
IN-RDA02-16-005
IN-RDA02-16-006
IN-RDA02-16-007
IN-RDA02-16-008
IN-RDA02-16-009
3.02
3.01
3.02
3.02
2.96
2.96
2.96
2.95
1.65
1.62
1.72
1.62
3.04
3.04
3.03
3.06
2.90
2.92
2.92
2.88
2.84
2.83
2.83
2.84
3.06
3.08
3.06
3.06
2.97
3.15
3.05
3.10
IN-RDA02-16-010
IN-RDA02-16-011
IN-RDA02-16-012
IN-RDA02-16-013
IN-RDA02-16-014
IN-RDA02-16-015
IN-RDA02-16-016
IN-RDA02-16-017
IN-RDA02-16-018
IN-RDA02-16-019
IN-RDA02-16-021
IN-RDA02-16-022
IN-RDA02-16-023
3.26
3.25
3.25
3.24
3.04
3.04
3.03
3.06
3.05
3.00
3.05
3.08
2.78
2.80
2.78
2.80
3.05
3.10
N.I
N.I
2.94
2.94
2.95
2.92
2.97
3.02
3.05
2.95
2.97
3.00
2.97
2.99
3.00
2.97
2.99
2.98
2.46
2.47
2.47
2.51
2.79
2.68
2.76
2.75
3.08
3.13
3.10
3.05
Ag (g/T) Co (g/T) Cd (g/T) Ni (g/T)

423.6
423.8
413.6
417.4
434
438
436
436
442.0
446.0
444.7
442.3
300.0
200.0
200.0
400.0
443.8
441.6
440.7
442.4
432.4
436.4
437.6
444.4
381.9
381.9
383.8
382.8
448.0
450.1
453.7
449.3
443.3
431.7
433.2
425.3
452.0
452.7
452.6
452.6
427.6
433.2
427.6
434.8
430.0
433.0
427.0
429.0
436.0
436.0
436.0
436.0
422.0
426.0
N.I
N.I
429.1
429.8
428.0
429.1
433.0
435.0
430.5
435.3
435.5
435.7
428.0
433.6
421.5
419.0
420.5
426.1
470.5
471.0
466.1
472.2
440.4
429.6
429.6
430.2
10.93
10.63
10.77
10.77
10.82
10.78
10.57
10.05
<10
<10
<10
<10
8.46
8.05
7.81
7.79
9.51
9.49
9.54
9.50
10.50
10.33
10.40
10.27
0.009%
0.008%
0.009%
0.007%
6.82
6.82
6.82
6.82
11.99
10.42
N.I
N.I
< 10
< 10
< 10
< 10
12
11
11
11
7.73
7.82
7.79
7.92
60
60
50
60
0.208%
0.208%
0.208%
0.208%
2146.7
2155.8
2149.5
2159.1
2176.1
2155.1
2166.4
2161.1
0.131%
0.131%
0.140%
0.140%
2129.5
2116.7
2086.5
2086.5
2258.8
2260.4
2252.4
2272.8
1963.5
1964.7
1933.1
1886.6
2158.9
2155.9
2120.8
2158.4
2100.0
2210.0
2150.0
2180.0
2306.5
2246.6
2310.5
2268.0
2324.6
2323.6
2322.9
2323.0
2090.6
2089.6
2083.4
2089.8
0.205%
0.204%
0.203%
0.204%
2120
2120
2120
2100
0.22%
0.22%
N.I
N.I
2194.0
2181.0
2197.0
2184.0
2209
2177
2215
2198
2097.1
2130.4
2125.8
2123.7
2088.3
2101.0
2062.6
2115.9
2490
2520
2520
2500
6.90
6.75
6.93
6.90
32.22
33.79
36.94
35.36
5.62
5.63
5.50
5.29
<20
<20
<20
<20
8.02
7.98
6.99
7.32
4.49
4.50
4.49
4.51
3.77
4.00
3.47
3.93
0.003%
0.003%
0.005%
0.004%
17
16
15
17
12.50
10.42
N.I
N.I
< 20
< 20
< 20
< 20
9
9
7
7
6.71
6.75
6.71
6.67
20
20
20
20
Tabla N1
Pgina 6 de 110
Fe (%)
Cu (%)
4.293
4.208
4.367
4.381
4.27
4.26
4.34
4.32
4.010
4.003
4.050
4.043
2.515
2.508
2.057
2.543
4.612
3.974
4.463
4.461
4.259
4.262
4.201
4.230
4.327
4.321
4.314
4.327
4.263
4.219
4.287
4.258
4.30
4.31
4.26
4.17
4.312
4.257
4.360
4.284
4.677
4.687
4.691
4.623
4.281
4.263
4.277
4.285
5.400
5.500
5.280
5.500
3.764
3.764
3.662
3.662
4.302
4.268
N.I
N.I
4.36
4.34
4.34
4.32
4.313
4.327
4.350
4.330
4.45
4.45
4.45
4.45
4.29
4.26
4.25
4.23
3.825
3.854
3.784
3.766
4.120
4.270
4.200
4.180
0.149
0.144
0.145
0.142
0.226
0.226
0.221
0.224
0.22
0.23
0.23
0.23
0.213
0.207
0.210
0.210
0.144
0.144
0.152
0.152
0.222
0.214
0.213
0.214
0.218
0.217
0.220
0.219
0.212
0.212
0.211
0.211
0.202
0.201
0.201
0.201
0.212
0.212
0.213
0.213
0.217
0.217
0.221
0.215
0.210
0.215
0.219
0.215
0.208
0.208
0.210
0.210
0.220
0.225
0.220
0.220
0.204
0.200
0.204
0.200
0.169
0.185
N.I
N.I
0.20
0.20
0.20
0.20
0.243
0.240
0.240
0.243
0.22
0.22
0.22
0.22
0.194
0.196
0.195
0.194
0.218
0.216
0.217
0.216
0.192
0.193
0.195
0.195
As (g/T) Sb (g/T) Mn (%) SiO2 (%)

0.093
0.094
0.095
0.094
2200
1850
1900
1800
939.8
919.8
918.2
922.8
833.1
833.1
757.4
833.1
400
400
300
300
332.0
337.2
341.1
349.5
952.6
975.8
927.4
963.6
938.8
931.5
949.4
951.1
955.8
946.6
949.9
954.9
1070
1120
1090
1110
994.0
969.8
1030.7
947.8
1007.7
1002.0
1004.1
1002.1
939.7
942.7
947.3
931.3
0.088%
0.079%
0.084%
0.080%
1150.0
1050.0
1100.0
1100.0
833.7
859.5
N.I
N.I
910
913
915
916
980
978
987
977
994.9
1005.2
1006.7
1010.8
878.2
918.5
893.1
938.3
0.13%
0.24%
0.23%
0.12%
0.089
0.088
0.088
0.088
0.070
0.062
0.046
0.062
4.06
4.02
3.99
4.02
4.98
4.92
4.96
4.95
349.0
340.4
362.0
359.8
148.6
153.7
137.3
143.2
385.9
384.9
386.0
391.0
430
460
440
440
557.6
539.8
477.1
379.8
398.1
398.4
397.6
397.9
350.7
353.0
352.0
345.5
0.060%
0.060%
0.056%
0.057%
480.0
450.0
500.0
450.0
292.7
310.7
N.I
N.I
349.0
349.0
334.0
336.0
0.093
0.093
0.091
0.087
0.097
0.098
0.097
0.098
0.099
0.101
0.100
0.100
0.102
0.101
0.105
0.102
0.050
0.050
0.051
0.051
0.097
0.098
0.098
0.099
0.089
0.090
0.092
0.087
0.057
0.057
0.057
0.057
0.096
0.094
N.I
N.I
0.095
0.096
0.095
0.095
5.22
5.20
5.22
5.16
4.26
4.27
4.28
4.30
4.30
4.31
4.26
4.27
406
405
406
403
318.4
320.3
320.9
319.5
429.4
428.6
434.9
360.0
0.43%
0.63%
0.77%
0.83%
0.096
0.096
0.097
0.096
0.079
0.078
0.077
0.078
0.069
0.067
0.067
0.068
0.081
0.082
0.083
0.081
3.96
3.94
4.00
4.06
4.82
4.83
4.80
4.81
2.10
2.25
2.20
2.30
3.84
3.84
3.60
3.64
4.40
4.31
N.I
N.I
4.01
3.96
4.00
4.02
3.96
4.27
4.34
3.99
0.20
0.19
0.17
0.19

--------------------------------------------------------------------------------------------------------------------------------------------------Concentrado de Zn IN-201
Laboratorio
Pb (%)
Zn (%)
IN-RDA02-16-001
1.33
1.32
1.30
1.32
57.31
57.36
57.30
57.28
56.87
56.86
56.83
56.82
56.93
56.93
56.91
56.91
35.52
35.59
35.63
35.08
56.5
56.4
56.6
56.4
57.7
57.6
57.6
57.7
50.37
50.37
50.15
50.04
56.88
56.86
56.88
56.82
56.91
56.91
56.94
56.88
56.67
57.09
57.12
57.08
63.0
63.1
63.0
62.9
57.16
57.13
57.13
57.12
57.00
57.18
57.16
57.14
56.80
56.75
56.86
56.81
57.14
56.98
N.I
N.I
57.00
57.00
57.02
57.01
56.9
56.8
56.9
56.9
57.00
56.97
56.96
56.94
57.11
57.13
57.24
57.11
50.5
50.3
50.2
49.9
57.34
57.61
57.36
57.34
56.91
57.08
57.00
57.28
IN-RDA02-16-002
IN-RDA02-16-003
IN-RDA02-16-004
IN-RDA02-16-005
IN-RDA02-16-006
IN-RDA02-16-007
IN-RDA02-16-008
IN-RDA02-16-009
1.32
1.31
1.32
1.32
1.28
1.27
1.27
1.27
0.68
0.69
0.70
0.70
1.26
1.26
1.25
1.26
1.21
1.23
1.20
1.22
1.24
1.24
1.24
1.24
1.25
1.26
1.26
1.24
1.35
1.36
1.33
1.31
IN-RDA02-16-010
IN-RDA02-16-011
IN-RDA02-16-012
IN-RDA02-16-013
IN-RDA02-16-014
IN-RDA02-16-015
IN-RDA02-16-016
IN-RDA02-16-017
IN-RDA02-16-018
IN-RDA02-16-019
IN-RDA02-16-021
IN-RDA02-16-022
IN-RDA02-16-023
1.33
1.34
1.33
1.32
1.25
1.26
1.26
1.25
1.18
1.24
1.28
1.29
1.30
1.30
1.30
1.30
1.42
1.44
N.I
N.I
1.25
1.25
1.25
1.25
1.25
1.24
1.21
1.27
1.27
1.28
1.27
1.27
1.25
1.26
1.25
1.26
1.15
1.15
1.15
1.17
1.22
1.20
1.21
1.18
1.37
1.36
1.36
1.35
Ag (g/T) Co (g/T) Cd (g/T) Ni (g/T)

273.4
294.1
292.4
291.2
304
306
303
303
309.0
307.3
308.3
307.3
200.0
300.0
200.0
200.0
304.0
306.4
298.8
292.7
306.4
302.0
312.8
305.2
270.0
268.2
269.1
269.1
312.4
318.0
311.6
313.5
292.8
295.9
292.7
292.6
306.3
300.2
295.8
303.4
266.8
266.8
261.8
267.3
296.1
297.6
298.2
296.2
307.0
292.0
301.0
294.0
323.0
323.0
323.0
323.0
299.0
297.0
N.I
N.I
298.8
299.8
300.3
299.0
304.0
301.7
299.0
300.0
300.9
302.4
302.7
303.4
304.0
294.7
292.7
294.8
323.3
326.2
330.4
333.0
301.7
302.1
307.3
300.6
8.70
8.57
9.00
8.73
8.80
8.47
8.54
8.41
<10
<10
<10
<10
6.71
6.28
6.94
6.69
10.13
10.92
10.76
10.69
8.20
8.07
7.77
8.03
0.011%
0.010%
0.010%
0.011%
4.82
4.82
4.82
4.82
8.35
8.12
N.I
N.I
< 10
< 10
< 10
< 10
8
9
8
9
5.80
5.71
5.76
5.80
60
60
50
60
0.256%
0.255%
0.252%
0.263%
2633.8
2600.0
2666.7
2700.0
2692.0
2641.8
2719.8
2710.8
0.158%
0.158%
0.158%
0.158%
2529.1
2517.6
2546.6
2524.4
2770.0
2764.8
2758.4
2791.6
2404.8
2345.2
2335.3
2311.7
2692.7
2818.4
2744.5
2756.5
2650.0
2680.0
2660.0
2600.0
2799.7
2811.2
2788.1
2763.0
2897.4
2872.7
2848.0
2842.3
2563.2
2592.8
2574.0
2592.8
0.229%
0.241%
0.248%
0.250%
2604.0
2604.0
2604.0
2604.0
0.27%
0.27%
N.I
N.I
2688.0
2660.0
2666.0
2655.0
2675
2715
2708
2688
2531.2
2552.2
2563.5
2568.0
2573.3
2569.4
2552.7
2568.2
3195
3160
3220
3210
9.10
9.30
9.67
9.50
29.08
29.86
29.86
29.86
8.18
7.96
7.82
7.68
<20
<20
<20
<20
9.44
9.60
9.24
10.82
5.74
5.76
5.79
5.76
6.53
6.10
6.33
6.40
0.003%
0.004%
0.002%
0.003%
14.00
14.00
14.00
14.00
15.09
13.81
N.I
N.I
< 20
< 20
< 20
< 20
11
10
10
10
10.19
10.12
10.06
10.04
20
20
30
30
Fe (%)
Cu (%)
4.216
4.389
4.182
4.304
4.59
4.60
4.55
4.56
4.003
4.013
3.960
3.940
2.360
2.458
2.423
2.374
4.034
4.012
3.943
3.941
4.204
4.193
4.292
4.222
4.134
4.121
4.127
4.127
4.367
4.326
4.336
4.403
4.25
4.24
4.24
4.36
4.237
4.263
4.121
4.239
4.754
4.768
4.744
4.762
4.365
4.345
4.309
4.334
4.050
4.200
4.150
4.230
3.375
3.472
3.375
3.320
4.270
4.282
N.I
N.I
4.29
4.29
4.28
4.32
4.363
4.337
4.323
4.337
4.48
4.51
4.52
4.46
4.21
4.20
4.21
4.23
3.892
3.865
3.837
3.803
4.200
4.240
4.310
4.170
0.152
0.148
0.147
0.144
0.134
0.125
0.125
0.126
0.13
0.13
0.13
0.13
0.123
0.123
0.123
0.127
0.088
0.088
0.088
0.088
0.122
0.123
0.121
0.124
0.129
0.129
0.129
0.130
0.120
0.120
0.121
0.120
0.108
0.107
0.107
0.108
0.127
0.126
0.128
0.125
0.124
0.130
0.130
0.132
0.127
0.129
0.127
0.128
0.124
0.124
0.123
0.125
0.120
0.128
0.137
0.130
0.132
0.124
0.120
0.120
0.088
0.089
N.I
N.I
0.12
0.12
0.12
0.12
0.147
0.146
0.143
0.146
Tabla N2
Pgina 7 de 110
0.13
0.13
0.13
0.13
0.117
0.115
0.117
0.115
0.125
0.126
0.126
0.113
0.118
0.118
0.120
0.117
As (g/T) Sb (g/T) Mn (%) SiO2 (%)

0.057
0.057
0.057
0.057
1900
2100
2250
2300
1049.1
1038.4
1070.7
1050.4
833.1
833.1
757.4
757.4
200
200
250
250
190.9
188.2
189.8
187.2
1077.8
1039.4
1082.4
1103.2
1045.0
1043.5
1039.9
1042.8
1038.1
1031.7
1041.2
1032.8
1230
1220
1220
1190
1123.7
1124.1
1115.5
1113.3
1100.0
1138.1
1109.2
1100.0
1043.7
1058.0
1056.7
1043.7
0.066%
0.081%
0.084%
0.086%
1700.0
1700.0
1800.0
1600.0
928.4
957.8
N.I
N.I
1015.0
1011.0
993.0
993.0
200.4
209.2
203.2
226.6
100.2
99.1
100.4
101.0
232.8
236.1
231.6
230.4
260
260
260
250
437.4
407.3
220.8
351.0
220.8
219.8
220.8
220.4
211.3
213.7
197.0
202.0
0.040%
0.050%
0.045%
0.049%
400.0
375.0
375.0
400.0
122.7
141.3
N.I
N.I
216.0
213.0
205.0
205.0
1081
1101
1101
1088
1132.5
1159.7
1162.5
1176.0
968.3
902.1
993.2
1022.2
0.08%
237
241
242
240
141.0
140.2
140.7
139.1
266.6
247.9
247.2
230.4
0.53%
0.16%
0.15%
0.08%
0.83%
0.65%
0.70%
0.055
0.055
0.056
0.056
0.039
0.039
0.039
0.039
2.91
2.89
2.92
2.94
3.17
3.16
3.14
3.07
0.055
0.054
0.053
0.052
0.050
0.051
0.050
0.051
0.061
0.06
0.062
0.061
0.062
0.062
0.061
0.061
0.030
0.030
0.030
0.031
0.061
0.060
0.060
0.061
0.052
0.053
0.057
0.056
0.033
0.033
0.033
0.033
0.058
0.058
N.I
N.I
0.058
0.057
0.058
0.058
3.34
3.28
3.28
3.30
3.17
3.11
3.13
3.13
3.11
3.07
3.03
3.13
0.058
0.059
0.059
0.059
0.047
0.048
0.048
0.049
0.036
0.036
0.037
0.037
0.049
0.051
0.051
0.050
2.63
2.70
2.61
2.63
3.85
3.82
3.85
3.84
1.60
1.52
1.58
1.55
2.62
2.32
2.40
2.50
2.96
2.96
N.I
N.I
2.84
2.80
2.80
2.77
2.58
2.49
2.46
3.11
0.17
0.10
0.09
0.09

--------------------------------------------------------------------------------------------------------------------------------------------------11. Anlisis Estadstico para el Ensayo de Aptitud

Las suposiciones subyacentes de la estadstica paramtrica residen en suponer la normalidad en
la distribucin de los datos. Este es quizs el principal inters en no aplicar estimadores
convencionales en favor de mtodos estadsticos robustos para la evaluacin de programas de
ensayos de aptitud de datos, lo que proporciona una poderosa herramienta por medio de la
realizacin de los clculos ampliamente adoptadas en la norma International Standard ISO 13528,
Statistical methods for use in proficiency testing by interlaboratory comparisons, que se ocupa de
los mtodos estadsticos para su uso en ensayos de aptitud para comparaciones interlaboratorios.
Es sabido que el uso de los valores medios en la evaluacin de los clculos de pruebas de
eficiencia tiene una pobre estabilidad al considerar el efecto de los valores atpicos (outliers), por lo
que la aplicacin de mtodos robustos de estimacin es recomendada. En muchos de los campos
de aplicacin cubiertos por las estadsticas de intercomparacin, en ocasiones no es de crtica
importancia las estimaciones desde el enfoque clsico, pero en ciertos casos debe ser tenido en
cuenta, en particular cuando la determinacin involucra un material complejo o cuando la
diversidad en el origen de los laboratorios participantes no es despreciable.
En el desarrollo de esta comparacin entre laboratorios, el protocolo estadstico se llev a cabo
para lograr la estimacin tanto del valor verdadero como de la desviacin estndar del Ensayo de
Aptitud. De acuerdo con esto, se ha considerado un enfoque estadstico con el fin de evaluar los
resultados analticos recibidos desde los participantes y a partir de los resultados, determinar el
ms adecuado a ser usado en la evaluacin del desempeo de los laboratorios, como le es la
aplicacin de estadstica robusta, usando la mediana y por medio del algoritmo A como se describe
en la norma ISO 13528.
11.1
Evaluacin del desempeo de los laboratorios
La evaluacin del desempeo de los laboratorios participantes se realiz de acuerdo con los
procedimientos aceptados internacionalmente. Se utiliz como criterio el clculo del parmetro z,
definido de la siguiente manera:
z = (x1/2 xref) SL
Donde:
x1/2
: Promedio para cada laboratorio = xi/ r
xref
: Valor Asignado a la concentracin de los analitos de la muestra enviada. En este caso se
corresponde a la media robusta (Alg A).
xi
: Valores individuales de cada laboratorio
: Nmero de replicados informados
: Desviacin estndar (estimador de la reproducibilidad o varianza entre laboratorios).
Este ltimo parmetro es obtenido mediante tratamiento estadstico, es decir, representa el desvo
estndar de los datos estadsticamente aceptables.
De acuerdo con la definicin dada, es posible clasificar a los laboratorios de la siguiente forma:
Pgina 8 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
11.1.1 Valores Asignados

Los valores asignados para cada material de concentrado de Zinc 200 y 201 se muestran en las
tablas identificadas como Tabla N3 y 4 respectivamente.
Parmetro
Analtico
Ag
As
Concentrado de Zinc IN-200

Valor Asignado
Unidad
DSR ~(1)
(Alg A)
g/T
433
11
ER %
0.99
0.096
0.008
4.44
Cd
0.215
0.009
1.66
Co
g/T
10
7.32
Cu
0.211
0.013
2.48
Fe
4.28
0.09
0.88
Mn
0.089
0.011
6.40
Ni
g/T
10
28.01
Pb
SiO2 (*)
%
%
2.98
4.15
0.11
0.40
1.42
4.87
Sb
g/T
390
77
10.13
Zn
54.13
0.26
0.19
Tabla N3
Parmetro
Analtico
Ag

Valor Asignado
Unidad
DSR ~(1)
(Alg A)
g/T
300
7
ER %
0.91
As
0.107
0.012
5.76
Cd
0.264
0.014
2.11
Co
g/T
12.99
Cu
0.124
0.007
2.21
1.80
Fe
4.21
0.19
Mn
0.053
0.007
6.45
Ni
Pb
g/T
%
11
1.27
5
0.06
20.59
1.86
SiO2 (*)
2.87
0.41
7.32
Sb
218
55
12.96
Zn
56.98
Tabla N4
0.25
0.17
(*): Valor estimativo
Pgina 9 de 110

--------------------------------------------------------------------------------------------------------------------------------------------------11.1.2 Resultado del desempeo de los laboratorios

En Anexo N3 se presentan los grficos indicadores de rendimiento a travs del Z-score.
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-007
IN-RDA01-16-001
IN-RDA01-16-021
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-023
IN-RDA01-16-018
IN-RDA01-16-010
IN-RDA01-16-017
IN-RDA01-16-002
IN-RDA01-16-014
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-003
IN-RDA01-16-008
IN-RDA01-16-011
IN-RDA01-16-022
Plata (Ag) Concentrado IN-200

Promedio
|Z-Score|
275
14.5
383
4.6
420
1.2
422
1.0
424
0.8
429
0.4
430
0.3
431
0.2
432
0.1
433
0.0
433
0.0
433
0.0
436
0.3
436
0.3
438
0.4
442
0.8
444
1.0
450
1.6
452
1.8
470
3.4
Resultado
Insatisfactorio
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Tabla N5
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-013
IN-RDA01-16-015
IN-RDA01-16-022
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-007
IN-RDA01-16-008
IN-RDA01-16-006
IN-RDA01-16-019
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-021
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-023
IN-RDA01-16-002
Arsnico (As) Concentrado IN-200

Promedio
|Z-Score|
0.081
1.8
0.083
1.6
0.085
1.4
0.091
0.6
0.091
0.6
0.093
0.4
0.094
0.2
0.094
0.2
0.095
0.1
0.095
0.1
0.098
0.2
0.099
0.3
0.100
0.5
0.100
0.5
0.110
1.6
0.110
1.7
0.180
10.1
0.194
11.7
Tabla N6
Pgina 10 de 110
Resultado
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Insatisfactorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-007
IN-RDA01-16-013
IN-RDA01-16-001
IN-RDA01-16-012
IN-RDA01-16-022
IN-RDA01-16-005
IN-RDA01-16-014
IN-RDA01-16-021
IN-RDA01-16-008
IN-RDA01-16-002
IN-RDA01-16-009
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-006
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-023
Cadmio (Cd) Concentrado IN-200

Promedio
|Z-Score|
0.136
8.8
0.194
2.4
0.204
1.2
0.208
0.8
0.209
0.7
0.209
0.6
0.210
0.5
0.212
0.4
0.212
0.3
0.215
0.0
0.215
0.0
0.216
0.1
0.216
0.2
0.219
0.4
0.220
0.6
0.220
0.6
0.226
1.2
0.228
1.5
0.232
1.9
0.251
4.0
Resultado
Insatisfactorio
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Tabla N7
Laboratorio
IN-RDA01-16-014
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-012
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-023
IN-RDA01-16-013
Cobalto (Co) Concentrado IN-200

Promedio
|Z-Score|
7
1.9
8
1.3
8
1.2
10
0.5
10
0.0
11
0.1
11
0.2
11
0.4
11
0.5
58
24.5
83
37.5
Tabla N8
Pgina 11 de 110
Resultado
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Insatisfactorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-015
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-016
IN-RDA01-16-008
IN-RDA01-16-014
IN-RDA01-16-012
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-009
IN-RDA01-16-011
IN-RDA01-16-005
IN-RDA01-16-022
IN-RDA01-16-010
IN-RDA01-16-006
IN-RDA01-16-019
IN-RDA01-16-013
IN-RDA01-16-001
IN-RDA01-16-002
IN-RDA01-16-017
Cobre (Cu) Concentrado IN-200

Promedio
|Z-Score|
0.148
4.8
0.177
2.6
0.194
1.3
0.195
1.2
0.200
0.8
0.201
0.7
0.202
0.7
0.209
0.1
0.210
0.1
0.212
0.0
0.213
0.1
0.215
0.3
0.216
0.4
0.217
0.5
0.218
0.5
0.219
0.6
0.220
0.7
0.221
0.8
0.224
1.0
0.228
1.3
0.242
2.3
Resultado
Insatisfactorio
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable
Tabla N9
Laboratorio
IN-RDA01-16-023
IN-RDA01-16-004
IN-RDA01-16-014
IN-RDA01-16-021
IN-RDA01-16-003
IN-RDA01-16-022
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-019
IN-RDA01-16-009
IN-RDA01-16-012
IN-RDA01-16-015
IN-RDA01-16-002
IN-RDA01-16-010
IN-RDA01-16-001
IN-RDA01-16-007
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-005
IN-RDA01-16-018
IN-RDA01-16-011
IN-RDA01-16-013
Hierro (Fe) Concentrado IN-200

Promedio
|Z-Score|
0.15
43.6
2.41
19.7
3.71
5.9
3.81
4.9
4.03
2.6
4.19
0.9
4.24
0.4
4.26
0.2
4.26
0.2
4.26
0.2
4.28
0.0
4.29
0.1
4.30
0.2
4.30
0.3
4.31
0.4
4.32
0.5
4.33
0.6
4.34
0.7
4.38
1.1
4.45
1.8
4.67
4.2
5.42
12.1
Tabla N10
Pgina 12 de 110
Resultado
Insatisfactorio
Insatisfactorio
Insatisfactorio
Insatisfactorio
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Insatisfactorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-011
IN-RDA01-16-014
IN-RDA01-16-004
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-003
IN-RDA01-16-013
IN-RDA01-16-007
IN-RDA01-16-001
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-019
IN-RDA01-16-008
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-010
Manganeso (Mn) Concentrado IN-200

Promedio
|Z-Score|
0.051
3.4
0.057
2.9
0.060
2.6
0.068
1.9
0.080
0.8
0.082
0.6
0.088
0.1
0.090
0.1
0.091
0.2
0.094
0.5
0.095
0.6
0.095
0.6
0.096
0.7
0.097
0.8
0.098
0.9
0.100
1.0
0.102
1.2
Resultado
Insatisfactorio
Cuestionable
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Tabla N11
Laboratorio
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-007
IN-RDA01-16-021
IN-RDA01-16-003
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-023
IN-RDA01-16-004
IN-RDA01-16-013
Nquel (Ni) Concentrado IN-200

Promedio
|Z-Score|
4
1.1
4
1.0
6
0.8
7
0.6
7
0.5
8
0.4
8
0.3
11
0.3
16
1.2
20
1.9
35
4.7
38
5.2
Tabla N12
Pgina 13 de 110
Resultado
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Insatisfactorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-014
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-018
IN-RDA01-16-019
IN-RDA01-16-017
IN-RDA01-16-002
IN-RDA01-16-001
IN-RDA01-16-005
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-008
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-023
IN-RDA01-16-011
Plomo (Pb) Concentrado IN-200

Promedio
|Z-Score|
1.65
12.4
2.48
4.7
2.74
2.2
2.79
1.8
2.84
1.4
2.91
0.7
2.94
0.4
2.96
0.2
2.98
0.0
2.99
0.0
3.00
0.1
3.02
0.3
3.04
0.5
3.04
0.6
3.04
0.6
3.05
0.6
3.07
0.8
3.07
0.8
3.08
0.9
3.09
1.0
3.25
2.5
Resultado
Insatisfactorio
Insatisfactorio
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable
Tabla N13
Laboratorio
IN-RDA01-16-023
IN-RDA01-16-013
IN-RDA01-16-014
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-022
IN-RDA01-16-008
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-011
IN-RDA01-16-004
IN-RDA01-16-007
xido de Slice (SiO2) Concentrado IN-200

Promedio
|Z-Score|
0.40
9.5
2.21
4.9
3.73
1.1
3.99
0.4
4.00
0.4
4.02
0.3
4.14
0.0
4.28
0.3
4.29
0.3
4.36
0.5
4.82
1.7
4.95
2.0
5.20
2.6
Tabla N14
Pgina 14 de 110
Resultado
Insatisfactorio
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-007
IN-RDA01-16-015
IN-RDA01-16-021
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-002
IN-RDA01-16-012
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-011
IN-RDA01-16-019
IN-RDA01-16-022
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-010
IN-RDA01-16-013
IN-RDA01-16-023
Antimonio (Sb) Concentrado IN-200

Promedio
|Z-Score|
146
3.2
302
1.1
320
0.9
340
0.6
342
0.6
350
0.5
350
0.5
353
0.5
387
0.0
398
0.1
405
0.2
413
0.3
443
0.7
470
1.0
489
1.3
583
2.5
6650
80.8
Resultado
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable
Insatisfactorio
Tabla N15
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-021
IN-RDA01-16-007
IN-RDA01-16-005
IN-RDA01-16-014
IN-RDA01-16-023
IN-RDA01-16-003
IN-RDA01-16-008
IN-RDA01-16-015
IN-RDA01-16-009
IN-RDA01-16-002
IN-RDA01-16-016
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-019
IN-RDA01-16-010
IN-RDA01-16-001
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-011
Zinc (Zn) Concentrado IN-200

Promedio
|Z-Score|
40.04
53.3
43.65
39.6
47.50
25.1
53.63
1.9
53.71
1.6
53.99
0.5
54.01
0.5
54.02
0.4
54.06
0.3
54.09
0.1
54.13
0.0
54.13
0.0
54.15
0.1
54.15
0.1
54.24
0.4
54.27
0.5
54.28
0.6
54.44
1.2
54.51
1.4
54.65
2.0
54.76
2.4
59.78
21.4
Tabla N16
Pgina 15 de 110
Resultado
Insatisfactorio
Insatisfactorio
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable
Insatisfactorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-011
IN-RDA01-16-007
IN-RDA01-16-001
IN-RDA01-16-009
IN-RDA01-16-021
IN-RDA01-16-012
IN-RDA01-16-015
IN-RDA01-16-013
IN-RDA01-16-016
IN-RDA01-16-005
IN-RDA01-16-017
IN-RDA01-16-010
IN-RDA01-16-018
IN-RDA01-16-023
IN-RDA01-16-002
IN-RDA01-16-006
IN-RDA01-16-003
IN-RDA01-16-008
IN-RDA01-16-014
IN-RDA01-16-022
Plata (Ag) Concentrado IN-201

Promedio
|Z-Score|
225
10.9
266
5.0
269
4.5
288
1.8
293
1.0
297
0.5
297
0.5
298
0.3
299
0.2
299
0.1
300
0.0
301
0.1
301
0.2
302
0.3
303
0.4
304
0.5
307
0.9
308
1.1
314
2.0
323
3.3
328
4.1
Resultado
Insatisfactorio
Insatisfactorio
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Insatisfactorio
Tabla N17
Laboratorio
IN-RDA01-16-013
IN-RDA01-16-004
IN-RDA01-16-015
IN-RDA01-16-022
IN-RDA01-16-016
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-012
IN-RDA01-16-003
IN-RDA01-16-006
IN-RDA01-16-019
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-002
Arsnico (As) Concentrado IN-201

Promedio
|Z-Score|
0.079
2.3
0.080
2.3
0.094
1.1
0.097
0.8
0.100
0.6
0.104
0.3
0.104
0.2
0.105
0.2
0.105
0.2
0.108
0.0
0.109
0.2
0.111
0.3
0.112
0.4
0.116
0.7
0.118
0.8
0.122
1.2
0.170
5.2
0.214
8.8
Tabla N18
Pgina 16 de 110
Resultado
Cuestionable
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Insatisfactorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-007
IN-RDA01-16-013
IN-RDA01-16-005
IN-RDA01-16-021
IN-RDA01-16-001
IN-RDA01-16-022
IN-RDA01-16-012
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-002
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-008
IN-RDA01-16-006
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-023
Cadmio (Cd) Concentrado IN-201

Promedio
|Z-Score|
0.158
7.6
0.235
2.1
0.242
1.6
0.253
0.8
0.255
0.6
0.257
0.5
0.257
0.5
0.258
0.4
0.260
0.3
0.265
0.0
0.265
0.1
0.267
0.2
0.269
0.4
0.270
0.4
0.270
0.4
0.275
0.8
0.277
0.9
0.279
1.1
0.287
1.6
0.320
3.9
Resultado
Insatisfactorio
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Tabla N19
Laboratorio
IN-RDA01-16-014
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-012
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-011
IN-RDA01-16-023
IN-RDA01-16-013
Cobalto (Co) Concentrado IN-201

Promedio
|Z-Score|
5
1.3
6
1.0
7
0.7
8
0.2
8
0.1
9
0.1
9
0.0
9
0.0
11
0.7
58
17.2
105
33.9
Tabla N20
Pgina 17 de 110
Resultado
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Insatisfactorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-015
IN-RDA01-16-008
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-016
IN-RDA01-16-007
IN-RDA01-16-005
IN-RDA01-16-022
IN-RDA01-16-012
IN-RDA01-16-014
IN-RDA01-16-003
IN-RDA01-16-009
IN-RDA01-16-001
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-013
IN-RDA01-16-006
IN-RDA01-16-002
IN-RDA01-16-019
IN-RDA01-16-017
Cobre (Cu) Concentrado IN-201

Promedio
|Z-Score|
0.088
5.2
0.089
5.1
0.107
2.3
0.116
1.1
0.118
0.8
0.120
0.5
0.120
0.5
0.123
0.2
0.123
0.1
0.124
0.0
0.124
0.1
0.124
0.1
0.127
0.4
0.128
0.6
0.128
0.6
0.129
0.7
0.129
0.7
0.129
0.8
0.130
0.9
0.130
0.9
0.146
3.2
Resultado
Insatisfactorio
Insatisfactorio
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Tabla N21
Laboratorio
IN-RDA01-16-023
IN-RDA01-16-004
IN-RDA01-16-014
IN-RDA01-16-021
IN-RDA01-16-003
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-019
IN-RDA01-16-010
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-009
IN-RDA01-16-001
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-012
IN-RDA01-16-017
IN-RDA01-16-008
IN-RDA01-16-018
IN-RDA01-16-002
IN-RDA01-16-011
Hierro (Fe) Concentrado IN-201

Promedio
|Z-Score|
0.15
21.2
2.40
9.4
3.39
4.3
3.85
1.9
3.98
1.2
3.98
1.2
4.13
0.4
4.21
0.0
4.21
0.0
4.23
0.1
4.23
0.1
4.27
0.3
4.27
0.3
4.28
0.3
4.30
0.4
4.34
0.7
4.34
0.7
4.36
0.8
4.49
1.5
4.58
1.9
4.76
2.8
Tabla N22
Pgina 18 de 110
Resultado
Insatisfactorio
Insatisfactorio
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-011
IN-RDA01-16-014
IN-RDA01-16-022
IN-RDA01-16-004
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-013
IN-RDA01-16-003
IN-RDA01-16-001
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-010
Manganeso (Mn) Concentrado IN-201

Promedio
|Z-Score|
0.030
3.4
0.033
3.0
0.036
2.5
0.039
2.2
0.050
0.5
0.050
0.5
0.051
0.4
0.054
0.0
0.055
0.2
0.055
0.3
0.057
0.5
0.058
0.6
0.058
0.7
0.059
0.8
0.061
1.0
0.061
1.1
0.061
1.2
Resultado
Insatisfactorio
Insatisfactorio
Cuestionable
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Tabla N23
Laboratorio
IN-RDA01-16-011
IN-RDA01-16-012
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-010
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-023
IN-RDA01-16-004
IN-RDA01-16-013
Nquel (Ni) Concentrado IN-201

Promedio
|Z-Score|
6
1.2
6
1.1
8
0.7
9
0.4
10
0.3
10
0.3
10
0.2
11
0.0
14
0.6
25
3.0
30
4.0
30
4.1
Tabla N24
Pgina 19 de 110
Resultado
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Insatisfactorio
Insatisfactorio
Insatisfactorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-006
IN-RDA01-16-007
IN-RDA01-16-017
IN-RDA01-16-013
IN-RDA01-16-016
IN-RDA01-16-012
IN-RDA01-16-008
IN-RDA01-16-019
IN-RDA01-16-005
IN-RDA01-16-018
IN-RDA01-16-003
IN-RDA01-16-014
IN-RDA01-16-001
IN-RDA01-16-002
IN-RDA01-16-011
IN-RDA01-16-009
IN-RDA01-16-023
IN-RDA01-16-015
Plomo (Pb) Concentrado IN-201

Promedio
|Z-Score|
0.69
9.7
1.18
1.5
1.20
1.1
1.22
0.9
1.24
0.4
1.24
0.4
1.25
0.3
1.25
0.3
1.25
0.2
1.25
0.2
1.26
0.2
1.26
0.1
1.27
0.1
1.27
0.1
1.30
0.6
1.32
0.9
1.32
0.9
1.33
1.1
1.34
1.2
1.36
1.5
1.43
2.7
Resultado
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable
Tabla N25
Laboratorio
IN-RDA01-16-023
IN-RDA01-16-013
IN-RDA01-16-014
IN-RDA01-16-019
IN-RDA01-16-022
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-015
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-004
IN-RDA01-16-007
IN-RDA01-16-011
xido de Slice (SiO2) Concentrado IN-201

Promedio
|Z-Score|
0.24
6.4
1.56
3.2
2.46
1.0
2.64
0.5
2.66
0.5
2.80
0.2
2.92
0.1
2.96
0.2
3.09
0.5
3.14
0.7
3.14
0.7
3.30
1.1
3.84
2.4
Tabla N26
Pgina 20 de 110
Resultado
Insatisfactorio
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable

---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
IN-RDA01-16-023
IN-RDA01-16-007
IN-RDA01-16-015
IN-RDA01-16-021
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-016
IN-RDA01-16-006
IN-RDA01-16-011
IN-RDA01-16-002
IN-RDA01-16-008
IN-RDA01-16-019
IN-RDA01-16-022
IN-RDA01-16-009
IN-RDA01-16-010
IN-RDA01-16-014
IN-RDA01-16-013
Antimonio (Sb) Concentrado IN-201

Promedio
|Z-Score|
1
3.9
100
2.1
132
1.6
140
1.4
189
0.5
206
0.2
210
0.2
210
0.2
220
0.0
225
0.1
233
0.3
240
0.4
248
0.5
258
0.7
354
2.5
388
3.1
460
4.4
Resultado
Insatisfactorio
Cuestionable
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable
Insatisfactorio
Insatisfactorio
Tabla N27
Laboratorio
IN-RDA01-16-004
IN-RDA01-16-021
IN-RDA01-16-007
IN-RDA01-16-005
IN-RDA01-16-014
IN-RDA01-16-002
IN-RDA01-16-008
IN-RDA01-16-017
IN-RDA01-16-009
IN-RDA01-16-003
IN-RDA01-16-018
IN-RDA01-16-010
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-023
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-019
IN-RDA01-16-001
IN-RDA01-16-022
IN-RDA01-16-006
IN-RDA01-16-011
Zinc (Zn) Concentrado IN-201

Promedio
|Z-Score|
35.46
85.6
50.23
26.9
50.23
26.8
56.48
2.0
56.81
0.7
56.85
0.5
56.86
0.5
56.88
0.4
56.91
0.3
56.92
0.2
56.97
0.0
56.99
0.1
57.01
0.1
57.06
0.3
57.07
0.3
57.12
0.6
57.14
0.6
57.15
0.7
57.31
1.3
57.41
1.7
57.65
2.7
63.00
23.9
Tabla N28
Pgina 21 de 110
Resultado
Insatisfactorio
Insatisfactorio
Insatisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Satisfactorio
Cuestionable
Insatisfactorio

--------------------------------------------------------------------------------------------------------------------------------------------------12.
Comentarios
Aquellos laboratorios que por razones de metodologa analtica y cuyo lmite de cuantificacin no
permite entregar un valor numrico no pudieron ser considerados en la evaluacin estadstica.
En la tabla N29, se resume el nmero de laboratorios satisfactorios, cuestionables y no
satisfactorios, para el concentrado de Zinc IN-200, evaluados mediante el parmetro Z Score.
Elemento
Satisfactorio
Cuestionable
Insatisfactorio
Ag
17
As
16
Cd
17
Co
Cu
18
Fe
15
Mn
14
Ni
10
Pb
SiO2
17
10
2
1
2
2
Sb
14
Zn
17
Tabla N29
En la tabla N30 se detallan los % CV iniciales promedio de todos los laboratorios para IN-200.
Parmetro Analtico
%CV
Ag
2.35
As
4.21
Cd
0.83
Co
4.11
Cu
1.20
Fe
1.55
Mn
1.92
Ni
6.86
Pb
SiO2
0.83
2.01
Sb
5.81
Zn
1.26
Tabla N30
Conclusiones:
Los elementos y/o parmetros Pb, Cu, Ag, As, Zn, Cd y SiO2 presentan bajo % CV inicial debido a
la alta precisin entre los laboratorios participantes. Elementos como; Sb, Fe Ni, Co y Mn
presentaron altos % CV inicial debido a los valores promedios reportados y/o a la alta dispersin de
algunos laboratorios.
Pgina 22 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
En la tabla siguiente, se resume el nmero de laboratorios satisfactorios, cuestionables y no

satisfactorios, para el concentrado de Zinc IN-201, evaluados mediante el parmetro Z Score.
Elemento
Satisfactorio
Cuestionable
Insatisfactorio
Ag
16
As
14
Cd
Co
17
9
1
0
2
2
Cu
17
Fe
17
Mn
13
Ni
Pb
19
SiO2
10
Sb
12
Zn
17
Tabla N31
En la tabla siguiente se detallan los % CV iniciales promedio de todos los laboratorios para IN-201.
Parmetro Analtico
%CV
Ag
2.02
As
4.83
Cd
0.99
Co
3.40
Cu
1.47
Fe
1.03
Mn
1.05
Ni
7.16
Pb
SiO2
1.04
4.60
Sb
6.25
Zn
0.17
Tabla N32
Conclusiones:
Los elementos Pb, Cu, Ag, As, Fe, Zn, Cd y Mn presentan bajo % CV inicial debido a la alta
precisin entre los laboratorios participantes. Elementos y/o parmetros; Sb, Ni, Co y SiO2
presentaron altos % CV inicial debido a los valores promedios reportados y/o a la alta dispersin de
algunos laboratorios.
Pgina 23 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
13.
Recomendaciones
Se recomienda a cada laboratorio con clasificacin de Insatisfactorio, evaluar las causas del
desvo de sus anlisis, desde el punto de vista analtico y clculo de resultados.
14.
Anexos
Anexo N1: Solicitud de anlisis

Anexo N2: Mtodos de Anlisis
Anexo N3: Tablas Estadsticas y Grficos
15.
16.
Referencias
Thompson. M. The International Harmonized Protocol for the Proficiency Testing of

Analytical Chemistry Laboratories. Pure Appl. Chem., Vol. 78, No. 1, pp. 145196, 2006.
ISO 13528-2005 Statistical methods for use in proficiency testing by interlaboratory

comparison.
ISO 17043-2010 Conformity assessment General requirements for proficiency testing.
Responsables
Vctor Anabaln Escobedo

Gerente Tcnico
INTEM
Vernica Dub Almendares

Jefe Control de Procesos
INTEM
Pgina 24 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
ANEXO N1
SOLICITUD DE ANLISIS
Pgina 25 de 110
ENSAYO DE APTITUD EN MUESTRAS DE CONCENTRADO DE ZINC

IN-RDA-02-16-CZN
Antofagasta 27 Abril de 2016

INTEM-RDA02-XXX/2016
Ref.: Ensayo de Aptitud N02/16
Sr.
Presente
De nuestra consideracin:
INTEM, Instituto Nacional de Tecnologa Estandarizacin y Metrologa, agradece su inters en
participar del 1 Ensayo de Aptitud ao 2016, IN-RDA-02-16-CZN, cuya matriz es Concentrado de Zinc.
Este programa busca poder evaluar el desempeo analtico de su laboratorio para evidenciar
objetivamente la calidad de sus resultados emitidos, evaluar la ejecucin de ensayos especficos o
mediciones, identificar errores, ya sea; con el desempeo de personal, calibracin de equipos y/o
adecuacin de procedimientos.
1. Identificacin de Muestras
1.1 Concentrado de Zn
1.
2.
3.
4.
IN-200-XX
IN-200-XX
IN-200-XX
IN-200-XX
1.2 Concentrado de Zn
1.
2.
3.
4.
IN-201-XX
IN-201-XX
IN-201-XX
IN-201-XX
2. Identificacin del Laboratorio

Para preservar la confidencialidad de los resultados, INTEM asigna un cdigo a cada laboratorio
colaborador, en este caso le corresponde IN-RDA02-16-XXX
3. Anlisis Solicitados
A cada muestra realizar 1 anlisis (SIMPLE) de los elementos indicados a continuacin:
Pgina 26 de 110

IN-RDA-02-16-CZN
Pb, Zn, Ag, Fe, Cu, Co, Cd, As, Sb, Ni, Mn y SiO2
Nota 1: Los laboratorios que no tengan implementados todos los ensayos, informarn resultados
para los elementos que inscribieron.
4. Requerimientos de Anlisis
Los mtodos de anlisis sern aquellos que tenga implementado vuestro laboratorio o si lo prefiere
utilice los mtodos propuestos en tabla N1.
Parmetro
Analtico
Zn
Pb
Ag
Co
Cd
Ni
Fe
Cu
As
Sb
Mn
SiO2
Mtodo
Unidad
Cifras
Volumetra
Digestin Multicida con cidos HCl, HNO3, HF, HClO4 y
lectura por Espectroscopia de Absorcin Atmica de llama.
Digestin de agua regia y lectura por Espectroscopia de
Absorcin Atmica de llama.
Digestin 3 cidos usando HNO3, HClO4, H2SO4 (Na2SO4 1%
como supresor) y lectura por Espectroscopia de Absorcin
Atmica de llama
Fusin Alcalina y lectura por Espectroscopia de Absorcin
Atmica de llama
Tabla N1
X.XX
X.X
g/T
X.X
g/T
X.XX
g/T
X.XX
g/T
X.XX
X.XXX
X.XXX
g/T
X.X
g/T
X.X
X.XX
X.XX
5. Informe de Resultados
Los laboratorios participantes debern enviar sus resultados antes del 31 de Mayo de 2016,
mediante archivo digital Excel de acuerdo a formato sealado en tabla N2 junto a vuestro cdigo
asignado en tem 2 de la presente solicitud.
Se solicita a los participantes informacin breve sobre el mtodo empleado (masa, aforo, tcnica
analtica e instrumental), en formato Excel y segn formato de tabla N3.
Pgina 27 de 110

IN-RDA-02-16-CZN
Cdigo del Laboratorio:__________________________

ID
Muestra
Zn
(%)
Pb
(%)
Ag
(g/T)
Co
(g/T)
Cd
(g/T)
Ni
(g/T)
Fe
(%)
Cu
(%)
As
(g/T)
Sb
(g/T)
Mn
(%)
SiO2
(%)
Tabla N2
Cdigo del Laboratorio:__________________________
Elemento
Mtodo
Masa
Muestra
(g)
Volumen
de Aforo
(mL)
cidos
(Tipo y
Cantidad)
Factor
Dilucin
Medio
cido Final
(%)
Tabla N3
6. Envo de Informe
El Informe debe ser enviado a las siguientes casillas electrnicas:
Vernica Dub A. (Jefa de Control de Procesos)
Fono: (56-55) 2893479, e-mail: veronica.dubo@intem.cl
Vctor Anabaln E. (Gerente Tcnico)
Fono: (56-55) 2893408, e-mail: victor.anabalon@intem.cl
Rosana Bustos (Asistente Administrativa)
Fono: (56-55) 2893408, e-mail: recepcion@intem.cl
De antemano gracias por su participacin.
Atentamente
Vernica Dub Almendares

Jefa de Control de Procesos
INTEM Antofagasta
Pgina 28 de 110
Supresor
Rango
Calibracin
Equipo

---------------------------------------------------------------------------------------------------------------------------------------------------
ANEXO N2
MTODOS DE ANLISIS
Pgina 29 de 110

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Codigo del Laboratorio: IN-RDA02-16-001
Mtodo
Masa Muestra
(g)
Zn
Volumetra
0.2500
---
Pb
Digestin con cidos
0.2500
250
Fe
Digestin con cidos
0.2500
250
Elem ento
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
---
---
---
---
---
10
Llama
---
10
Llama
10 ml. HCl
Supresor
10 ml.HNO3
Cu
Mn
Digestin con cidos
Digestin con cidos
0.2500
0.2500
250
250
Digestin con cidos
0.2500
250
---
---
10-20-40
Varian 55B
1-5-10
Agilent 240
Varian 55B
10 ml.HNO3
5-10-20
Agilent 240
10 ml. HCl
5-10-20
Varian 55B
10 ml.HNO3
3-5-10
Agilent 240
10 ml. HCl
1-3-5
Varian 55B
1-3-5-10
Agilent 240
---
---
10
10
Llama
Llama
10 ml. HCl
---
10
Llama
1-3-5
10 ml.HNO3
Ag
Ensayo a fuego
Equipo
20-40-60
10 ml. HCl
10 ml.HNO3
Cd
Rango Calibracin
Varian 55B
Agilent 240
10
---
---
---
---
---
Gravimetra
Masa Muestra
(g)
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Micro balanza - sartorius
Elem ento
Zn
Pb
Ag
Mtodo
Determinacin de Zinc por
Volumetra - Complexometra
Determinacin de Plomo por

Espectrofotometra de Absorcin
Atmica
Determinacin de Plata por
Atmica
0,20-0,25
0,15-0,25
100
0,15-0,25
100
Cd
Determinacin de Cadmio por

Atmica
0,15-0,25
100
Fe
Determinacin de Hierro por

Atmica
0,15-0,25
100
Cu
Determinacin de Cobre por

Atmica
0,15-0,25
100
As
Determinacin de Arsnico por

Atmica
0,25-0,50
100
Sb
Determinacin de Antimonio por

Atmica
0,25-0,50
100
cido clorhdrico HCl p.a.

32 a 37 % d= 1,18 cido
ntrico HNO3 p.a. 64 a
67 % d=1,40
32 a 37 % d= 1,18 cido
67 % d=1,40
32 a 37 % d= 1,18 cido
67 % d=1,40
32 a 37 % d= 1,18 cido
67 % d=1,40
32 a 37 % d= 1,18 cido
67 % d=1,40
32 a 37 % d= 1,18 cido
67 % d=1,40
cido ntrico HNO3 p.a.
64 a 67 % d=1,40 cido
clorhdrico HCl p.a. 32 a
37 % d= 1,18
cido ntrico HNO3 p.a.
64 a 67 % d=1,40 cido
clorhdrico HCl p.a. 32 a
37 % d= 1,18
Equipo
Titulador Digital Titronic
20-160
0,5-4,0
25
0,5-4
25
25-800
25
5,0-20,0
30
10,0-40,0
30
5,0-40,0
Pgina 30 de 110
Espectrofotmetro de Absorcin
Atmica VARIAN SPECTRO AA
240FS
240FS
240FS
240FS
240FS
240FS
240FS

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Elem ento
Mtodo
Masa Muestra
(g)
Volum en de
Aforo (m l)
Ag
Fe
Pb
Espectroscopia de Absorcin
Atmica de llama
0,1000 g
100
Zn
Volumetra
0,2000 g
-----
Co
Cd
Ni
Cu
As
Sb
Mn
Espectroscopia de Emisin
Atmica
0,3000 g
50
SiO2
Gravimetra
0,5000 g
Masa Muestra
(g)
cidos (Tipo y
Cantidad
HCl conc. 10 ml
HNO3 conc. 5 ml
HClO4 conc. 2 ml
HCl conc. 10 ml
HNO3 conc. 5 ml
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
Ag (0,025-1,50) mg/L
Fe (0,1-3,0) mg/L
Atmica, Varian AA240FS
Pb (1,0-50) mg/L
Titulador digital, Schott
----Instruments, Titronic Universal
Co (0,02-0,20) mg/L
Cd (0,50-20,00) mg/L
Ni (0,02-0,20) mg/L
Espectrometro Plasma de Emision
Cu (1,00-30,00) mg/L
Atomica, Shimadzu ICPE 9000
As (4,00-40,00) mg/L
Sb (1,00-40,00) mg/L
Mn (0,20-4,00) mg/L
-----
HCl (40%)
-----
-----
-----
-----
HCl conc. 10 ml
HNO3 conc. 5 ml
-----
HCl (40%)
-----
-----
HCl conc. 15 ml
HClO4 conc. 8 ml
H2SO4 dil. 0,5 ml
HF conc. 4 ml
-----
-----
-----
-----
Balanza Analtica Mettler Toledo,

XP 504
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
PH 5.5
---
Elem ento
Zn
Mtodo
Volumetra
aprox. 0.2500
300
Fe
Absorcin Atmica de Llama
aprox. 0.2000
250
Cd
aprox. 0.2000
100
Cu
Ag
Pb
aprox. 0.2000
aprox. 0.2000
100
100
aprox. 0.2000
100
20 ml AR
20 ml AR
20 ml AR
20 ml AR
20 ml AR
20 ml AR
10
PH 2.0
---
PH 2.0
---
PH 2.0
PH 2.0
---
---
---
---
1, 3, 6 ppm
Analyst 400 de Perkin
1, 3, 5 ppm
1, 2, 3 ppm
Elmer
Elmer
Elmer
0.2, 0.5, 1 ppm

Elmer
10
PH 2.0
---
1, 5, 10 ppm
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
10% HCL
____
2.0-5.0-10.0
Varian 280FS
25% HCL
____
0.5-1.0-2.0
Varian 240FS
10% HCL
____
2.0-5.0-10.0
Varian 280FS
10% HCL
____
5.0-10.0-20.0
Varian 280FS
10% HCL
____
0.2-1.0-5.0-10.0
Varian 280FS
Elmer
Elem ento
Mtodo
Masa Muestra
(g)
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Pb
EAA
0.2500 g
100
HCLO4 (4ml)
Ag
EAA
0.2500 g
100
Cd
EAA
0.2500 g
100
Fe
EAA
0.2500 g
100
HNO3 (10 ml)+HCL (5 ml)+
10X
Directo
HCLO4(2 ml)
HCLO4 (4 ml)
HCLO4 (4 ml)
Cu
EAA
0.2500 g
100
HCLO4 (4 ml)
Sb
EAA
0.5000 g
100
HNO3(10ml)
As
EAA
0.5000 g
100
HNO3(10ml)
Zn
VOL
0.2500 g
____
HNO3(10 ml) +HCL(5 ml)+

H2SO4 (3ml)
Directo
10X
Directo
Directo
Directo
____
Pgina 31 de 110
10% HCL Ac. Tartrico 10% w /v (10ml) 2.0-5.0-10.0
Varian 280FS
10% HCL
____
2.0-5.0-10.0
Varian 280FS
Solucin
____
____
Bureta Digital
Brand

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Elem ento
Mtodo
Masa Muestra
(g)
Zn
Volumetria
0.5000
Pb
EAA
0.2000
Ag
EAA
0.2000
Co
ICP
0.5000
Cd
ICP
Ni
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Agua Regia
500
HF, HCL, HClO4
Acetato
2% HCl
5,0-20,0
Perkin Elmer AAS-Analyst-100

500
HF, HCL, HClO4
50
HF, HCL, HClO4
15 % HCl
0,5-5,0

2% HCl
1,00-20,00
0.5000
50
ICP
ICP
HF, HCL, HClO4
2% HCl
1,00-20,00
ICP
ICP
0.5000
ICP
50
HF, HCL, HClO4
HNO3
1,00-20,00
ICP
Fe
EAA
ICP
0.2000
500
HF, HCL, HClO4
0.2% HCl
2,50-12,50

Cu
As
EAA
0.5000
500
HF, HCL, HClO4
0.2% HCl
2,50-12,50

ICP
0.2000
50
HNO3, H2SO4
HNO3, H2SO4
20,00-50,00
ICP
ICP
Sb
ICP
0.5000
100
HF, HCL, HClO4
15 % HCl
1,00-20,00
ICP
ICP
Mn
EAA
0.5000
50
HF, HCL, HClO4
0.2% HCl
2,50-12,50
Mn
EAA
0.5000
50
HF, HCL, HClO4
0.2% HCl
1,00-20,00
ICP
ICP
Si
Gravimetria
0.5000
Fusion Alcalina
2% HCl
Balanza Analitica
Balanza Analitica
Mtodo
Masa Muestra
(g)
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
Volumetra
0.25
--
3 cidos
--
--
--
--
0.5
100
4 acidos
--
10% HCL
--
--
0.5
100
4 acidos
--
10% HCL
--
--
0.5
100
4 acidos
--
10% HCL
--
--
0.2
200
4 acidos
--
10% HCL
--
--
0.5
100
4 acidos
--
10% HCL
--
--
0.2
200
4 acidos
--
10% HCL
--
--
0.5
100
4 acidos
--
10% HCL
--
--
0.5
100
2 acidos
--
10% HCL
--
--
0.5
100
4 acidos
--
10% HCL
--
--
0.2
200
4 acidos
--
10% HCL
--
--
0.2
100
Fusin peroxido de Sodio
--
10% HCL
--
--
Espectrofotometro de Absorcin
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Masa Muestra
(g)
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
0.400
---
HCl+HNO3+H2SO4
---
---
---
0 - 50 ml
0 - 50 ml
Rango Calibracin
Equipo
Bureta clase A
Bureta clase A

Elem ento
Zn
Pb
Ag
Co
Cd
Ni
Fe
Cu
As
Sb
Mn
Si
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Atmica
Titulador Automtico
Elem ento
Zn
Fe
Mtodo
VOLUM
(EDTA)
VOLUM
(K2Cr2O7)
Bureta Digital
JENCONS
Bureta Digital
JENCONS
0.500
---
HCl+HNO3+H2SO4
---
---
---
SiO2
GRAVIM
0.500
---
HCl+HNO3+H2SO4
---
---
---
---
---
Cu
EAA
0.200
200
H2SO4
---
10% HCl
---
0 - 16 ug/ml
Agilent 240
As
EAA
1.000
100
HCl+HNO3
---
10% HCl
---
0 - 80 ug/ml
Agilent 240
Ag
EAA
1.000
100.0
HNO3+HCl
---
25% HCl
AlNO3
0 - 4 ug/ml
Agilent 240
Pb
EAA
0.200
200.0
HCl+HNO3
---
10% HCl
---
0 - 100 ug/ml
Agilent 240
Sb
EAA
1.000
100.0
HNO3+HCl
---
10% HNO3
Tartrico
0 - 100 ug/ml
Agilent 240
Cd
EAA
0.200
200.000
H2SO4
---
H2SO4
---
0.2 - 5.0 ug/ml
Agilent 240
Mn
EAA
0.200
200.000
H2SO4
---
H2SO4
---
0.2 - 5.0 ug/ml
Agilent 240
Pgina 32 de 110

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Mtodo
Masa Muestra
(g)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Ag
Fire Assay Gravimetra
Supresor
Rango Calibracin
Equipo
10.00
As
Digestin Multicida
0.20
100
HCl,HNO3,HBr
Microbalanza
15
Cd
Digestin Multicida
0.20
100
ICP-OES
HCl,HNO3,HBr
15
Co
Digestin Multicida
0.20
ICP-OES
100
HCl,HNO3,HBr
15
Cu
Digestin Multicida
ICP-OES
0.20
100
HCl,HNO3,HBr
15
Fe
ICP-OES
Digestin Multicida
0.20
100
HCl,HNO3,HBr
15
ICP-OES
Mn
Digestin Multicida
0.20
100
HCl,HNO3,HBr
15
ICP-OES
Ni
Digestin Multicida
0.20
100
HCl,HNO3,HBr
15
ICP-OES
Pb
Sb
Digestin Multicida
0.20
100
HCl,HNO3,HBr
15
ICP-OES
Elem ento
Volum en de
Aforo (m l)
Si
Zn
Volumetra
0.50
HCl,HNO3,HSO4
Elem ento
Mtodo
Masa Muestra
(g)
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
Pb
E.A.A
0.2000 gr
250 ml
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
--
10 % HCl
0,1 % Na2SO4
0-100 mg/L
Varian 240
Zn
E.A.A
1.0000 gr
250 ml
--
10 % HCl
0,1 % Na2SO4
0-50 mg/L
Varian 240
Ag
E.A.A
1.0000 gr
100 ml
--
25 % HCl
0,1 % Na2SO4
0-50 mg/L
Varian 240
Co
E.A.A
1.0000 gr
50 ml
--
10 % HCl
0,1 % Na2SO4
0-5 mg/L
Varian 240
Cd
E.A.A
2.5000 gr
50 ml
--
10 % HCl
0,1 % Na2SO4
0-2.5 mg/L
Varian 240
Ni
E.A.A
2.5000 gr
50 ml
--
10 % HCl
0,1 % Na2SO4
0-50 mg/L
Varian 240
Fe
E.A.A
1.0000 gr
100 ml
0-500 mg/L
Varian 240
Cu
E.A.A
1.0000 gr
100 ml
0- 500mg/L
Varian 240
As
E.A.A
1.0000 gr
100 ml
Sb
E.A.A
1.0000 gr
100 ml
Mn
E.A.A
1.0000 gr
100 ml
Si
E.A.A
0.1000 gr
250 ml
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
HNO3 (5 ml)
HCl
(15ml)
HNO3 (5 ml)
HCl
(15ml)
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
HNO3 (7 ml)
HCl
(15ml)
HClO4 (5ml)
HF (5ml)
Fusin con Perxido
---
10 % HCl
0,1 % Na2SO4
10 % HCl
0,1 % Na2SO4
--
10 % HCl
0,1 % Na2SO4
0- 100mg/L
Varian 240
--
10 % HCl
0,1 % Na2SO4
0- 100mg/L
Varian 240
--
10 % HCl
0,1 % Na2SO4
0- 20mg/L
Varian 240
--
10 % HCl
0,1 % Na2SO4
0- 200mg/L
Varian 240
Pgina 33 de 110

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Cdigo del Laboratorio: IN-RDA02-16-12
Elem ento
Mtodo
Masa Muestra
(g)
Volum en de
Aforo (m L)
Zn
VOLUMETRICO
0.25
----
Pb
ABSORCION ATOMICA
0.25
250
Ag
ABSORCION ATOMICA
0.50
50
Co
ABSORCION ATOMICA
1.00
25
Cd
ABSORCION ATOMICA
0.25
100
Ni
ABSORCION ATOMICA
1.00
25
Fe
ABSORCION ATOMICA
0.25
250
cidos
(Tipo y Cantidad)
Agua Regia+H2SO4
Ataque Multiacida (HCl,
HNO3, HF, HClO4)
HNO3, HF, HClO4)
HNO3, HF, HClO4)
HNO3, HF, HClO4)
HNO3, HF, HClO4)
HNO3, HF, HClO4)
HNO3, HF, HClO4)
Factor
Dilucin
Medio cido
Final
Supresor
Rango Calibracin
Equipo
(%)
----
----
----
----
----
----
25% HCl
----
10-20-50 / 5-10-20
Agilent 200 serie AA
----
25% HCl
----
2-5-10
----
25% HCl
----
2-5-10
----
25% HCl
----
2-5-10
----
25% HCl
----
2-5-10
----
25% HCl
----
20-50-100
5-10-20
Cu
ABSORCION ATOMICA
0.25
100
----
25% HCl
----
As
ABSORCION ATOMICA
0.50
50
Agua Regia
----
25% HCl
----
Sb
ABSORCION ATOMICA
0.50
50
Agua Regia
----
25% HCl
Acido Tartarico
2-5-10
Mn
ABSORCION ATOMICA
0.50
50

HNO3, HF, HClO4)
----
25% HCl
----
5-10-20
Masa Muestra
(g)
Volum en de
Aforo (m L)
Medio cido
Final
Supresor
Rango Calibracin
Equipo
10 gr/rplica
(5 rplicas)
0-200.0 mg
microbalanza
Buretas
Varian
2-5-10 /
10-20-50
Elem ento
Ag
Mtodo
Fundicin y Copelacin Va Seca
cidos
(Tipo y Cantidad)
Ntrico al 30% y 70%
Factor
Dilucin
-
(%)
Ntrico al 30% y
70%
Zn
Volumtrico
0.500 gr
300 ml
Clorhdrico, perclrico,
ntrico. 10 ml de c/u
Ph 7.5
Sol. Estantadizada.
Factor de un estndar
de valor conocido
Pb, Co, Cd, Ni,

Fe, Cu, As, Sb,
Mn
Absorcin Atmica
0.200 gr
200 ml
Ntrico, Perclrico a 5 Ml
c/u. Clorhdrico 20 ml.
10-200
al 10%
Segn la
concentracin
SiO2
Gravimetra
5 gr
Clorhdrico, Ntrico como

agua regia
20%
Mtodo
Masa Muestra
(g)
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
Zn
Volumtrico
0.2500
--
HCl-HNO3
--
--
--
--
--
Pb
Absorcin Atmica
0.1000
100
HCl-HNO3
--
10% HCl
--
--
--
Ag
Ensayo al Fuego
1.0000
--
--
--
--
--
--
--
Co
Absorcin Atmica
2.0000
100
HCl-HNO3
--
10% HCl
--
--
Perkin Elmer Aanalyst 200
Cd
Absorcin Atmica
2.0000
100
HCl-HNO3
--
10% HCl
--
--
Ni
Absorcin Atmica
2.0000
100
HCl-HNO3
--
10% HCl
--
--
Fe
Volumtrico
0,2500-0,5000
--
HCl-HNO3
--
--
--
--
--
Cu
Absorcin Atmica
0.1000
100
HCl-HNO3
--
10% HCl
--
--
As
Volumtrico
2.5000
--
H2SO4
--
--
--
--
--
Sb
Absorcin Atmica
0.5000
100
HCl-HNO3
--
10% HCl
--
--
Mn
Absorcin Atmica
2.0000
100
HCl-HNO3
--
10% HCl
--
--
Si
Gravimtrico
0.5000
100
HCl-HNO3
--
--
--
--
De acuerdo a peso
Crisol de platino capacidad de 50
con estndar de valor
ml
conocido
Elem ento
Pgina 34 de 110

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Elem ent
Method
Sam ple Mass Volum e capacity

(g)
(m l)
Ni-Co
Fusion - ICP
500
Ag-Cd
Multi-acid digestion - AA
200
Ag-Cd
Multi-acid digestion - AA
200
Cu-Pb
Multi-acid digestion - ICP
2.5
500
Fe-Mn
0.5
500
Zn
Multi-acid digestion - titration
1.25
250
Si
Multi-acid digestion - gravimetry
2.5
500
Masa Muestra
(g)
Volum en de
Aforo (m L)
As-Sb
Acids
(Type and quantity)
Dilution
Factor
Matrix Final Acid

%
Suppressor
Range of calibration
10% HNO3
0 - 50 mg/l
ICP
25% HCl
0 - 6 mg/l
AAS
12.5% HCl
0 - 6 mg/l
AAS
10
10% HNO3
0 - 200 mg/l
ICP
10% HCl
0 - 200 mg/l
ICP
Burette
Balance
10% HCl
0 - 100 mg/l
ICP
Medio cido
Final
Supresor
Rango Calibracin
Equipo
Bureta de 50ml.
Espectrofotmetro de AA Varian
55b, 280 FS/ Agilent 280 FS.
Ultra Micro Balanza y Balanza
analtica.
HNO3 - 15 ml
HCl - 20 ml
HNO3 - 15 ml
HCl - 20 ml
HNO3 1/1 - 30 ml
HCl - 20ml
H2SO4 1/1 - 20 ml
HNO3 - 5ml
HCl - 30ml
H2SO4 - 5ml
HNO3 - 10ml
HCl - 20 ml
H2SO4 1/1 - 5 ml
HNO3 - 20ml
HCl - 20 ml
HF - 10 ml
H2SO4 - 30ml
HCl - 50 ml
Equipm ent
Elem ento
Mtodo
cidos
(Tipo y Cantidad)
Factor
Dilucin
(%)
Zn
Volumtrico
0.25
HCl, HNO3, H2SO4.
Pb
Absorcin Atmica
0.25
100
HCl, HNO3.
10
10% HCl
0 - 20 ppm
Ag
Absorcin Atmica
10.00
HNO3.
15% HNO3 .
Co
Absorcin Atmica
2.00
50
HCl, HNO3, HClO4, HF.
25% HCl
0 - 5 ppm
Cd
Absorcin Atmica
0.25
100
HCl, HNO3.
10% HCl
0 - 10 ppm
Ni
Absorcin Atmica
2.00
50
HCl, HNO3, HClO4, HF.
25% HCl
0 - 2 ppm
Fe
Absorcin Atmica
0.25
HCl, HNO3, H2SO4.
Cu
Absorcin Atmica
0.25
100
HCl, HNO3.
10% HCl
0 - 20 ppm
Bureta de 25ml.
As
Absorcin Atmica
1.00
100
HNO3.
10% HCl
Sol. Ac. Tartrico al

10%
0 - 20 ppm
Sb
Absorcin Atmica
1.00
100
HNO3.
10% HCl
Sol. Ac. Tartrico al

10%
0 - 10 ppm
Mn
Absorcin Atmica
0.25
100
HCl, HNO3.
10% HCl
0 - 20 ppm
SiO2
Absorcin Atmica
1.00
HCl, HNO3, HClO4.
Masa Muestra
(g)
Volum en de
Aforo (m L)
cidos
Factor
Dilucin
Medio cido
Final
Supresor
Rango Calibracin
Equipo
Sin Supresor
30-300 ppm
AA-7000 Marca Shimadzu
Balanza analtica.
Elem ento
Mtodo
(Tipo y Cantidad)
(%)
Pb
Espectrometra de Absorcin
Atmica
0.5
50
Clorhdrico, Ntrico (3:1)
Zn
Volumtrico Complexomtrico
0.2
Aprox 300
No Aplica
No Aplica
Titulacin a pH 5,5
Titulador Universal de mbolo
0.1
100
30
Sin Supresor
0,05-2 ppm
0.1
100
30
Sin Supresor
10-300 ppm
0.1
100
30
Sin Supresor
0,5-3 ppm
Ag
Fe
Cu
Atmica
Atmica
Atmica
Pgina 35 de 110

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Elem ento
ZINC
ZINC
Mtodo
VOLUMTRICO
COMPLEXOMTRICO CON EDTA
VOLUMTRICO
COMPLEXOMTRICO CON EDTA
Masa Muestra
(g)
Volum en de
Aforo (m L)
0,2000 - 0,2020
22,1 - 22,3
0,2000 - 0,2020
23,2 - 23,5
PLATA
ABSORCIN ATOMICA
0,2000 - 0,2020
PLOMO
ABSORCIN ATOMICA
0,2000 - 0,2020
HIERRO
ABSORCIN ATOMICA
0,2000 - 0,2020
cidos
(Tipo y Cantidad)
HCL, HNO3,p.a. y
15ml aprox
HCL, HNO3,p.a. y
10ml aprox
HCL, HNO3,p.a. y
25ml aprox
HCL, HNO3,p.a. y
25ml aprox
HCL, HNO3,p.a. y
25ml aprox
otros,
Factor
Dilucin
Medio cido
Final
Supresor
Rango Calibracin
Equipo
(%)
BALANZA ANALITICA DE 5
DIGITOS , BURETA,ETC.
BALANZA ANALITICA DE 5
DIGITOS , BURETA,ETC.
MUFLA BALANZA ANALITICA DE
6 DIGITOS
6 DIGITOS
6 DIGITOS
EDTA
EDTA
Dilution
Factor
Suppressor
Range of calibration
Equipm ent
(Type and quantity)
Final Acid (%)
otros,
otros,
otros,
otros,
Laboratory Code: IN-RDA02-16-019

Sam ple
Elem ent
Method
Mass (g)
Volum e
Capacity (m L)
cids
Matrix
Zn
fused bead; XRF
0.5
---
---
---
---
---
15-80 %
XRF
Pb
fusion, ICP
0.25
500
50 m l HCl
10 % HCL
---
0-10 %
ICP
Co
Multi-acid digestion HCl, HNO3: ICP
250
25 ml HCl, 25 ml HNO3
---
0-0.5 %
ICP
Cd
250
---
0-0.4 %
ICP
Ni
250
---
0-0.15 %
ICP
Fe
fusion, ICP
0.25
500
50 m l HCl
---
0-10 %
ICP
Cu
250
---
0-1 %
ICP
As
250
---
0-0.5 %
ICP
Sb
250
---
0-0.5 %
ICP
Mn
250
---
0-0.25 %
ICP
Si
fusion, ICP
0.25
500
50 m l HCl
10 % HCL
---
0-10 %
ICP
Masa Muestra
(g)
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
10 % HCL 10 %
HNO3
10 % HCL 10 %
HNO3
10 % HCL 10 %
HNO3
10 % HCL
10 % HCL 10 %
HNO3
10 % HCL 10 %
HNO3
10 % HCL 10 %
HNO3
10 % HCL 10 %
HNO3
Elem ento
Mtodo
Zn
100
Pb
100 y 50
0.20 a 2.00 mg/l
Ag
10 y 5
50.00 a 500.00 ug/l
30.00 a 1000.00 ug/l
Cobre
Cd
Ni
Fe
Cu
Standard Methods 3120B

Inductively Coupled Plasma (ICP)
Method , EPA 3050 B Acid
Digestion of Sediments, sludges
and soils
0.5000 g aprox.
(0.5000 a
0.5006 g)
100 ml
HNO3 conc., ACS,

relacin (1:1), cantidad
10 ml.
HNO3 conc., ACS,
cantidad 10 ml.
HCl conc. ACS, relacin
(1:2), cantidad 15 ml.
0.50 a 5.00 mg/l
50
1
500
10.00 a 500.00 ug/l

pH < 2 unid.
No Aplica
20.00 a 1000.00 ug/l

1.00 a 10.00 mg/l
10 y 2
0.20 a 2.00 mg/l
25
50.00 a 500.00 ug/l
Sb
50.00 a 500.00 ug/l
Mn
5 y 2.5
0.20 a 2.00 mg/l
As
Pgina 36 de 110
ICP-OES, Marca : Perkin Elmer,

Modelo: Optima 2100 DV, No.
Serie: 080N6101501

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Elem ento
Mtodo
Masa Muestra
(g)
Volum en de
Aforo (m l)
cidos
(Tipo y Cantidad
Factor de
Dilucin
Medio cido
Final (%)
Supresor
Rango Calibracin
Equipo
Pb
AAS
0,500
100
HCl y H2S04
10
90
-----
-----
-----
Ag
AAS
0,500
100
HCl y H2S04
0,00
90
-----
-----
-----
Co
AAS
0,500
100
HCl y H2S04
0,00
90
-----
-----
-----
Cd
AAS
0,500
100
HCl y H2S04
25
90
-----
-----
-----
Ni
AAS
0,500
100
HCl y H2S04
0,00
90
-----
-----
-----
Fe
AAS
0,500
100
HCl y H2S04
25
90
-----
-----
-----
Cu
AAS
0,500
100
HCl y H2S04
0,00
90
-----
-----
-----
As
Volumetra
1,00
-----
-----
-----
-----
-----
-----
-----
Sb
Volumetra
0,5
-----
-----
-----
-----
-----
-----
-----
Mn
AAS
0,500
100
HCl y H2S04
0,00
90
-----
-----
-----
Si
AAS
0,500
100
HCl y H2S04
0,00
90
-----
-----
-----
Pgina 37 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
ANEXO N3
TABLAS ESTADSTICAS Y GRFICOS
Pgina 38 de 110

--------------------------------------------------------------------------------------------------------------------------------------------------Material
: Concentrado IN-200
Elemento
: Plata (Ag)
ITERACCION
f = 1,5s*
---
---
15
16
16
16
16
16
x*-f
---
419
417
417
417
417
417
x*+f
---
448
450
450
450
450
450
LAB
Prom lab
IN-RDA01-16-004
275
419
419
419
419
419
419
IN-RDA01-16-007
383
419
419
419
419
419
419
IN-RDA01-16-001
420
420
420
420
420
420
420
IN-RDA01-16-021
422
422
422
422
422
422
422
IN-RDA01-16-015
424
424
424
424
424
424
424
IN-RDA01-16-016
429
429
429
429
429
429
429
IN-RDA01-16-013
430
430
430
430
430
430
430
IN-RDA01-16-012
431
431
431
431
431
431
431
IN-RDA01-16-023
432
432
432
432
432
432
432
IN-RDA01-16-018
433
433
433
433
433
433
433
IN-RDA01-16-010
433
433
433
433
433
433
433
IN-RDA01-16-017
433
433
433
433
433
433
433
IN-RDA01-16-002
436
436
436
436
436
436
436
IN-RDA01-16-014
436
436
436
436
436
436
436
IN-RDA01-16-006
438
438
438
438
438
438
438
IN-RDA01-16-005
442
442
442
442
442
442
442
IN-RDA01-16-003
444
444
444
444
444
444
444
IN-RDA01-16-008
450
448
448
448
448
448
448
IN-RDA01-16-011
452
448
448
448
448
448
448
IN-RDA01-16-022
470
448
448
448
448
448
448
PROMEDIO
426
433
433
433
433
433
433
DS
39
10
10
10
10
10
10
X*
433
433
433
433
433
433
433
S*
10
11
11
11
11
11
11
Pgina 39 de 110
Pgina 40 de 110
Laboratorios
IN-RDA01-16-011
IN-RDA01-16-022
IN-RDA01-16-023
IN-RDA01-16-003
IN-RDA01-16-022
490
470
450
430
410
390
370
350
330
310
290
270
250
230
210
190
170
150
IN-RDA01-16-008
Grfico de valores individuales para Ag en el Ensayo
IN-RDA01-16-021
IN-RDA01-16-018
IN-RDA01-16-005
IN-RDA01-16-006
IN-RDA01-16-014
IN-RDA01-16-002
IN-RDA01-16-017
IN-RDA01-16-010
IN-RDA01-16-018
IN-RDA01-16-023
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-021
IN-RDA01-16-001
IN-RDA01-16-007
IN-RDA01-16-004
490
470
450
430
410
390
370
350
330
310
290
270
250
230
210
190
170
150
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-001
Concentracin (Ag g/T)

--------------------------------------------------------------------------------------------------------------------------------------------------Grfico de Valores Individuales

Intervalo de Valor Asignado Ag 422 - 444 g/T
- - - - - Intervalo valor
asignado

IN-RDA01-16-022
IN-RDA01-16-011
IN-RDA01-16-008
IN-RDA01-16-003
IN-RDA01-16-005
IN-RDA01-16-006
IN-RDA01-16-014
IN-RDA01-16-002
IN-RDA01-16-017
IN-RDA01-16-010
IN-RDA01-16-018
IN-RDA01-16-023
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-016
IN-RDA01-16-021
IN-RDA01-16-001
IN-RDA01-16-007
18.0
16.0
14.0
12.0
10.0
8.0
6.0
4.0
2.0
0.0
-2.0
-4.0
-6.0
-8.0
-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-24.0
-26.0
-28.0
-30.0
-32.0
-34.0
-36.0
-38.0
-40.0
IN-RDA01-16-015
Grfico de Sesgo Relativo Porcentual

Valor asignado: Ag = 433 g/T
IN-RDA01-16-004
Sesgo (g/T)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Laboratorio
Pgina 41 de 110
IN-RDA01-16-022
IN-RDA01-16-011
IN-RDA01-16-008
IN-RDA01-16-003
IN-RDA01-16-005
IN-RDA01-16-006
IN-RDA01-16-014
IN-RDA01-16-002
IN-RDA01-16-017
IN-RDA01-16-010
IN-RDA01-16-018
IN-RDA01-16-023
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-021
IN-RDA01-16-001
IN-RDA01-16-007
6.0
5.0
4.0
3.0
2.0
1.0
0.0
-1.0
-2.0
-3.0
-4.0
-5.0
-6.0
-7.0
-8.0
-9.0
-10.0
-11.0
-12.0
-13.0
-14.0
-15.0
-16.0
-17.0
-18.0
IN-RDA01-16-004
z-score
Grfico de Z-Score
Ag= 433 g/T, = 11

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Arsnico (As)
ITERACCION
f = 1,5s*
---
---
0.011
0.013
0.013
0.013
0.013
0.013
x*-f
---
0.085
0.084
0.084
0.084
0.084
0.084
x*+f
---
0.106
0.109
0.109
0.109
0.109
0.109
LAB
IN-RDA01-16-004
IN-RDA01-16-013
IN-RDA01-16-015
IN-RDA01-16-022
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-007
IN-RDA01-16-008
IN-RDA01-16-006
IN-RDA01-16-019
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-021
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-023
IN-RDA01-16-002
Prom lab
0.081
0.083
0.085
0.091
0.091
0.093
0.094
0.094
0.095
0.095
0.098
0.099
0.100
0.100
0.110
0.110
0.180
0.194
0.085
0.085
0.085
0.091
0.091
0.093
0.094
0.094
0.095
0.095
0.098
0.099
0.100
0.100
0.106
0.106
0.106
0.106
0.085
0.085
0.085
0.091
0.091
0.093
0.094
0.094
0.095
0.095
0.098
0.099
0.100
0.100
0.106
0.106
0.106
0.106
0.085
0.085
0.085
0.091
0.091
0.093
0.094
0.094
0.095
0.095
0.098
0.099
0.100
0.100
0.106
0.106
0.106
0.106
0.085
0.085
0.085
0.091
0.091
0.093
0.094
0.094
0.095
0.095
0.098
0.099
0.100
0.100
0.106
0.106
0.106
0.106
0.085
0.085
0.085
0.091
0.091
0.093
0.094
0.094
0.095
0.095
0.098
0.099
0.100
0.100
0.106
0.106
0.106
0.106
0.085
0.085
0.085
0.091
0.091
0.093
0.094
0.094
0.095
0.095
0.098
0.099
0.100
0.100
0.106
0.106
0.106
0.106
PROMEDIO
DS
X*
S*
0.105
0.031
0.095
0.007
0.096
0.007
0.096
0.008
0.096
0.007
0.096
0.008
0.096
0.007
0.096
0.008
0.096
0.007
0.096
0.008
0.096
0.007
0.096
0.008
0.096
0.007
0.096
0.008
Pgina 42 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
IN-RDA01-16-002
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-021
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-012
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-022
IN-RDA01-16-015
IN-RDA01-16-013
0.260
0.250
0.240
0.230
0.220
0.210
0.200
0.190
0.180
0.170
0.160
0.150
0.140
0.130
0.120
0.110
0.100
0.090
0.080
0.070
IN-RDA01-16-004
Concentracin (%)
Grfico de resultados
Intervalo de Valor Asignado As 0.088 - 0.104 %
Grfico de valores individuales para As en el Ensayo

0.260
0.240
0.200
0.180
0.160
0.140
0.120
0.100
0.080
Laboratorios
Pgina 43 de 110
IN-RDA01-16-023
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-004
IN-RDA01-16-003
0.060
IN-RDA01-16-002
Concentracin (%)
0.220

---------------------------------------------------------------------------------------------------------------------------------------------------
IN-RDA01-16-002
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-021
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-012
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-022
IN-RDA01-16-015
IN-RDA01-16-013
120.0
115.0
110.0
105.0
100.0
95.0
90.0
85.0
80.0
75.0
70.0
65.0
60.0
55.0
50.0
45.0
40.0
35.0
30.0
25.0
20.0
15.0
10.0
5.0
0.0
-5.0
-10.0
-15.0
-20.0
IN-RDA01-16-004
Sesgo (%)

Valor asignado: As = 0.096 %
Laboratorio
Pgina 44 de 110
IN-RDA01-16-002
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-021
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-022
IN-RDA01-16-015
IN-RDA01-16-013
13.00
12.60
12.20
11.80
11.40
11.00
10.60
10.20
9.80
9.40
9.00
8.60
8.20
7.80
7.40
7.00
6.60
6.20
5.80
5.40
5.00
4.60
4.20
3.80
3.40
3.00
2.60
2.20
1.80
1.40
1.00
0.60
0.20
-0.20
-0.60
-1.00
-1.40
-1.80
-2.20
-2.60
-3.00
IN-RDA01-16-012
Grfico de Z-Score
As= 0.096 %, = 0.008
IN-RDA01-16-004
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Cadmio (Cd)
ITERACCION
f = 1,5s*
---
---
0.012
0.014
0.014
0.014
0.014
0.014
x*-f
---
0.203
0.201
0.201
0.201
0.201
0.201
x*+f
---
0.227
0.228
0.228
0.228
0.228
0.228
LAB
Prom lab
IN-RDA01-16-004
0.136
0.203
0.203
0.203
0.203
0.203
0.203
IN-RDA01-16-007
0.194
0.203
0.203
0.203
0.203
0.203
0.203
IN-RDA01-16-013
0.204
0.204
0.204
0.204
0.204
0.204
0.204
IN-RDA01-16-001
0.208
0.208
0.208
0.208
0.208
0.208
0.208
IN-RDA01-16-012
0.209
0.209
0.209
0.209
0.209
0.209
0.209
IN-RDA01-16-022
0.209
0.209
0.209
0.209
0.209
0.209
0.209
IN-RDA01-16-005
0.210
0.210
0.210
0.210
0.210
0.210
0.210
IN-RDA01-16-014
0.212
0.212
0.212
0.212
0.212
0.212
0.212
IN-RDA01-16-021
0.212
0.212
0.212
0.212
0.212
0.212
0.212
IN-RDA01-16-008
0.215
0.215
0.215
0.215
0.215
0.215
0.215
IN-RDA01-16-002
0.215
0.215
0.215
0.215
0.215
0.215
0.215
IN-RDA01-16-009
0.216
0.216
0.216
0.216
0.216
0.216
0.216
IN-RDA01-16-003
0.216
0.216
0.216
0.216
0.216
0.216
0.216
IN-RDA01-16-016
0.219
0.219
0.219
0.219
0.219
0.219
0.219
IN-RDA01-16-019
0.220
0.220
0.220
0.220
0.220
0.220
0.220
IN-RDA01-16-015
0.220
0.220
0.220
0.220
0.220
0.220
0.220
IN-RDA01-16-006
0.226
0.226
0.226
0.226
0.226
0.226
0.226
IN-RDA01-16-010
0.228
0.227
0.227
0.227
0.227
0.227
0.227
IN-RDA01-16-011
0.232
0.227
0.227
0.227
0.227
0.227
0.227
IN-RDA01-16-023
0.251
0.227
0.227
0.227
0.227
0.227
0.227
PROMEDIO
0.213
0.215
0.215
0.215
0.215
0.215
0.215
DS
0.022
0.008
0.008
0.008
0.008
0.008
0.008
X*
0.215
0.215
0.215
0.215
0.215
0.215
0.215
S*
0.008
0.009
0.009
0.009
0.009
0.009
0.009
Pgina 45 de 110
Laboratorios
Pgina 46 de 110
0.250
0.240
0.230
0.220
0.210
0.200
0.190
0.180
IN-RDA01-16-010
IN-RDA01-16-006
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-023
0.260
IN-RDA01-16-023
0.270
IN-RDA01-16-011
Grfico de valores individuales para Cd en el Ensayo
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-009
IN-RDA01-16-002
IN-RDA01-16-008
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-005
IN-RDA01-16-022
IN-RDA01-16-012
IN-RDA01-16-001
IN-RDA01-16-013
IN-RDA01-16-007
IN-RDA01-16-004
0.180
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-001
Concentracin (Cd %)

---------------------------------------------------------------------------------------------------------------------------------------------------
Grfico de Valores Individuales

Intervalo de Valor Asignado Cd 0.206 - 0.224 %
0.270
0.260
0.250
0.240
0.230
0.220
0.210
0.200
0.190
- - - - - Intervalo valor asignado

---------------------------------------------------------------------------------------------------------------------------------------------------
IN-RDA01-16-023
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-006
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-009
IN-RDA01-16-002
IN-RDA01-16-008
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-005
IN-RDA01-16-022
IN-RDA01-16-012
IN-RDA01-16-001
IN-RDA01-16-013
IN-RDA01-16-007
18.0
16.0
14.0
12.0
10.0
8.0
6.0
4.0
2.0
0.0
-2.0
-4.0
-6.0
-8.0
-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-24.0
-26.0
-28.0
-30.0
-32.0
-34.0
-36.0
-38.0
-40.0
IN-RDA01-16-004
Sesgo (%)

Valor asignado: Cd = 0.215 %
Laboratorio
Pgina 47 de 110
IN-RDA01-16-023
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-006
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-009
IN-RDA01-16-002
IN-RDA01-16-008
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-022
IN-RDA01-16-012
IN-RDA01-16-001
IN-RDA01-16-013
IN-RDA01-16-007
6.0
5.0
4.0
3.0
2.0
1.0
0.0
-1.0
-2.0
-3.0
-4.0
-5.0
-6.0
-7.0
-8.0
-9.0
-10.0
IN-RDA01-16-005
Grfico de Z-Score
Cd= 0.215 %, = 0.009
IN-RDA01-16-004
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Cobalto (Co)
ITERACCION
f = 1,5s*
---
---
x*-f
---
x*+f
---
13
13
13
13
13
13
LAB
Prom lab
IN-RDA01-16-014
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-011
10
10
10
10
10
10
10
IN-RDA01-16-012
10
10
10
10
10
10
10
IN-RDA01-16-007
11
11
11
11
11
11
11
IN-RDA01-16-003
11
11
11
11
11
11
11
IN-RDA01-16-015
11
11
11
11
11
11
11
IN-RDA01-16-019
11
11
11
11
11
11
11
IN-RDA01-16-023
58
13
13
13
13
13
13
IN-RDA01-16-013
83
13
13
13
13
13
13
PROMEDIO
21
10
10
10
10
10
10
DS
25
X*
11
10
10
10
10
10
10
S*
Pgina 48 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Co 8 - 12 g/T
91
81
71
61
51
41
31
21
11
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-021
IN-RDA01-16-014
Laboratorios
Pgina 49 de 110
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-007
101
91
81
71
61
51
41
31
21
11
1
IN-RDA01-16-003
Concentracin (Co g/T)
Grfico de valores individuales para Co en el Ensayo

---------------------------------------------------------------------------------------------------------------------------------------------------
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-021
660.00
610.00
560.00
510.00
460.00
410.00
360.00
310.00
260.00
210.00
160.00
110.00
60.00
10.00
-40.00
IN-RDA01-16-014
Sesgo (%)

Valor asignado: Co = 10 g/T
Laboratorio
Grfico de Z-Score
Co= 10 g/T, = 2
38.0
33.0
23.0
18.0
13.0
8.0
3.0
Laboratorio
Pgina 50 de 110
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-021
-2.0
IN-RDA01-16-014
z-score
28.0

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Cobre (Cu)
ITERACCION
f = 1,5s*
---
---
0.019
0.020
0.020
0.020
0.020
0.020
x*-f
---
0.193
0.191
0.191
0.191
0.191
0.191
x*+f
---
0.232
0.231
0.231
0.231
0.231
0.231
LAB
Prom lab
IN-RDA01-16-004
0.148
0.193
0.193
0.193
0.193
0.193
0.193
IN-RDA01-16-015
0.177
0.193
0.193
0.193
0.193
0.193
0.193
IN-RDA01-16-023
0.194
0.194
0.194
0.194
0.194
0.194
0.194
IN-RDA01-16-021
0.195
0.195
0.195
0.195
0.195
0.195
0.195
IN-RDA01-16-016
0.200
0.200
0.200
0.200
0.200
0.200
0.200
IN-RDA01-16-008
0.201
0.201
0.201
0.201
0.201
0.201
0.201
IN-RDA01-16-014
0.202
0.202
0.202
0.202
0.202
0.202
0.202
IN-RDA01-16-012
0.209
0.209
0.209
0.209
0.209
0.209
0.209
IN-RDA01-16-003
0.210
0.210
0.210
0.210
0.210
0.210
0.210
IN-RDA01-16-007
0.212
0.212
0.212
0.212
0.212
0.212
0.212
IN-RDA01-16-009
0.213
0.213
0.213
0.213
0.213
0.213
0.213
IN-RDA01-16-011
0.215
0.215
0.215
0.215
0.215
0.215
0.215
IN-RDA01-16-005
0.216
0.216
0.216
0.216
0.216
0.216
0.216
IN-RDA01-16-022
0.217
0.217
0.217
0.217
0.217
0.217
0.217
IN-RDA01-16-010
0.218
0.218
0.218
0.218
0.218
0.218
0.218
IN-RDA01-16-006
0.219
0.219
0.219
0.219
0.219
0.219
0.219
IN-RDA01-16-019
0.220
0.220
0.220
0.220
0.220
0.220
0.220
IN-RDA01-16-013
0.221
0.221
0.221
0.221
0.221
0.221
0.221
IN-RDA01-16-001
0.224
0.224
0.224
0.224
0.224
0.224
0.224
IN-RDA01-16-002
0.228
0.228
0.228
0.228
0.228
0.228
0.228
IN-RDA01-16-017
0.242
0.232
0.231
0.231
0.231
0.231
0.231
PROMEDIO
0.208
0.211
0.211
0.211
0.211
0.211
0.211
DS
0.020
0.012
0.012
0.012
0.012
0.012
0.012
X*
0.213
0.211
0.211
0.211
0.211
0.211
0.211
S*
0.013
0.013
0.013
0.013
0.013
0.013
0.013
Pgina 51 de 110
Laboratorios
Pgina 52 de 110
0.210
0.200
0.190
0.180
0.170
0.160
0.150
0.140
0.130
IN-RDA01-16-013
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-010
IN-RDA01-16-022
IN-RDA01-16-017
0.220
IN-RDA01-16-023
0.230
IN-RDA01-16-002
0.240
IN-RDA01-16-022
0.250
IN-RDA01-16-001
Grfico de valores individuales para Cu en el Ensayo
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-005
0.130
IN-RDA01-16-013
IN-RDA01-16-011
IN-RDA01-16-009
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-014
IN-RDA01-16-008
IN-RDA01-16-016
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-015
IN-RDA01-16-004
0.140
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-001
Concentracin (Cu %)

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Cu 0.198 - 0.224 %
0.250
0.240
0.230
0.220
0.210
0.200
0.190
0.180
0.170
0.160
0.150
Laboratorio
Pgina 53 de 110
IN-RDA01-16-017
IN-RDA01-16-002
IN-RDA01-16-001
IN-RDA01-16-013
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-010
IN-RDA01-16-022
IN-RDA01-16-005
IN-RDA01-16-011
IN-RDA01-16-009
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-012
3.0
2.5
2.0
1.5
1.0
0.5
0.0
-0.5
-1.0
-1.5
-2.0
-2.5
-3.0
-3.5
-4.0
-4.5
-5.0
-5.5
IN-RDA01-16-014
IN-RDA01-16-008
IN-RDA01-16-016
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-015
IN-RDA01-16-004
z-score
IN-RDA01-16-017
IN-RDA01-16-002
IN-RDA01-16-001
IN-RDA01-16-013
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-010
IN-RDA01-16-022
IN-RDA01-16-005
IN-RDA01-16-011
IN-RDA01-16-009
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-014
IN-RDA01-16-008
IN-RDA01-16-016
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-015
IN-RDA01-16-004
Sesgo (%)

---------------------------------------------------------------------------------------------------------------------------------------------------

Valor asignado: Cu = 0.211 %
13.0
9.0
5.0
-3.0
1.0
-11.0
-7.0
-15.0
-19.0
-23.0
-27.0
-31.0
-35.0
Laboratorio
Grfico de Z-Score
Cu= 0.211 %, = 0.013

--------------------------------------------------------------------------------------------------------------------------------------------------Material
Elemento
: Hierro (Fe)
ITERACCION
f = 1,5s*
---
---
0.12
0.14
0.14
0.14
0.14
0.14
x*-f
---
4.16
4.13
4.13
4.13
4.13
4.13
x*+f
---
4.40
4.42
4.42
4.42
4.42
4.42
LAB
Prom lab
IN-RDA01-16-023
0.15
4.16
4.16
4.16
4.16
4.16
4.16
IN-RDA01-16-004
2.41
4.16
4.16
4.16
4.16
4.16
4.16
IN-RDA01-16-014
3.71
4.16
4.16
4.16
4.16
4.16
4.16
IN-RDA01-16-021
3.81
4.16
4.16
4.16
4.16
4.16
4.16
IN-RDA01-16-003
4.03
4.16
4.16
4.16
4.16
4.16
4.16
IN-RDA01-16-022
4.19
4.19
4.19
4.19
4.19
4.19
4.19
IN-RDA01-16-006
4.24
4.24
4.24
4.24
4.24
4.24
4.24
IN-RDA01-16-008
4.26
4.26
4.26
4.26
4.26
4.26
4.26
IN-RDA01-16-019
4.26
4.26
4.26
4.26
4.26
4.26
4.26
IN-RDA01-16-009
4.26
4.26
4.26
4.26
4.26
4.26
4.26
IN-RDA01-16-012
4.28
4.28
4.28
4.28
4.28
4.28
4.28
IN-RDA01-16-015
4.29
4.29
4.29
4.29
4.29
4.29
4.29
IN-RDA01-16-002
4.30
4.30
4.30
4.30
4.30
4.30
4.30
IN-RDA01-16-010
4.30
4.30
4.30
4.30
4.30
4.30
4.30
IN-RDA01-16-001
4.31
4.31
4.31
4.31
4.31
4.31
4.31
IN-RDA01-16-007
4.32
4.32
4.32
4.32
4.32
4.32
4.32
IN-RDA01-16-017
4.33
4.33
4.33
4.33
4.33
4.33
4.33
IN-RDA01-16-016
4.34
4.34
4.34
4.34
4.34
4.34
4.34
IN-RDA01-16-005
4.38
4.38
4.38
4.38
4.38
4.38
4.38
IN-RDA01-16-018
4.45
4.40
4.40
4.40
4.40
4.40
4.40
IN-RDA01-16-011
4.67
4.40
4.40
4.40
4.40
4.40
4.40
IN-RDA01-16-013
5.42
4.40
4.40
4.40
4.40
4.40
4.40
PROMEDIO
4.03
4.28
4.28
4.28
4.28
4.28
4.28
DS
1.01
0.08
0.08
0.08
0.08
0.08
0.08
X*
4.28
4.28
4.28
4.28
4.28
4.28
4.28
S*
0.08
0.09
0.09
0.09
0.09
0.09
0.09
Pgina 54 de 110
Laboratorios
Pgina 55 de 110
IN-RDA01-16-011
IN-RDA01-16-022
IN-RDA01-16-013
IN-RDA01-16-018
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-005
IN-RDA01-16-017
IN-RDA01-16-007
IN-RDA01-16-001
IN-RDA01-16-010
IN-RDA01-16-019
6.45
6.05
5.65
5.25
4.85
4.45
4.05
3.65
3.25
2.85
2.45
2.05
1.65
1.25
0.85
0.45
0.05
IN-RDA01-16-016
Grfico de valores individuales para Fe en el Ensayo
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-002
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-019
IN-RDA01-16-008
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-004
IN-RDA01-16-023
5.65
5.25
4.85
4.45
4.05
3.65
3.25
2.85
2.45
2.05
1.65
1.25
0.85
0.45
0.05
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-001
Concentracin ( Fe %)


Intervalo de Valor Asignado Fe 4.19 - 4.37 %

--------------------------------------------------------------------------------------------------------------------------------------------------Grfico de Sesgo Relativo Porcentual

Valor asignado: Fe = 4.28 %
IN-RDA01-16-013
IN-RDA01-16-011
IN-RDA01-16-018
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-007
IN-RDA01-16-016
IN-RDA01-16-001
IN-RDA01-16-001
IN-RDA01-16-017
IN-RDA01-16-010
IN-RDA01-16-010
IN-RDA01-16-002
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-019
IN-RDA01-16-008
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-004
IN-RDA01-16-023
Sesgo (%)
30.0
25.0
20.0
15.0
10.0
5.0
0.0
-5.0
-10.0
-15.0
-20.0
-25.0
-30.0
-35.0
-40.0
-45.0
-50.0
-55.0
-60.0
-65.0
-70.0
-75.0
-80.0
-85.0
-90.0
-95.0
-100.0
Laboratorio
Pgina 56 de 110
IN-RDA01-16-013
IN-RDA01-16-011
IN-RDA01-16-018
IN-RDA01-16-005
IN-RDA01-16-016
IN-RDA01-16-017
IN-RDA01-16-002
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-004
14.0
12.0
10.0
8.0
6.0
4.0
2.0
0.0
-2.0
-4.0
-6.0
-8.0
-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-24.0
-26.0
-28.0
-30.0
-32.0
-34.0
-36.0
-38.0
-40.0
-42.0
-44.0
-46.0
IN-RDA01-16-008
Grfico de Z-Score
Fe= 4.28 %, = 0.09
IN-RDA01-16-023
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Manganeso (Mn)
ITERACCION
f = 1,5s*
---
---
0.016
0.017
0.017
0.017
0.017
0.017
x*-f
---
0.075
0.072
0.072
0.072
0.072
0.072
x*+f
---
0.107
0.105
0.105
0.105
0.105
0.105
LAB
IN-RDA01-16-011
IN-RDA01-16-014
IN-RDA01-16-004
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-003
IN-RDA01-16-013
IN-RDA01-16-007
IN-RDA01-16-001
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-019
IN-RDA01-16-008
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-010
Prom lab
0.051
0.057
0.060
0.068
0.080
0.082
0.088
0.090
0.091
0.094
0.095
0.095
0.096
0.097
0.098
0.100
0.102
0.075
0.075
0.075
0.075
0.080
0.082
0.088
0.090
0.091
0.094
0.095
0.095
0.096
0.097
0.098
0.100
0.102
0.075
0.075
0.075
0.075
0.080
0.082
0.088
0.090
0.091
0.094
0.095
0.095
0.096
0.097
0.098
0.100
0.102
0.075
0.075
0.075
0.075
0.080
0.082
0.088
0.090
0.091
0.094
0.095
0.095
0.096
0.097
0.098
0.100
0.102
0.075
0.075
0.075
0.075
0.080
0.082
0.088
0.090
0.091
0.094
0.095
0.095
0.096
0.097
0.098
0.100
0.102
0.075
0.075
0.075
0.075
0.080
0.082
0.088
0.090
0.091
0.094
0.095
0.095
0.096
0.097
0.098
0.100
0.102
0.075
0.075
0.075
0.075
0.080
0.082
0.088
0.090
0.091
0.094
0.095
0.095
0.096
0.097
0.098
0.100
0.102
PROMEDIO
DS
X*
S*
0.085
0.016
0.091
0.011
0.089
0.010
0.089
0.011
0.089
0.010
0.089
0.011
0.089
0.010
0.089
0.011
0.089
0.010
0.089
0.011
0.089
0.010
0.089
0.011
0.089
0.010
0.089
0.011
Pgina 57 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Mn 0.078 - 0.100 %
0.120
0.115
0.110
0.105
0.100
0.095
0.090
0.085
0.080
0.075
0.070
0.065
0.060
0.055
0.050
0.045
0.040
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-010
IN-RDA01-16-008
IN-RDA01-16-019
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-001
IN-RDA01-16-007
IN-RDA01-16-013
IN-RDA01-16-003
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-004
IN-RDA01-16-014
IN-RDA01-16-011
Laboratorios
Pgina 58 de 110
IN-RDA01-16-023
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-004
IN-RDA01-16-003
0.120
0.115
0.110
0.105
0.100
0.095
0.090
0.085
0.080
0.075
0.070
0.065
0.060
0.055
0.050
0.045
0.040
IN-RDA01-16-001
Concentracin (%)
Grfico de valores individuales para Mn en el Ensayo

IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-012
IN-RDA01-16-008
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-001
IN-RDA01-16-007
IN-RDA01-16-013
IN-RDA01-16-003
IN-RDA01-16-023
IN-RDA01-16-022
IN-RDA01-16-004
IN-RDA01-16-014
20.00
18.00
16.00
14.00
12.00
10.00
8.00
6.00
4.00
2.00
0.00
-2.00
-4.00
-6.00
-8.00
-10.00
-12.00
-14.00
-16.00
-18.00
-20.00
-22.00
-24.00
-26.00
-28.00
-30.00
-32.00
-34.00
-36.00
-38.00
-40.00
-42.00
-44.00
-46.00
-48.00
-50.00
IN-RDA01-16-021

Valor asignado: Mn = 0.089 %
IN-RDA01-16-011
Sesgo (%)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Pgina 59 de 110
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-012
IN-RDA01-16-008
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-001
IN-RDA01-16-007
IN-RDA01-16-013
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-004
IN-RDA01-16-014
1.40
1.20
1.00
0.80
0.60
0.40
0.20
0.00
-0.20
-0.40
-0.60
-0.80
-1.00
-1.20
-1.40
-1.60
-1.80
-2.00
-2.20
-2.40
-2.60
-2.80
-3.00
-3.20
-3.40
-3.60
-3.80
-4.00
IN-RDA01-16-023
Grfico de Z-Score
Mn= 0.089 %, = 0.011
IN-RDA01-16-011
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Nquel (Ni)
ITERACCION
f = 1,5s*
---
---
x*-f
---
x*+f
---
16
18
18
18
18
18
LAB
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-007
IN-RDA01-16-021
IN-RDA01-16-003
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-023
IN-RDA01-16-004
IN-RDA01-16-013
Prom lab
4
4
6
7
7
8
8
11
16
20
35
38
4
4
6
7
7
8
8
11
16
16
16
16
4
4
6
7
7
8
8
11
16
16
16
16
4
4
6
7
7
8
8
11
16
16
16
16
4
4
6
7
7
8
8
11
16
16
16
16
4
4
6
7
7
8
8
11
16
16
16
16
4
4
6
7
7
8
8
11
16
16
16
16
PROMEDIO
DS
X*
S*
14
12
8
5
10
5
10
5
10
5
10
5
10
5
10
5
10
5
10
5
10
5
10
5
10
5
10
5
Pgina 60 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
Intervalo de Valor Asignado Ni 5 - 15 g/T
46
41
36
31
26
21
16
11
6
IN-RDA01-16-004
IN-RDA01-16-013
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-010
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-007
IN-RDA01-16-011
IN-RDA01-16-012
Laboratorios
Pgina 61 de 110
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-007
IN-RDA01-16-004
57
53
49
45
41
37
33
29
25
21
17
13
9
5
1
IN-RDA01-16-003
Concentracin (g/T)
Grfico de valores individuales para Ni

en el Ensayo

IN-RDA01-16-013
IN-RDA01-16-004
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-010
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-011
300.0
280.0
260.0
240.0
220.0
200.0
180.0
160.0
140.0
120.0
100.0
80.0
60.0
40.0
20.0
0.0
-20.0
-40.0
-60.0
-80.0
-100.0
IN-RDA01-16-021

Valor asignado: Ni = 10 g/T
IN-RDA01-16-012
Sesgo (%)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Laboratorio
Pgina 62 de 110
IN-RDA01-16-013
IN-RDA01-16-004
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-010
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-007
IN-RDA01-16-011
11.50
10.50
9.50
8.50
7.50
6.50
5.50
4.50
3.50
2.50
1.50
0.50
-0.50
-1.50
IN-RDA01-16-012
z-score

Ni= 10 g/T, = 5

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Plomo (Pb)
ITERACCION
f = 1,5s*
---
---
0.15
0.16
0.16
0.16
0.16
0.16
x*-f
---
2.85
2.82
2.82
2.82
2.82
2.82
x*+f
---
3.15
3.14
3.14
3.14
3.14
3.14
LAB
Prom lab
IN-RDA01-16-004
1.65
2.85
2.85
2.85
2.85
2.85
2.85
IN-RDA01-16-021
2.48
2.85
2.85
2.85
2.85
2.85
2.85
IN-RDA01-16-022
2.74
2.85
2.85
2.85
2.85
2.85
2.85
IN-RDA01-16-014
2.79
2.85
2.85
2.85
2.85
2.85
2.85
IN-RDA01-16-007
2.84
2.85
2.85
2.85
2.85
2.85
2.85
IN-RDA01-16-006
2.91
2.91
2.91
2.91
2.91
2.91
2.91
IN-RDA01-16-016
2.94
2.94
2.94
2.94
2.94
2.94
2.94
IN-RDA01-16-003
2.96
2.96
2.96
2.96
2.96
2.96
2.96
IN-RDA01-16-018
2.98
2.98
2.98
2.98
2.98
2.98
2.98
IN-RDA01-16-019
2.99
2.99
2.99
2.99
2.99
2.99
2.99
IN-RDA01-16-017
3.00
3.00
3.00
3.00
3.00
3.00
3.00
IN-RDA01-16-002
3.02
3.02
3.02
3.02
3.02
3.02
3.02
IN-RDA01-16-001
3.04
3.04
3.04
3.04
3.04
3.04
3.04
IN-RDA01-16-005
3.04
3.04
3.04
3.04
3.04
3.04
3.04
IN-RDA01-16-012
3.04
3.04
3.04
3.04
3.04
3.04
3.04
IN-RDA01-16-013
3.05
3.05
3.05
3.05
3.05
3.05
3.05
IN-RDA01-16-008
3.07
3.07
3.07
3.07
3.07
3.07
3.07
IN-RDA01-16-009
3.07
3.07
3.07
3.07
3.07
3.07
3.07
IN-RDA01-16-015
3.08
3.08
3.08
3.08
3.08
3.08
3.08
IN-RDA01-16-023
3.09
3.09
3.09
3.09
3.09
3.09
3.09
IN-RDA01-16-011
3.25
3.15
3.15
3.15
3.15
3.15
3.15
PROMEDIO
2.90
2.98
2.98
2.98
2.98
2.98
2.98
DS
0.33
0.09
0.09
0.09
0.09
0.09
0.09
X*
3.00
2.98
2.98
2.98
2.98
2.98
2.98
S*
0.10
0.11
0.11
0.11
0.11
0.11
0.11
Pgina 63 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Pb 2.87 - 3.09 %
3.40
3.30
3.20
3.10
3.00
2.90
2.80
2.70
2.60
2.50
2.40
2.30
2.20
2.10
2.00
1.90
1.80
1.70
1.60
1.50
1.40
IN-RDA01-16-015
IN-RDA01-16-023
IN-RDA01-16-011
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-023
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-005
IN-RDA01-16-001
IN-RDA01-16-002
IN-RDA01-16-017
IN-RDA01-16-019
IN-RDA01-16-018
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-006
IN-RDA01-16-007
IN-RDA01-16-014
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-004
Laboratorios
Pgina 64 de 110
IN-RDA01-16-019
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
3.40
3.30
3.20
3.10
3.00
2.90
2.80
2.70
2.60
2.50
2.40
2.30
2.20
2.10
2.00
1.90
1.80
1.70
1.60
1.50
1.40
IN-RDA01-16-001
Concentracin ( Pb %)
Grfico de valores individuales para Pb en el Ensayo

---------------------------------------------------------------------------------------------------------------------------------------------------

Valor asignado: Pb = 2.98 %
13.0
9.0
5.0
Sesgo ( % )
1.0
-3.0
-7.0
-11.0
-15.0
-19.0
-23.0
-27.0
-31.0
IN-RDA01-16-011
IN-RDA01-16-023
IN-RDA01-16-015
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-013
IN-RDA01-16-005
IN-RDA01-16-005
IN-RDA01-16-012
IN-RDA01-16-001
IN-RDA01-16-001
IN-RDA01-16-002
IN-RDA01-16-017
IN-RDA01-16-019
IN-RDA01-16-018
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-006
IN-RDA01-16-007
IN-RDA01-16-014
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-004
-35.0
Laboratorio
Pgina 65 de 110
IN-RDA01-16-011
IN-RDA01-16-023
IN-RDA01-16-015
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-002
IN-RDA01-16-017
IN-RDA01-16-019
IN-RDA01-16-018
IN-RDA01-16-016
IN-RDA01-16-006
IN-RDA01-16-007
IN-RDA01-16-014
IN-RDA01-16-022
IN-RDA01-16-021
3.0
2.5
2.0
1.5
1.0
0.5
0.0
-0.5
-1.0
-1.5
-2.0
-2.5
-3.0
-3.5
-4.0
-4.5
-5.0
-5.5
-6.0
-6.5
-7.0
-7.5
-8.0
-8.5
-9.0
-9.5
-10.0
-10.5
-11.0
-11.5
-12.0
-12.5
-13.0
-13.5
-14.0
-14.5
-15.0
IN-RDA01-16-003
Grfico de Z-Score
Pb= 2.98 %, = 0.11
IN-RDA01-16-004
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: xido de Silicio (SiO2)
ITERACCION
---
f = 1,5s*
---
0.481
0.594
0.594
0.594
0.594
0.594
x*-f
---
3.658
3.558
3.558
3.558
3.558
3.558
x*+f
---
4.620
4.746
4.746
4.746
4.746
4.746
LAB
IN-RDA01-16-023
IN-RDA01-16-013
IN-RDA01-16-014
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-022
IN-RDA01-16-008
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-011
IN-RDA01-16-004
IN-RDA01-16-007
Prom lab
0.402
2.213
3.730
3.990
3.998
4.023
4.139
4.278
4.285
4.355
4.815
4.953
5.200
3.658
3.658
3.730
3.990
3.998
4.023
4.139
4.278
4.285
4.355
4.620
4.620
4.620
3.658
3.658
3.730
3.990
3.998
4.023
4.139
4.278
4.285
4.355
4.620
4.620
4.620
3.658
3.658
3.730
3.990
3.998
4.023
4.139
4.278
4.285
4.355
4.620
4.620
4.620
3.658
3.658
3.730
3.990
3.998
4.023
4.139
4.278
4.285
4.355
4.620
4.620
4.620
3.658
3.658
3.730
3.990
3.998
4.023
4.139
4.278
4.285
4.355
4.620
4.620
4.620
3.658
3.658
3.730
3.990
3.998
4.023
4.139
4.278
4.285
4.355
4.620
4.620
4.620
PROMEDIO
DS
X*
S*
3.88
1.27
4.14
0.32
4.15
0.35
4.15
0.40
4.15
0.35
4.15
0.40
4.15
0.35
4.15
0.40
4.15
0.35
4.15
0.40
4.15
0.35
4.15
0.40
4.15
0.35
4.15
0.40
Pgina 66 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
5.80
5.40
5.00
4.60
4.20
3.80
3.40
3.00
2.60
2.20
1.80
1.40
1.00
0.60
0.20
IN-RDA01-16-007
IN-RDA01-16-004
IN-RDA01-16-011
IN-RDA01-16-015
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-022
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-019
IN-RDA01-16-014
IN-RDA01-16-013

IN-RDA01-16-023
Concentracin (%)

Intervalo de Valor Asignado SiO2 3.75 - 4.55 %
Laboratorios
Pgina 67 de 110
IN-RDA01-16-023
IN-RDA01-16-022
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-011
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-004
5.70
5.50
5.30
5.10
4.90
4.70
4.50
4.30
4.10
3.90
3.70
3.50
3.30
3.10
2.90
2.70
2.50
2.30
2.10
1.90
1.70
1.50
1.30
1.10
0.90
0.70
0.50
0.30
0.10
IN-RDA01-16-003
Concentracin (%)
Grfico de valores individuales para SiO2 en el Ensayo

IN-RDA01-16-007
IN-RDA01-16-004
IN-RDA01-16-011
IN-RDA01-16-015
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-022
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-014
IN-RDA01-16-013
40.0
30.0
20.0
10.0
0.0
-10.0
-20.0
-30.0
-40.0
-50.0
-60.0
-70.0
-80.0
-90.0
-100.0
IN-RDA01-16-019

Valor asignado: SiO2 = 4.15 %
IN-RDA01-16-023
Sesgo (%)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Laboratorio
Pgina 68 de 110
IN-RDA01-16-007
IN-RDA01-16-004
IN-RDA01-16-011
IN-RDA01-16-015
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-022
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-019
IN-RDA01-16-014
IN-RDA01-16-013
4.00
3.50
3.00
2.50
2.00
1.50
1.00
0.50
0.00
-0.50
-1.00
-1.50
-2.00
-2.50
-3.00
-3.50
-4.00
-4.50
-5.00
-5.50
-6.00
-6.50
-7.00
-7.50
-8.00
-8.50
-9.00
-9.50
-10.00
IN-RDA01-16-023
z-score
Grfico de Z-Score
Si= 4.15 %, = 0.40

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Antimonio (Sb)
ITERACCION
f = 1,5s*
---
---
105
116
116
116
116
116
x*-f
---
282
274
274
274
274
274
x*+f
---
492
506
506
506
506
506
LAB
IN-RDA01-16-007
IN-RDA01-16-015
IN-RDA01-16-021
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-002
IN-RDA01-16-012
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-011
IN-RDA01-16-019
IN-RDA01-16-022
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-010
IN-RDA01-16-013
IN-RDA01-16-023
Prom lab
146
302
320
340
342
350
350
353
387
398
405
413
443
470
489
583
6650
282
302
320
340
342
350
350
353
387
398
405
413
443
470
492
492
492
282
302
320
340
342
350
350
353
387
398
405
413
443
470
492
492
492
282
302
320
340
342
350
350
353
387
398
405
413
443
470
492
492
492
282
302
320
340
342
350
350
353
387
398
405
413
443
470
492
492
492
282
302
320
340
342
350
350
353
387
398
405
413
443
470
492
492
492
282
302
320
340
342
350
350
353
387
398
405
413
443
470
492
492
492
PROMEDIO
DS
X*
S*
749
1523
387
70
390
68
390
77
390
68
390
77
390
68
390
77
390
68
390
77
390
68
390
77
390
68
390
77
Pgina 69 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Sb 313 - 467 gT
8850
8450
8050
7650
7250
6850
6450
6050
5650
5250
4850
4450
4050
3650
3250
2850
2450
2050
1650
1250
850
450
50
IN-RDA01-16010
IN-RDA01-16013
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16023
IN-RDA01-16014
IN-RDA01-16-019
IN-RDA01-16009
IN-RDA01-16022
IN-RDA01-16019
IN-RDA01-16011
IN-RDA01-16008
IN-RDA01-16006
IN-RDA01-16012
IN-RDA01-16002
IN-RDA01-16016
IN-RDA01-16003
IN-RDA01-16021
IN-RDA01-16015
IN-RDA01-16007
Laboratorios
Pgina 70 de 110
IN-RDA01-16-023
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-003
8850
8450
8050
7650
7250
6850
6450
6050
5650
5250
4850
4450
4050
3650
3250
2850
2450
2050
1650
1250
850
450
50
IN-RDA01-16-002
Concentracin (g/T)
Grfico de valores individuales para Sb en el Ensayo

---------------------------------------------------------------------------------------------------------------------------------------------------
IN-RDA01-16-023
IN-RDA01-16-013
IN-RDA01-16-010
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-022
IN-RDA01-16-019
IN-RDA01-16-011
IN-RDA01-16-008
IN-RDA01-16-006
IN-RDA01-16-012
IN-RDA01-16-002
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-015
2000.0
1900.0
1800.0
1700.0
1600.0
1500.0
1400.0
1300.0
1200.0
1100.0
1000.0
900.0
800.0
700.0
600.0
500.0
400.0
300.0
200.0
100.0
0.0
-100.0
IN-RDA01-16-007
Sesgo (%)

Valor asignado: Sb = 390 g/T
Laboratorio
Pgina 71 de 110
IN-RDA01-16-023
IN-RDA01-16-013
IN-RDA01-16-010
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-022
IN-RDA01-16-019
IN-RDA01-16-011
IN-RDA01-16-008
IN-RDA01-16-006
IN-RDA01-16-002
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-015
99.0
94.0
89.0
84.0
79.0
74.0
69.0
64.0
59.0
54.0
49.0
44.0
39.0
34.0
29.0
24.0
19.0
14.0
9.0
4.0
-1.0
IN-RDA01-16-012
Grfico de Z-Score
Sb= 390 g/T, = 77
IN-RDA01-16-007
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Zinc (Zn)
ITERACCION
f = 1,5s*
---
---
0.32
0.40
0.40
0.40
0.40
0.40
x*-f
---
53.81
53.73
53.73
53.73
53.73
53.73
x*+f
---
54.45
54.52
54.52
54.52
54.52
54.52
LAB
Prom lab
IN-RDA01-16-004
40.04
53.81
53.81
53.81
53.81
53.81
53.81
IN-RDA01-16-021
43.65
53.81
53.81
53.81
53.81
53.81
53.81
IN-RDA01-16-007
47.50
53.81
53.81
53.81
53.81
53.81
53.81
IN-RDA01-16-005
53.63
53.81
53.81
53.81
53.81
53.81
53.81
IN-RDA01-16-014
53.71
53.81
53.81
53.81
53.81
53.81
53.81
IN-RDA01-16-023
53.99
53.99
53.99
53.99
53.99
53.99
53.99
IN-RDA01-16-003
54.01
54.01
54.01
54.01
54.01
54.01
54.01
IN-RDA01-16-008
54.02
54.02
54.02
54.02
54.02
54.02
54.02
IN-RDA01-16-015
54.06
54.06
54.06
54.06
54.06
54.06
54.06
IN-RDA01-16-009
54.09
54.09
54.09
54.09
54.09
54.09
54.09
IN-RDA01-16-002
54.13
54.13
54.13
54.13
54.13
54.13
54.13
IN-RDA01-16-016
54.13
54.13
54.13
54.13
54.13
54.13
54.13
IN-RDA01-16-018
54.15
54.15
54.15
54.15
54.15
54.15
54.15
IN-RDA01-16-017
54.15
54.15
54.15
54.15
54.15
54.15
54.15
IN-RDA01-16-013
54.24
54.24
54.24
54.24
54.24
54.24
54.24
IN-RDA01-16-012
54.27
54.27
54.27
54.27
54.27
54.27
54.27
IN-RDA01-16-019
54.28
54.28
54.28
54.28
54.28
54.28
54.28
IN-RDA01-16-010
54.44
54.44
54.44
54.44
54.44
54.44
54.44
IN-RDA01-16-001
54.51
54.45
54.45
54.45
54.45
54.45
54.45
IN-RDA01-16-006
54.65
54.45
54.45
54.45
54.45
54.45
54.45
IN-RDA01-16-022
54.76
54.45
54.45
54.45
54.45
54.45
54.45
IN-RDA01-16-011
59.78
54.45
54.45
54.45
54.45
54.45
54.45
PROMEDIO
53.01
54.13
54.13
54.13
54.13
54.13
54.13
DS
4.13
0.23
0.23
0.23
0.23
0.23
0.23
X*
54.13
54.13
54.13
54.13
54.13
54.13
54.13
S*
0.22
0.26
0.26
0.26
0.26
0.26
0.26
Pgina 72 de 110
Laboratorios
Pgina 73 de 110
48.00
45.00
42.00
39.00
36.00
33.00
30.00
IN-RDA01-16-001
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-017
IN-RDA01-16-011
51.00
IN-RDA01-16-023
54.00
IN-RDA01-16-022
57.00
IN-RDA01-16-022
60.00
IN-RDA01-16-006
Grfico de valores individuales para Zn en el Ensayo
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-018
IN-RDA01-16-016
IN-RDA01-16-002
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-008
IN-RDA01-16-003
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-021
IN-RDA01-16-004
31.00
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-001
Concentracin ( Zn %)

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Zn 53.87 - 54.39 %
61.00
58.00
55.00
52.00
49.00
46.00
43.00
40.00
37.00
34.00
28.00
25.00
Laboratorio
Pgina 74 de 110
IN-RDA01-16-011
IN-RDA01-16-022
IN-RDA01-16-006
IN-RDA01-16-001
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-017
IN-RDA01-16-018
IN-RDA01-16-016
IN-RDA01-16-002
IN-RDA01-16-009
IN-RDA01-16-015
30.0
25.0
20.0
15.0
10.0
5.0
0.0
-5.0
-10.0
-15.0
-20.0
-25.0
-30.0
-35.0
-40.0
-45.0
-50.0
-55.0
-60.0
-65.0
IN-RDA01-16-008
IN-RDA01-16-003
IN-RDA01-16-011
IN-RDA01-16-022
IN-RDA01-16-006
IN-RDA01-16-001
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-017
IN-RDA01-16-018
IN-RDA01-16-016
IN-RDA01-16-002
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-008
IN-RDA01-16-003
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-021
IN-RDA01-16-004
Sesgo ( % )
16.0
14.0
12.0
10.0
8.0
6.0
4.0
2.0
0.0
-2.0
-4.0
-6.0
-8.0
-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-24.0
-26.0
-28.0
-30.0
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-021
IN-RDA01-16-004
z-score

---------------------------------------------------------------------------------------------------------------------------------------------------

Valor asignado: Zn = 54.13 %
Laboratorio
Grfico de Z-Score
Zn= 54.13 %, = 0.26

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Plata (Ag)
ITERACCION
f = 1,5s*
---
---
10
10
10
10
10
x*-f
---
292
290
290
290
290
290
x*+f
---
309
311
311
311
311
311
LAB
Prom lab
IN-RDA01-16-004
225
292
292
292
292
292
292
IN-RDA01-16-011
266
292
292
292
292
292
292
IN-RDA01-16-007
269
292
292
292
292
292
292
IN-RDA01-16-001
288
292
292
292
292
292
292
IN-RDA01-16-009
293
293
293
293
293
293
293
IN-RDA01-16-021
297
297
297
297
297
297
297
IN-RDA01-16-012
297
297
297
297
297
297
297
IN-RDA01-16-015
298
298
298
298
298
298
298
IN-RDA01-16-013
299
299
299
299
299
299
299
IN-RDA01-16-016
299
299
299
299
299
299
299
IN-RDA01-16-005
300
300
300
300
300
300
300
IN-RDA01-16-017
301
301
301
301
301
301
301
IN-RDA01-16-010
301
301
301
301
301
301
301
IN-RDA01-16-018
302
302
302
302
302
302
302
IN-RDA01-16-023
303
303
303
303
303
303
303
IN-RDA01-16-002
304
304
304
304
304
304
304
IN-RDA01-16-006
307
307
307
307
307
307
307
IN-RDA01-16-003
308
308
308
308
308
308
308
IN-RDA01-16-008
314
309
309
309
309
309
309
IN-RDA01-16-014
323
309
309
309
309
309
309
IN-RDA01-16-022
328
309
309
309
309
309
309
PROMEDIO
296
300
300
300
300
300
300
DS
22
X*
300
300
300
300
300
300
300
S*
Pgina 75 de 110
Laboratorios
Pgina 76 de 110
IN-RDA01-16-014
IN-RDA01-16-022
IN-RDA01-16-022
IN-RDA01-16-023
IN-RDA01-16-003
IN-RDA01-16-006
IN-RDA01-16-002
IN-RDA01-16-023
IN-RDA01-16-018
IN-RDA01-16-010
IN-RDA01-16-017
IN-RDA01-16-005
IN-RDA01-16-016
IN-RDA01-16-013
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-008
Grfico de valores individuales para Ag en el Ensayo
IN-RDA01-16-021
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-021
IN-RDA01-16-009
IN-RDA01-16-001
IN-RDA01-16-007
IN-RDA01-16-011
IN-RDA01-16-004
340
330
320
310
300
290
280
270
260
250
240
230
220
210
200
190
180
170
160
IN-RDA01-16-005
350
340
330
320
310
300
290
280
270
260
250
240
230
220
210
200
190
180
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-001
Concentracin ( Ag g/T)

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Ag 293 - 307 g/T
Laboratorio
Pgina 77 de 110
IN-RDA01-16-002
IN-RDA01-16-006
IN-RDA01-16-002
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-014
IN-RDA01-16-008
IN-RDA01-16-022
IN-RDA01-16-014
IN-RDA01-16-008
IN-RDA01-16-003
IN-RDA01-16-023
IN-RDA01-16-023
IN-RDA01-16-003
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-005
IN-RDA01-16-016
IN-RDA01-16-013
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-018
Grfico de Z-Score
Ag= 300 g/t, = 7
IN-RDA01-16-010
Laboratorio
IN-RDA01-16-010
IN-RDA01-16-017
IN-RDA01-16-005
IN-RDA01-16-016
IN-RDA01-16-013
5.0
4.5
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
-0.5
-1.0
-1.5
-2.0
-2.5
-3.0
-3.5
-4.0
-4.5
-5.0
-5.5
-6.0
-6.5
-7.0
-7.5
-8.0
-8.5
-9.0
-9.5
-10.0
-10.5
-11.0
-11.5
-12.0
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-021
IN-RDA01-16-009
IN-RDA01-16-001
IN-RDA01-16-007
IN-RDA01-16-011
IN-RDA01-16-004
Sesgo ( % )
10.0
IN-RDA01-16-021
IN-RDA01-16-009
IN-RDA01-16-001
IN-RDA01-16-007
IN-RDA01-16-011
IN-RDA01-16-004
z-score

---------------------------------------------------------------------------------------------------------------------------------------------------

Valor asignado: Ag = 300 g/T
6.0
2.0
-2.0
-6.0
-10.0
-14.0
-18.0
-22.0
-26.0
-30.0

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Arsnico (As)
ITERACCION
---
f = 1,5s*
---
0.017
0.018
0.018
0.018
0.018
0.018
x*-f
---
0.089
0.089
0.089
0.089
0.089
0.089
x*+f
---
0.123
0.125
0.125
0.125
0.125
0.125
LAB
IN-RDA01-16-013
IN-RDA01-16-004
IN-RDA01-16-015
IN-RDA01-16-022
IN-RDA01-16-016
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-012
IN-RDA01-16-003
IN-RDA01-16-006
IN-RDA01-16-019
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-002
Prom lab
0.079
0.080
0.094
0.097
0.100
0.104
0.104
0.105
0.105
0.108
0.109
0.111
0.112
0.116
0.118
0.122
0.170
0.214
0.089
0.089
0.094
0.097
0.100
0.104
0.104
0.105
0.105
0.108
0.109
0.111
0.112
0.116
0.118
0.122
0.123
0.123
0.089
0.089
0.094
0.097
0.100
0.104
0.104
0.105
0.105
0.108
0.109
0.111
0.112
0.116
0.118
0.122
0.123
0.123
0.089
0.089
0.094
0.097
0.100
0.104
0.104
0.105
0.105
0.108
0.109
0.111
0.112
0.116
0.118
0.122
0.123
0.123
0.089
0.089
0.094
0.097
0.100
0.104
0.104
0.105
0.105
0.108
0.109
0.111
0.112
0.116
0.118
0.122
0.123
0.123
0.089
0.089
0.094
0.097
0.100
0.104
0.104
0.105
0.105
0.108
0.109
0.111
0.112
0.116
0.118
0.122
0.123
0.123
0.089
0.089
0.094
0.097
0.100
0.104
0.104
0.105
0.105
0.108
0.109
0.111
0.112
0.116
0.118
0.122
0.123
0.123
PROMEDIO
DS
X*
S*
0.114
0.031
0.106
0.011
0.107
0.011
0.107
0.012
0.107
0.011
0.107
0.012
0.107
0.011
0.107
0.012
0.107
0.011
0.107
0.012
0.107
0.011
0.107
0.012
0.107
0.011
0.107
0.012
Pgina 78 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
Intervalo de Valor Asignado As 0.095 - 0.119 %
0.260
0.240
0.220
Concentracin (%)
0.200
0.180
0.160
0.140
0.120
0.100
0.080
0.060
IN-RDA01-16-002
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-007
IN-RDA01-16-008
IN-RDA01-16-016
IN-RDA01-16-022
IN-RDA01-16-015
IN-RDA01-16-004
IN-RDA01-16-013
0.040
Grfico de valores individuales para As en el Ensayo

0.260
0.240
0.220
0.180
0.160
0.140
0.120
0.100
0.080
0.060
Laboratorios
Pgina 79 de 110
IN-RDA01-16-023
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-004
IN-RDA01-16-003
0.040
IN-RDA01-16-002
Concentracin (%)
0.200

IN-RDA01-16-002
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-007
IN-RDA01-16-008
IN-RDA01-16-022
IN-RDA01-16-015
IN-RDA01-16-004
100.00
95.00
90.00
85.00
80.00
75.00
70.00
65.00
60.00
55.00
50.00
45.00
40.00
35.00
30.00
25.00
20.00
15.00
10.00
5.00
0.00
-5.00
-10.00
-15.00
-20.00
-25.00
-30.00
IN-RDA01-16-016

Valor asignado: As = 0.107%
IN-RDA01-16-013
Sesgo (%)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Grfico de Z-Score
As= 0.107 %, = 0.012
10.00
9.00
8.00
7.00
6.00
4.00
3.00
2.00
1.00
0.00
-1.00
-2.00
Laboratorio
Pgina 80 de 110
IN-RDA01-16-002
IN-RDA01-16-014
IN-RDA01-16-009
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-019
IN-RDA01-16-006
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-007
IN-RDA01-16-008
IN-RDA01-16-016
IN-RDA01-16-022
IN-RDA01-16-015
IN-RDA01-16-004
-3.00
IN-RDA01-16-013
z-score
5.00

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Cadmio (Cd)
ITERACCION
f = 1,5s*
---
---
0.020
0.021
0.021
0.021
0.021
0.021
x*-f
---
0.245
0.243
0.243
0.243
0.243
0.243
x*+f
---
0.285
0.285
0.285
0.285
0.285
0.285
LAB
Prom lab
IN-RDA01-16-004
0.158
0.245
0.245
0.245
0.245
0.245
0.245
IN-RDA01-16-007
0.235
0.245
0.245
0.245
0.245
0.245
0.245
IN-RDA01-16-013
0.242
0.245
0.245
0.245
0.245
0.245
0.245
IN-RDA01-16-005
0.253
0.253
0.253
0.253
0.253
0.253
0.253
IN-RDA01-16-021
0.255
0.255
0.255
0.255
0.255
0.255
0.255
IN-RDA01-16-001
0.257
0.257
0.257
0.257
0.257
0.257
0.257
IN-RDA01-16-022
0.257
0.257
0.257
0.257
0.257
0.257
0.257
IN-RDA01-16-012
0.258
0.258
0.258
0.258
0.258
0.258
0.258
IN-RDA01-16-014
0.260
0.260
0.260
0.260
0.260
0.260
0.260
IN-RDA01-16-009
0.265
0.265
0.265
0.265
0.265
0.265
0.265
IN-RDA01-16-002
0.265
0.265
0.265
0.265
0.265
0.265
0.265
IN-RDA01-16-016
0.267
0.267
0.267
0.267
0.267
0.267
0.267
IN-RDA01-16-003
0.269
0.269
0.269
0.269
0.269
0.269
0.269
IN-RDA01-16-019
0.270
0.270
0.270
0.270
0.270
0.270
0.270
IN-RDA01-16-015
0.270
0.270
0.270
0.270
0.270
0.270
0.270
IN-RDA01-16-008
0.275
0.275
0.275
0.275
0.275
0.275
0.275
IN-RDA01-16-006
0.277
0.277
0.277
0.277
0.277
0.277
0.277
IN-RDA01-16-010
0.279
0.279
0.279
0.279
0.279
0.279
0.279
IN-RDA01-16-011
0.287
0.285
0.285
0.285
0.285
0.285
0.285
IN-RDA01-16-023
0.320
0.285
0.285
0.285
0.285
0.285
0.285
PROMEDIO
0.261
0.264
0.264
0.264
0.264
0.264
0.264
DS
0.030
0.012
0.012
0.012
0.012
0.012
0.012
X*
0.265
0.264
0.264
0.264
0.264
0.264
0.264
S*
0.013
0.014
0.014
0.014
0.014
0.014
0.014
Pgina 81 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Cd 0.250 - 0.278 %
0.330
0.320
0.310
0.300
0.290
0.280
0.270
0.260
0.250
0.240
0.230
0.220
0.210
0.200
0.190
0.180
0.170
0.160
0.150
0.140
0.130
0.120
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-023
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-002
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-012
IN-RDA01-16-022
IN-RDA01-16-001
IN-RDA01-16-021
IN-RDA01-16-005
IN-RDA01-16-013
IN-RDA01-16-007
IN-RDA01-16-004
Laboratorios
Pgina 82 de 110
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
0.330
0.320
0.310
0.300
0.290
0.280
0.270
0.260
0.250
0.240
0.230
0.220
0.210
0.200
0.190
0.180
0.170
0.160
0.150
0.140
0.130
0.120
IN-RDA01-16-001
Concentracin (Cd %)
Grfico de valores individuales para Cd en el Ensayo

IN-RDA01-16-023
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-002
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-012
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-005
IN-RDA01-16-013
IN-RDA01-16-007
21.0
19.0
17.0
15.0
13.0
11.0
9.0
7.0
5.0
3.0
1.0
-1.0
-3.0
-5.0
-7.0
-9.0
-11.0
-13.0
-15.0
-17.0
-19.0
-21.0
-23.0
-25.0
-27.0
-29.0
-31.0
-33.0
-35.0
-37.0
-39.0
-41.0
IN-RDA01-16-001

Valor asignado: Cd = 0. 264 %
IN-RDA01-16-004
Sesgo (%)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Pgina 83 de 110
IN-RDA01-16-023
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-006
IN-RDA01-16-008
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-002
IN-RDA01-16-009
IN-RDA01-16-014
IN-RDA01-16-012
IN-RDA01-16-001
IN-RDA01-16-021
IN-RDA01-16-005
IN-RDA01-16-013
IN-RDA01-16-007
4.50
4.00
3.50
3.00
2.50
2.00
1.50
1.00
0.50
0.00
-0.50
-1.00
-1.50
-2.00
-2.50
-3.00
-3.50
-4.00
-4.50
-5.00
-5.50
-6.00
-6.50
-7.00
-7.50
-8.00
IN-RDA01-16-022
Grfico de Z-Score
Cd= 0.264 %, = 0.014
IN-RDA01-16-004
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Cobalto (Co)
ITERACCION
---
f = 1,5s*
---
x*-f
---
x*+f
---
13
13
13
13
13
13
LAB
Prom lab
IN-RDA01-16-014
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-012
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-011
11
11
11
11
11
11
11
IN-RDA01-16-023
58
13
13
13
13
13
13
IN-RDA01-16-013
105
13
13
13
13
13
13
PROMEDIO
21
DS
32
X*
S*
Pgina 84 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Co 6 - 12 g/T
111
101
91
81
71
61
51
41
31
21
11
IN-RDA01-16-023
IN-RDA01-16-013
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-011
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-010
IN-RDA01-16-021
IN-RDA01-16-014
Grfico de valores individuales para Co en el Ensayo

121
111
91
81
71
61
51
41
31
21
11
Laboratorios
Pgina 85 de 110
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-007
1
IN-RDA01-16-003
Concentracin (Co g/T)
101

---------------------------------------------------------------------------------------------------------------------------------------------------

Valor asignado: Co = 9 g/T
950.00
850.00
750.00
Sesgo (%)
650.00
550.00
450.00
350.00
250.00
150.00
50.00
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-011
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-010
IN-RDA01-16-021
IN-RDA01-16-014
-50.00
Laboratorio
Grfico de Z-Score
Co= 9 g/T, = 3
38.0
33.0
23.0
18.0
13.0
8.0
3.0
Laboratorio
Pgina 86 de 110
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-011
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-012
IN-RDA01-16-010
IN-RDA01-16-021
-2.0
IN-RDA01-16-014
z-score
28.0

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Cobre (Cu)
ITERACCION
f = 1,5s*
---
---
0.010
0.010
0.010
0.010
0.010
0.010
x*-f
---
0.114
0.113
0.113
0.113
0.113
0.113
x*+f
---
0.134
0.134
0.134
0.134
0.134
0.134
LAB
Prom lab
IN-RDA01-16-004
0.088
0.114
0.114
0.114
0.114
0.114
0.114
IN-RDA01-16-015
0.089
0.114
0.114
0.114
0.114
0.114
0.114
IN-RDA01-16-008
0.107
0.114
0.114
0.114
0.114
0.114
0.114
IN-RDA01-16-021
0.116
0.116
0.116
0.116
0.116
0.116
0.116
IN-RDA01-16-023
0.118
0.118
0.118
0.118
0.118
0.118
0.118
IN-RDA01-16-016
0.120
0.120
0.120
0.120
0.120
0.120
0.120
IN-RDA01-16-007
0.120
0.120
0.120
0.120
0.120
0.120
0.120
IN-RDA01-16-005
0.123
0.123
0.123
0.123
0.123
0.123
0.123
IN-RDA01-16-022
0.123
0.123
0.123
0.123
0.123
0.123
0.123
IN-RDA01-16-012
0.124
0.124
0.124
0.124
0.124
0.124
0.124
IN-RDA01-16-014
0.124
0.124
0.124
0.124
0.124
0.124
0.124
IN-RDA01-16-003
0.124
0.124
0.124
0.124
0.124
0.124
0.124
IN-RDA01-16-009
0.127
0.127
0.127
0.127
0.127
0.127
0.127
IN-RDA01-16-001
0.128
0.128
0.128
0.128
0.128
0.128
0.128
IN-RDA01-16-011
0.128
0.128
0.128
0.128
0.128
0.128
0.128
IN-RDA01-16-010
0.129
0.129
0.129
0.129
0.129
0.129
0.129
IN-RDA01-16-013
0.129
0.129
0.129
0.129
0.129
0.129
0.129
IN-RDA01-16-006
0.129
0.129
0.129
0.129
0.129
0.129
0.129
IN-RDA01-16-002
0.130
0.130
0.130
0.130
0.130
0.130
0.130
IN-RDA01-16-019
0.130
0.130
0.130
0.130
0.130
0.130
0.130
IN-RDA01-16-017
0.146
0.134
0.134
0.134
0.134
0.134
0.134
PROMEDIO
0.121
0.124
0.124
0.124
0.124
0.124
0.124
DS
0.013
0.006
0.006
0.006
0.006
0.006
0.006
X*
0.124
0.124
0.124
0.124
0.124
0.124
0.124
S*
0.007
0.007
0.007
0.007
0.007
0.007
0.007
Pgina 87 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Cu 0.117 - 0.131 %
0.160
0.155
0.150
0.145
0.140
0.135
0.130
0.125
0.120
0.115
0.110
0.105
0.100
0.095
0.090
IN-RDA01-16-002
IN-RDA01-16-019
IN-RDA01-16-017
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-023
IN-RDA01-16-006
IN-RDA01-16-013
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-001
IN-RDA01-16-009
IN-RDA01-16-003
IN-RDA01-16-014
IN-RDA01-16-012
IN-RDA01-16-022
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-016
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-008
IN-RDA01-16-015
IN-RDA01-16-004
Grfico de valores individuales para Cu en el Ensayo

0.150
0.145
0.140
0.130
0.125
0.120
0.115
0.110
0.105
0.100
0.095
0.090
0.085
Laboratorios
Pgina 88 de 110
IN-RDA01-16-019
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
0.080
IN-RDA01-16-001
Concentracin (Cu %)
0.135
Laboratorio
Pgina 89 de 110
IN-RDA01-16-017
IN-RDA01-16-019
IN-RDA01-16-002
IN-RDA01-16-006
IN-RDA01-16-013
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-001
IN-RDA01-16-009
IN-RDA01-16-003
IN-RDA01-16-014
IN-RDA01-16-012
IN-RDA01-16-022
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-017
IN-RDA01-16-019
IN-RDA01-16-002
IN-RDA01-16-006
IN-RDA01-16-013
IN-RDA01-16-010
IN-RDA01-16-011
IN-RDA01-16-001
IN-RDA01-16-009
IN-RDA01-16-003
IN-RDA01-16-014
IN-RDA01-16-012
IN-RDA01-16-022
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-016
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-008
IN-RDA01-16-015
IN-RDA01-16-004
Sesgo (%)
17.0
IN-RDA01-16-016
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-008
IN-RDA01-16-015
IN-RDA01-16-004
z-score

---------------------------------------------------------------------------------------------------------------------------------------------------

Valor asignado: Cu = 0.124 %
13.0
9.0
5.0
-3.0
1.0
-11.0
-7.0
-15.0
-19.0
-23.0
-27.0
-31.0
-35.0
Laboratorio
Grfico de Z-Score
Cd= 0.124 %, = 0.007
3.0
2.5
2.0
1.5
1.0
0.5
0.0
-0.5
-1.0
-1.5
-2.0
-2.5
-3.0
-3.5
-4.0
-4.5
-5.0
-5.5

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Hierro (Fe)
ITERACCION
---
f = 1,5s*
---
0.25
0.29
0.29
0.29
0.29
0.29
x*-f
---
3.98
3.92
3.92
3.92
3.92
3.92
x*+f
---
4.47
4.50
4.50
4.50
4.50
4.50
LAB
Prom lab
IN-RDA01-16-023
0.15
3.98
3.98
3.98
3.98
3.98
3.98
IN-RDA01-16-004
2.40
3.98
3.98
3.98
3.98
3.98
3.98
IN-RDA01-16-014
3.39
3.98
3.98
3.98
3.98
3.98
3.98
IN-RDA01-16-021
3.85
3.98
3.98
3.98
3.98
3.98
3.98
IN-RDA01-16-003
3.98
3.98
3.98
3.98
3.98
3.98
3.98
IN-RDA01-16-005
3.98
3.98
3.98
3.98
3.98
3.98
3.98
IN-RDA01-16-007
4.13
4.13
4.13
4.13
4.13
4.13
4.13
IN-RDA01-16-013
4.16
4.16
4.16
4.16
4.16
4.16
4.16
IN-RDA01-16-019
4.21
4.21
4.21
4.21
4.21
4.21
4.21
IN-RDA01-16-010
4.21
4.21
4.21
4.21
4.21
4.21
4.21
IN-RDA01-16-006
4.23
4.23
4.23
4.23
4.23
4.23
4.23
IN-RDA01-16-022
4.23
4.23
4.23
4.23
4.23
4.23
4.23
IN-RDA01-16-009
4.27
4.27
4.27
4.27
4.27
4.27
4.27
IN-RDA01-16-001
4.27
4.27
4.27
4.27
4.27
4.27
4.27
IN-RDA01-16-015
4.28
4.28
4.28
4.28
4.28
4.28
4.28
IN-RDA01-16-016
4.30
4.30
4.30
4.30
4.30
4.30
4.30
IN-RDA01-16-012
4.34
4.34
4.34
4.34
4.34
4.34
4.34
IN-RDA01-16-017
4.34
4.34
4.34
4.34
4.34
4.34
4.34
IN-RDA01-16-008
4.36
4.36
4.36
4.36
4.36
4.36
4.36
IN-RDA01-16-018
4.49
4.47
4.47
4.47
4.47
4.47
4.47
IN-RDA01-16-002
4.58
4.47
4.47
4.47
4.47
4.47
4.47
IN-RDA01-16-011
4.76
4.47
4.47
4.47
4.47
4.47
4.47
PROMEDIO
3.95
4.21
4.21
4.21
4.21
4.21
4.21
DS
0.97
0.17
0.17
0.17
0.17
0.17
0.17
X*
4.23
4.21
4.21
4.21
4.21
4.21
4.21
S*
0.16
0.19
0.19
0.19
0.19
0.19
0.19
Pgina 90 de 110
Laboratorios
Pgina 91 de 110
IN-RDA01-16-002
IN-RDA01-16-022
IN-RDA01-16-011
IN-RDA01-16-018
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-008
IN-RDA01-16-012
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-001
IN-RDA01-16-009
IN-RDA01-16-019
6.45
6.05
5.65
5.25
4.85
4.45
4.05
3.65
3.25
2.85
2.45
2.05
1.65
1.25
0.85
0.45
0.05
IN-RDA01-16-017
Grfico de valores individuales para Fe en el Ensayo
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-022
IN-RDA01-16-006
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-013
IN-RDA01-16-007
IN-RDA01-16-005
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-004
IN-RDA01-16-023
5.65
5.25
4.85
4.45
4.05
3.65
3.25
2.85
2.45
2.05
1.65
1.25
0.85
0.45
0.05
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-001
Concentracin ( Fe %)

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Fe 4.02 - 4.40 %

---------------------------------------------------------------------------------------------------------------------------------------------------

Valor asignado: Fe = 4.21%
IN-RDA01-16-011
IN-RDA01-16-002
IN-RDA01-16-018
IN-RDA01-16-008
IN-RDA01-16-017
IN-RDA01-16-012
IN-RDA01-16-015
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-001
IN-RDA01-16-001
IN-RDA01-16-009
IN-RDA01-16-022
IN-RDA01-16-006
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-007
IN-RDA01-16-005
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-004
IN-RDA01-16-023
Sesgo (%)
30.0
25.0
20.0
15.0
10.0
5.0
0.0
-5.0
-10.0
-15.0
-20.0
-25.0
-30.0
-35.0
-40.0
-45.0
-50.0
-55.0
-60.0
-65.0
-70.0
-75.0
-80.0
-85.0
-90.0
-95.0
-100.0
Laboratorio
Pgina 92 de 110
IN-RDA01-16-011
IN-RDA01-16-002
IN-RDA01-16-018
IN-RDA01-16-008
IN-RDA01-16-017
IN-RDA01-16-012
IN-RDA01-16-016
IN-RDA01-16-009
IN-RDA01-16-022
IN-RDA01-16-006
IN-RDA01-16-010
IN-RDA01-16-007
IN-RDA01-16-005
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-014
IN-RDA01-16-004
4.0
2.0
0.0
-2.0
-4.0
-6.0
-8.0
-10.0
-12.0
-14.0
-16.0
-18.0
-20.0
-22.0
-24.0
-26.0
IN-RDA01-16-019
Grfico de Z-Score
Fe= 4.21 %, = 0.19
IN-RDA01-16-023
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Manganeso (Mn)
ITERACCION
---
f = 1,5s*
---
0.009
0.010
0.010
0.010
0.010
0.010
x*-f
---
0.045
0.043
0.043
0.043
0.043
0.043
x*+f
---
0.064
0.064
0.064
0.064
0.064
0.064
LAB
IN-RDA01-16-011
IN-RDA01-16-014
IN-RDA01-16-022
IN-RDA01-16-004
IN-RDA01-16-021
IN-RDA01-16-023
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-013
IN-RDA01-16-003
IN-RDA01-16-001
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-010
Prom lab
0.030
0.033
0.036
0.039
0.050
0.050
0.051
0.054
0.055
0.055
0.057
0.058
0.058
0.059
0.061
0.061
0.061
0.045
0.045
0.045
0.045
0.050
0.050
0.051
0.054
0.055
0.055
0.057
0.058
0.058
0.059
0.061
0.061
0.061
0.045
0.045
0.045
0.045
0.050
0.050
0.051
0.054
0.055
0.055
0.057
0.058
0.058
0.059
0.061
0.061
0.061
0.045
0.045
0.045
0.045
0.050
0.050
0.051
0.054
0.055
0.055
0.057
0.058
0.058
0.059
0.061
0.061
0.061
0.045
0.045
0.045
0.045
0.050
0.050
0.051
0.054
0.055
0.055
0.057
0.058
0.058
0.059
0.061
0.061
0.061
0.045
0.045
0.045
0.045
0.050
0.050
0.051
0.054
0.055
0.055
0.057
0.058
0.058
0.059
0.061
0.061
0.061
0.045
0.045
0.045
0.045
0.050
0.050
0.051
0.054
0.055
0.055
0.057
0.058
0.058
0.059
0.061
0.061
0.061
PROMEDIO
DS
X*
S*
0.051
0.010
0.055
0.006
0.053
0.006
0.053
0.007
0.053
0.006
0.053
0.007
0.053
0.006
0.053
0.007
0.053
0.006
0.053
0.007
0.053
0.006
0.053
0.007
0.053
0.006
0.053
0.007
Pgina 93 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Mn 0.046 - 0.060 %
0.067
0.062
0.057
0.052
0.047
0.042
0.037
0.032
0.027
0.022
0.017
0.012
0.007
IN-RDA01-16-012
IN-RDA01-16-009
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16-010
IN-RDA01-16-019
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-001
IN-RDA01-16-003
IN-RDA01-16-013
IN-RDA01-16-007
IN-RDA01-16-008
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-004
IN-RDA01-16-022
IN-RDA01-16-014
IN-RDA01-16-011
0.002
Grfico de valores individuales para Mn en el Ensayo
0.070
0.065
0.055
0.050
0.045
0.040
0.035
0.030
0.025
Laboratorios
Pgina 94 de 110
IN-RDA01-16-023
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-004
IN-RDA01-16-003
0.020
IN-RDA01-16-001
Concentracin (%)
0.060

---------------------------------------------------------------------------------------------------------------------------------------------------
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-012
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-001
IN-RDA01-16-003
IN-RDA01-16-013
IN-RDA01-16-007
IN-RDA01-16-008
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-004
IN-RDA01-16-022
IN-RDA01-16-014
20.00
15.00
10.00
5.00
0.00
-5.00
-10.00
-15.00
-20.00
-25.00
-30.00
-35.00
-40.00
-45.00
-50.00
IN-RDA01-16-011
Sesgo (%)

Valor asignado: Mn = 0.053 %
Laboratorio
Pgina 95 de 110
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-012
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-001
IN-RDA01-16-003
IN-RDA01-16-013
IN-RDA01-16-007
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-004
IN-RDA01-16-022
IN-RDA01-16-014
1.40
1.20
1.00
0.80
0.60
0.40
0.20
0.00
-0.20
-0.40
-0.60
-0.80
-1.00
-1.20
-1.40
-1.60
-1.80
-2.00
-2.20
-2.40
-2.60
-2.80
-3.00
-3.20
-3.40
-3.60
-3.80
-4.00
IN-RDA01-16-008
Grfico de Z-Score
Mn= 0.053 %, = 0.007
IN-RDA01-16-011
z-score
Laboratorio

--------------------------------------------------------------------------------------------------------------------------------------------------Material
Elemento
: Nquel (Ni)
ITERACCION
---
f = 1,5s*
---
x*-f
---
x*+f
---
17
18
18
18
18
18
LAB
IN-RDA01-16-011
IN-RDA01-16-012
IN-RDA01-16-007
IN-RDA01-16-003
IN-RDA01-16-010
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-023
IN-RDA01-16-004
IN-RDA01-16-013
Prom lab
6
6
8
9
10
10
10
11
14
25
30
30
6
6
8
9
10
10
10
11
14
17
17
17
6
6
8
9
10
10
10
11
14
17
17
17
6
6
8
9
10
10
10
11
14
17
17
17
6
6
8
9
10
10
10
11
14
17
17
17
6
6
8
9
10
10
10
11
14
17
17
17
6
6
8
9
10
10
10
11
14
17
17
17
PROMEDIO
DS
X*
S*
14
9
10
5
11
4
11
5
11
4
11
5
11
4
11
5
11
4
11
5
11
4
11
5
11
4
11
5
Pgina 96 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------
Intervalo de Valor Asignado Ni 7 - 16 g/T
46
41
36
31
26
21
16
11
6
IN-RDA01-16-013
IN-RDA01-16-004
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-012
IN-RDA01-16-011
Laboratorios
Pgina 97 de 110
IN-RDA01-16-023
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-007
IN-RDA01-16-004
57
53
49
45
41
37
33
29
25
21
17
13
9
5
1
IN-RDA01-16-003
Concentracin (g/T)
Grfico de valores individuales para Ni en el Ensayo

IN-RDA01-16-013
IN-RDA01-16-004
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-007
IN-RDA01-16-012
200.0
180.0
160.0
140.0
120.0
100.0
80.0
60.0
40.0
20.0
0.0
-20.0
-40.0
-60.0
-80.0
-100.0
IN-RDA01-16-003

Valor asignado: Ni = 11 g/T
IN-RDA01-16-011
Sesgo (%)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Grfico de Z-Score
Ni= 11 g/T, = 5
5.50
4.50
2.50
1.50
0.50
-0.50
Laboratorio
Pgina 98 de 110
IN-RDA01-16-013
IN-RDA01-16-004
IN-RDA01-16-023
IN-RDA01-16-014
IN-RDA01-16-015
IN-RDA01-16-019
IN-RDA01-16-021
IN-RDA01-16-010
IN-RDA01-16-003
IN-RDA01-16-007
IN-RDA01-16-012
-1.50
IN-RDA01-16-011
z-score
3.50

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Plomo (Pb)
ITERACCION
---
f = 1,5s*
---
0.09
0.09
0.09
0.09
0.09
0.09
x*-f
---
1.17
1.18
1.18
1.18
1.18
1.18
x*+f
---
1.34
1.36
1.36
1.36
1.36
1.36
LAB
Prom lab
IN-RDA01-16-004
0.69
1.17
1.17
1.17
1.17
1.17
1.17
IN-RDA01-16-021
1.18
1.18
1.18
1.18
1.18
1.18
1.18
IN-RDA01-16-022
1.20
1.20
1.20
1.20
1.20
1.20
1.20
IN-RDA01-16-006
1.22
1.22
1.22
1.22
1.22
1.22
1.22
IN-RDA01-16-007
1.24
1.24
1.24
1.24
1.24
1.24
1.24
IN-RDA01-16-017
1.24
1.24
1.24
1.24
1.24
1.24
1.24
IN-RDA01-16-013
1.25
1.25
1.25
1.25
1.25
1.25
1.25
IN-RDA01-16-016
1.25
1.25
1.25
1.25
1.25
1.25
1.25
IN-RDA01-16-012
1.25
1.25
1.25
1.25
1.25
1.25
1.25
IN-RDA01-16-008
1.25
1.25
1.25
1.25
1.25
1.25
1.25
IN-RDA01-16-019
1.26
1.26
1.26
1.26
1.26
1.26
1.26
IN-RDA01-16-005
1.26
1.26
1.26
1.26
1.26
1.26
1.26
IN-RDA01-16-018
1.27
1.27
1.27
1.27
1.27
1.27
1.27
IN-RDA01-16-003
1.27
1.27
1.27
1.27
1.27
1.27
1.27
IN-RDA01-16-014
1.30
1.30
1.30
1.30
1.30
1.30
1.30
IN-RDA01-16-001
1.32
1.32
1.32
1.32
1.32
1.32
1.32
IN-RDA01-16-002
1.32
1.32
1.32
1.32
1.32
1.32
1.32
IN-RDA01-16-011
1.33
1.33
1.33
1.33
1.33
1.33
1.33
IN-RDA01-16-009
1.34
1.34
1.34
1.34
1.34
1.34
1.34
IN-RDA01-16-023
1.36
1.34
1.34
1.34
1.34
1.34
1.34
IN-RDA01-16-015
1.43
1.34
1.34
1.34
1.34
1.34
1.34
PROMEDIO
1.25
1.27
1.27
1.27
1.27
1.27
1.27
DS
0.14
0.05
0.05
0.05
0.05
0.05
0.05
X*
1.26
1.27
1.27
1.27
1.27
1.27
1.27
S*
0.06
0.06
0.06
0.06
0.06
0.06
0.06
Pgina 99 de 110
Laboratorios
Pgina 100 de 110
1.30
1.20
1.10
1.00
0.90
0.80
0.70
0.60
0.50
IN-RDA01-16-011
IN-RDA01-16-002
IN-RDA01-16-001
IN-RDA01-16-014
IN-RDA01-16-003
IN-RDA01-16-018
IN-RDA01-16-005
IN-RDA01-16-015
1.40
IN-RDA01-16-023
1.50
IN-RDA01-16-023
1.60
IN-RDA01-16-022
1.70
IN-RDA01-16-009
Grfico de valores individuales para Pb en el Ensayo
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-019
0.60
IN-RDA01-16-012
IN-RDA01-16-008
IN-RDA01-16-012
IN-RDA01-16-016
IN-RDA01-16-013
IN-RDA01-16-017
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-004
0.70
IN-RDA01-16-011
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-004
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-001
Concentracin ( Pb %)

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Pb 1.21 - 1.33 %
1.70
1.60
1.50
1.40
1.30
1.20
1.10
1.00
0.90
0.80
0.50
Laboratorio
Pgina 101 de 110

IN-RDA01-16-001
IN-RDA01-16-002
IN-RDA01-16-001
IN-RDA01-16-002
IN-RDA01-16-015
IN-RDA01-16-023
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-023
IN-RDA01-16-009
IN-RDA01-16-011
IN-RDA01-16-014
IN-RDA01-16-014
IN-RDA01-16-011
IN-RDA01-16-003
IN-RDA01-16-005
IN-RDA01-16-019
IN-RDA01-16-008
IN-RDA01-16-012
IN-RDA01-16-016
IN-RDA01-16-013
IN-RDA01-16-003
Grfico de Z-Score
Pb= 1.27 %, = 0.06
IN-RDA01-16-018
Laboratorio
IN-RDA01-16-018
IN-RDA01-16-005
IN-RDA01-16-019
IN-RDA01-16-008
IN-RDA01-16-012
3.0
2.5
2.0
1.5
1.0
0.5
0.0
-0.5
-1.0
-1.5
-2.0
-2.5
-3.0
-3.5
-4.0
-4.5
-5.0
-5.5
-6.0
-6.5
-7.0
-7.5
-8.0
-8.5
-9.0
-9.5
-10.0
IN-RDA01-16-016
IN-RDA01-16-013
IN-RDA01-16-017
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-004
Sesgo ( % )
14.0
10.0
6.0
2.0
-2.0
-6.0
-10.0
-14.0
-18.0
-22.0
-26.0
-30.0
-34.0
-38.0
-42.0
-46.0
-50.0
IN-RDA01-16-017
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-021
IN-RDA01-16-004
z-score

---------------------------------------------------------------------------------------------------------------------------------------------------

Valor asignado: Pb = 1.27 %

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: xido de Slice (SiO2)
ITERACCION
---
f = 1,5s*
---
0.57
0.62
0.62
0.62
0.62
0.62
x*-f
---
2.35
2.25
2.25
2.25
2.25
2.25
x*+f
---
3.48
3.48
3.48
3.48
3.48
3.48
LAB
IN-RDA01-16-023
IN-RDA01-16-013
IN-RDA01-16-014
IN-RDA01-16-019
IN-RDA01-16-022
IN-RDA01-16-016
IN-RDA01-16-003
IN-RDA01-16-015
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-004
IN-RDA01-16-007
IN-RDA01-16-011
Prom lab
0.24
1.56
2.46
2.64
2.66
2.80
2.92
2.96
3.09
3.14
3.14
3.30
3.84
2.35
2.35
2.46
2.64
2.66
2.80
2.92
2.96
3.09
3.14
3.14
3.30
3.48
2.35
2.35
2.46
2.64
2.66
2.80
2.92
2.96
3.09
3.14
3.14
3.30
3.48
2.35
2.35
2.46
2.64
2.66
2.80
2.92
2.96
3.09
3.14
3.14
3.30
3.48
2.35
2.35
2.46
2.64
2.66
2.80
2.92
2.96
3.09
3.14
3.14
3.30
3.48
2.35
2.35
2.46
2.64
2.66
2.80
2.92
2.96
3.09
3.14
3.14
3.30
3.48
2.35
2.35
2.46
2.64
2.66
2.80
2.92
2.96
3.09
3.14
3.14
3.30
3.48
PROMEDIO
DS
X*
S*
2.67
0.90
2.92
0.38
2.87
0.36
2.87
0.41
2.87
0.36
2.87
0.41
2.87
0.36
2.87
0.41
2.87
0.36
2.87
0.41
2.87
0.36
2.87
0.41
2.87
0.36
2.87
0.41
Pgina 102 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Si 2.46 - 3.28 %
3.70
3.30
Concentracin (%)
2.90
2.50
2.10
1.70
1.30
0.90
0.50
IN-RDA01-16-011
IN-RDA01-16-007
IN-RDA01-16-004
IN-RDA01-16-008
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-022
IN-RDA01-16-019
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-003
0.10
Grfico de valores individuales para Si en el Ensayo

4.10
3.70
2.90
2.50
2.10
1.70
1.30
0.90
0.50
Laboratorios
Pgina 103 de 110
IN-RDA01-16-023
IN-RDA01-16-022
IN-RDA01-16-019
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-011
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-004
0.10
IN-RDA01-16-003
Concentracin (%)
3.30

IN-RDA01-16-011
IN-RDA01-16-007
IN-RDA01-16-004
IN-RDA01-16-008
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-022
IN-RDA01-16-014
IN-RDA01-16-013
40.00
30.00
20.00
10.00
0.00
-10.00
-20.00
-30.00
-40.00
-50.00
-60.00
-70.00
-80.00
-90.00
-100.00
IN-RDA01-16-019

Valor asignado: Si = 2.87 %
IN-RDA01-16-023
Sesgo (%)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Pgina 104 de 110
IN-RDA01-16-011
IN-RDA01-16-007
IN-RDA01-16-004
IN-RDA01-16-008
IN-RDA01-16-009
IN-RDA01-16-015
IN-RDA01-16-003
IN-RDA01-16-016
IN-RDA01-16-019
IN-RDA01-16-014
IN-RDA01-16-013
3.00
2.50
2.00
1.50
1.00
0.50
0.00
-0.50
-1.00
-1.50
-2.00
-2.50
-3.00
-3.50
-4.00
-4.50
-5.00
-5.50
-6.00
-6.50
-7.00
IN-RDA01-16-022
Grfico Z-Score
Si= 2.87 %, = 0.41
IN-RDA01-16-023
z-score
Laboratorio

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Antimonio (Sb)
ITERACCION
---
f = 1,5s*
---
70
83
83
83
83
83
x*-f
---
151
135
135
135
135
135
x*+f
---
290
301
301
301
301
301
LAB
IN-RDA01-16-023
IN-RDA01-16-007
IN-RDA01-16-015
IN-RDA01-16-021
IN-RDA01-16-003
IN-RDA01-16-012
IN-RDA01-16-016
IN-RDA01-16-006
IN-RDA01-16-011
IN-RDA01-16-002
IN-RDA01-16-008
IN-RDA01-16-019
IN-RDA01-16-022
IN-RDA01-16-009
IN-RDA01-16-010
IN-RDA01-16-014
IN-RDA01-16-013
Prom lab
1
100
132
140
189
206
210
210
220
225
233
240
248
258
354
388
460
151
151
151
151
189
206
210
210
220
225
233
240
248
258
290
290
290
151
151
151
151
189
206
210
210
220
225
233
240
248
258
290
290
290
151
151
151
151
189
206
210
210
220
225
233
240
248
258
290
290
290
151
151
151
151
189
206
210
210
220
225
233
240
248
258
290
290
290
151
151
151
151
189
206
210
210
220
225
233
240
248
258
290
290
290
151
151
151
151
189
206
210
210
220
225
233
240
248
258
290
290
290
PROMEDIO
DS
X*
S*
224
107
220
47
218
49
218
55
218
49
218
55
218
49
218
55
218
49
218
55
218
49
218
55
218
49
218
55
Pgina 105 de 110

---------------------------------------------------------------------------------------------------------------------------------------------------

Intervalo de Valor Asignado Sb 163 - 273 gT
571
541
511
481
451
421
391
361
331
301
271
241
211
181
151
121
91
61
31
1
IN-RDA01-16010
IN-RDA01-16014
IN-RDA01-16-021
IN-RDA01-16-022
IN-RDA01-16013
IN-RDA01-16009
IN-RDA01-16-019
IN-RDA01-16022
IN-RDA01-16019
IN-RDA01-16008
IN-RDA01-16002
IN-RDA01-16011
IN-RDA01-16006
IN-RDA01-16016
IN-RDA01-16012
IN-RDA01-16003
IN-RDA01-16021
IN-RDA01-16015
IN-RDA01-16007
IN-RDA01-16023
Laboratorios
Pgina 106 de 110
IN-RDA01-16-023
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-003
576
551
526
501
476
451
426
401
376
351
326
301
276
251
226
201
176
151
126
101
76
51
26
1
IN-RDA01-16-002
Concentracin g/T)
Grfico de valores individuales para Sb en el Ensayo

IN-RDA01-16-013
IN-RDA01-16-014
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-022
IN-RDA01-16-019
IN-RDA01-16-008
IN-RDA01-16-002
IN-RDA01-16-011
IN-RDA01-16-006
IN-RDA01-16-016
IN-RDA01-16-012
IN-RDA01-16-021
IN-RDA01-16-015
IN-RDA01-16-007
120.0
110.0
100.0
90.0
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0
0.0
-10.0
-20.0
-30.0
-40.0
-50.0
-60.0
-70.0
-80.0
-90.0
-100.0
-110.0
-120.0
IN-RDA01-16-003

Valor asignado: Sb = 218 g/T
IN-RDA01-16-023
Sesgo ( %)
---------------------------------------------------------------------------------------------------------------------------------------------------
Laboratorio
Grfico de Z-Score
Sb= 218 g/T, = 55
6.0
5.0
4.0
3.0
1.0
0.0
-1.0
-2.0
-3.0
-4.0
Laboratorio
Pgina 107 de 110
IN-RDA01-16-013
IN-RDA01-16-014
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-022
IN-RDA01-16-019
IN-RDA01-16-008
IN-RDA01-16-002
IN-RDA01-16-011
IN-RDA01-16-006
IN-RDA01-16-016
IN-RDA01-16-012
IN-RDA01-16-003
IN-RDA01-16-021
IN-RDA01-16-015
IN-RDA01-16-007
-5.0
IN-RDA01-16-023
z-score
2.0

---------------------------------------------------------------------------------------------------------------------------------------------------
Material
Elemento
: Zinc (Zn)
ITERACCION
---
f = 1,5s*
---
0.33
0.38
0.38
0.38
0.38
0.38
x*-f
---
56.65
56.60
56.60
56.60
56.60
56.60
x*+f
---
57.31
57.36
57.36
57.36
57.36
57.36
LAB
Prom lab
IN-RDA01-16-004
35.46
56.65
56.65
56.65
56.65
56.65
56.65
IN-RDA01-16-021
50.23
56.65
56.65
56.65
56.65
56.65
56.65
IN-RDA01-16-007
50.23
56.65
56.65
56.65
56.65
56.65
56.65
IN-RDA01-16-005
56.48
56.65
56.65
56.65
56.65
56.65
56.65
IN-RDA01-16-014
56.81
56.81
56.81
56.81
56.81
56.81
56.81
IN-RDA01-16-002
56.85
56.85
56.85
56.85
56.85
56.85
56.85
IN-RDA01-16-008
56.86
56.86
56.86
56.86
56.86
56.86
56.86
IN-RDA01-16-017
56.88
56.88
56.88
56.88
56.88
56.88
56.88
IN-RDA01-16-009
56.91
56.91
56.91
56.91
56.91
56.91
56.91
IN-RDA01-16-003
56.92
56.92
56.92
56.92
56.92
56.92
56.92
IN-RDA01-16-018
56.97
56.97
56.97
56.97
56.97
56.97
56.97
IN-RDA01-16-010
56.99
56.99
56.99
56.99
56.99
56.99
56.99
IN-RDA01-16-016
57.01
57.01
57.01
57.01
57.01
57.01
57.01
IN-RDA01-16-015
57.06
57.06
57.06
57.06
57.06
57.06
57.06
IN-RDA01-16-023
57.07
57.07
57.07
57.07
57.07
57.07
57.07
IN-RDA01-16-013
57.12
57.12
57.12
57.12
57.12
57.12
57.12
IN-RDA01-16-012
57.14
57.14
57.14
57.14
57.14
57.14
57.14
IN-RDA01-16-019
57.15
57.15
57.15
57.15
57.15
57.15
57.15
IN-RDA01-16-001
57.31
57.31
57.31
57.31
57.31
57.31
57.31
IN-RDA01-16-022
57.41
57.31
57.31
57.31
57.31
57.31
57.31
IN-RDA01-16-006
57.65
57.31
57.31
57.31
57.31
57.31
57.31
IN-RDA01-16-011
63.00
57.31
57.31
57.31
57.31
57.31
57.31
PROMEDIO
55.70
56.98
56.98
56.98
56.98
56.98
56.98
DS
5.15
0.22
0.22
0.22
0.22
0.22
0.22
X*
56.98
56.98
56.98
56.98
56.98
56.98
56.98
S*
0.22
0.25
0.25
0.25
0.25
0.25
0.25
Pgina 108 de 110


Intervalo de Valor Asignado Zn 56.73 - 57.23 %
62.00
60.00
58.00
56.00
54.00
52.00
50.00
48.00
46.00
44.00
42.00
40.00
38.00
36.00
34.00
32.00
30.00
IN-RDA01-16-006
IN-RDA01-16-011
IN-RDA01-16-022
IN-RDA01-16-023
IN-RDA01-16-022
IN-RDA01-16-001
IN-RDA01-16-019
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-010
IN-RDA01-16-018
IN-RDA01-16-003
IN-RDA01-16-009
IN-RDA01-16-017
IN-RDA01-16-008
IN-RDA01-16-002
IN-RDA01-16-014
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-021
Laboratorios
Pgina 109 de 110
IN-RDA01-16-021
IN-RDA01-16-019
IN-RDA01-16-018
IN-RDA01-16-017
IN-RDA01-16-016
IN-RDA01-16-015
IN-RDA01-16-014
IN-RDA01-16-013
IN-RDA01-16-012
IN-RDA01-16-011
IN-RDA01-16-010
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-007
IN-RDA01-16-006
IN-RDA01-16-005
IN-RDA01-16-003
IN-RDA01-16-002
IN-RDA01-16-004
Grfico de valores individuales para Zn en el Ensayo
62.00
60.00
58.00
56.00
54.00
52.00
50.00
48.00
46.00
44.00
42.00
40.00
38.00
36.00
34.00
32.00
30.00
IN-RDA01-16-001
Concentracin ( Zn %)
IN-RDA01-16-004

--------------------------------------------------------------------------------------------------------------------------------------------------Grfico de Sesgo Relativo Porcentual

Valor asignado: Zn = 56.98 %
IN-RDA01-16-011
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-001
IN-RDA01-16-019
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-015
IN-RDA01-16-016
IN-RDA01-16-010
IN-RDA01-16-018
IN-RDA01-16-003
IN-RDA01-16-009
IN-RDA01-16-017
IN-RDA01-16-008
IN-RDA01-16-002
IN-RDA01-16-014
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-021
Laboratorio
Pgina 110 de 110
IN-RDA01-16-011
IN-RDA01-16-006
IN-RDA01-16-022
IN-RDA01-16-001
IN-RDA01-16-019
IN-RDA01-16-012
IN-RDA01-16-013
IN-RDA01-16-023
IN-RDA01-16-015
IN-RDA01-16-016
Laboratorio
IN-RDA01-16-010
IN-RDA01-16-018
IN-RDA01-16-003
IN-RDA01-16-009
IN-RDA01-16-008
IN-RDA01-16-002
IN-RDA01-16-014
IN-RDA01-16-005
IN-RDA01-16-007
IN-RDA01-16-021
30.0
25.0
20.0
15.0
10.0
5.0
0.0
-5.0
-10.0
-15.0
-20.0
-25.0
-30.0
-35.0
-40.0
-45.0
-50.0
-55.0
-60.0
-65.0
-70.0
-75.0
-80.0
-85.0
-90.0
IN-RDA01-16-017
Grfico de Z-Score
Zn= 56.98 %, = 0.25
IN-RDA01-16-004
z-score
IN-RDA01-16-004
Sesgo ( % )
12.00
10.00
8.00
6.00
4.00
2.00
0.00
-2.00
-4.00
-6.00
-8.00
-10.00
-12.00
-14.00
-16.00
-18.00
-20.00
-22.00
-24.00
-26.00
-28.00
-30.00
-32.00
-34.00
-36.00
-38.00
-40.00

Informe B - Ensayo de Aptitud in-RDA-02-16-CZN

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Informe B - Ensayo de Aptitud in-RDA-02-16-CZN

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__________________________________________________________________

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

Antecedentes Generales ............................................................................................................. 3

Laboratorios Participantes ........................................................................................................... 4

Descripcin de las Muestras ....................................................................................................... 4

Identificacin de las Muestras ..................................................................................................... 4

Preparacin de las Muestras ....................................................................................................... 5

Test de Homogeneidad ............................................................................................................... 5

Declaracin de la Confidencialidad ............................................................................................. 5

Requerimientos de Anlisis ......................................................................................................... 5

Resultados de anlisis ......................................................................................................... 5-7

Anlisis Estadstico para el Ensayo de Aptitud ....................................................................... 8

Evaluacin del desempeo de los laboratorios ................................................................... 8

Valores Asignados ........................................................................................................... 9

Resultado del desempeo de los laboratorios ......................................................... 10-21

Comentarios ..................................................................................................................... 22-23

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

--------------------------------------------------------------------------------------------------------------------------------------------------ALFRED H. KNIGHT DEL PER S.A.C.

LABORATORIO QUMICO CASTRO

ALEXSTEWART ASSAYERS ARGENTINA S.A.

LABORATORIOS ANALITICOS DEL SUR EIRL.

LABORATORY SERVICES INTERNATIONAL

MINERA CENTINELA AMSA

LABORATORIO QUMICO CONDE MORALES

MINERA SAN CRISTOBAL S. A.

ERSA GLOBAL MEX, S.A. DE C.V.

NYRSTAR MINERA EL TOQUI

INSPECTORATE CHILE LTDA..

SGS DEL PER S.A.C.

INSPECTORATE SERVICES PERUS.A.C.

EMPRESA MINERA SINCHI WAYRA S. A.

LABANNCY CIA. LTDA.

STEWART BLAITT Y CIA. LTDA.

4. Descripcin de las Muestras

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

--------------------------------------------------------------------------------------------------------------------------------------------------6. Preparacin de las Muestras

10. Resultados de anlisis

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

Ag (g/T) Co (g/T) Cd (g/T) Ni (g/T)

As (g/T) Sb (g/T) Mn (%) SiO2 (%)

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

Ag (g/T) Co (g/T) Cd (g/T) Ni (g/T)

As (g/T) Sb (g/T) Mn (%) SiO2 (%)

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

--------------------------------------------------------------------------------------------------------------------------------------------------11. Anlisis Estadstico para el Ensayo de Aptitud

Evaluacin del desempeo de los laboratorios

: Promedio para cada laboratorio = xi/ r

: Valores individuales de cada laboratorio

: Nmero de replicados informados

: Desviacin estndar (estimador de la reproducibilidad o varianza entre laboratorios).

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

11.1.1 Valores Asignados

Concentrado de Zinc IN-200

Concentrado de Zinc IN-201

(*): Valor estimativo

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

--------------------------------------------------------------------------------------------------------------------------------------------------11.1.2 Resultado del desempeo de los laboratorios

Plata (Ag) Concentrado IN-200

Arsnico (As) Concentrado IN-200

INSTITUTO NACIONAL DE TECNOLOGA, ESTANDARIZACION Y METROLOGA LTDA.

Cadmio (Cd) Concentrado IN-200

Cobalto (Co) Concentrado IN-200