Constantes de antoine

NH3
A
B
C

4.4854
926.132
240.17

1 bar=750.0617mmhg

log10Pvap=A-[B/(TC+C)]bar

C=g_nh3/
100g_h20
0.105
0.244
0.32
0.38
0.576
0.751
1.02
1.31
1.53
1.71
1.98
2.11
2.58
2.75
3
H2O
5.11564
1687.537
230.17

Presion
parcial
mmhg
0.791
1.83
2.41
2.89
4.41
5.8
7.96
10.31
11.91
13.46
15.75
16.94
20.86
22.38
23.5

@25C

Y con Pt=585
X
0.0013539675 0.00111176
0.0031380215 0.00258353
0.0041366999 0.00338824
0.0049646974 0.00402353
0.0075957216 0.00609882
0.0100138122 0.00795176
0.0137945376
0.0108
0.0179401068 0.01387059
0.0207820761
0.0162
0.0235504077 0.01810588
0.0276679842 0.02096471
0.0298207936 0.02234118
0.036976637 0.02731765
0.0397781807 0.02911765
0.0418521817 0.03176471
nh3
temperaturas

Equilibrio
0.045
0.04
0.035
0.03
0.025
0.02
0.015
0.01
0.005
0

presiones de saturacin
Bar
mmHg
xA
20 8.42716223 6320.89146
21 8.6958341 6522.41193
22 8.97092362 6728.74604
23 9.25252528 6939.96466
24 9.54073376 7156.13879
25 9.83564393 7377.33961
26 10.1373508 7603.6384
27 10.4459497 7835.10655
28 10.7615357 8071.81556
29 11.0842045 8313.83703
30 11.4140515 8561.24262

0.005

0.01

PA=PA*xA
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

0.015

0.02

yA=PA/(Pt-PA)

0
0
737.733961
1.2610836946
1475.46792
2.5221673891
2213.20188
3.7832510837
2950.93585
5.0443347782
3688.66981
6.3054184728
4426.40377
7.5665021673
5164.13773
8.8275858619
5901.87169 10.0886695564
6639.60565
11.349753251
7377.33961 12.6108369455

0.025

ilibrio

0.02

0.025

0.03

0.035

ln(p)=A-B/(C+T_K)
NH3
A
B
C

t_C
H2O

16.9481
2132.5
-32.98

18.3036
3816.44
-46.13

PA_mmHg
0 3193.81918
5 3827.83155
10 4554.6158
15 5382.59754
20 6320.39013
25 7376.7557
30 8560.56636
35 9880.76585
40 11346.3321
45 12966.2411
50 14749.4318
55 16704.7735
60 18841.0342
65 21166.8513
70 23690.7048
75 26420.8916
80 29365.5032
85 32532.4045
90 35929.2155
95 39563.2945
100 43441.7239

@20C
PH2O_mmHg
4.4485141199
6.3907113353
9.0416025845
12.6099982234
17.3514645832
23.5752794626
31.6517822929
42.0200540264
55.1958541016
71.7797358501
92.4652575183
118.047203668
149.429731065
187.63435413
233.807687547
289.2288674
355.316577258
433.635611515
525.902915052
633.993045553
759.943012475

xA
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

xA

Pt=xA*PA+
(1-xA)*PH2O yA=(PA/Pt)*xA
17.351464583
0
647.6553312
0.9758879185
1277.9591978
0.9891380165
1908.2630644
0.9936350363
2538.566931
0.995898915
3168.8707977
0.9972622007
3799.1746643
0.9981731333
4429.4785309
0.9988248189
5059.7823975
0.9993141419
5690.0862641
0.999695058
6320.3901307
1

0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

P VS xA

P VS xA/yA @20C
xA

1000

yA

800

7000

600

6000
Presin en mmHg

5000

400

4000
Presin en mmHh 3000

200

2000

-0.

1000
0
-0.1 0.1

0.3

0.5

xA,yA

0.7

0.9

1.1

@30C
Pt=xA*PA+
(1-xA)*PH2O yA=(PA/Pt)*xA
31.651782293
0
884.54324034
0.9677951255
1737.4346984
0.9854259698
2590.3261564
0.9914465414
3443.2176145
0.9944844992
4296.1090725
0.9963162269
5149.0005306
0.9975411319
6001.8919886
0.9984179098
6854.7834467
0.9990765053
7707.6749047
0.9995893472
8560.5663628
1

P VS xA/yA @30C
10000
8000
6000
Presin en mmHg

4000
2000
0
-0.1 0.1

0.3

0.5

Axis Title
xA

yA

0.7

0.9

1.1