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Uv8
D.R. Manenti , P.A. Soares , A.N. Mdenes , R. Bergamasco , S.M. Palcio , V.J.P. Vilar . (1) Programa de PsGraduao em Engenharia Qumica da Universidade Estadual de Maring, Av. Colombo 5790, Maring-PR, Brasil,
diegomanenti@hotmail.com. (2) LSRE Laboratory of Separation and Reaction Engineering Associate Laboratory
LSRE/LCM, Faculdade de Engenharia, Universidade do Porto (FEUP), R. Dr. Roberto Frias, Porto, Portugal. (3)
Programa de Ps-Graduao em Engenharia Qumica da Universidade Estadual do Oeste do Paran, R. da Faculdade
645, Toledo-PR, Brasil.
determined
by
analyses
throughout
the
experiments.
A new experiment, considering the optimum
photo-Fenton variables values, was carried out in a
pilot plant installed at FEUP, Portugal. The solar
collector consists of a CPC unit (illuminated volume
(Vi) = 5.1 L; Vi/Vt = 0.34; illuminated time (ti) = 0.25
min; dark time (tdark) = 0.50 min; ACPC = 0.455 m2) of
four borosilicate tubes (SchottDuran type 3.3,
Germany, cut-off at 280 nm, internal diameter 50
mm, length 1500 mm and width 1.8 mm) connected
in series by polypropylene junctions, with their CPC
mirrors in electropolished anodized aluminum,
supported by a aluminum structure, oriented to
south and tilted 41 (local latitude). A volume of 15
L of electro-treated textile wastewater was added to
the recirculation tank of the CPC units and
homogenized by turbulent recirculation. The pH
was adjusted (2.8) with sulfuric acid, and iron
sulfate salt (100 mg Fe2+ L-1) was added. In the
kinetic experiment the first dose of H2O2 added was
500 mg L-1 and during the reaction the
concentration was maintained between 100 and
500 mg L-1 by the addition of small amounts of H2O2
as consumed, measuring the concentration of H2O2
in small time intervals. For biodegradability tests, a
new photo-Fenton experiment was performed
maintaining all parameters, with exception for H2O2
dose. In this case, a small amount of H2O2 was
added to photoreactor, and after H2O2 total
consumption, a sample was taken for bioassays
and a new dose of H2O2 was added. The intensity
of solar UV radiation is measured by a global UV
radiometer (ACADUS 85-PLS), which provides data
in terms of incident W UV m-2. A final experiment,
considering the consumption of H2O2, amount of UV
radiation (integrated by the UV radiometer) or
partial mineralization, was carried until reached the
biodegradability set point. At this moment the
reaction stopped, and the pre-treated textile
wastewater was neutralized with NaOH to a pH
around 7, leading to iron precipitation, followed by a
period of three hours for sedimentation of iron
sludge. After that, the electro-photo-treated was
submitted to the biological aerated reactor.
The lab-scale biological oxidation reactor is
composed by a cylindrical glass container (1 L),
equipped with a magnetic stirrer and a compressor
to supply air. pH, temperature and dissolved
oxygen were monitored by a multiparameter Hanna
(model HI 9829). The biological reactor was firstly
colonized using activated sludge from a
conventional municipal wastewater treatment plant,
and small amounts of electro-photo-treated textile
wastewater was added during three days in order to
adapt the biomass. After this preliminary adaptation
period, the electro-photo-treated (1 L) was added
into the biological reactor, after settling the biomass
present inside. The biological reactor was operated
under aerobic conditions, to promote nitrogen
removal and also to remove biodegradable organic
compounds. pH was controlled between 7.5 and
8.5, and oxygen concentration was maintained
between 0.5 and 2 mg O2 L-1.
discharge limits
legislation.
imposed
by
the
Portuguese
Conclusions
Considering the combination of a EC, photoFenton reaction and a biological oxidation system,
in order to reach a final COD < 150 mg O2 L-1, the
energy dose required for the photo-Fenton reaction
is 6.9 kJUV L-1 (t30W = 60 min; T = 30 oC; pH = 2.8;
-2
Figure 2. Electrocoagulation/solar-photo-Fenton/biological treatment sequence of the real textile wastewater. I1, I2 and I3 =
intervals between each process (pH adjust, addition of iron and sludge).
Acknowledgements
Diego R. Manenti and Petrick A. Soares acknowledge their Ph.D. fellowships (BEX 9794/11-5 and 5512/10-7
processes) supported by CAPES. V. Vilars acknowledges Cincia 2008 Program.
References
[1] V.J.P. Vilar, L.X. Pinho, A.M.A. Pintor, R.A.R. Boaventura, Solar Energy, 85 (2011) 1927.
[2] C. H. Langford, J. H. Carey. Canadian Journal Chemistry, 53 (1975) 2430.
[3] F.R. Espinoza-Quiones, M.M.T. Fornari, A.N. Mdenes, S.M. Palcio, S.M. Silva, N. Symanski, A.D.
Krumov, D.E.G. Trigueros, Chemical Engineering Journal, 151 (2009), 59.
[4] S.M. Palcio, F.R. Espinoza-Quiones, A.N. Mdenes, C.C. Oliveira, F.H. Borba, F.G. Silva Jr., Journal
of Hazardous Materials, 172 (2009) 330.