Documentos de Académico
Documentos de Profesional
Documentos de Cultura
The Oil Sands and Heavy Oil Technology Conference & Exhibition
July 14-16, 2009
Calgary, Alberta, Canada.
Introductory Remarks
on Agenda
& Terminology
POST CRASH
-
Section
Introduction
Section Topics
What we will cover
Terminology HC -101
What is Bitumen ?
Bitumen Recovery
Mining
Extraction & Froth Treatment
Tailings Management
Water use
Costs
Alternatives
min
10
15
40
In Situ Recovery
Thermal Methods and Costs
Reasons and Alternatives to SAGD
New Technologies
4
Why Upgrade ?
Upgrading
Break
20
40
30
min
Section
Section Topics
30
Where to Upgrade
15
Environmental
Challenges
30
Summary
10
Q&A
30
Overview of Key Points
15
30
Light Products
Heavy Products
%wS
< 0.5
2 to 3 %
4 to 5 %
What Is Bitumen ?
Location of the main deposits
Quality (fractions) v. Conventional Crudes
History of Development Landmarks
Production Projections
Markets
What is Bitumen ?
8
Albian
Bitumen
1,600 billion bbl
in place
Saudi
270
AB-Can
Recoverable
175
4 billion
produced
to date
9
Naphtha
40%
Distillate
20%
Gasoil
Residue
0%
n
vy
e
a
m
e
u
H
t
Bi
ab
r
A
y
a
M
10
5
actual
planned
2030
2
1
1960
1980
2000
2020
2040
11
4
Peace River In Situ
million
barrels
per day
2
1
Athabasca Mining
2000
LENEF Consulting (1994) Limited
2010
2020
2030
12
PRODUCTION
OR
RECOVERY
UPGRADE
TO
SYNTHETICS
REFINING
MARKETS
DILBIT/SYNBIT/Variants
DILUENT
may still need some
PARTIAL
FIELD
UPGRADE ?
in situ or above ground
LENEF Consulting (1994) Limited
13
4
million
barrels
per day
will more
move to US ?
(see later)
2
1
Alberta Upgraders
2000
LENEF Consulting (1994) Limited
2010
2020
2030
14
Source: CAPP-2008
15
Pacific rim
Fort McMurray
Edmonton
PADD V
PADD IV
PADD II
existing
pipelines
PADD I
PADD III
Courtesy Enbridge
new markets
Canadian
supplied today
Mexico
16
Potential Issues
17
18
Bitumen Recovery
Mining
Thermal in situ
and each may see new developments
19
20
MINING
EXTRACTION
tree clearing
bitumen
froth to
treatment
overburden
slurry
crusher & cyclofeeder
tailings
MFT & CT
containment
sand
storage
TAILINGS MANAGEMENT
tailings oil
recovery
tailings settling
basin
water recycling
Courtesy Syncrude
21
EXTRACTION:
EXTRACTION
tree
clearing produces froth
- Primary
MINING
- Froth Treatment
bitumen
froth to
treatment
overburden
slurry
crusher & cyclofeeder
tailings
MFT & CT
containment
sand
storage
TAILINGS MANAGEMENT
tailings oil
recovery
tailings settling
basin
water recycling
Courtesy Syncrude
22
Naphtha
Inclined Plate
Settler
Scroll
Centrifuge
60% B
30% W
10% S
Froth Tank
Second
Stage
Feed Drum
Cuno Filter
to added
centrifuging
(plant 67)
and Diluent
Recovery
Unit (DRU)
Disc
Centrifuge
Naphtha
Recovery
Unit (NRU)
Tailings
Primary
Conditioned Separation
Cell
Slurry
Deaerator
PSC Froth
Middlings
Primary Flotation
Steam
Froth Screen
Froth Feed
Tanks
Froth
Primary Flotation
Tailings
Screen
Bitumen to
Froth
Treatment
Secondary
Flotation
Thickener
Cyclones
Overflow
Sec Flot
Tailings
Warm
Water
Tank
Froth
Underflow
Tailings
Pond
Recycle
Water Pond
24
Syncrude/Suncor
Gravity sepn.
solvent recovery
Similar
Froth
Shell
Gravity sepn.
solvent recovery
Paraffinic
solvent
LENEF Consulting (1994) Limited
Bitumen Losses
as % of Bitumen on Mined Sand
Froth Treatment
2%
Primary Extraction
Mining 2-3%
8-10%
Source: Syncrude
& others
25
TAILINGS MANAGEMENT
MFT &
gypsum
cycloned total
tailings
CT storage
water recycling
from
plant
beached
total tailings
tailings sand
storage
beach runoff
beached
total tailings
tailings settling
basin (water
MFT & inventory)
water recycling
MFT to make CT
Courtesy Syncrude
26
all figures
are VOLUME
all figures
in m3 based
Key:
make up water
ex. Upgrader
recycle water
7.1
tailings streams
combined
water
9.4
feed ore
4.7
0.5
sand
& clay
~5
bitumen
1.1
froth
Froth
Treatment
4.9
0.8
0.1
1.0
0.63
7.1
bitumen product
tailings pond
water
Hydrotransport
& PSV
sand storage
1.4
2.6
Solids
Water
consolidated
sand, trapped
fines & trapped
interstitial
water
recycle
water from
sand runoff
recycle
water from
pond settling
1.7
0.3
solids
in MFT
water trapped
in pond
water in MFT
30+% w solids
27
Operating Costs
Estimated $ Cdn (2007) / WTI= $90
total $ 18.50
Tailings 2.50
Froth
Treatment 2.00
Primary Extrn
7.00
Source: LENEF/Various
Overburden 2.00
Mining & 5.00
Hydrotransport
energy portion
approx. $ 5.00
@ $ 8 / GJ
28
29
In Situ Recovery
Why?: too much overburden for mining
30
31
SAGD Facility
EAST
Oil Producer
Steam Injector
Steam Chamber
Slots
Oil Sand Formation
Steam Flow
Oil Flow
Q:\Facility\SAGD\Sag-0022.cdr
32
Bitumen Cleanup
diluent
produced gas
produced
fluids
Dilbit
product
produced
water
sand to
disposal
tanks,pumps
etc. not shown
steam to
SAGD
chemicals
STEAM
BOILERS
natural
gas
LENEF Consulting (1994) Limited
WATER
TREATMENT
make up
water
brine to
disposal well
33
Operating Costs
estimated $ Cdn (2007) / WTI=$90
total $ 16.00
miscellaneous
0.90
oil separation
3.50
Capital
water treatment
drilling
1.00
0.60
reservoir
stimulation 10.00
3.00
Source: LENEF/various
energy portion
approx. $ 11
34
PRODUCTION
OR
RECOVERY
UPGRADE
TO
SYNTHETICS
REFINING
MARKETS
DILBIT or SYNBIT
- Recovery Energy
- Diluent for Transport
DILUENT
PARTIAL
FIELD
UPGRADE
10
5
35
diluent for
transport @ $90 WTI
35
Solvent Assisted
In situ combustion/gasification
(old & new!)
Above Ground
Reduced bitumen residues
(raw or emulsified)
along with
NG replacement, all
involve, or
potentially involve,
an element of
partial upgrading
and
reduced diluent
36
Below Ground
reminder
SAGD Facility
EAST
Oil Producer
Steam Injector
Steam Chamber
Slots
Oil Sand Formation
Steam Flow
Oil Flow
Q:\Facility\SAGD\Sag-0022.cdr
Below Ground
(Alternative Recovery Options)
Solvent Assisted
-
37
Below Ground
(partial Combustion/Gasification)
produced
fluids
air
Old
~ 500 m
produced
fluids
air
New
Hz well
38
THAITM PROCESS
Hot gases heat oil
in front of
combustion zone
Air injected in
near vertical
combustion
front
TOE
HEEL
Operating Costs
estimated $ Cdn (2007) / WTI=$90
total $ 16.00
miscellaneous
water treatment
drilling
0.90
oil separation
3.50
Capital
1.00
0.60
reservoir
stimulation 10.00
3.00
Source: LENEF/various
energy portion
approx. $ 11
THAI would
eliminate ~ 80-90% of
the direct energy cost
40
Above Ground
41
Bitumen
lighter
product
Residue
direct combustion
emulsion combustion
could be gasification?
Issues:
- cost vs. benefits
- flue gas desulphurization
- increased CO2 emissions
LENEF Consulting (1994) Limited
42
43
lower viscosity
less/no diluent for long distance transport
residue reduction/destruction (partial upgrade)
energy by product for SAGD recovery
economic at smaller scale (15 to 30,000 b/day)
Other Features:
- Go beyond simple physical processes distillation & deasphalting
- Include thermally bases residue reduction
Ivanhoe HTP
ETX Systems
LENEF Consulting (1994) Limited
44
45
46
47
Conventional
Light / Heavy
crude blend
% volume
o API
32-35
Typical
Sweet SCO
bitumen
100
some ideal
properties
80
60
40
20
naphtha
Jet Fuel
smoke point
> 21
24
Diesel
Cetane
> 45
50
Gas Oil to
conversion
units
UOPk> 11.75
11. 9
30-35
mix
15
~ 11.3
35
residue
11. 3
residue
questions
lowsome
volume
hydrocarbon
lowonquality
poor quality
high
volume
distillates
low quality limit
many refiners
to 10% or less
of crude diet
high volume
high
volume
high
metals
of low
quality
high
coke
feedstock for
precursors
cat cracking
refineries
0
LENEF Consulting (1994) Limited
48
Full Upgrading
Original Coker Based Upgraders
Ebullated Bed upgrading
Natural Gas use and impact
New Approaches to Upgrading
Changing View of SCO Targets
Hydrogen Management
Upgrader By-Products
49
PRIMARY UPGRADE
original
SECONDARY UPGRADE
gas treatment
hydroprocessing
units
coker
bitumen
synthetic
crude oil
bitumen
coke
ebullated bed
hydroprocess
hydrogen
natural gas
residue
50
Light gases
& LPGs
Unstabilized
Naphtha
fractionator
250-300 kPa
Gas oil
stripper
950oF
steam
coke
steam
FR Coker
Gas oil
coke
feed
Delayed Coking
(several licensors)
LENEF Consulting (1994) Limited
51
reactor products
to fractionator
flue gas to CO boiler
and cleanup
scrubber
steam
reactor
feed
burner
coke
steam
air
52
Hydrotreater
53
Pressure
Swing
Absorber
unit
HT
Shift
SMR
CO2
CO
hydrogen
steam
steam
generation
trace
sulphur
removal
Steam
Methane
Reforming
(SMR)
natural
gas
LENEF Consulting (1994) Limited
54
% volume
32-35o API
Sweet SCO
100
some ideal
properties
80
60
40
20
some questions
on hydrocarbon
mix
naphtha
Jet Fuel
smoke point
> 21
24
Diesel
Cetane
> 45
50
Gas Oil to
conversion
units
UOPk> 11.75
11. 9
15
35
11. 3
residue
poor quality
distillates limit
many refiners
to 10% or less
of crude diet
high volume
of low quality
feedstock for
cat cracking
refineries
55
PRIMARY UPGRADE
SECONDARY UPGRADE
gas treatment
hydroprocessing
units
coker
bitumen
synthetic
crude oil
bitumen
coke
ebullated bed
hydroprocess
hydrogen
natural gas
residue
Second generation
56
Courtesy: Axens
57
Slurry Hydroconversion
a new breed of hydroconversion
58
59
Upgrading
Hydrogen
production
added 250
quality
synthetic
quality
today
400
80
Recovery
Mining 300
In Situ 1250
varies!
upgrader fuel
(no coke burning)
Source: OSTRM / various
60
8
7
6
5
4
3
2
1
0
2000
WCSB
2005
2010
2015
2020
2025
2030
61
Asphalt qualityseasonal
DAO for FCCU feed
62
coking
ebullated bed hydroconversion
slurry hydroconversion
SAGD
+ Upgrading
Upgrading
Metals &
Asphaltenes
20
40
60
noncoking thermal
or deasphalting
combinations
80
% volume of
63
SDA Residue
Gasification
Coke
Gasification
NG
$8/mmbtu
$15-20/ barrel
SMR equivalent
$ 5-8 / tonne
SMR equivalent
3
2
feedstock
cost /
000 scf
$ US
capex
other
opex
64
65
Hydrogen
Natural Gas
COKING
OR
ORIGINAL
Bitumen
H +RESIDUE
CONVERSION
HYDROTREAT
Synthetic
Crude
OK quality
HYDROCRACK
Synthetic
Crude
Higher Quality
coke
Bitumen
NEWER
NG-FREE
APPROACHES
HYDROCONVERSION
SDA &/OR
MILD THERMAL
GASIFIER
Hydrogen
66
fuel
gas
Atmospheric
distillation
AGO
Hydrotreater
Vac
column
Frac
hot
HPS
VGO
product
or blend
streams
Hydrocracker
Bitumen
Primary
Upgading
Vac
VGOs
& lighter
VGO
bleed
to gasifier
to gasifier
only main oil flows shown
growing trend
LENEF Consulting (1994) Limited
67
Visbreaking
Light gases
& LPGs
Soaker
drum
Atmospheric
Distillation
Unstabilized
FR Naphtha
Vacuum
Flasher
steam
steam
Visbreaker
LGO
steam
Visbreaker
VGO
feed
steam
Visbreaker
Tar to fuel ,
Gasifer, or
DA Unit
68
Deasphalting
make up
solvent
DAO
separator
Extractor
Feed
100
Pitch
stripper
DAO
stripper
l
su
u
ph
Pitch
40
ic
ke
a
an
di
um
20
% of contaminant
60
DAO
CC
R
solvent
circulation
80
0
0
20
40
60
80
100
69
1/
Courtesy: GE
70
cash flow
$ million/yr
Coking/SMR
Thermal/DAU +Hydrogen
5,000
Capex
@ 12% IRR
4,000
3,000
revenues
opcosts
2,000
1,000
380
0
Capex
IRR
NPV10
LENEF Consulting (1994) Limited
$ 7,000 mil.
15%
$ 3,100 mil
margin
555
margin
$ 7,800 mil.
16%
$ 4,200 mil
71
Primary
Conversion
Secondary
Processing
Hydrogen
Existing
Suncor
Syncrude
Husky, Lloydminster
AOSP (Shell)
OPTI/Nexen
CNRL (S/U now)
Delayed Coking
Fluid Coking/Ebullated Bed H+
E-B H+ / Delayed Coking
E-B H+
Thermal Cracking/De-asph.
Delayed Coking
Hydrotreating
Hydrotreating
Hydrotreating
Hydrotreating
HYDROCRACKING
Hydrotreating
SMR
SMR
SMR
SMR + 3rd party
Resid gasification
SMR
De-asphalting/Pyrolysis
none
none
E-B H+
HYDROCRACKING
Resid gasification
* North West
*
*
*
*
Petro-Can/UTS
Total
Statoil
Delayed Coking
Hydrotreating
SMR
all full upgrader projects have signalled intent to consider gasification in later expansions
* Total / Fort Hills/NWU & BA all delayed pending better times/next stage of funding
LENEF Consulting (1994) Limited
72
Hydrogen management
fuel gases
54%
distribution
of added
hydrogen
to products
10
2 10
C5+ product
added
hydrogen
ammonia
propane
7
17
butane
to SCO
net
butane
hydrogen
sulphide
20%
80%
total hydrogen
in system
Hydrogen in bitumen feed
LENEF Consulting (1994) Limited
73
Courtesy: BA Energy
74
By-Products
1.
can be
considered
similar
streams
1.a. Asphaltenes
2.
Sulphur:
3.
Carbon Dioxide
75
1.
metric-t/day
Fort McMurray
Suncor (some used for energy)
Syncrude **(some converted to energy)
CNRL
Present
8,200
8,200
_______
16,400
2012
2015
16,000
16,000
8,500
40,500
16,000
16,000
8,500
40,500
400
800 ?
800 ?
4,200 ?
3,200 ?
8,200 ?
?
_____
400
800
16,400
800
400
800
400
800
400
Saskatchewan
Husky Lloydminster
Newgrade/Coop Refinery
76
2.
World Production:
Canadian Production:
Est. by 2030:
Canada Seaborne exports:
Sulphur Business
- World supply/demand now back to short supply (thank you, India & China!)
- but Oil Sands will probably put it back into surplus within 5-10 years
77
78
Pacific rim
Fort McMurray
Edmonton
PADD V
PADD IV
PADD II
existing
pipelines
PADD I
PADD III
Courtesy Enbridge
LENEF Consulting (1994) Limited
new markets
Canadian
supplied today
Mexico
79
today
80
% WTI
60
40
2000
2001
2002
2003
2004
2005
2006
2007 2008
Source: Sproule
LENEF Consulting (1994) Limited
80
81
1.
2.
82
84.40
( 1.50)
( 36.65)
46.35 (51.5% of WTI)
( 10.00)
( 6.00)
30.35
83
Post Payout **
20
6
5
$/barrel
4
$/barrel
10
3
2
1
current
60
90
120
60
120
90
New Royalty
pre-payout post-payout
30.35
30.35
( 2.40)
( 9.45)
27.95
20.90
84
89.75
( 1.00)
(46.45)
( 9.00)
33.30
12.00
21.30
24.00
9.70
the capex
issue in a
nutshell
85
30
20
12% IRR
10
0
* unleveraged
60
80
100
120
86
10.40
8.00
includes
royalty
SAGD
+ UG
27.50
Industry
LENEF Consulting (1994) Limited
8.00
15.70
24.60
Alberta Gov.only
Alberta/Federal Gov
87
Where to Upgrade
Recent Plans for Alberta
Whats Happening to Change the Picture ?
Canada v. U.S. Refineries
88
3.5
Petro-Canada et al
3.0
Total / Synenco
Statoil (NAOSC)
2.5
NWU
B A Energy
CNRL
Nexen-OPTI
2.0
Husky
Syncrude
Suncor
Shell et al
1.5
1.0
0.5
0
2015-2020
Projections
LENEF Consulting (1994) Limited
89
announced
intentions
by U.S. refiners
3
CAPP Projections
some may
never get built
upgraded in
Alberta
Bitumen
largely shipped
to US
0
Current
Bitumen Prod.
Upgrading
2015-2020 projections
LENEF Consulting (1994) Limited
90
Environmental Challenges
the elephant in the room
Greenhouse Gas Intensity
Water Use & Management
Footprint & Land Reclamation
91
POST CRASH
-
Greenhouse Gases
Oil Sands compared to other crude sources
3500
transport
refining
3000
by-product
combustion
2500
end use
0
2000
Canadian Mexico
Light
Heavy
SCO
Bitumen Venezuelan
Blend Upgraded
92
Upgrading
Hydrogen
production
added
quality 250
Recovery
Mining 300
synthetic
quality
today
400
80
In Situ 1250
varies!
upgrader fuel
(no coke burning)
Source: OSTRM / various
93
Energy
Hydrogen
(0.95 GJ HHV)
kg CO2
kg CO2
100
100
(2,400 scf)
5
5
50
50
98
104
20
79
80
53
33
0
NG
Bitumen
Residue
Note:
- Expected increase in CO2
Pet Coke
CO2 dilute
CO2 capture ready
NG
Bitumen
Residue
Pet Coke
Note:
- Expected increase in total CO2
- Res./Pet coke have lower dilute CO2
94
kg CO2
per m3
35 API
crude
blend
22 API
crude
low
6,000
Bitumen Recovery
Upgrading and Refining
high
Capture
ready CO2
5,000
Dilute CO2
?
4,000
3,000
2,000
Production
Refining
By-Products
Trans.Fuel
end use
95
Bitumen Recovery
Upgrading and Refining
worst case
Dilute CO2
5,000
4,000
Capture
ready CO2
by-product
credits
3,000
2,000
by-product
credits
Capture-ready
impact
Production
Refining
By-Products
Trans.Fuel
End use
96
% relative to
O/S Mining
150
new technology
potential
100
50
96A
Carbon Dioxide
Canada:
Alberta:
700 mega-t/year
220 mega-t/year
55 mega-t/year
4
3
current
~2020
97
total
Mega-tonne/yr CO2
150
125
100
75
50
est. capture-ready
25
0
Current
LENEF Consulting (1994) Limited
~ 2020
98
Coal Bed
Methane
15,000
9,000
2,000
10,000
EOR
potential
value-added
opportunities
aquifers
99
6,440
saline aquifers
cost to sequester
$ / tonne
150
Source: CERI-2003
100
50
50
100 M-t/year
100
120 kg/b
106 kg/b
98 kg/b
91 kg/b
$ 2 cents/barrel
$ 12 cents/barrel
$ 6 cents/barrel
$ 59 cents/barrel
102
5
4
3
2
1
0
Fabbisogno totale
Fabbisogno ricircolato
Fabbisogno netto
Mining
Upgrading
103A
$ million / year
14
12
10
8
Universities
Govt.Labs
Totals
6
4
2
0
Extr
Support
Extraction
Support
Technology Technology
Total
Total
Albian Sands
Athabasca
River
settling basin
Syncrude
Suncor
105
$ million / year
16
14
12
10
Universities
Govt.Labs
Industry Totals
Totals
8
6
4
2
0
Tailings
Tailings
LR
Land
Reclamation
Total
Total
106
107
Carbon Capture & Storage (CCS) will accelerate, and the costs
will in the long run be borne by the consumer
Water and mining-based land reclamation are the next (and present !)
environmental frontiers to challenge the industry in Alberta
108
Added reading
Oil Sands
Technology Roadmap
Alberta Chamber of Resources
2004 (www.acr-alberta.com)
Added reading