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Thermochemistry
1 1
ΔHrx = ΔHf° (T ) = HHBr
°
( g,T ) − HH° ( g,T ) − HBr° ( l ,T )
2 2
2 2
∴ ΔHf° (T ) = HHBr
°
( g,T )
We can now tabulate Hf° (298.15K ) values for all known compounds.
e.g.
CH4 (g,T,1 bar) + 2O2 (g,T,1 bar) = CO2 (g,T,1 bar) + 2H2O(l,T, 1 bar)
CH4 (g,T,1 bar) + 2O2 (g,T,1 bar) = CO2 (g,T,1 bar) + 2H2O(l,T, 1 bar)
5.60 Spring 2007 Lecture #6 page 3
ΔHII = HO − HO = 0
2 2
In general,
ν ≡ stoichiometric coefficient
⎛ ∂H ⎞
Recall ⎜ ⎟ = Cp
⎝ ∂T ⎠ p
⎛ ∂ΔH ⎞
∴ ⎜ ⎟ = ΔC p =
⎝ ∂T ⎠ p
∑i ν i C p i (products ) − ∑i ν i C p i (reactants )
, ,
e.g.
CH4 (g,T,1 bar) + 2O2 (g,T,1 bar) = CO2 (g,T,1 bar) + 2H2O(l,T, 1 bar)
T2 ⎛ ∂ΔH ⎞
∫T ⎜ ⎟ dT = ΔH (T2 ) − ΔH (T1 )
1 ⎝ ∂T ⎠ p
T2 ⎛ ∂H ⎞
ΔH (T2 ) = ΔH (T1 ) + ∫ ⎜ ⎟ dT
T1
⎝ ∂T ⎠ p
T2
ΔH (T2 ) = ΔH (T1 ) + ∫ ΔC p dT
T1