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Value
242.07 MW
205 bar
540 C
203.8 kg/s
44.9 bar
540 C
187.7 kg/s
0.075 bar
4
2
87%
Q i [kW ] = m .h
(1)
(2)
Nm3 O2
] = 1.87C + 5.6( H O / 8) + 0.7S
kg fuel
(3)
Nm3 air
] = (1 / 0.21).O2 min
kg fuel
(4)
O2 min[
After determination of the mentioned parameters of the
thermal power plant (TPP), pressure and mass flow rate of
bled steams, which can be achieved via optimization, are to
be ascertained. By using Mollier diagram and
thermodynamic tables for steam and thermodynamic
equations, pressure, temperature, mass flow rate, enthalpy
and entropy of each stream is obtained and given in Table
2.
To calculate the boiler capacity, the h-s diagram of the
plant should be utilized, which is illustrated in Figure 2.
Total heat transfer rate of each package included in the
boiler gives the boiler capacity. For this purpose, the heat
transfer rate of the each package is calculated by Eq. 1.
Here, m is the mass flow rate of water/steam and h is the
126 / Vol. 14 (No. 3)
Va(th)[
Va[
Nm3 O2
] = n.Va(th)
kg fuel
(5)
State
Water
Steam
Steam
Steam
Steam
Steam
Steam
Steam
Steam
Steam/Water
Steam/Water
Steam/Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Fuel
Air
Air
Combustion gas
Combustion gas
Air
Air
Air
Water
T[C]
253.14
538.23
329.08
539.12
327.13
473.48
378.82
289.88
192.23
96.70
62.22
40.32
40.32
40.25
58.31
63.31
45.25
90.00
95.00
122.00
127.00
154.00
185.98
196.47
191.47
218.00
223.00
25.00
26.55
250.00
326.17
179.37
25.00
34.60
25.00
40.56
P [kPa]
20537.00
18929.00
4712.00
4284.00
4523.00
2603.50
1337.20
658.90
267.60
90.04
22.08
7.50
7.50
1510.50
1469.20
86.29
21.16
1427.80
256.50
1386.40
631.50
1345.00
1345.00
2495.00
20620.00
20579.00
4335.00
101.32
102.82
102.07
102.07
101.32
101.32
101.32
101.32
1510.50
m [kg/s]
205.80
203.80
187.70
187.70
16.09
8.65
9.41
9.39
8.94
8.48
4.78
138.10
169.60
171.70
171.70
26.80
31.58
171.70
18.32
171.70
9.39
171.70
205.80
24.74
205.80
205.80
16.09
110.80
325.40
304.20
397.20
418.50
4384.30
4487.80
325.40
169.60
V N ( air ) [
V DG (th ) [
V CO 2 [
Nm 3 Gas
] = V CO 2 + V SO 2 + V N ( fuel ) + V N ( air ) (6)
kg fuel
Nm 3 CO 2
] = 1.87 C
kg fuel
Nm 3 SO 2
] = 0 .7 S
kg fuel
Nm 3 N 2
] = 0 .8 N
kg fuel
(10)
Nm 3 H 2 O
] = 1.244 (W + 9 H )
kg fuel
(11)
Nm 3 Gas
] = V DG (th ) + V H 2O
kg fuel
(12)
Nm 3 Gas
] = VWG (th ) + ( n 1)V a (th )
kg fuel
(13)
V H 2O [
(7)
(9)
VWG (th ) [
V SO 2 [
s [kJ/kg K]
2.8220
6.3269
6.3878
7.1655
6.4046
7.2257
7.2557
7.2925
7.3387
7.3809
7.4559
7.5226
0.5766
0.5757
0.8099
0.8726
0.6418
1.1929
1.2504
1.5493
1.6028
1.8823
2.1971
2.2970
2.2495
2.4990
2.5454
0.0000
6.9544
7.5321
8.2628
7.8957
6.9534
6.9857
6.9534
0.5798
Nm 3 N 2
] = 3.76O2 min
kg fuel
V N ( fuel ) [
h [kJ/kg]
1102.03
3369.00
3016.76
3532.07
3017.01
3401.76
3212.88
3038.84
2851.08
2667.35
2475.13
2345.32
168.75
169.80
245.26
265.05
189.39
378.06
398.19
513.13
533.86
650.17
789.87
837.32
823.55
940.73
958.56
0.00
-160.87
70.40
-4059.27
-4027.97
-162.45
-152.41
-162.45
171.08
(8)
VWG [
Nm air
Va [
] = m fuel .V a
kg fuel
3
Nm air
VG [
] = m fuel .VWG
kg fuel
(14)
(15)
m fuel =
Qboiler
Huboiler
(16)
TG ( OUT ) [ D C ] =
Q i
VG .Cp G
+ TG ( IN )
(17)
(18)
(22)
( ) m ehe m i hi
e
i
Q j Wcv =
T
E D = 1 0
Ti
j
(23)
Q j W cv + E i E e
i
e
( )
E = m [h h 0 T 0 (s s 0 ) + e CH
(24)
(25)
m i = m e
e CH = x n (e CH ) n + R T0 x n ln x n
W net [ MW ] = W T W aux
3. Exergy Analysis
The exergy of a system is defined as the maximum
available work that can be done by the system-environment
combination. Higher values of exergy means a higher value
of obtainable work. The exergy analysis is the composite of
the first and second laws of thermodynamics. In this
analysis heat does not have the same value as work, and
exergy loss represents a real loss of work. When analyzing
novel and complex thermal systems, experience needs to be
supplemented by more rigorous quantitative analytical
tools. Exergy analysis provides those tools and it helps in
locating weak spots in a process. This analysis provides a
quantitative measure of the quality of the energy in terms of
its ability to perform work and leads to a more rational use
of energy (Oktay, 2009).
Conservation of mass, conservation of energy and
exergy destruction equations for any control volume at
steady state with negligible kinetic and potential energy
changes can be written as in Eqs. (21)-(23). By neglecting
the potential and kinetic exergy changes of the system, Eq.
(24) defines the total exergy rate. In Eq. (24), the subscript
0 indicates the reference conditions, which are, in this
study, ambient temperature as 25C and atmospheric
pressure as 101.32 kPa, respectively.
e CH ( fuel ) = .( LHV )
(27)
In Eq. 27, eCH ( fuel ) is the fuel specific exergy, and the
exergy factor based on the lower heating value ( ) is
given by [11],
h
(28)
E P
E
(29)
257.73MW
15.65MW
110.8 kg/s
Net power
242.10 MW
37.16
2,333,445 ton/year
State
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Water
Steam
Steam
Steam
Steam
Steam
Steam
steam
Steam
Steam/Water
Steam/Water
Steam/Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Fuel
Air
Air
Combustion
gas
Combustion
gas
Air
Air
Air
Water
31
32
33
34
35
36
EPH
[MW]
54.60
303.11
209.64
262.84
17.89
10.83
9.92
8.16
5.97
4.00
1.23
14.79
0.25
0.48
1.45
0.26
0.09
4.65
0.55
9.59
0.57
16.08
28.70
3.89
32.42
41.22
3.29
0.00
0.42
18.34
0.51
0.51
0.47
0.47
0.04
0.02
0.02
0.02
0.02
0.02
0.01
0.34
0.42
0.43
0.43
0.07
0.05
0.43
0.05
0.43
0.02
0.43
0.51
0.06
0.51
0.51
0.04
694.73
0.00
0.00
Etotal
[MW]
55.12
303.62
210.11
263.31
17.93
10.85
9.95
8.18
5.99
4.02
1.24
15.14
0.68
0.91
1.88
0.32
0.13
5.07
0.60
10.02
0.59
16.50
29.22
3.95
32.93
41.74
3.33
694.73
0.42
18.34
46.00
69.98
115.98
14.92
68.80
83.72
0.00
3.89
0.00
0.49
0.00
0.00
0.00
0.42
0.00
3.89
0.00
0.91
ECH [MW]
Exergy
destruction
[MW]
Percent exergy
destruction[%]
Percent
exergy
efficiency[%]
0.13
14.34
299.10
22.10
11.75
0.47
1.10
1.04
1.11
1.18
1.42
1.23
0.04
3.99
83.29
6.15
3.27
0.13
0.30
0.29
0.31
0.33
0.40
0.34
76.27
55.57
50.22
92.21
27.98
67.53
74.48
82.65
85.41
96.11
86.12
91.58
0.66
0.18
54.91
3.63
1.01
50.57
359.10
100.00
34.84
N [%]
0.58
1.23
0.52
2.00
1.15
0.98
0.27
0.59
1.46
0.31
W [%]
52.00
24.69
49.33
26.25
38.12
27.38
31.17
18.64
24.26
20.36
A [%]
16.07
29.52
16.92
7.47
28.48
11.62
22.32
22.98
19.58
31.36
LHV [kJ/kg]
5876.3
11156.42
6395.4
16084.64
6797
14734
10253.54
13455.42
14625.82
10604.66
Figure 4. Exergy destruction rate, exergy efficiency, and generated net power of the different power plants.
Figure 5. CO2 emissions and fuel rates of the different power plants.
5. Conclusions
In this study, initially a thermal power plant is designed
and then an exergy analysis is performed for this plant. The
exergy destruction rates and exergy efficiencies of each
component of the plant are evaluated. The analysis includes
9 different lignite types. Also fuel rates and CO2 emission
values of each case are determined and compared.
Several important results drawn from this study are
summarized below:
Total generated power of the Sivas Kangal lignite
considered in this study is found to be 242.07 MW and its
net energy efficiency is 37.16 %. Total exergy destruction
and the net exergetic efficiency of the plant is 359.10 MW
and 34.84% respectively. Exergy analysis shows that the
Int. J. of Thermodynamics (IJoT)
Nomenclature
A
Ash [%]
C
Carbon [%]
Specific heat [kJ/kg K, kJ/Nm3K]
Cp
e
Specific exergy [kJ/kg]
E
Time rate of exergy [MW]
FWH Feed Water Heater
Energy efficiency [%]
h
LHV
m
n
N
O
P
Q
S
s
T
W
Subscripts
a
Air
B
Boiler
CH
Chemical
CV
Control volume
D
Destruction
DG
Dry gas
ECO
Economizer
EVA
Evaporator
G
Combustion gas
i
Inlet
KN
Kinetic
o
Outlet
P
Product
PH
Physical
PT
Potential
R.H
Re-heater
S.H
Super-heater
ST
Steam turbine
th
Theoretic
WG
Wet gas
References:
Appendix 1.
Air fan
Air
pre-heater
Boiler
E in
E out
E 35
E 29
W fan
E 29 + E 31
E 30 + E 32
E 1 + E 3
+ E + E
28
E D
W
E 2 + E 4 + E 31
W fp
30
E 3 + E 5
+ E + E
6
E 2 + E 4
W ST
11
E12 + E17
+ E
E 13 + E 34
E11 + E14
+ E
E 15 + E 17
E10 + E15
+ E
E16 + E18
E 9 + E18
+ E
E 19 + E 20
E 8 + E 20
E 21 + E 22
33
16
FWH 5
W ct
+ E 3 + E 28 + E 30
E E E
4
E 7 + E 22
+ E
FWH 2
E 6 + E 25
+ E
E 24 + E 26
E 5 + E 26
E 1 + E 27
E 23
E 7 E 8 E 9
E 10 E11 E
(Wct ) + E12
+ E + E
17
33
E13 E34
FWH 1
Condense
Pump (P1)
E 13
E 14
W P
Circulation
Pump (P2)
E 23
E 25
W P
Overall plant
E 28 + E 35
E 32
E13 + E 34
E12 + E17 + E 33 + W ct
E18 E15
E10 + E19 E16
E 9 + E18 + E 21
E E
E 20 E18
E 9 + E19 E 21
17
18
20
E 8 + E 21
E E
22
E 22 E 20
E E
23
E 23
E 7 + E 22 + E 24
E 7 + E 22
+ E E
E 6 + E 25 + E 27
E E
26
E 5 + E 26
E E
27
W P
+ E E
14
W P
+ E E
23
25
W net + E 28
+ E E
35
fp
WGT
(E2 E5 E6 E7 E8 E9 E10 E11 E12) + (E4 E3)
E 10 + E15 + E19
E E
15
13
W net
31
E15 E14
E11 + E16 E17
24
27
30
E11 + E 14 + E 16
E E
24
24
28
21
Deaerator
( E 2 E 1 ) + ( E 4 E 3 )
E + E + E + W
31
W ST + E 2 + E 4
E E E
19
21
FWH 3
E 30 E 29
E 31 E 32
16
19
FWH 4
fan
E 29 + E 31
E 30 E 32
+ E8 + E 9
+ E + E
10
FWH 6
E 35 E 29
W
W fp + E 1
+ E12
Condenser
+ E 35 E 29
E P
E
F
W fan
Steam
turbine
32
21
E 26 E 25
E27 + E 6 E 24
E 1 E 26
E 5 E 27
E13 E14
W
P
E 23 E 25
W
P
W net
E 28 + E 35