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STATES OF MATTER
1.
2.
3.
4.
5.
6.
or
V
T
cons tan t ,
V1
T1
V2
T2
7.
or
P
T
const ,
P1
T1
P2
T2
8.
9.
11.
12.
PV
for ideal
n.R.T .
13.
14.
nb
nRT.
16.
17.
18.
19.
20.
21.
22.
23.
dv
dn
24.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Ans 3.
Ans 4.
Ans 5.
It 22400 ml.
Ans 6.
Ans 7.
Ans 8.
P1 = X1 x P (total)
Ans 9.
76
Q.2
Q.3
Q.4
Q.5
Q.6
Q.7
P.V 2 .T 2
?
n
temperature?
Q.8
Q.9
77
Ans 5.
Ans 6.
N .m
(m 3 ) 2 ( K ) 2
mal
N .m 4 k 2 mal
Ans 8.
n2 a
v2
nb
n.R.T .
Ans 9.
Ans 10. Surface tension can explain (i) capillary action. (ii)
Spherical shape of small drops of liquid.
Three Marks Questions
Q.1
Ans
PV
nRT , or T
Or T
Q.2
PV
nR
50. Ans
Ans.
P1V1
T1
P2 V2
,
T2
1 x v2
1 x 34 .05
at 0 o C
(54 b 273 ) 273
Or V2 = 11.35 ml
Now 11.35 ml of vapours at 0 oC and 1 bar pressure weight
0.0625 gm
78
Q.3
20
10moles, n(O2 )
2
n( H 2 )
x P( total )
n ( H 2 ) n (V2 )
80
32
2.5contest.
10
x 1bar
10 2.5
0.8bar
P2 = ?
or P2
500
200
2.5 bar
Ans
no2
=
Q.6
4
32
nH 2 x
RT
V
0.0821 x 273
2
x
2
1
1
8
1 22 .4
25 .2 atm. Ans
79
Ans
inside the balloon gas exerts pressure and size becomes larger.
Q.8
What do you mean by ideal gas and real gas? Why do real
gases deviate from ideal behaviors?
Ans
PV
n RT
P
n
. RT
v
m 1
m RT
, , R.T .
.
M V
V M
RT
P.
(Where P
M
PxP
RT
M
m
)
v
const.
Q.10 Critical temperature of CO2 and CH4 gases are 31.10C and 81.90C respectively. Which of these has strong intermolecular
forces & why?
Ans CO2 has strong vander waals forces of attraction than CH4. b/c
of greater polarity and high molecular wt.
80
Ans
1Atm
PM
, O2 at 250 C , 1atm, O2 at O 0 C , 2 atm, O2 at 2730 C , 1 atm.
RT
PM
P
, R, M are constant, so d depends upon
so at 250C,
RT
T
P
T
1
P 1
o
Hence increasing order of
, At 273 C, 1atm
298
T 546
P,V , P2 V2
200 x10 1 x V2 or
Total Volume
2000 L
4 x 10 6
Volume for 1breath 0.5 x 10 3 L
81