Documentos de Académico
Documentos de Profesional
Documentos de Cultura
BATCH 2014
GROUP 1
Hassan Ali
M Mohtashim
P-1339031
M Umair Awam
Naveed Aqeel
Shakeel Ahmed
S.M Daniyal Naeem
Mashood ul Haq
Hamza Ishtiaque
Abid Hussain
SUBMITED TO:
SIR FARAZ SUFIYAN
LABORATORY MEASUREMENT OF pH OF
LIVE WATERS AT HIGH TEMPERATURE AND
PRESSURE
TABLE OF CONTENT
INTRODUCTION
CASE OF STUDY
ANALSIS
Well A
Well B
SPE 121695
INTRODUCTION:
This paper describes a new technique for measuring pH on live formation water samples in the
laboratory at high temperature and pressure. The technique involves adding pH sensitive dyes to
pressurized single phase water samples collected using a formation tester and spectroscopically
determining the pH in the laboratory at reservoir conditions. Due to the lack of standard
laboratory techniques for such measurements at high temperatures and pressures, current practice
involves flashing the single phase water sample to ambient conditions, analyzing the flashed
water and gas phases, and then using water chemistry models to predict pH at reservoir
conditions. Uncertainties in the thermodynamic models for formation waters at high temperature
and pressure, as well as uncertainties associated with the flash process and possible precipitation
of salts can propagate as errors into scale and corrosion models. It is proposed that the direct pH
measurement on live water samples described here be used as an additional input for the water
chemistry models to improve confidence in their predictions. This will allow for more efficient
selection of completion materials and planning for scale treatment and mitigation.
Water sampling in exploration wells is usually done to obtain information regarding the scaling
and corrosion potential of the water, understand reservoir connectivity, and establish the salinity
of the water for petrophysical evaluation. Corrosion potential of the water is important for
material selection for tubing, pipeline, and process equipment. Scaling potential is critical for the
selection of an optimal development strategy to prevent scale formation by choice of operating
conditions, to select and deploy scale inhibitors when needed, or both. Correct water resistivity is
important for interpreting openhole wireline logs accurately.
two spectra overlay each other unless there is a slight color due to presence of ferrous ions in the
formation water. This recorded spectrum is used as the baseline spectrum for all subsequent runs. The
next step involves transferring a controlled volume of the dye solution into the formation water chamber
and mixing it to create a 7.5% v/v solution of dye in formation water. The formation water in the lines
and in the optical cell is then displaced with this formation water-dye mixture solution, again ensuring
that the pressure in the system is maintained. The pH is calculated from the recorded spectra of the
formation water-dye mixture solution as outlined in the theory section. By varying the pressure and
temperature and recording the spectra at each setting, one can obtain pH as a function of these
parameters. The optical signal is continuously monitored to detect light scattering caused by any solid or
gas coming out of solution because of change in pressure and temperature.
ANALYSIS:
Well A
The zone of interest in Well A is a thick permeable water zone several thousand feet above the oil
productive target and is considered a potential water supply source for secondary recovery. The
actual pH conditions can have a significant impact on equipment design selection based on the
corrosion potential.
Tables 1 and 2 summarize the key details for the two samples (A -1 and A-2) collected in this zone.
The reconditioned samples were flashed to obtain the gas/water ratio (GWR) to generate a gas
stream that is analyzed by gas chromatography and a water stream that is analyzed for all the ions.
For these two samples, the dissolved gas was negligible (very low measured GWR), so no gas
composition is reported as there was not enough gas to conduct a gas chromatographic analysis.
Note the change in pH value from the immediate flash condition to room temperature at which ion
analysis is done, primarily caused by CO2 exchange with ambient air. Solid precipitation was not
observed for these flashed samples. Table 2 lists the key species analyzed for the two streams that
are used as inputs in the model predictions. The electroneutrality imbalance was less than 3% for the
two samples.
Table 1: Sample collection details and physical properties measured by flash process.
Table 3: Summary of pH measurements and model predictions for samples from Well A
Well B
The zone of interest in Well B is a water-bearing section below the oil target and considered
representative of water that may accompany oil production at sometime in the field life. Since there was
no downhole in situ pH measurement made on this sample during sample acquisition, the Chain of
Custody validation could not be implemented for this case. Another point to note is that the reservoir
pressure for this formation is 19,542 psi, which is beyond the calibrated range (10,000 psi) for the
spectroscopic pH method. This limit is not an equipment or process limit, but is a limit imposed by the
pressure range for which the calibration of the dye constants was done.
The live pH measurements compare well with predictions from Model 1 with differences of 0.1 to 0.2
units that are acceptable given the inherent error bars for the measurement and model predictions. Model
2 also agrees well at the lower pressures, but shows larger discrepancies from both measurements as well
as Model 1 predictions at higher pressures.