Documentos de Académico
Documentos de Profesional
Documentos de Cultura
A2
P,0
+ C
P,\T+CP,2T2
+C
P,3T3
Page
314
322
A-B/{C+T)
A3
Wu-Stiel Parameter Y
326
A4
327
A5
330
A6
331
A7
332
Valid at temperature T.
A8
335
A9
336
A10
337
, f* = T / 298.15 K
338
T*= Tl 298.15 K
339
314
Appendix A
Table Al Physical Constants and Perfect-Gas Heat-Capacity Coefficients
Compound Name
Formula
Dipm
pb
CO
111.6
184.6
231.1
272.7
261.4
309.2
301.0
341.9
333.4
336.4
322.8
331.1
371.6
363.2
352.4
398.8
424.0
447.3
469.1
489.5
190.55
305.33
369.85
425.25
408.2
469.80
460.4
507.90
497.5
504.5
488.8
500.0
540.15
530.4
520.5
568.95
594.90
617.65
638.85
658.65
4.599
4.871
4.247
3.792
3.65
3.375
3.39
3.035
3.01
3.12
3.08
3.13
2.735
2.73
2.77
2.49
2.29
2.105
1.955
1.83
99.2
148.3
203.
255.
263.
304.
306.
370.
367.
367.
359.
358.
432.
421.
416.
492.
548.
603.
660.
713.
0.0
0.0
0.0
0.0
0.1
0.0
0.1
0.0
169.3
225.5
266.9
303.1
304.3
336.6
340.5
366.8
394.4
282.4
364.9
419.6
464.8
465.
504.0
518.
537.3
566.7
5.04
4.60
4.02
3.53
3.45
3.17
3.28
2.83
2.62
130.4
181.
240.
300.
0.0
0.4
0.3
0.4
0.5
0.4
238.7
284.0
318.0
393.
443.7
503.
5.47
4.49
4.07
162.
219.
276.
/. Alkanes
methane
ethane
propane
^-butane
isobutane
rc-pentane
2-methylbutane
n-hexane
2-methylpentane
3-methylpentane
2,2-dimethylbutane
2,3-dimethylbutane
-heptane
2-methyl hexane
2,2-dimethylpentane
/j-octane
-nonane
rc-decane
-undecane
-dodecane
2. Alkenes
ethylene
propylene
1 -butene
1-pentene
2-methyl-1-butene
1-hexene
2-methyl-2-pentene
1-heptene
1-octene
3. Alkadienes
propadiene
1,2-butadiene
1,2-pentadiene
CH4
C2H6
C3H8
C
4H10
4H10
5HI2
C 5 H |2
C
6H14
6H14
6H14
6HI4
6HI4
7H16
7H16
7H16
C9H20
C,0H22
CnH24
C
12H26
2H4
C3H6
C
4H8
5H10
5H10
6H12
6HI2
7 14
8H16
C3H4
C4H6
C5H8
350.
351.
440.
464.
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.3
0.3
0.2
0.4
0.011
0.099
0.153
0.199
0.183
0.251
0.227
0.299
0.278
0.272
0.232
0.247
0.349
0.329
0.287
0.398
0.445
0.489
0.535
0.575
0.089
0.144
0.191
0.233
0.236
0.285
0.229
0.358
0.386
0.313
0.255
0.173
Appendix A
315
Jmol-'K"1
Cp.\
Jmol-'K"2
Cp2
Jmol-'-K"3
CP3
Jmol-'K"'
Molecular
Compound Name
Weight
/. Alkanes
1.925E+1
5.409E+0
-4.224E+0
9.487E+0
-1.390E+0
-3.626E+0
-9.525E+0
-4.413E+0
-1.057E+1
-2.386E+0
-1.663E+1
-1.461E+1
-5.146E+0
-3.939E+1
-5.010E+1
-6.096E+0
-8.374E+0
-7.913E+0
-8.395E+0
-9.328E+0
5.213E-2
1.781E-1
3.063E-1
3.313E-1
3.847E-1
4.873E-1
5.066E-1
5.820E-1
6.184E-1
5.690E-1
6.293E-1
6.150E-1
6.762E-1
8.642E-1
8.956E-1
7.712E-1
8.729E-1
9.609E-1
1.054E+0
1.149E+0
1.197E-5
-6.938E-5
-1.586E-4
-1.108E-4
-1.846E-4
-2.580E-4
-2.729E-4
-3.119E-4
-3.573E-4
-2.870E-4
-3.481E-4
-3.376E-4
-3.651E-4
-6.289E-4
-6.360E-4
-4.195E-4
-4.823E-4
-5.288E-4
-5.799E-4
-6.347E-4
-1.132E-8
8.713E-9
3.215E-8
-2.822E-9
2.895E-8
5.305E-8
5.723E-8
6.494E-8
8.085E-8
5.033E-8
6.850E-8
6.820E-8
7.658E-8
1.836E-7
1.736E-7
8.855E-8
1.031E-7
1.131E-7
1.237E-7
1.359E-7
16.0436
30.069
44.096
58.123
58.123
72.150
72.150
86.177
86.177
86.177
86.177
86.177
100.203
100.203
100.203
114.230
128.257
142.284
156.311
170.337
methane
ethane
propane
rc-butane
isobutane
rc-pentane
2-methylbutane
n-hexane
2-methylpentane
3-methylpentane
2,2-dimethylbutane
2,3-dimethylbutane
-heptane
2-methylhexane
2,2-dimethylpentane
-octane
rc-nonane
n-decane
n-undecane
rc-dodecane
2. Alkenes
3.806E+0
3.710E+0
-2.994E+0
-0.134E+0
1.057E+1
-1.746E+0
-1.475E+1
-3.303E+0
-4.099E+0
1.566E-1
2.345E-1
3.532E-1
4.329E-1
3.997E-1
5.309E-1
5.669E-1
6.297E-1
7.239E-1
-8.348E-5
-1.160E-4
-1.990E-4
-2.317E-4
-1.946E-4
-2.903E-4
-3.341E-4
-3.512E-4
-4.036E-4
1.755E-8
2.205E-8
4.463E-8
4.681E-8
3.314E-8
6.054E-8
7.963E-8
7.607E-8
8.675E-8
28.054
42.080
56.107
70.134
70.134
84.161
84.161
98.188
112.214
9.906E+0
1.120E+1
8.826E+0
1.977E-1
2.724E-1
3.880E-1
-1.182E-4
-1.468E-4
-2.280E-4
2.782E-8
3.089E-8
5.246E-8
40.065
54.091
68.118
ethylene
propylene
1-butene
1-pentene
2-methyl-1-butene
1 -hexene
2-methyl-2-pentene
1-heptene
1 -octene
3. Alkadienes
propadiene
1,2-butadiene
1,2-pentadiene
316
Appendix A
Table Al(con/d) Physical Constants and Perfect-Gas Heat-Capacity Coefficients
Compound Name
Tc
Formula
K
Pc
Dipm
CO
1
MPa cm'-mol" debye
4. Alkyl Cyclopentanes
cyclopentane
C5H10
C H
methylcyclopentane
6 12
ethylcyclopentane
C7H14
rc-propylcyclopentane C 8 H 1 6
322.4
345.0
376.6
404.1
511.7
532.7
569.5
603.
4.51
3.78
3.40
3.0
260.
319.
375.
425.
0.0
0.0
0.196
0.231
0.271
0.335
5. Alkyl Cyclohexanes
C H
cyclohexane
6 12
methylcyclohexane
C 7 H |4
C H
ethylcyclohexane
8 16
ra-propylcyclohexane C 9 H |8
353.8
374.1
404.9
429.9
553.5
572.2
609.
639.0
4.07
3.47
3.0
2.80
308.
368.
450.
0.3
0.0
0.0
0.212
0.236
0.243
0.258
0.9
0.6
0.196
0.210
6. Alkyl Cycloalkenes
cyclopentene
cyclohexene
7. Acetylenes
C5Hg
H
6 10
317.4
356.1
506.0
560.5
4.34
acetylene
methylacetylene
1-pentyne
C2H2
C3H4
C5H8
188.4
249.9
313.3
308.3
402.4
493.5
6.14
5.63
4.05
112.7
164.
278.
0.0
0.7
0.9
0.190
0.215
0.164
562.06
591.75
617.16
630.3
617.0
616.2
425.6
637.3
4.895
4.108
3.609
3.732
3.541
3.511
3.21
3.127
259.
316.
374.
369.
376.
379.
0.0
0.4
0.4
0.5
0.3
0.1
C 9 H ]2
C9H12
353.2
383.8
409.3
417.6
412.3
411.5
177.1
228.4
275
0.1
0.212
0.263
0.302
0.310
0.325
0.320
0.326
0.399
CH3Br
CH3C1
CH3F
C2H5Br
C2H5C1
C2H5F
C3H7C1
C4H9C1
276.6
249.1
194.7
311.5
285.5
235.5
320.4
351.6
464.0
416.3
315.0
503.9
460.4
375.3
503.0
542.0
6.61
6.70
5.6
6.23
5.27
5.02
4.58
3.68
138.9
113.2
215.
199.
169.
254.
312.
1.8
1.9
1.8
2.0
2.0
2.0
2.0
2.0
0.153
0.187
0.229
0.191
0.215
0.235
0.218
8. Alkyl Benzenes
benzene
toluene
ethylbenzene
o-xylene
m-xylene
p-xylene
cumene
mesitylene
6H6
C7H8
C
8HI0
^-8^10
*--8^10
C
8H10
9. Alkyl Halides
methyl bromide
methyl chloride
methyl fluoride
ethyl bromide
ethyl chloride
ethyl fluoride
propyl chloride
1-chlorobutane
Appendix
Table Al(con/d)
317
Cpj
J-mol-'-K4
Molecular
Jmol-'K"3
Cp.2
Jmor'K-1 Jmol-'K"2
Compound Name
Weight
4. AlkyI Cyclopentanes
-5.362E+1
-5.011E+1
-5.531E+1
-5.597E+1
5.426E-1
6.381E-1
7.511E-1
8.449E-1
-3.031E-4
-3.642E-4
-4.396E-4
-4.924E-4
6.485E-8
8.014E-8
1.004E-7
1.117E-7
70.134
84.161
98.188
112.214
-5.454E+1
-6.192E+1
-6.389E+1
-6.252E+1
6.113E-1
7.842E-1
8.893E-1
9.889E-1
-2.523E-4
-4.438E-4
-5.108E-4
-5.795E-4
1.321E-8
9.366E-8
1.103E-7
1.291E-7
84.161
98.188
112.214
126.241
-4.151E+1
-6.865E+1
4.631E-1
7.252E-1
-2.579E-4
-5.414E-4
5.434E-8
1.644E-7
68.118
82.145
2.682E+1
1.471E+1
1.807E+1
7.578E-2
1.864E-1
3.511E-1
-5.007E-5
-1.174E-4
-1.913E-4
1.412E-8
3.224E-8
4.098E-8
26.038
40.065
68.118
-3.392E+1
-2.435E+1
-4.310E+1
-1.585E+1
-2.917E+1
-2.509E+1
-3.936E+1
-1.959E+1
4.739E-1
5.125E-1
7.072E-1
5.962E-1
6.297E-1
6.042E-1
7.842E-1
6.724E-1
-3.017E-4
-2.765E-4
-4.811E-4
-3.443E-4
-3.747E-4
-3.374E-4
-5.087E-4
-3.692E-4
7.130E-8
4.911E-8
1.301E-7
7.528E-8
8.478E-8
6.820E-8
1.291E-7
7.700E-8
78.113
92.140
106.167
106.167
106.167
106.167
120.194
120.194
1.443E+1
1.388E+1
1.382E+1
6.657E+0
-0.553E+0
4.346E+0
-3.345E+0
-2.613E+0
1.091E-1
1.014E-1
8.616E-2
2.348E-1
2.606E-1
2.180E-1
3.626E-1
4.497E-1
-5.401E-5
-3.889E-5
-2.071E-5
-1.472E-4
-1.840E-4
-1.166E-4
-2.508E-4
-2.937E-4
1.000E-8
2.567E-9
-1.985E-9
3.804E-8
5.548E-8
2.410E-8
7.448E-8
8.081E-8
94.939
50.488
34.033
108.966
64.515
48.060
78.541
92.568
cyclopentane
methylcyclopentane
ethylcyclopentane
rt-propylcyclopentane
5. Alkyl Cyclohexanes
cyclohexane
methylcyclohexane
ethylcyclohexane
-propylcyclohexane
6. Alkyl Cycloalkenes
cyclopentene
cyclohexene
7. Acetylenes
acetylene
methylacetylene
1-pentyne
8. Alkyl Benzenes
benzene
toluene
ethylbenzene
o-xylene
m-xylene
p-xylene
cumene
mesitylene
10. Alkyl Halides
methyl bromide
methyl chloride
methyl fluoride
ethyl bromide
ethyl chloride
ethyl fluoride
propyl chloride
1-chlorobutane
318
Appendix A
Table Al(con/d) Physical Constants and Perfect-Gas Heat-Capacity Coefficients
Compound Name
10. Refrigerants
Rll
R12
R22
R32
R123
R124
R125
R134a
R141b
RI42b
R143a
R152a
Formula
Pc
pb
Dipm
OJ
CCI3F
CCI2F2
CHC1F2
CH2F2
C2HC12F3
C2HC1F4
C2HF5
C2H2F4
C2H3C12F
C2H3CIF2
C2H3F3
C2H4F2
296.4
243.0
232.3
221.4
301.0
261.1
224.6
247.0
4.403
4.129
4.988
5.83
3.674
3.634
3.631
4.056
4.23
4.246
3.811
4.52
245.7
215.9
168.5
121.
278.1
243.7
209.8
198.1
253.7
263.9
225.8
249.0
471.15
384.95
369.3
351.56
456.94
395.65
339.4
374.21
477.26
410.25
346.25
386.44
CH 4 0
C2H60
C3HgO
C4H,0O
C 5 H, 2 0
C 6 H, 4 0
C7H|60
C g H |g O
C9H20O
C10H22O
C,,H 24 0
337.7
351.4
370.3
390.9
411.1
430.2
449.8
468.3
486.7
506.1
512.6
513.88
536.74
563.01
588.11
610.7
632.5
652.5
671.5
689.0
533.1
330.4
350.3
0.189
0.204
0.221
0.271
193.6
179.5
0.4
0.5
1.4
2.0
1.4
1.5
1.6
2.1
2.0
2.1
2.3
2.3
8.092
6.132
5.168
4.424
3.909
3.47
3.135
2.86
2.63
2.41
118.
167.1
219.
275.
326.
381.
435.
490.
546.
600.
1.7
1.7
1.7
1.8
1.7
1.8
1.7
2.0
1.7
1.8
0.556
0.644
0.623
0.593
0.579
0.560
0.560
0.587
679.
1.92
718.
1.6
506.8
523.2
4.69
3.83
228.
286.
1.7
1.9
0.281
0.299
0.326
0.223
0.251
0.256
11. 1-Alkanols
methanol
ethanol
1-propanol
1-butanol
1 -pentanol
1-hexanol
1-heptanol
1-octanol
1-nonanol
1-decanol
1-undecanol
1-dodecanol
I2 H 26
C3H602
C4Hg02
0.326
0.362
Appendix A
319
Jmol-'K"
Jmol-'K"
JmoHK-
Cp,l
Jmol-'K"4
Molecular
Compound Name
Weight
//. Refrigerants
3.209E+1
2.352E+1
1.864E+1
3.679E+1
0.602E+1
3.277E+1
2.360E+1
1.678E+1
2.162E-1
2.263E-1
1.443E-1
-6.290E-2
5.052E-1
2.189E-1
2.837E-1
2.864E-1
-2.334E-4
-2.335E-4
-3.115E-5
3.754E-4
-7.632E-4
5.751E-5
-1.230E-4
-2.273E-4
8.869E-8
8.586E-8
-6.659E-8
-3.216E-7
5.183E-7
-1.840E-7
-5.672E-8
1.133E-7
1.709E+1
1.791E+1
2.845E+1
2.638E-1
2.156E-1
8.474E-2
-1.369E-4
-1.492E-6
2.449E-4
-1.871E-8
-1.359E-7
-2.837E-7
2.115E+1
9.014E+0
2.470E+0
3.266E+0
3.869E+0
4.811E+0
4.907E+1
6.171E+0
1.280E+0
1.457E+1
7.092E-2
2.141E-1
3.325E-1
4.180E-1
5.045E-1
5.891E-1
6.778E-1
7.607E-1
8.817E-1
8.947E-1
2.587E-5
-8.390E-5
-1.855E-4
-2.242E-4
-2.639E-4
-3.010E-4
-3.447E-4
-3.797E-4
-4.791E-4
-3.921E-4
-2.852E-8
1.373E-9
4.296E-8
4.685E-8
5.120E-8
5.426E-8
6.046E-8
6.263E-8
9.801 E-8
3.451E-8
9.224E+0
1.103E+0
-5.338E-4
7.779E-8
32.042
46.069
60.096
74.122
88.149
102.176
116.203
130.230
144.256
158.283
172.310
186.337
1.655E+1
7.235E+0
2.245E-1
4.072E-1
-4.342E-5
-2.092E-4
2.914E-8
2.855E-8
74.079
88.106
137.368
120.914
86.469
52.024
152.931
136.477
120.022
102.031
116.950
100.496
84.041
66.050
Rll
R12
R22
R32
R123
R124
R125
R134a
R141b
R142b
R143a
R152a
//. 1-Alkanols
methanol
ethanol
1-propanol
1-butanol
1-pentanol
1-hexanol
1-heptanol
1 -octanol
1-nonanol
1-decanol
1 -undecanol
1-dodecanol
12. Alky I Acetates
methyl acetate
ethyl acetate
320
Appendix A
Table Al(con/d) Physical Constants and Perfect-Gas Heat-Capacity Coefficients
Compound Name
pc
Formula
K
r/c
Dipm
CO
13. Monatomics
87.3
3.19
119.9
27.1
165.0
150.8
3.31
209.4
44.4
289.7
4.87
0.114
5.5
2.76
5.84
74.9
72.9
91.2
41.6
118.4
0.0
0.0
0.0
0.0
0.0
0.001
-0.473
0.005
-0.029
0.008
239.2
20.4
77.4
90.2
416.9
33.2
126.2
154.6
7.98
1.3
3.39
5.04
123.8
65.1
89.8
73.4
0.0
0.0
0.0
0.0
0.090
-0.218
0.039
0.025
CO
N0 2
81.7
294.3
304.1
132.9
431.
7.38
3.5
10.1
93.9
93.2
167.8
0.0
0.1
0.4
0.239
0.066
0.834
239.8
213.5
373.2
405.5
373.2
647.3
11.35
8.94
22.12
72.5
98.6
57.1
1.5
0.9
1.8
0.250
0.081
0.344
argon
helium
krypton
neon
xenon
14. Diatomics
chlorine
hydrogen (normal)
nitrogen
oxygen
IS. Inorganic Oxides
carbon dioxide
carbon monoxide
nitrogen dioxide
AT
He
Kr
Ne
Xe
CI2
H
2~
N2
o2
co2
Appendix
Table Al(con/d)
Jmol"'K"'
321
CpA
Jmol-'K"2
Molecular
P,2
Jmol-'K"3
Jmol-'K 4
Compound Name
Weight
13. Monatomics
2.080E+1
2.080E+1
2.080E+1
2.080E+1
2.080E+1
39.948
3.017
83.800
20.179
131.300
argon
helium
krypton
neon
xenon
14. Diatomics
2.693E+1
3.224E+1
3.115E+1
2.811E+1
3.384E-2
1.924E-3
-1.357E-2
-3.680E-6
-3.869E-5
1.055E-5
2.680E-5
1.746E-5
1.547E-8
-3.596E-9
-1.168E-8
-1.065E-8
70.906
2.016
28.013
32.000
chlorine
hydrogen (normal)
nitrogen
oxygen
15. Inorganic Oxides
1.980E+1
3.087E+1
2.423E+1
7.344E-2
-1.285E-2
4.836E-2
-5.602E-5
2.789E-5
-2.081E-5
1.715E-8
-1.272E-8
0.293E-9
44.010
28.010
46.006
2.731E+1
3.194E+1
3.224E+1
2.383E-2
1.436E-3
1.924E-3
1.707E-5
2.432E-5
1.055E-5
-1.185E-8
-1.176E-8
-3.596E-9
17.030
34.076
18.015
carbon dioxide
carbon monoxide
nitrogen dioxide
16. Other Compounds
ammonia
hydrogen sulfide
water
322
Appendix A
Table A2 Vapour-Pressure Coefficients of Antoine Equation
Compound Name
Formula
T
max
K
~YT
m
Km
5.77884
5.94631
6.95075
5.95358
5.91911
5.99028
6.04913
5.72763
5.99479
5.99139
5.87001
5.94371
6.02701
6.00310
397.847
662.404
1467.362
945.089
901.914
1071.187
1081.748
1031.938
1152.210
1162.069
1080.723
1132.099
1267.592
1238.864
-61.890
-16.387
71.564
-33.256
-30.947
-40.384
-33.333
-64.846
-44.579
-44.870
-43.308
-43.656
-56.354
-53.283
91
136
310
195
188
269
218
300
285
288
273
287
298
288
127
200
370
273
263
300
295
321
334
338
320
331
373
363
6.04394
6.06280
6.08321
6.10213
6.10740
1351.938
1430.630
1504.405
1572.831
1627.417
-64.030
-71.323
-78.319
-85.088
-92.661
325
340
269
283
400
400
424
450
470
490
5.87310
5.95357
5.64740
5.97160
584.293
788.339
806.813
1045.272
-18.288
-25.705
-45.514
-39.552
150
166
213
285
190
226
270
305
5.99426
1154.952
-47.068
288
340
6.04107
6.06241
1266.473
1356.472
-52.948
-60.051
293
315
369
400
6.56901
1030.052
-12.571
140
190
6.07423
1130.531
-40.846
213
245
1. Alkanes
methane
ethane
propane
n-butane
isobutane
n-pentane
2-methylbutane
n-hexane
2-methylpentane
3-methylpentane
2,2-dimethylbutane
2,3-dimethylbutane
/i-heptane
2-methylhexane
2,2-dimethylpentane
rc-octane
-nonane
rc-decane
-undecane
n-dodecane
CH4
C2H6
C3Hg
C 4 H ]0
C4H10
C5H12
C5H12
C
6H14
6H14
6H14
6HI4
6H14
7H16
7H16
7HI6
CgH)8
C9H20
C ]0 H 22
H i "24
C 12 H 25
2. Alkenes
ethylene
propylene
1-butene
1 -pentene
2-methyl-1-butene
1-hexene
2-methyl-2-pentene
1-heptene
1-octene
C2H4
C3H6
C4H8
C
5H10
5H10
6H12
6 12
C 7 H, 4
C
8H16
3. Alkadienes
propadiene
1,2-butadiene
1,2-pentadiene
C3H4
C4H6
C5H8
Appendix A
323
Formula
B
K
C
K.
6.02877
5.99178
6.00807
6.03046
1133.199
1188.320
1296.209
1385.284
-40.735
-46.843
-52.755
-59.904
288
288
300
325
325
345
380
405
6.00569
5.95366
5.98475
6.01886
1223.273
1273.962
1348.000
1465.252
-48.061
-51.395
-55.894
-64.759
290
298
316
345
355
374
395
430
T
mm
T
max
K
4. Alkyl Cyclopentana
cyclopentane
methylcyclopentane
ethylcyclopentane
n-propylcyclopentane
5H10
6H12
C 7 H, 4
C
8H16
6H12
7H14
8H16
5. Alkyl Cyclohexanes
cyclohexane
methylcyclohexane
ethylcyclohexane
-propyl cyclohexane
C 9 H ]8
6. Alkyl Cycloalkenes
cyclopentene
cyclohexene
7. Acetylenes
acetylene
methylacetylene
1-pentyne
8. Alkyl Benzenes
benzene
toluene
ethylbenzene
o-xylene
m-xylene
p-xylene
cumene
mesitylene
9. Alkyl Halides
methyl bromide
methylchloride
methyl fluoride
ethyl bromide
ethyl chloride
ethyl fluoride
ethyl iodide
propyl chloride
I-chlorobutane
5H8
6H10
5.99698
1221.700
-50.001
309
365
C2H2
C3H4
C5H8
6.19114
697.810
-21.688
193
207
C 9 H |2
C 9 H, 2
6.01905
6.08436
6.08206
5.94220
6.46290
6.11376
6.06528
6.16365
1204.637
1347.620
1425.305
1387.336
1641.628
1452.215
1464.366
1592.442
-53.081
-53.363
-59.735
-66.741
-42.251
-57.992
-64.915
-66.245
294
308
298
280
285
330
330
360
378
385
365
330
333
412
424
450
CH3Br
CH3CI
CH3F
C2H5Br
C2H5C1
C2H5F
C2H5I
C3H7CI
C4H9C1
6.22430
6.11875
5.10201
6.11352
6.11833
6.34446
6.06765
6.07206
5.94963
1049.898
902.201
406.764
1121.957
1033.161
947.816
1222.418
1120.381
1167.428
-27.831
-29.961
-62.797
-38.409
-34.194
-17.076
-44.782
-44.089
-55.725
203
183
165
300
218
170
300
245
257
277
250
217
348
285
255
330
320
351
6H6
C7H8
CgHjQ
CgH10
^8^10
^8^10
i1
324
Appendix A
Table A2(con/d) Vapour-Pressure Coefficients of Antoine Equation
Compound Name
Formula
T
max
K
B
K
C
~K~
T
min
6.01505
1043.600
-36.566
243
335
6.096617
821.095
-31.640
210
240
6.17338
6.00691
874.648
1049.840
-37.217
-42.820
210
250
260
330
10. Refrigerants
Rll
R12
R22
R32
R123
R124
R125
R134a
R141b
R142b
R143a
R152a
//. 1-Alkanots
CC13F
CC12F2
CHC1F2
CH2F2
C2HC12F3
C2HC1F4
C2HF5
C2H2F4
C2H3CI2F
C2H3CIF2
C2H3F3
C2H4F2
methanol
ethanol
1-propanol
1-butanol
1-pentanol
1-hexanol
1-heptanol
1-octanol
1-nonanol
1-decanol
1-undecanol
1 -dodecanol
CH 4 0
C2H60
C3HgO
C 4 H ]0 O
C5H120
C 6 H 14 0
C 7 H, 6 0
C 8 H 18 0
C9H20O
C|0H22O
CH 2 4 0
C|2H260
7.24693
7.24222
6.87065
6.76666
6.31559
6.20107
6.10824
6.80512
5.83497
5.76028
1605.615
1595.811
1438.587
1460.309
1292.273
1305.984
1323.566
1752.302
1297.059
1315.019
-31.317
-46.702
-74.598
-83.939
-111.313
-119.249
-126.909
-99.080
-147.711
-154.022
274
292
330
296
347
325
336
327
364
378
336
365
377
390
420
430
449
386
486
504
5.70652
1388.338 -163.157
400
538
C3H602
C4H802
6.25449
6.20229
1189.608
1232.542
260
271
351
373
-50.035
-56.563
Appendix A
325
Formula
T
mm
max
13. Monatomics
argon
helium
krypton
neon
xenon
Ar
He
Kr
Ne
Xe
6.99579
448.390
-3.130
72
84
6.20961
540.493
-9.141
127
208
5.13001
395.205
-38.582
161
163
Cl2
H2
6.07922
867.371
-26.253
206
271
5.65650
5.81534
260.222
319.165
-6.069
-6.409
63
55
85
101
co2
7.52161
1384.861
74.840
267
303
NH3
H2S
H20
7.06252
1650.27
-46.804
333
403
14. Diatomics
chlorine
hydrogen (normal)
nitrogen
oxygen
CO
N0 2
326
Appendix A
Table A3 Wu-Stiel Parameter Y
Compound Name
water
ammonia
acetone
ethylene oxide
hydrogen chloride
Y
1.000
0.739
0.652
0.565
0.565
Alcohols
methanol
ethanol
n-propanol
/-propanol
0.652
0.213
-0.052
0.052
AlkyI Halldes
methyl chloride
methyl fluoride
0.304
0.739
Refrigerants
Rll
R12
R22
R32
R123
R124
R125
R134a
R141b
R142b
R143a
R152a
0.015
0.021
0.164
0.704
-0.001
-0.001
0.180
0.073
0.483
Appendix A
ill
XnIR
XnIR
MPa
334.18
335.64
815.39
857.32
1394.84
301.15
496.02
605.66
435.86
518.39
419.71
44.29
210.83
653.13
1082.43
425.06
413.66
374.80
1055.00
1148.34
1117.88
623.34
689.57
614.97
332.75
281.00
261.51
681.35
408.95
143.41
26.87
507.21
536.90
620.44
872.64
800.37
-108.17
-102.17
77.43
-187.85
225.98
-257.34
-100.82
-159.48
10.23
-87.28
-39.66
-15.19
19.21
66.16
152.69
-89.98
-31.42
-26.24
310.77
142.73
81.28
126.78
-37.19
33.79
-100.00
21.33
-12.63
159.13
420.11
64.12
215.96
80.78
137.05
55.91
34.73
112.28
0.1
Alcohol mixtures
methanol
acetone
benzene
chloroform
2,3-dimethylbutane
ethanol
ethyl acetate
ethanol
1-propanol
methyl acetate
2-propanol
acetone
benzene
cyclohexane
ethyl acetate
n-heptane
w-hexane
methylcyclopentane
toluene
benzene
ethyl acetate
2-propanol
fl-heptane
H-hexane
acetone
benzene
carbon tetrachloride
cyclohexane
328
0.1
0.1
0.1
0.1
0.1
313
323
333
0.1
0.1
0.1
0.1
0.1
0.1
313
333
0.1
0.1
0.1
0.1
0.1
348
0.1
313
333
348
0.1
0.1
328
0.1
0.07
0.1
0.1
0.07
328
Appendix A
Table A4(con/d) Wilson Parameters Xx2IR and k2XIR
X2]/R
MPa
145.77
334.35
210.40
921.77
700.02
619.81
411.47
446.76
30.69
20.01
23.01
105.55
212.56
92.15
80.58
52.68
0.1
rc-hexane
methyl acetate
methylcyclohexane
methylcyclopentane
acetone'
cyclohexane
tt-hexane'
methylcyclopentane
ethylcyclohexane
hexylene glycol
n-octane
-84.50
-52.04
71.27
94.22
134.14
49.99
37.05
87.52
115.36
-2.088
81.24
304.16
457.61
118.77
481.86
199.28
26.38
153.13
249.06
103.07
-102.77
40.27
-12.17
147.41 |
183.49 '
85.51
-12.00
181.62
48.98
-100.44
-208.67
-39.29
-227.92
-121.24
805.67
-67.87
0.1
0.05
0.05
0.1
carbon tetrachloride
chloroform
2,3-dimethylbutane
heptane
2,3-dimethylbutane
ethyl acetate
methyl acetate
methyl ethylketone
methyl acetate
327.98
-36.33
477.20
550.00
107.63
-184.93
-227.00
-116.55
173.67
-6.376
-167.18
118.24
79.24
112.56
-46.55
56.98
-118.32
348.05
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
kn)R
Components
1
2- propanol
ethyl acetate
methylcyclohexane
-octane
2,2,4-trimethylpentane
l-butanol
benzene
toluene
Aromatic hydrocarbon mixtures
benzene
toluene
ethylbenzene
Other mixtures
acetone
chloroform
cyclohexane
acetone
carbon tetrachloride
chloroform
cyclohexane
cyclopentane
rc-heptane
313
333
0.07
0.05
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
348
308
303
338
Appendix A
329
rc-hexane
hexene-1
hexylene glycol
water
ll2IR
2
^-heptane
hexene-1
methylcyclopentane
n-octane
1,2,3-trich loropropane
1,2,3-trichloropropane
ethylcyclohexane
acetone
acetonitrile
ethanol
ethanol'
-259.08
208.93
136.92
-233.85
58.57
78.97
1807.76
707.27
810.21
480.80
482.67
444.72
242.63
646.44
575.68
598.08
626.09
-140.83
-88.42
151.76
556.83
286.99
38.72
221.23
349.27
192.38
-95.50
237.04
103.31
511.17
977.43
529.10
methanol
1-propanol
see References
Xn/R
MPa
K
365
0.1
0.1
422
0.1
0.1
0.05
0.1
0.1
0.1
283
343
0.1
0.1
313
333
330
Appendix A
Table A5 T-K-Wilson Parameters knIR and X2XIR
Cornponents
1
Water mixtures
water
luIR
X2lIR
MPa
acetonitrile1
rt-butanol
ethyl acetate1
triethylamine
1098.8
316.11
1343.3
1120.9
-516.04
273.05
-751.71
-682.23
0.104
0.208
0.063
0.125
0.1
0.1
0.1
0.1
333
298
333
338
cyclohexane
acetonitrile1
61.91
-14.91
994.00
105.02
2.674
1.653
0.1
0.1
298
333
Other mixtures
methanol
ethyl acetate
see References
Appendix A
Table A6 NRTL (Renon) Parameters gyJR, g2\IR
Components
1
SnIR
K
an
331
au
K
MPa
Alcohol mixtures
ethanol
methanol
ethyl acetate
rc-heptane'
151.47
565.80
162.03
345.19
0.300
0.200
0.1
0.1
343
303
acetone1
2-propanone2
H-hexane1
-50.46
211.69
86.16
446.09
14.07
-6.934
0.3017
0.200
0.3001
0.1
0.1
0.1
308
283
303
cyclohexane1
w-heptane'
rt-hexane1
acetonitrile2
^-heptane'
-octane'
acetonitrile2
ethanol'
693.79
553.74
632.43
224.87
616.19
453.85
618.29
112.43
-61.03
491.14
1451.90
671.80
250.69
1643.20
0.4841
0.2911
0.2913
0.300
0.316
1.8262
0.300
0.2978
0.2974
0.300
0.200
0.400
0.200
0.200
0.1
0.1
0.1
0.1
0.01
0.02
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
298
338
293
333
Other mixtures
acetone
ethyl acetate
H-hexane
water
ethanol
ethyl acetate2
ethyl acetate
2-propanone2
toluene2
'2 see References
881.97
545.25
583.83
618.29
-363.99
-175.17
224.88
245.98
673.23
44.28
48.77
1263.08
366.44
1057.60
333
283
343
343
333
343
283
283
332
Appendix A
Table A 7 UNIQUAC Parameters unIR and ulxIR
Components
1
unIR
u2i/R
-96.90
-56.05
-38.37
-50.58
-143.50
-7.18
660.19
-107.54
-83.96
-95.31
2.49
4.84
-2.66
-119.36
-131.25
68.72
-123.54
-138.90
-235.47
-68.00
-90.10
-113.70
-148.29
-154.11
-167.61
-118.27
-130.78
-127.48
-110.15
-108.93
-103.04
-123.57
210.95
-132.12
-141.16
359.10
988.60
902.56
912.41
926.31
1463.90
-292.39
579.61
508.39
516.12
1419.33
1325.89
1636.05
414.46
404.49
430.51
920.39
947.20
1315.02
1349.20
1369.41
1269.49
594.60
574.22
571.73
1383.93
573.43
1254.65
1356.90
1441.57
1425.20
1425.20
-67.70
1083.75
1009.48
328-337
308
318
331-343
326-336
317-333
338-349
335-347
308
323
306
332
322-336
305
321
293
324-329
340-351
328
278
308
338
313
328
343
333-349
320
352-433
333
331-349
318
348
333
308
328
Alcohol mixtures
methanol
acetone
benzene
chloroform
2,3-dimethylbutane
ethanol
ethyl acetate
methyl acetate
rc-heptane
ethanol
-hexane
acetone
acetonitrile
benzene
chloroform
cyclohexane
ethyl acetate
methylcyclopentane
methyl acetate
rc-decane
n-heptane
-hexane
-octane
-propanol
toluene
Appendix A
Table A7(con/d) UNIQUAC Parameters u.JR and u7JR
Components
I
rt-propanol
-butanol
uuIR
2
benzene
cyclohexane
ethyl acetate
rc-decane
rc-hexane
toluene
benzene
cyclohexane
rc-hexane
/i-octane
u2xIR
-155.10
-136.92
-173.42
-190.31
-201.82
-144.11
-195.40
-181.24
-175.51
-198.09
-159.24
-236.21
928.50
1328.49
1284.75
539.64
1137.20
1326.05
818.34
928.90
1299.00
1591.50
1370.74
1098.91
318
298
338
333
363
318
369-377
318
298
318
298
382-388
147.12
174.00
247.13
43.39
-121.79
4.33
-11.20
-16.69
33.15
-181.49
-192.00
-6.47
-143.88
-207.37
19.07
-32.03
27.92
-77.13
-220.57
123.57
-44.04
-214.26
-48.05
-72.96
4.30
-90.40
-108.79
-51.54
-37.52
83.58
65.28
70.13
69.48
15.19
233.81
248.71
56.47
203.46
278.33
31.35
87.50
31.94
132.43
330.69
-82.85
83.67
309.41
89.77
108.24
34.27
303
318
318
313
336-352
283
313
343
322-352
323
343
344-352
323
330-350
318
333-347
298
341-352
354-378
352-383
354-381
351-382
345-381
371-383
298-329
acetone
acetonitrile
carbon tetrachloride
chloroform
cyclohexane
cyclopentane
ethyl acetate
methylcyclopentane
methyl acetate
rc-heptane
rc-hexane
toluene
toluene
2-butanone
cyclohexane
ethyl acetate
methylcyclopentane
rt-heptane
-hexane
333
334
Appendix A
Table A7(con/d) UNIQUAC Parameters unIR and u2l/R
Components
u2l/R
ethyl acetate
-105.50
137.11
333
rt-hexane
n-pentane
acetonitrile
cyclohexane
methylcyclopentane
acetone
acetonitrile
benzene
ethyl acetate
-33.08
-22.83
545.79
-145.56
-138.84
-117.85
61.92
115.13
-107.58
80.91
-222.02
284.81
380.68
387.38
148.27
1097.59
583.03
305.71
261.51
266.31
23.71
172.73
162.13
572.52
294.10
2057.42
877.04
569.86
1081.40
-27.38
-64.56
-71.06
-50.82
38.69
78.37
1371.36
318
305-322
318
343-352
333
309-339
350-364
298
313
323
343
313
328
351-372
338-368
365-384
333
323
1
ethylbenzene
unIR
2
Other mixtures
Thermophysical Properties of Fluids Downloaded from www.worldscientific.com
by 187.209.238.252 on 01/10/15. For personal use only.
acetone
-heptane
n-hexane
water
ethanol
methanol
-butanol
rc-propanol
toluene
Appendix A
Table A8 UNIQUAC Parameters r, q and q'
r
<7
<?'
1.43
2.11
2.78
3.45
1.43
1.97
2.51
3.05
0.96
0.92
0.89
0.88
3.19
3.92
4.60
4.66
2.40
2.97
3.51
3.54
2.40
2.97
3.51
3.54
1.80
2.48
3.15
3.82
4.50
5.17
5.85
7.20
1.70
2.24
2.78
3.31
3.86
4.40
4.94
6.02
1.70
2.24
2.78
3.31
3.86
4.40
4.94
6.02
2.57
1.87
3.25
3.33
2.70
3.97
3.30
3.48
2.80
4.64
3.97
0.92
2.34
1.72
2.88
2.82
2.34
3.01
2.47
3.12
2.58
3.55
3.01
1.40
2.34
1.72
2.88
2.82
2.34
3.01
2.47
3.12
2.58
3.55
3.01
1.00
Alcohols
methanol
ethanol
rc-propanol
fl-butanol
Aromatic hydrocarbons
benzene
toluene
ethylbenzene
o,m-,p-xylene
Alkanes
ethane
propane
-butane
rc-pentane
rc-hexane
rc-heptane
n-octane
H-decane
Other compounds
acetone
acetonitrile
2-butanone
carbon tetrachloride
chloroform
cyclohexane
cyclopentane
ethyl acetate
methyl acetate
methylcyclohexane
methylcyclopentane
water
335
336
Appendix A
Table A9 Lennard-Jones Potential Parameters Determined from Viscosity Data
Compound Name
c
nm
g3
0.3758
0.4443
0.5118
0.4687
0.5278
0.5784
0.5949
148.6
215.7
237.1
531.4
330.1
341.1
399.3
0.7451
320.
0.4163
0.4678
0.5198
0.6476
224.7
298.9
319.
204.
0.6182
297.1
3. Alkyl Cyclohexanes
cyclohexane
methylcyclohexane
ethylcyclohexane
0.4033
0.4761
231.8
251.8
0.5349
0.5932
412.3
377
481.8
362.6
576.7
0.4936
0.5205
469.8
521.3
0.3542
0.2551
0.3655
0.2820
0.4047
93.3
10.22
178.9
32.8
231.
0.4217
0.2827
0.3798
0.3467
316
59.7
71.4
106.7
0.3941
0.3690
0.3828
195.2
91.7
232.4
8. Alkyl Acetates
9. Monatomics
argon
helium
krypton
neon
xenon
chlorine
hydrogen (normal)
nitrogen
oxygen
carbon dioxide
carbon monoxide
nitrous oxide
6. Alkyl Halides
methyl bromide
methyl chloride
ethyl chloride
0.3626
0.4530
0.4549
/ / . Inorganic Oxidesi
5. Alkyl Benzenes
benzene
toluene'
ethylbenzene
o-xylene
m-xylene
/?-xylene
10. Diatomlcs
4. Acetylenes
acetylene
methyl acetylene
methanol
ethanol
1-propanol
1-butanol
I -pentanol
1-hexanol
1-heptanol
methyl acetate
ethyl acetate
2. Alkenes
ethylene
propylene
1-butene'
2-pentene'
e/kB
7. 1-Alkanols
A Alkanes
methane
ethane
propane
rc-butane
isobutane
rc-pentane
rc-hexane
tt-heptane
-octane'
a
nm
Compound Name
0.4118
0.4182
0.4898
449.2
350.
300.
ammonia
hydrogen
hydrogen
hydrogen
hydrogen
water
bromide
chloride
fluoride
sulfide
0.2900
0.3353
0.3339
0.3148
0.3623
0.2641
558.3
449.
344.7
330.
301.1
809.1
Appendix A
337
Compound Name
T
K
^(298.15)
uPa's
1. Alkanes
H-hexane1
rt-heptane1
rc-octane1
H-nonane
rc-decane1
n-undecane
ra-dodecane1
2. Alkyl
280- 390
2 9 0 -350
280-390
280-340
280- 430
280-350
280- 430
294.9
389.0
509.2
657.6
849.8
1071.9
1358.5
-5.873
-6.265
-6.496
-4.187
-7.156
-2.784
-7.807
11.047
12.022
12.682
4.513
14.258
0.752
16.011
-7.384
-8.411
-9.404
-0.327
-11.396
2.032
-13.863
2.211
2.655
3.219
280-400
220-380
280-350
290-350
290--350
2 9 0 . 350
290 390
603.7
554.5
628.3
751.0
583.0
603.3
659.3
-3.995
-5.349
-3.558
-3.077
-2.885
-3.593
-3.260
4.399
9.343
3.603
2.176
2.276
3.606
2.824
-1.067
-6.216
-0.047
0.901
0.608
-0.014
0.436
0.663
2.223
280^ 340
290-350
290 -340
290 -340
290--330
545.1
1080.9
1928.3
2471.8
3344.4
-29.905
-11.794
10.613
-31.898
- 147.37
84.017
-82.539
23.390
-17.155
-49.640
60.329
83.208
-78.605
448.53 -464.62
28.429
5.563
-21.288
27.325
163.47
274^ 372
890.5
-10.728
-27.208
11.656
4.294
5.659
Benzenes
benzene
toluene
ethylbenzene
o-xylene
m-xylene
p-xylene
mesitylene
3. 1-Alkanols
methanol
ethanol
1-propanol
1-butanol
1-pentanol
4. Other
water
Compounds
26.279
338
Appendix A
Table Al 1 Liquid Thermal-Conductivity Coefficients of Selected Compounds
at Atmospheric Pressure (accuracy better than 2%)
Compound Name
j T_
K
/. Alkanes
n-hexane
rc-heptane'
H-octane
n-nonane
-decane
-undecane
-dodecane
A(298.15)
mW-m-'-K"1
1.219
290 -330
190 -370
280 -350
280 -360
300 -380
280 -380
290 380
120.7
122.8
128.9
131.6
132.2
133.5
135.1
3.110
1.730
2.217
1.853
1.088
1.667
1.531
-3.329
-0.730
-1.619
-0.998
0.302
-0.715
-0.417
0.403
0.146
-0.391
0.049
-0.114
290 -350
190 -360
141.1
131.1
1.696
1.452
-0.696
-0.224
-0.226
290-360
290-360
290-360
129.9
130.2
127.8
1.452
1.458
1.603
-0.362
-0.341
-0.580
-0.090
-0.117
-0.023
270-330
280-340
290-370
290-360
290-340
199.2
165.6
149.2
147.6
145.6
3.163
5.357
1.040
1.694
0.769
-4.029
-7.967
0.093
-1.117
0.635
1.866
3.610
-0.133
0.423
-0.404
274-370
606.7
-1.265
3.705
-1.439
2. Alkyl Benzenes
benzene2
toluene'
ethylbenzene
o-xylene
m-xylene
p-xylene
mesitylene
3. 1-Alkanols
methanol
ethanol
1-propanol
1 -butanol
1-pentanol
4. Other Compounds
water'
Appendix A
339
REFERENCES
Physical Constants and Perfect-Gas Heat-Capacity Coefficients
R.C. Reid J.M. Prausnitz and B.E. Poling, The Properties of Gases and Liquids,
4th Ed. (McGraw Hill, 1988).
Except : 1) w-alkanes, alkyl benzenes and ^-alcohols critical constants:
- I. Cibulka, Fluid Phase Equil. (in press, 1995).
2) refrigerants (except Rl 1, R12) critical constants, boiling temperatures and
perfect-gas heat-capacity coefficients:
M.O. McLinden, Int. J. Refrig. 13 (1990) 149.
3) Rl 1 and R12 perfect-gas heat-capacity coefficients:
- C.L. Yaws, H.M. Ni and P.Y. Chiang, Chem. Eng. May 9 (1988) 91.
4) Refrigerants dipole moments:
C.W.Meyer and G.Morrison, J.Phys.Chem. 95 (1991) 3860.
5) Pitzer's parameter calculated from McLinden's values (see above).
Table Al
Data
340
Appendix A
B
Thermophysical Properties of Fluids Downloaded from www.worldscientific.com
by 187.209.238.252 on 01/10/15. For personal use only.
Supplementary Information
In this Appendix we will elaborate on the definitions of molecular, perfect-gas,
configurational, residual and excess properties of pure fluids and mixtures. We also
review the thermodynamic relations required in the calculation of the fugacity of a
component in a mixture.
and may therefore be expressed as the sum of a molecular part and a configurational
part. We therefore have for a property X
where A0' is called the molecular property and A"' is the configurational property.
The relation, given in Chapter 2, between the molecular properties and the perfectgas properties can easily be derived. The partition function for a perfect gas, QV&, is
obtained by setting the potential energy 1l to zero. The configuration integral,
Eq.( 1.31), then reduces to VN. Consequently, the molecular partition function and the
perfect-gas partition function are related simply by
and
342
Appendix B
It follows from Eq.(B.4) that the perfect-gas part of a thermodynamic property may
be expressed in terms of the molecular contribution plus terms in N and V. For
example, the Helmholtz free energy of the perfect gas, obtained from Eq.(1.18) with
Q = ?pg> ma Y be written
A = -kBT\nQ
-kBT\nQmo^NkBT\nV
(B.5)
= Amo1 - NkBT \nV
Similarly, the perfect-gas entropy is related to the molecular contribution as follows:
S p g = kBT(d\nQPZ/dT)v + kB In (2pg
= kBT(d\nQmoi/dT)v
(fi.6)
= S mol + M B lnK
and it is easy to show that
UW=Umo]
and
CPg = C'.
(B.7)
The form of Eqs.(B.7) is as expected as these properties of the perfect gas are
independent of volume.
(B.8)
This separation is often useful because quite different techniques apply to the
prediction of these different kinds of property.
Although the variables T and Vm are natural in statistical mechanics based on
the canonical ensemble, practical considerations usually dictate the use of T and P. It
Appendix B
343
The relation between XPS(T, Vm) and X?HT,P) is given by the identities
344
Appendix B
The integrals that appears in these equations are easy to evaluate in terms of the
equation of state of the perfect gas (a Maxwell equation is sometimes needed to
obtain the partial derivative in terms of the equation of state). As an example,
consider the molar Helmholtz free energy for which (8Am/8Vm)T = -P and hence
where
is the compression factor. The key relations between the two kinds of residual
property are summarised in Table B1.
Appendix B
345
where X pg is the molar perfect-gas property for the pure component i and
Amix-^mS ' s m e so " ca ll e< i 'deal mixing term equal to the change in X^ on mixing
the components at constant temperature and pressure. It is sometimes convenient to
consider a different quantity, the excess molar property X^_, defined by
Here, X^ is the value of the molar property for an ideal mixture and ^f*is the actual
(rather than perfect-gas) value of the molar property for the pure component i at the
specified temperature and pressure. This excess property is then the difference
between the actual value of the property for the mixture and that which would prevail
in an ideal mixture at the same temperature and pressure. The ideal mixing terms
may all be derived from the change in molar Helmholtz free energy on mixing the
perfect gases at constant temperature and volume.1 Starting from Eq.(2.25), it is
easy to show that
All other ideal mixing terms follow from this expression and the results are given in
Table B2. Since A m i x [/ P g = 0, A m i x ^P g is most closely related to the change in
molar entropy on mixing:
The ideal mixing term for molar entropy is derived below in Example B. 1.
' Since there is no change in pressure when perfect gases are mixed at constant temperature
and volume, there is no distinction between that situation and mixing at constant tempera
ture and pressure.
346
Appendix B
Table B2 Ideal Mixing Terms
Property (X
(^mixX^)
RT^x, \nx,
/fpg
-/?*, In*,
RT pT[ x, lnx,
Gpg
rf*
^rinjc,
l\ ^B, c?%,
EXAMPLE B. 1
The mixing process is depicted in Figure B.l. Amounts , and n2 of two perfect
gases are initially contained separately at temperature T and pressure P in a closed
vessel. The partition separating the two gases is then removed so that they may mix
adiabatically and, being perfect gases, this process involves no change in pressure
Figure B.l
and, in a perfect gas, (PIT) dVm = -Rd\r\ P, the change in entropy on mixing the
perfect gases is given by
Appendix B
347
The residual molar Gibbs free energy is itself given by the identity
dP
(B.21)
In order to convert this relation into one that can be evaluated readily from an
equation of state that gives P as a function of T and Vm, we change the variable of
integration from P to the total (not molar) volume V, making use of the relation
V{dPldV)Tn = - n{dPldn)TV, and, after some working, we obtain:
348
Appendix B
and this is the relation used directly to obtain expressions for the mixture fugacity in
terms of an equations of state. Since G^es = Hs - TSS, the mixture fugacity
coefficient may also be obtained from the residual enthalpy and residual entropy:
and this equation may be used to obtain cpt in terms of an equation of state.
The fugacity coefficient may also be obtained in another way by noting that
property X, molar property Xm and partial molar property Xi are related by
Since /ujes is identical with the partial molar residual Gibbs free energy, it follows
from (B.20) and (B.26) that RT\xv(pi is the partial molar analogue of RT]n(pmix and
hence that
This relation was used in Section 5.4 together with expressions for the partial
derivatives of rn</>mjx with respect to rand P obtained by operating on Eq.(B.25).
Appendix B
349
and
where * denotes a property of the pure liquid. Subtracting these two equations we
obtain
Index
acentric factor, 78
Lee-Kesler scheme, 83
activity coefficient, 162
infinite dilution, 177-183
activity, 162
activity-coefficient models
ASOG, 184
NRTL, 173-174
UNIFAC, 185
UNIQUAC equations, 174-176
Wilson & T-K-Wilson, 167-172
Antoine's vapour pressure equation, 166
ASOG, 184
Benedict-Webb-Rubin (HS) equation of
state,133-136
compression factor, 134
partial fugacity coefficient, 136
residual enthalpy, 135
residual entropy, 135
bubble-point calculations, 211-216
Brokaw equations
thermal conductivity calculation, 285
canonical ensemble, 2
canonical partition function, 4
molecular partition function, 8
canonical partition function, 4
collision cross section, 264
compression factor
Lee-Kesler scheme, 82
Peng-Robinson, 129
Redlich-Kwong, 126
Soave, 127
water, 88
configuration integral, 12
corresponding states
Ely-Hanley scheme, 291-297
four-parameter model, 87
Lee-Kesler scheme, 79-86
three-parameter model, 75
352
Index
entropy (con/d)
perfect-gas contributions, 17-30
residual: Benedict-WebbRubin(HS),135
residual: Lee-Kesler scheme, 82
residual: Peng-Robinson, 130
residual: Soave, 128
residual: van der Waals,122
residual: virial equation, 61
residual: water,88
equations of state
Benedict-Webb-Rubin (HS),133-136
Keenan: for water, 88-89
Peng-Robinson, 129-130
properties derived from, 116
Redlich-Kwong, 125-126
Soave, 126-128
vanderWaals, 117-123
volume-translation methods, 130-132
Eucken factor, 266
excess properties, 345
modified Eucken formula, 268
excess transport properties, 269
initial density dependence, 270
intermediate-density range, 271
very-dense-gas range, 273
liquid range, 273
Thodos scheme, 286
flash calculations
isenthalpic flash, 222-223
isentropic flash, 223-224
isothermal flash, 218-222
fugacity
derivation, 317
in terms of virial coefficients, 61
Gibbs free energy
in terms of partition function, 7
perfect-gas contributions, 17-30
residual, 344
hard-spheres
dilute gas: thermal conductivity, 263
dilute gas: transport properties, 259
dilute gas: viscosity, 261
Helmholtz free energy
in terms of partition function, 6
perfect-gas contributions, 17-30
residual, 344