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Documentos de Profesional
Documentos de Cultura
e
Document Name: ASTM D86: Standard Test Method for Distillation of
Petroleum Products at Atmospheric Pressure
Official Incorporator:
THE EXECUTIVE DIRECTOR
c6
Designation: D 86 - 07
-U II
INTfiRNARONAL
1. Scope'
1.1 This test method covers the atmospheric distillation of
petroleum products using a laboratory batch distillation unit to
detennine quantitatively the boiling range characteristics of
such products as light and middle distillates, automotive
spark-ignition engine fuels, aviation gasolines. aviation turbine
fuels. I-D an~ 2-D regular and low sulfur diesel fuels, special
petroleum spirits, naphthas, white spirits, kerosines, and
Grades I and 2 burner fuels.
1.2 The test method is designed for the analysis of distillate
fuels; it is not applicable to products containing appreciable
quantities of residual material.
1.3 This test method covers both manual and automated
instruments.
\,4 Unless otherwise noted, the values stated in SI units are
to be regarded as the standard. The values given in parentheses
are provided for information only.
1.5 This standard does not purport to address all of the
safety concerns, if any, associated with its Zlse. It is the
responsibility of the user of this standard to establish appropriate safety and health practices and detennine the applicability of regulatory limitations prior to llse.
2. Referenced Documents
2.1 All standards are subject to reVISIon. and parties to
agreement on this test method are to apply the most recent
edition of the standards indicated below, unless otherwise
specified. such as in contractual agreements or regulatory rules
where earlier versions of the methodes) identified may be
required.
2.2 ASTM Standards: 2
I This test method is under the jurisdiction of ASTM Committee D02 on
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee
D02.08.0A on Distillation.
In the IP. the equivalent te5t method is published under the designation IP 123.
It is under the jurisdiction of the Standardization Committee.
Current edition approved Jan. 15, 2007. Published February 2007. Originally
approved in 1921. Last previous edition approved in 2005 as D 86-05.
2 For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Amlllal Book of ASTM
Standards volume information. refer to the standard's Document Sununary page on
the ASTM website.
3 Available from Energy Institute, 61 New Cavendish St., London, WIG 7AR,
U.K., http://www.energyinst.org.uk.
.086-07
TABLE 1 Preparation of Apparatus
Group 1
Group 2
Group 3
125
7C (7F)
low
125
125
125
7C(7F)
low
7C (7F)
low
8C (8F)
B
38
B
38
50
50
QC
13-18
13-18
13-18
nol above
of
55-65
not above
ambient
55-65
55-65
not above
ambient
ambient
i3-18 A
55-5 A
13-ambientA
55-ambient A
Flask, mL
ASTM distillation thermometer
IP distillation thermometer range
Flask support board
diameter of hole, mm
Group 4
high
not above
ambient
C
OF
13-18
13-18
55-65
55--65
3. Terminology
3.1 Definitions:
3.1.1 charge volume, n-the volume of the specimen, 100
mL, charged to the distillation flask at the temperature specified in Table 1.
3.1.2 decomposition, n-of a hydrocarbon, the pyrolysis or
cracking of a molecule yielding smaller molecules with lower
boiling points than the original molecule.
3.1.2.1 Discussion-Characteristic indications of thermal
decomposition are evolution of fumes and erratic temperarure
readings that usually decrease after any attempt is made to
adjust the heat.
3.1.3 decomposition point, n-the corrected thermometer
reading that coincides with the first indications of thermal
decomposition of the liquid in the flask.
3.1.3.1 Discussion-The decomposition point, as determined under the conditions of this test method, does not
necessarily correspond to the decomposition temperature in
other applications.
3.1.4 d,y point, It-the corrected thermometer reading that
is observed at the instant the last drop of liquid (exclusive of
any drops or film of liquid on the side of the flask or on the
temperature sensor), evaporates from the lowest point in the
distillation flask.
3.1.4.1 Discussion-The end point (final boiling point),
rather than the dry point, is intended for general use. The dry
point can be reported in connection with special purpose
naphthas, such as those used in the paint industry. Also, it is
substituted for the end point (final boiling point) whenever the
sample is of such a nature that the precision of the end point
(final boiling point) cannot consistently meet the requirements
given in the precision section.
3.1.5 dynamic holdup, n-the amount of material present in
the neck of the flask, in the sidearm of the flask, and in the
condenser tube during the distillation.
3.1.6 emergent stem effect, n-the offset in temperature
reading caused by the use of total immersion mercury-in-glass
thermometers in the partial immersion mode.
3.1.6.1 Discussion-In the partial immersion mode, a portion of the mercury thread, that is, the emergent portion, is at
a lower temperature than the immersed portion, resulting in a
shrinkage of the mercury thread and a lower temperature
reading.
2
0086-07
3.1.18 temperature reading, n-the temperature obtained by
a temperature measuring device or system that is equal to the
thermometer reading described in 3.1.19.
3.1.18.1 corrected temperature reading, n-the temperature
reading, as described in 3. L 18, corrected for barometric
pressure.
3.1.19 thermometer reading (oJ' thelmometer result), n-the
temperature of the saturated vapor measured in the neck of the
flask below the vapor tube, as determined by the prescribed
thermometer under the conditions of the test.
3.1.19.1 corrected thennometer reading, n-the thermometer reading, as described in 3.1.19, corrected for barometric
pressure.
I.-Jhermometer
dlTT-::~
__ Bath Cover
Heat
Resistant
Boards
Blotting
Paper
Burner.1l---~\1
Gas Lin
Support -*,.I'$'~':1
6. Apparatus
<0 D 86-07
Top View
Approx. 300
,.-!..--_----I=I--LI~5 min,
r-------I=I--LI
m;n,
- -.:'...
......... "1';
I,
,13"-,,m~l~n,,-+-+-,' :... 0
:
=,'
",'
~~
II
-\1
II
l
r
: ~
:!
I
1/---------~\lll-- ...
:1
~1I~~j
II
Approx. 200
length of part
in balh
approx.390
Front View
Side View
i-Condenser bath
11-Dislillation flask
2-Bath cover
3-Bath temperature sensor
4-Balh overflow
5-8alh drain
6-Condenser lube
12-Temperalure sensor
i3-Flask support board
14-Flask support platform
15-Ground connection
i6-Electric heater
17-Knob for adjusting level
7-Shield
a-Viewing window
of support platform
is-Power source cord
9a-Voltage regulator
9b-Vollmeter or ammeter
9c-Power switch
gd-Power light indicator
i9-Receiver cylinder
20-Receiver cooling bath
21-Receiver cover
1D-Venl
cO D86-07
Drilled out to fit
Pt100 Probe
Knurled knob
.Cone 1:10
Mala NS 19{26
Compression
(PTFE)
tllt
0>
10
Dimensions in mm
Cone-shaped for
perfect centering
in neck of
distillation flask
7CffJ'
7CIIT' 5C and ASTM 7F for the low range thennometers, and
ASTM 8CffJ'
8CIIT' 6C and ASTM 8F for the high range thermometers.
6.3.1.1 Thermometers that have been exposed for an extended period above an observed temperature of 370"C shall
not be reused without a verification of the ice point or checked
as prescribed in Specification E I and Test Method E 77.
Compression
without O-ring
Single O-ring
Viton or
perfluoro elastomer
ture of the bulb is approaching a critical range in the glass and the
thermometer may lose its calibration.
a low IBP may have one or more readings obscured by the centering
device. See also 10.14.3.l.
D86-07
Group 2
Group 3
Group 4
Sample
characteristics
Distillate type
Vapor pressure at
37.8 C, kPa
10QDF, psi
(Test Methods
D323, D 4953,
05190, D 5191,
D 5482,
IP 69 or
IP394)
Distillation, IBP DC
'F
EP DC
'F
D
~65.5
;:;,9.5
<65.5
<9.5
<:65.5
<9.5
:;;;100
s;212
",;250
,;;;250
~4a2
<482
s;482
>250
>482
<65.5
<9.5
>100
>212
..250
>482
8. Preparation of Apparatus
8.1 Refer to Table 1 and prepare the apparatus by choosing
the appropriate distillation flask, temperature measuring device, and flask support board, as directed for the indicated
group. Bring the temperature of the receiving cylinder, the
flask, and the condenser bath to the indicated temperature.
8.2 Make any necessary provisions so that the temperature
of the condenser bath and the receiving cylinder will be
maintained at the required temperatures. The receiving cylinder shall be in a bath such that either the liquid level is at least
NOTE 6-If there are no, or inadequate, facilities for storage below
lQ"C, the sample may also be stored at a temperature below 20"C,
provided the operator ensures that the sample container is tightly closed
and leak-free,
NOTE 7-Jf there are no, or inadequate. facilities for storage below
.086-07
TABLE 3 Sampling, Storage, and Sample Conditioning
Group 1
Temperature of sample bottle
'C
'C
'F
Temperature of sample after
conditioning prior to analysis
If sample is wet
If resample is still wet G
Group 2
Group 3
Group 4
<10
<50
'F
<lOA
<SOA
'C
<10
<10
<50
<10
'F
<50
<50
resample
resample
dry in accordance with 7.5.2
ambient
ambient
ambient
ambient
Ambient or
Ambient or
9 to 21"C above pour pointS
Ambient or
Ambient or
48 to 70"F above pour pointS
dry in accordance with 7.5.3
Under certain circumstances, samples can also be stored at temperatures below 20"C (68"F). See also 7.3.2 and 7.3.3.
a If sample is (semi)-solid at ambient temperature, see also 10.3.1.1.
e If sample is known to be wet, resampling may be omitted. Dry sample in accordance with 7.5.2 and 7.5.3.
9.1.3 A procedure to determine the maguitude of the temperature lag is described in Annex A3.
9.1.4 A procedure to emulate the emergent stem effect is
described in Appendix X4.
9.1.5 To verify the calibration of the temperature measnrement system at elevated temperatures, use hexadecane. The
temperature measurement system shall indicate, at 50% recovered, a temperature comparable to that shown in Table 4 for the
respective apparatus under Group 4 distillation conditions.
NOTE Il-Because of the high melting point of hexadecane, Group 4
verification distillations will have to be carried out with condenser
temperatures >20C.
:.> Supporting data have been filed at ASTM International Headquarters and may
be obtailled by requesting Research Report RR: D02-IS80.
MD.
.086-07
TABLE 4 True and Min and Max D 86 50 % Recovered Bolling Points COC)A
Manual
Automated
Distillation
conditions
max 0 86
50 % boiling
Distillation
conditions min
08650%
boiling point
D8650%
Distillation
conditions max
08650%
boiling point
boiling point
Distillation
conditions min
point
ASTMlIP true
Toluene
Hexadecane
Group 1, 2, and
3
Group 1, 2,
Group 1, 2, and
boiling point
and 3
Group 1, 2,
and 3
110.6
105.9
111.8
108.5
109.7
ASTMII P true
boiling point
Group 4
Group 4
Group 4
Group 4
287.0
272.2
283.1
277.0
280.0
The manual and automated temperatures show in this table are the values for the 95 % tolerance interval for the 99 % population coverage. The I7Oposed tolerance
is approximately 3 x sigma. Infonnation on the values in this table can be found in RR:D02-15BO.
A
10.5 Fit the temperature sensor through a snug-fitting device, as described in 6.4, to mechanically center the sensor in
the neck of the flask. In the case of a thermometer, the bulb is
centered in the neck and the lower end of the capillary is level
with the highest point on the bottom of the inner wall of the
vapor tube (see Fig. 5). In the case of a thermocouple or
resistance thermometer, follow the manufacturer's instructions
as to placement (see Fig. 6).
10. Procedure
10.1 Record the prevailing barometric pressure.
10.2 Groups 1 and 2-Fit a low range thermometer provided with a snug-fitting cork or stopper of silicone rubber, or
equivalent polymeric material, tightly into the neck of the
sample container and bring the temperature of the sample to the
temperature indicated in Table 3.
10.3 Groups 1, 2, 3, and 4-Check that the temperature of
the sample is as shown in Table 3. Pour the specimen precisely
to the lOO-mL mark of the receiving cylinder, and transfer the
contents of the receiving cylinder as completely as practical
into the distillation flask, ensuring that none of the liquid flows
into the vapor tube.
.086-07
A: Align inside
lower
portion of flask
I~(---@
test, the vapor and liquid around the temperature sensor are not
in thermodynamic equilibrium. The distillation rate will consequently have an effect on the measured vapor temperature.
The distillation rate shall, therefore, be kept as constant as
possible throughout the test.)
NOTE 16--When testing gasoline samples, it is not uncommon to see
the condensate suddenly fonn non-miscible liquid phases and bead up on
the temperature measuring device and in the neck of the boiling flask at a
vapor temperature of around 160C. This may be accompanied by a sharp
(about 3C) dip in the vapor temperature and a drop in the recovery rate.
The phenomenon, which may be due to the presence of trace water in the
sample, may last for 10 to 30 s before the temperature recovers and the
condensate starts flowing smoothly again. This point is sometimes
colloquially referred to as the Hesitation Point.
10.12 Repeat any distillation that did not meet the requirements described in 10.9, 10.10, and 10.11.
10.13 If a decomposition point, as described in 3.1.3, is
observed, discontinue the heating and proceed as directed in
10.17.
10.14 In the interval between the IBP and the end of the
distillation, observe and record data necessary for the calculation and reporting of the results of the test as required by the
9
.086-07
TABLE 5 Conditions During Test Procedure
Temperature of cooling bath A
Temperature of bath around
receiving cylinder
Group 1
Group 2
Group 3
o-S
0-5
{}-BO
OF
0-1
32-34
32-40
32-140
13-18
S5-<lS
13-18
32-40
13-18
S5-<lS
S5-<lS
DC
OF
Group 4
of charge
temperature
Time from first application of heal to
initial boiling point, min
5-10
5-10
5-10
5-15
60-100
60-100
4-5
4-5
4-S
4-5
Smax
5 max
Smax
Smax
the proper condenser bath temperature will depend upon the wax content of the sample and of its distillation fractions. The test is generally performed using one single
condenser temperature. Wax formation in the condenser can be deduced from (s) the presence of wax particles in the distillate coming offlhe drip tip, (b) a higher distillation
loss than what would be expected based on the initial boiling point of the specimen, (c) an erratic recovery rate and (11) the presence of wax particles during the removal
of residual liquid by swabbing with a lint-free cloth (see 8.3). The minimum temperature that permits satisfactory operation shall be used. In general, a bath temperature
in the 0 to 4DC range is suitable for kerosine, Grade No.1 fuel oil and Grade No. 1-D diesel fuel oil. In some cases involving Grade No.2 tuel oil, Grade No. 2-D diesel
fuel oil, gas oils and similar distillates, it may be necessary to hold the condenser bath temperature in the 38 to 60C range.
A
where:
temperature at the volume % recorded one reading
C1
prior to the volume % in question, e,
C2 ;::: temperature at the volume % recorded in question,
"C,
;:::
.086-07
TABLE 6 Approximate Thermometer Reading Correction
11. Calculations
11.1 The percent total recovery is the sum of the percent
recovery (see 10.18) and the percent residue (see 10.19).
Deduct the percent total recovery from 100 to obtain the
percent loss.
11.2 Do not correct the barometric pressure for meniscus
depression, and do not adjust the pressure to what it would be
at sea level.
C,
+ I,)
+ IJ
+ If)
"C
"F
0.35
0.38
0.40
0.42
0.45
0.47
0.50
0.52
0.54
0.63
0.68
0.72
0.76
0.81
0.85
0.89
0.94
0.98
1.02
1.07
1.11
1.15
1.20
1.24
1.28
1.33
1.37
1.41
1.46
30-50
86-122
50-70
70-90
90-110
110-130
130--150
150-170
170-190
190-210
210--230
230--250
250-270
270-290
290-310
310-330
330-350
350-370
370--390
390-410
122--158
158-194
194-230
230-266
266-302
302-338
338-374
374-410
410-446
0.57
0.59
0.62
0.64
446-482
482-518
518-554
554-590
590-626
62&-662
662-698
698-734
734-770
0.66
0.69
0.71
0.74
0.76
0.78
0.81
+ (L -
0.5)/{1
+ (101.3 -
+ (L
- 0.5)/{1
+ (760 -
L, ~ 0.5
PkJ/8.00}
P)/60.0}
(6)
(7)
where:
L
(3)
= observed loss,
Le = corrected loss,
Pk = pressure, kPa, and
P = pressure, rom Hg.
(4)
NOTE 22-Eq 6 and 7 above have been derived from the data in Table
7 and Eqs 5 and 6 in Test Method D 86 - 95 and earlier versions. It is
probable that Eq 6 and 7 shown were the original empirical equations from
which the table and equations in the Test Method D 86 - 95 and earlier
versions were derived.
"F
50-86
"C
10-30
C,
Temperature Range
(5)
where:
11.4.1 Calculate the corresponding corrected percent recovery in accordance with the following equation:
R,
~R
+(L-L,)
where:
L = percent loss or observed loss,
Le = corrected loss,
R = percent recovery, and
Rc = corrected percent recovery.
11
(8)
.086-07
TABLE 7 Data Points for Determining Slope, Sc or SF
Slope at %
TL al %
Tuat%
Vu' V L
IBP
10
20
30
40
50
60
70
80
90
95
EP
0
5
5
0
10
10
0
20
20
10
30
20
20
40
20
30
50
20
40
60
20
50
70
20
60
80
20
70
90
20
80
90
10
90
95
5
V,"
95
VEP-95
where:
12. Report
L
observed loss,
Pe ;;;; percent evaporated, and
P r :::: percent recovered.
~TL
+ (TH-TJ(R-RJI(RH-RJ
(10)
where:
12
.086-07
TABLE 8 Repeatability and Reproducibility for Group 1
Manual
RepeatabilityA
Evaporated
Paint, %
IBP
5
10
20
30-70
80
90
95
FBP
A
Manual
ReproduclbllityA
Automated
RepeatabiJityA
Automated
ReproducibilityA
OF
of
of
of
3.3
10
3.9
7.2
13
1.9+0.8680
1.2+0.8680
1.2+0.868c
1.2+0.8680
1.2+0.8680
1.2+0.86Sc
1.2+0.86So
3.4+0.868F
2.2+O.868F
2.2+0.868F
2.2+O.868F
2.2+0.868 F
2.2+O.868F
2.2+O.86S F
5.6
3.1+1.7480
2.0+1.7480
2.0+1.7480
2.0+1.748 0
2.0+1.74S o
Q.8+1.74Sc
1.1+1.74So
5.6+1.748F
3.6+1.74SF
3.6+1.748F
3.6+1.748F
3.6+1.748F
1.4+1.748F
1.9+1.748 F
3.8+O.678F
3.0+O.678F
2.0+O.678F
2.0+0.678 F
2.0+0.678 F
2.0+O.67SF
4.5+O.67S F
4.4+2.08 0
3.3+2.080
3.3+2.080
2.6+2.08c
1.7+2.08c
0.7+2.0Sc
2.6+2.0So
7.9+2.0SF
6.0+2.0SF
6.0+2.08F
4.7+2.08 F
3.0+2.0S F
1.2+2.0SF
4.7+2.0S F
7.2
13
2.1+0.6780
1.7+0.678c
1.1+0.6780
1.1+0.6780
1.1+0.6780
1.1+0.67Sc
2.5+0.67So
4.4
8.9
16
3.9
So or SF is the average slope (or rate of change) calculated in accordance with 13.2.
U2)
13.1 Precision:
where:
TEP or THR i.s the temperature. in C or OF at the percent
volume recovered indicated by the subscript,
VEP or VHR is the volume % recovered.
13.1.1 The precision of this test method has been determined by the statistical examination of interlaboratory test
EP
point.
13.2.5 Par points between 10 to 85 % recovered which are
not shown in Table 7, the slope is calculated as follows:
Sc (or SF) = 0.05
UD
where:
is the slope, C/volume %,
Se
SF
= is the slope, Flvolume %.
VL
(13)
data.
Tu
TL
Vu
(T (V+IO) - T (V-lO)
end point
sponding to TU,
sponding to Tb and
VEP = is the volume % recovered or evaporated corresponding to the end point.
13.2.4 In the event that the distillation end point occurs prior
13
.086-07
TABLE 9 Repeatability and Reproducibility for Groups 2, 3 and 4 (Manual Method)
ReproducibililyA
RepeatabilityA
IBP
5--95 %
FBP
% volume at
tempera1ure reading
OF
OF
1.0+0.3580
1.0+0.4180
0.7+0.36S o
1.9+O.35SF
1.8+0.41 SF
1.3+0.36SF
2.8+0.93S o
1.B+1.3380
3.1+0.4280
5.0+0.93SF
3.3+1.33SF
5.7+O.42SF
0.7+0.9218 0
O.7+1.661S F
1.5+1.78/80
1.53+3.20/SF
14, Keywords
14.1 batch distillation; distillates; distillation; laboratory
distillation; petroleum products
D 86-97.
14
<41' 086-07
TABLE 10 Repeatability and Reproducibility for Groups 2. 3 and 4 (Automated)
RepeatabilityA
ReproducibiJityA
Coliected, %
"C
[BP
2%
5%
3.5
3.5
1.1 +1.088 0
10,%
1.2+1.4280
1.2+1.4280
20-70 %
ao%
90-95 %
FBp
1.2 + 1.4280
"F
"C
6.3
6.3
2.0+1.08S F
2.2 + 1.42S F
2.2+ 1,42S F
2.2 + 1,42S F
"F
a.5
2,6 + 1.928e
2.0 +2.538 0
15.3
4.7 + 1.92SF
3.0 +2.648 0
5.4+ 2.64SF
5.2 + 3.97SF
5.4 + 2.64S F
3.6 + 2.53S F
18.9
3.6 +2.53S F
2.9 +3.978 0
1.1 + 1.088e
2.0+ 1.0aS F
3.0+2.6480
2.0+2.5380
3.5
6.3
10.5
A Be or SF is the average slope (or rate of change) calculated in accordance with 13.5.
ANNEXES
(Mandatory Information)
AI. REPEATABILITY AND REPRODUCffiILITY DEFINITION AIDS
Al.l Table Al.1 is an aid for determining which repeatability and reproducibility table or section, is to be used.
Method
Manual
Temperature Scale
"C
"F
Automated
"C
2,3,4
Manual
"C
2,3,4
Automated
"C
"F
"F
"F
Use
Repeatability
Reproducibility
Table 8
Table 8
Table 8
Table 8
Table 9
Table 9
Table 10
Table 10
Table 8
Table 8
Table 8
Table 8
Table 9
Table 9
Table 10
Table 10
15
.086-07
A2.6 Flask Support Board-The flask support board shall
be constructed of ceramic or other heat-resistant material, 3 to
6 mm in thickness. Flask support boards are classified as A, B,
or C, based on the size of the centrally located opening, the
dimension of which is shown in Table 1. The flask support
board shall be of sufficient dimension to ensure that thermal
heat to the flask only comes from the central opening and that
extraneous heat to the flask other than through the central
opening is minimized. CWarning-Asbestos-containing materials shall not be used in the construction of the flask support
board.)
16
.086-07
I rtaNFORCIHO BEAD
/ REINFORCING SEIID
.----,L-.,
r------r---.
,....-19122011191261
r-----,-'---,
,-------,,-'---,
17.6:t 1.3 mm 1.0
215:l3rnm
t7.S1.3 1.0.
2.1 :to.7
O.7 mm WALL
215:l3mm
"11"0
I~~
,,~
I~I
c---l--O:::::;,-
I
'J.-!
"\~. ,..;
fli::::i
131 J.3mm
1 :l 0.5 mm 0.0.
1.0 i D.15avnWAU.
137:t;3mm
137:t3mm
1313mm
-esitmmO.o._
-G9tmmO.D.-G9:ttmmO.D.-
FlaskA,100 mL
,li22i
Flask B, 125 mL
FIG. A2.1 Flask A, 100 ml, Flask 8, 125 ml. and Flask B
8 with Ground Glass Joint, 125 mL
17
81
.086-07
dimensions in mm
ApproX.2
,
,,
Approx.60
Dimensions In mm
PoUshed
19
.086-07
A3. DETERMINATION OFTHE DIFFERENCE IN LAG TI!Vill BETWEEN AN ELECTRONIC TEMPERATURE
MEASUREMENT SYSTEM AND A MERCURYIN-GLASS THERMOMETER
%.
A4.S.2 If the intent of the distillation is to solely determine
the value of Exxx or Rxxx, discontinue the distillation after at
least another 2 mL of distillate have been collected. Otherwise,
continue the distillation, as described in Section 10, and
determine the observed loss, as described in 11.1.
A4.5.2.1 If the intent of the distillation is to determine the
value of Exxx and the distillation was terminated after about 2
mL of distillate was collected beyond the desired temperature,
allow the distillate to drain into the receiving graduate. Allow
the contents of the flask to cool to below approximately 400C
and then drain its contents into the receiving graduate. Note the
volume of product in the receiving graduate to the nearest 0.5
mL at 2 min intervals until two successive observations agree.
A4.5.2.2 The amount recovered in the receiving graduate is
the percent recovery. Determine the amount of observed loss
by subtracting the percent recovery from 100.0.
.086-07
A4.6.2 Continue the distillation, as described in Section 10,
(A4.I)
(A4.2)
where:
I'volume %
A4.8 Precision:
APPENDIXES
(Nonmandatory Information)
TIOE ("G)
+ t,)
740) (460 + ~)
0.00012 (760 -
TlOE("F)
(XU)
(5.3 -
(Xl.2)
TSOE("G)
3.6) = 95.3
(X1.5)
+ [(104.5 - 92.7)
5)/(10 - 5)] = 93.I"F
92.7
(X1.6)
93.9
+ [(108.9 -
93.9)
(Xl.7)
+ (4.7 -
33.7)
= 33.7 + [(40.3 -
201
+ [(228 -
201)
(X1.8)
(XI.4)
181.6)
= 182.8"C
(X1.9)
.086-07
T9!)E(F)
358.9
+ [(394.8
- 358.9)
(Xl.l0)
S~Le
180.5
+ [(200.4 -
357)
98.6 kPa
Remarks:
Barometric pressure
corrected
101.3 !cPa
observed
98.6 kPa
740 In 89
recovered
(Xl.ll)
liP
(X1.12)
5
I.
15
2.
181.7C
+ [(392 -
180.5)
Barometric pressure:
Anz.lyst:
Equipment No:
10:
361.0F
359.1F
39.5
<6
54.5
..
E.
200.4
21'5.0
70
25.5
33.0
74.0
93
108.0
123.0
142.0
166.5
4.
5.
~C
85
90
recovered, "
residue, X
loss, X
180.5
94.2
1.1
'.7
of
78
91
10.
115
13.
'"
199
22.
253
288
332
357
393
419
0,
760 nm 89
26.2
33.7
40.3
46.8
55.3
74.a
93.9
108.9
124,0
10.0
167.6
181.6
20t.6
216.2
19.2
92.7
104.5
116.2
131.5
166.7
201.0
",ocedure
arlthmetlcl!l/~
evaporated
5
I.
15
2.
'"
4.
5.
255.1
28'1.4
80
228.0
333.6
358.9
394.8
421.1
70
05
9.
95
95,3
1.1
3
22
GTcvOf'
26.7
34.1
40.7
47.3
65.7
84.9
101.9
116.9
134.1
156.0
168.4
1BZ.a
202.4
0'
80
93.4
105.2
117.1
150.2
184.9
215,3
Z42.4
m.'
312.8
335.1
361.0
396.3
<0086-07
X2. EXAMPLES OF CALCULATION OF REPEATABILITY AND REPRODUCffiILITY OF VOLUME % (RECOVERED OR
EVAPORATED) AT A PRESCRffiED TEMPERATURE READING
- 9.8
- 5.5/1.1
X2.2.1 For a Group 1 sample exhibiting distillation characteristics as per Table X2.1, as determined by an automated unit,
the reproducibility of the volume evaporated,Rvolume %, at
93.3'C (200'F) is determined as follows:
X2.2.1.1 Determine first the slope at the desired tempera-
-5.0
R volume %
RI(SF)
- 9.8/1.9
- 5.1
ture:
Sc%
(X2.1)
-1.1
SF %
+ 2.0 (Sc)
10
20
30
40
84
94
103
112
183
202
217
233
Distillation Point
Evaporated, mL
TemperatureO C
TemperatureO F
10
20
30
40
83
94
103
111
VolUme (mL)
Recovered at
93.3C (200F)
Volume (mLO
Evaporated at
93.3C (200 F)
Q
(X2.2)
18.4
+ 2.0 X 1.1
-5.5
R - 6.0
Temperature OF
18.0
X2.2.2 From Table 9, determine the value of R, the reproducibility at the observed percentage distilled. In this case, the
observed percentage distilled is 18 % and
- 3.3
TemperatureO C
T (10
R - 3.3
Distillation Point
Recovered, mL
+ 2.0 (SF)
x 1.9
182
201
217
232
- 6.0 + 2.0
X3. TABLES OF CORRECTED LOSS FROM MEASURED LOSS AND BAROMETRIC PRESSURE
23
086-07
.086-07
. .-
76.1
80.8
k=
ttrough
""'M"'"
a
1
2
,
4
5
B
7
0.37
0.63
0.89
1.15
1.41
I.S8
1.94
U!6
18
17
19
18
19
20
4.55
4.81
5.07
5.33
5."
0.0
0.1
0.2
'.2
a0.'
.
0.00
'.00
0.00
0.05
0.08
0.10
0.13
0.16
0.18
0.21
0.24
0.110
'.00
0.03
0.08
'.08
0.09
0.12
0.15
0.18
0.11l
0.21
0.24
0.27
12
2.20
2.118
2.72
2.98
3.24
3.50
3.76
4.03
"!415 .29
""
"
."
T,""",
T.""",
0.35
0.65
..
0
0.96
1.25
1.56
2.16
2.46
2.76
3.07
3.37
3.67
3.W
3."
4.27
4.58
4.88
5.18
5.16
5.43
5.48
5.78
6.08
6.39
6."
10
11
a.
0.5
o.e
0.'
0.7
M
,a..
84.5
872
B1.S
".
OS.
8S,6
91.4
91.5
93.0
93.1
94.0
94.1
95.4
96.
029
0.71
0.27
0.25
0.73
0.75
1.26
1.77
22e
023
02'
0.78
1.33
UB
2.43
2.98
3.53
3.33
'.08
0.20
0.60
1.4<>
1."
2."
3.19
3.1B
4.38
4.36
96.'
"'.2
97.8
97.9
98.3
0.18
0.82
1.46
2.09
2.73
0.18
0.84
1.52
2.19
2.87
3.65
'.55
4.23
0.14
0."
1,67
2.28
3.00
'.90
5.14
97.1
....
98,9
98.8
99.4
0.13
0.87
1.62
2.37
3.12
:'1.87
:'l.87
4.62
5.37
6.12
6.87
6,87
7.62
. .7
9.12
9.86
10.61
11.36
12.11
12.86
12.S6
13.61
14.35
14.36
15.11
0.11
0,89
0.00
0.07
0.15
0.22
'.22
11.30
0.30
0.37
0.45
0.52
0."
0.60
0.67
".
".
101.4
103.5
-0,02
1.03
2.08
3.13
4.18
5'.23
6.28
7.33
B.'"
'.43
10.48
11.53
12,59
12.59
13.64
14.69
15.74
16.74
16.79
17.84
18.89
19,94
19.94
20.99
-0.17
""
Units
80.'
'.ro
0.93
0,87
101
1.38
1.70
2.04
2.39
2.13
2.73
31ll
3.41
S.41
3.16
3.76
4.10
4.44
4.78
4.7B
5.13
5.47
5.81
6.16
6.50
e."
7.16
7.18
....
0.00
'.00
0.03
0.07
0.10
0.14
0.17
0.21
0.24
0.27
0.31
0.31
0.69
""
1.46
1-'4
..
2.23
2.61
2.6'
3.00
3,00
3..
3.76
4.15
'.53
\.14
1.57
1.99
2.42
2-'4
3.27
3.70
3.10
4.12
4.55
1.20
1.67
2.14
2.61
3.08
3,08
S.55
3.55
'"
2.79
3.30
3.80
.01
'.02
4.49
4.82
4.6a
'.95 5.38
'.96
.
w ." 5."
4.97
6.35
'.92 5.4<> 5.90 ,'.35
5.30
6.96
... ....
7.22
7.81
7.61
7.11S
7.119
,.es
.es
7.38
7.87
8,38
6.38
8.89
9.40
9,91
9.91
10.41
0.00
0.04
0.08
0.12
0.15
D.19
0.19
0.23
027
0.31
0.35
0.110
'.00
0.04
0.09
0.13
Q.17
0.17
0.21
0.26
0.30
0.34
0.38
0.00
0.05
0.09
0.14
0.19
0.23
0.28
0.33
0.38
0,42
Q.42
0.00
0.05
0.10
0.15
0.20
0.5
025
0.31
0.36
0.41
0."
8 ..
'"
"" ...
..
5.18
5.73
'2e
'28
5."
6.25
6.58
'.58
7.10
7.53
7."
e ...
8.81
5.69
6.01
6.07
6,45
5A5
,.,
5."
6.83
7.""
7.77
8.24
B.71
8.71
9.18
'.09
>57
6.17
B.77
7.36
7.66
7."
e.56
9.15
9.75
"9 10.35
10.14 10.94
10.69 11.64
11.24 12.14
,.9
7.94
8.49
'.56
0.00
0.06
0.11
0.17
0.22
0.28
0.33
O.SS
0.39
0.44
0.50
0.00
'.00
0.08
0.12
0.18
0.24
0.30
0.36
0.42
0.48
0.54
'.04
,.,
3.37
4.01
3.71
4.42
4.65
52.
5.92
6.56
7.20
7.84
8,47
8.47
9.11
9.75
10.39
11.03
11.D3
11.66
12.30
12.94
10.32
11.00
11.68
12.35
13.03
13.71
'.84
,."
5.85
5.65
6.56
7.28
7.99
8.71
S.71
9.42
9.4210.13
10.85
11.56
11.58
12.27
12.99
13.70
14.41
0.00
0.06
a.'"
0.13
0.19
0.26
0.32
0.38
0.45
0.51
0.57
0.00
'.00
0.07
0.14
0.0
020
0.27
0."
'.M
0.41
0,47
0.47
0.54
0.61
0.00
'.00
0.07
0.14
021
0'1
0.29
0."
0.43
O.llO
0.57
0.64
'.32
5.58
6.26
6.25
,."
6."
7.61
B.29
8.97
'.38
Us
2.47
3.25
'.05
4.84
0.09
0.92
1.75
2.56
3.41
'.25
'25
0.09
0.94
1.81
2.89
....
'.56
S.63
6.6S
6.41
7.20
7.99
8.78
9.57
'.57
10.36
10,36
11.15
11.S3
11.93
12.72
13.51
14.30
15.09
15.88
6,74
6.74
7.07
8.41
"4
10.07
10.90
11.74
12.57
13.40
14.23
15.07
15.90
16.73
'.44
5.S1
5.31
6.18
7.06
7.93
8.81
9.68
10.56
10.55
11.43
12.31
13.18
14.06
14.93
15.80
16.68
16.66
17.55
17.65
0.00
'.00
0.06
O.OS
0.16
0.24
0."
0.39
0,41
0,47
0.55
0.63
0.71
0.00
'.00
0.08
0,17
0.17
0.25
0.33
0.'"
0.42
0.50
0.59
0.58
0.B7
0.87
0.75
0.00
'.00
0.09
0.17
0.26
0.35
0.44
'.44
0.52
0."
0.61
0.70
0.79
...
5.08
5,91
5.91
'.68
'.09
0.04
0.96
,.6
1.87
2.79
'.70
4,62
5.53
5
..
M'
7.38
8.21
8.27
9.19
10.10
11.02
11,93
12.65
12.85
13.16
13.76
14.68
15.59
16,60
16.50
17.42
18.33
0.00
0.09
0.18
027
0'7
0.37
0.46
.65
'55
0."
0.73
0.82
0.S2
0.02 -0.00
0,98 1.00
1.94 200
2.90
2.SO
.00
a.S!!
'.00
4.Bl
5.00
4.81
5.77 6.00
'.00
6.73 7.00
7.69 '.00
e.oo
..,5
0.05 '.00
'.110
9.60
10.00
'.60
10.56 11.00
11.52 12.00
12,48 13.00
12.48
13.44
134' 14.00
14AO 15.00
14.40
15.36 18.00
16.00
16.31 17.00
17.27 16.00
18.00
18.23 19.00
19.19 20.00
0.00
0.10
0.19
0.29
0.38
0.48
0.58
0.67
0.77
0.96
0."
0.00
0.10
0.20
D.SD
0.30
0.4<>
0.4<1
0.50
0.60
0.70
0.80
0.90
.."
0.00
0.11
0.21
0.32
0.42
0.53
0.03
0.63
0.74
0.84
0.95
,."
0.00
0.11
0.22
'.22
0.33
0.45
0.56
0.87
0.S7
0.78
0.76
0.69
1.00
0.00
'.00
0.12
0.24
0.35
'.35
0.47
0,59
0.59
0.71
0.83
0.94
1.06
'.65
0.00
0.13
0.25
0.38
0.50
0.63
0.75
..
,O.eo
1.00
1.110
1.13
1.17
2.51
'.84
5.18
'.52
7. .
9.20
10.53
11.87
13.21
14.55
16.89
17.22
".22
18.56
1&. .
19.90
21.24
22.58
23.91
25.25
2525
26.59
".,
0.00
0.13
0.27
0,40
0.40
0.54
0.67
O.eo
O.eo
0.S4
0.94
1.07
,.0
120
FIG. X3.1 Corrected Loss from Observed Loss and Barometric Pressure kPa
BaromelrlcPr885l1'e. mmJ-/g.
""m
",,'''gh
"",,,.h
""'Lon
U"'"
u"'"
a0
,,
2
5
6
7
e
T,,,,"
T,,''''
10
11
12
13
14
15
16
17
19
18
19
20
""
"
0.0
0.1
0.2
'.2
0.3
'.3
0.'
0.5
a0.5
.
0.7
,.
O.
O.
a0.'
.
571
605
'"
...
607
633
.sa
."
'" '"
'" "'"
634
63'
654
671
5.06
5.32
5.58
5.68
2.16
2,46
2.46
2.16
2.76
3.06
3,36
3.36
3.86
3."
3.06
3.96
W
.27
'.57
4.87
5.17
5.47
5.71
5.77
6.07
B.rn
s.rn
4.43
4.78
5.12
5.46
5.45
5.80
8.14
6.49
'.03
6."
7.17
0.00
0.03
0.<15
0.05
0.08
0.10
0.13
0.16
0.18
0.21
0.23
0.00
0.03
'.03
0.06
0.1l6
0.09
0.12
0.15
0.18
021
024
0.27
0.00
0.03
0.07
0.10
Q.14
0.14
0.17
0.21
0.24
0.27
0.31
0.00
0.04
0.08
0.11
0.15
0.19
0.23
0.27
0.31
0.34
.'.80"
U6
U'
572
5as
665
6"
"6
697
5ge
706
715
716
722
'"
723
728
020
'"
0.80
O.BO
0.16
0.18
0.92
0.62
1.45
2.09
2.72
----->
0.31
0.69
1.07
1.48
1.46
1.84
2.22
2.61
un
2.99
3.37
3.76
4.14
4.52
4.91
5,29
5.29
5.67
6.06
6.44
6.82
721
7.59
7.97
0.37
0.63
0.69
o.es
1.15
1.41
1.87
1.93
2.19
2."
2.72
2.98
3.24
3.50
3.76
4.02
.~,
.2e
'.54
0.35
o.es
O.BS
0.95
125
1.55
655
0.33
0.67
'.67
1.01
1.36
1.70
2.04
2.38
2.72
3.07
3.41
3.75
'.09
0.29
0.71
1.14
,.5
1.99
2.41
2.64
2."
325
326
S.69
3.69
4.11
4.54
4.96
5.39
5.,
5.24
6.24
6.66
7.09
7.61
7."
B.38
8.36
8.79
0.27
025 023
'25
0.73 0.75 o.n
0.77
1.20 12,
126
1.32
1.67 1.77
1.S7
l.n 1.87
2.14 2.27 2.42
2,42
2.61
2.76 2.97
2.78
3.07 3.29 3.52
3.54
3.79
4.07
4.01
4,48
4,46
4.81
4.Bl
5.17
5.71
4.94
5.31
5.41
5.82
5.B2
6.26
6.81
5.88
5.8S
6."
6.35 5.53
7."
6.82
7.34
7.91
7.28 7.85
8.46
7.B5
B.46
1.75
7.75 8.35
9.01
9.06
8.22
8.86
9.08
8.69
B.69
9.37 10.11
9.15
10.66
10.38 11.20
'.62 10.36
0.00
0.04
0.08
0.00
0.13
0.17
0.21
0.25
0.30
O.SO
0.34
0.38
0.00
0.05
0.09
0.14
0.19
0.23
0.28
0.33
0.37
0.42
,..
'.30 '.62
."
'.33
,."
,.'"
0.00
0.05
0.10
0.15
0.20
0.25
0.30
0.35
0.41
0,46
0.46
0.00
0.05
0.11
0.16
0.22
0.27
0.33
0.38
0.S8
0.44
0.49
,.'"
no
m
733
1.39
1.99
2.58
3.18
3.77
4.36
4.98
4."
5.55
<15
8"
6.74
7.34
7.93
7."
e.53
9.12
'.72
10.31
10.91
11.50
12.09
3.99
'.63
5.27
5.90
5.54
'.54
7.17
7.81
'.44
'.08
'.00
9,71
9.71
10.35
10.98
11.62
12.25
12.89
0.16
0.84
0."
1.51
2.19
2.96
2."
'.54
4.21
'.88
5.56
6.23
6.91
7.58
8.26
e."
'.93
9.61
10.28
10.95
11.53
11.63
12.30
12.98
13.65
13.55
0.00
0.06
0.1l6
0.12
0.18
0.'8
02.
0.30
0.35
0.36
0.42
0,48
O.4S
0.64
'.00
0.08
0.1l6
0.13
0.19
0.25
0.32
0.36
0.S8
0.44
0.51
0.57
'.57
0.00
0.07
0.13
020
0.27
0.34
0.40
0.47
0.54
rJ.61
'.53
'.72
'.64
,."
'.63
72.
"" '"
."
7"
741
742
745
7"
749
750
752
753
755
0.11
0.89
1.68
1."
2.46
3.25
A"'
OD7
0.14
0.86
0.85
1.57
22.
220
2.99
3.70
4.41
5.12
5.53
5."
6.54
7.25
7.96
e.67
'.67
'.38
10,09
10.09
10.80
11.51
12.22
12.93
13.64
14.35
0.13
0.87
1.62
2.36
3.1'
3.'1
3.88
3.66
4.60
5.9:;;
5.S:;;
6.09
B.09
5."
7.58
7.56
8.33
9.07
9.82
9.92
10.57
11.31
12.06
12.80
13.56
14.29
15.04
0.00
OJYl
0.07
0.14
021
0.28
0.2B
0.36
0.43
0.50
0.57
0..
0.00
0.07
0.15
0.22
0.30
0.37
0,45
0.52
o.eo
0.50
"7
."
5.60
6."
7,17
7.17
7.95
8.74
9.52
10.31
11.09
11.86
11.88
12.56
12.66
13.45
14.23
15.02
15.80
15.00
0.91
1.74
2.57
3.40
4.23
5.5
6.!!6
5.B8
6.71
8.71
7.54
8.37
a.37
9.19
10.02
10,85
10.85
11.68
12.51
13.33
14.16
14.99
,5.82
15.82
16.64
4.41
626
62.
6.15
7.02
7.69
7.89
6.76
8.76
9.SS
10.50
11.37
12.24
1224
13.11
13.96
13.98
14.85
15,72
15.72
16.59
17.46
0.05
0.95
1.86
2.n
2.77
3.58
'.58
4.59
.
.0
550
6.41
7.32
8.23
9.14
10.05
10.96
11.87
12.76
12.78
13.68
14.59
15.50
16,41
17.32
18.23
1B.23
'.00
0.08
0.09
0.16
02.
0.31
0.39
0.47
0.55
0.63
0.71
0.00
0.08
0.17
0."
0.33
0.41
0.50
0.56
0.58
0.66
0.75
0.00
'.00
O.OS
0.09
0.17
.,6
0.35
0.43
0.52
0.61
0.70
0.78
0.00
0.09
0.18
0.27
0.S8
0.38
0.45
0.55
0.84
0.73
0.,
'.03
'.00
4.82
,."
,.'"
0.93
....I.'"
2.67
3.>.
'.63
756
756
759
7"
761
781
0.02 -0.00
1.00
0."
1.93 2.00
2.88
3.00
2."
3.63
3."
'.00
4.79 5.00
5.74
5.00
.110
5.59
7.00
7.84
'.00
8.BO
8.60
9.00
9.55 10.00
10.50 11.00
11.46 12.00
12.110
12.41 13.00
13.36 14.00
14.31 15.00
15.27 15.00
16.00
16.22
".22 17.00
17.17 19.00
lB.OO
18.12 19.01
19.08 20.01
'.79
'.59
."
0.00
0.10
0.19
0.29
0.'"
0."
O.4B
0.57
0.67
0.76
"5
,..
0.00
0.10
0.20
0.30
0.40
0.50
0.60
O.eo
0.10
0.70
,.eo
o.eo
0.90
755
765
767
758
770
,.,
'"
'.00
FIG. X3.2 Corrected Loss from Observed Loss and Barometric Pressure mm Hg
24
782
76.
764
0.110
0.00
0.11
0.21
0.32
0."
0.42
0.53
0.03
0.74
0.84
0.95
'.63
,."
....
.,
'.50
."
0.00
0.11
0.22
0.33
0."
0.44
'.44
0.56
0.87
0.78
0.89
1.00
0.00
0.12
0.24
0.35
0.47
0.59
0.71
0.82
0.94
1.06
'.59
771
'"
774
776
-0.13
1.13
2.36
2."
'.63
'.88
6.13
7.39
7.38
e.63
9.88
11.13
12.38
13.63
14.86
16.13
17.38
17.36
18.63
19.88
21.13
22.38
23.64
24.89
-0.17
1.i7
1.17
2.50
3.83
S.83
5.17
5.50
7."
9.17
10.SO
10.50
11.84
13.17
14.51
15.84
"-'4
17.17
18.51
19.84
21.18
22.51
23.84
25.18
26.51
0.00
0.13
0.5
025
0.38
0.50
0.63
0.75
0.88
0."
1.00
1.13
0.00
0.15
0.21
0.27
0.40
0.53
'.53
0.67
0.80
0.93
1.07
1.20
..'.63"
'.63
'."
22"
'.50
<0 D86-07
X4. PROCEDURE TO EMULATE THE EMERGENT STEM ERROR OF A
MERCURYINGLASS THERMOMETER
X4.1 When an electronic or other sensor without an
emergent stem error is used, the output of this sensor or the
associated data system should emulate the output of a mercuryinglass thermometer. Based on information supplied by four
manufacturers of automated Test Method D 86 equipment. the
averaged equations shown in X4.2 and X4.3 have been
reported to be in use.
ASTM7CTeir
(X4.1)
ASTM 8C Tellr
(X4.2)
where:
Tell'
Tell/'
Tt
= true temperature in
eters,
X4.2 When a low range thermometer would have been
used, no stem correction is to be applied below 20C. Above
this temperature, the correction is calculated using the following formula:
mometers, and
25
e.
<0 D86-07
"Percent Recovered" Report Form
Ambient
Ambient temperature
temperature at
at the
the start
start of
of tre
the
Date:
Date:
Time
Time
Operator:
Operator:
Ambient barometric
barometric pressure
pressure at
at the
the start
start of
of
Ambient
test
the test
/.F,;:",===::~========:===::~=::===~
Volume of
0 condensate observed In the
.."
reEeiving
reEeiving cylindsf
cylindsf lit
lit .3!'ly
.3!'ly pOint
pOint in
in the
the
distlUation, expressed as a ):J9rcentage
):J9rcentage of the
charge
charge volume.
volume. In
In connection
connection with
with
simultaneous
simultaneous terrperatU'e
terrperatU'e reading
reading
.r
~'~
temoerature ('DC
Ambient temperature
(Ie).
A1mosoheric pressure
orese.:ure kPa
kPa
A1mospheric
Condenser 1smp13rature
e
1smD13rature (OC)
Percent
Percent
Re covere d
Recovered
'
Temper<lture
Temper<lture mea:::urlng
mea:::urlng dSl/lce
dSl/lce reac:lng-s
reac:lngs
~~""~ro~m;e~t=r;IC~Pl~;.;,,;.:u:r.:;::;:;:;;:::::::;;:===
barometriC pressure
~.
~
~
/'
Correclad
Correclad
Temperature
",CJ
Readin"
Read,"
Time Dr
Dr
Time
L I mill
mL!
m
f"0
ro
GrOL..p
GrOL..p 1,2
1, 2 &
& 3:
3:
Group 4:
Group 18<2:
~ IGroup
55 to
to 10
10 mrnutes
mrnutes
55 to 15 minutes
60 to 100 5&onds
/
/~
4 ta 5
18P
I El P
5
10
10
15
15
20
25
30
35
35
40
40
Volume of condensatE:!
I:olume
condensats observ&l
observsd in the
receiving cylinder whsn the final baiting
boitlng pont
is observed
/~I~;,a;";',m~U~m~D~e~rc~e;n;t;recover;;:;;e;d;::====~I
45
~~/
~~I:;TI~m~e-;fro~m~5~m:;:';:'n::;fl;:.';-k;:t~O:;F::::8P;:::-=<;:5;:::rru;:n=ut;:e~sI
I
Percent RssiduB
Percent
T01al RecQ'1'erv
RecQ'1'erv
Percent T01al
Percent Loss
Rec(l"I,1'erv
C(Jrrec1ed Percent Rec(I'I,1'erv'
---- ~
-------
----~
------
_-
.-----"
Con'edad
Con"ec1ecl Loss
Corrected Total Recover\,
Comments".
Comments.
FIG. XS.1 Percent Recovered Report Form
26
II
Dt""~lrl1:
DP"'5Stre"
combined Percent Recover.,- and Percent
RESidue In the flask corrected for barometric
pressure
I!COmblned
<0086-07
Lab.ratory:
itt!
Hn the
r at ~nj point In ~:e
percentage
the
at~~-',as apontln
the of the
IVow,
Irl';.'~;i::' -,.,
i::~=
~'.~ '.N"~"
~ _n=_',:;;,"':-
pressure II<Pa)
IK~a)
I :, Dressure
/"
/
'
./
Recovered
Corretted
Temperature
Reading rq
Time Of
mL/min
,at
lOt
Irq
IrCl
~=~):2&3:
~~I2&3:
GrouP
...--
---
JI IP
.~
........
....r.r
Percent
"roup
roup 1 &
& 2:
;;,-= 3 to 44 minutes
minute,
~~
'~~..?',,1,
=~:a 2, 3~_4~:
&4:4t05ml/rm
to 5 mil rm
ffiI;;i\isk
rate from 5% recoveredlto5
to 5
mli1l1ask
25
3J
,/
35
40
,./
./
,..-/
.
...-
Jl5
90
_90
5 ml residue
96
FBP
,
.//
,./
L
.//'
ett as
fla,~x::::,ed
I:~~:r"'
I~~~:; ,~~~.,I the na,s;x::::s
----- ---,/
--- /
......--
..,/
/
./'
FBP
the IInaI
final boilng
IMa>Inl:rn
IMa:<ITIIJTIII
.,/'
/'
,..,/'
.-'"
/"
~
the
~i~~
pont Is ;";""ed
i~~ed
/-"
"
,/
/"
'
.,/'
/'"'
/ IVowof,
V:~O,fl
. '/
/
-------- --------./
/
'
./
ReeDYeIV
Percent Recovery
Residue
Percent Ilesidue
Percent Total
Percsnr
iDlal Recovery
Percent
PercenllLoss
.oss
Correcl~d
CorrectecIPercent I
,./
./
...-,.-
65
.
//'
., //
,..-'
/
,
.//
./
, ob..vedj In the
,..-'
/
..../'
,/
./'
-5~'-;"'
5 to 15 minutes
60 to 100 seconds
,econds
~~~:
time tr~cm nrst ~I'."aticn
, heat ro
~::~":,
. I of
20
j5
n,""',"
to5~ minutes
;52t~'~
to 10rrdnutes
rrinutes
4~:
'5
10
I the
''''e
\5P'CI6ed I
~ device r~a~~~~
;::66(j
""'~ or:grapi'jcal
iWfth
,.,"""
./'
Percent
rea~ng
I
iwhiCh-are'
it;ioi:ma
:Ples"e
, ('C)
~I'C
h CaTl&tion with
IResdJe ~ ~,~C:::ltecovery
IResrue
Recovery ;,
.-'"
../
----......-......--
~=~
I~=~ Recovery co"ecceo
L"""c~ 1011
'w
~Lo"r
II
='~'
=e
I~~
It< I
i I
IPercent
I~ombine~tt
;Resid.Ie i1i1 the
01. flask
""" corrected
corrected filr
filr barometric
Ipressure
Comments:
21
.086-07
SUMMARY OF CHANGES
Subcommittee D02.08 has identified the location of selected changes to tins standard since the last issue
(D 86-0S) that may impact the use of this standard. (Approved Jan. IS, 2007.)
Subcommittee D02.08 has identified the location of selected changes to this standard since the last issue,
(D 86-04b), that may impact the use of this standard. (Approved July I, 2005.)
ff not revised, either reapproved or withdrawn. Your comments are invIted either for revision of this standard or for additional standardS
and should be addressed to ASTM Intemational Headquarters. Your comments will receive careful consideration at a meeting of the
responsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you should
make your views known to the ASTM Committee on Standards, at the address shown below.
This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,
United States. Individual reprints (!.lingle or multiple copies) of this standard may be obtained by contacting ASTM at the above
address or at 610-832-9585 (phone), 610-832-9555 (fax), or service@astm.org (e-maJ1); or through the ASTM website
(www.astm.org).
28