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FIITJEE

JEE(Advanced)-2015
ANSWERS, HINTS & SOLUTIONS
CRT I
(Paper-1)

ALL INDIA TEST SERIES

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

Q. No.

PHYSICS

CHEMISTRY

MATHEMATICS

1.

A, B

A, B, C, D

2.

C, D

A, B, C

A, B, C

3.

A, B, D

A, C

C, D

4.

A, C

B, C

A, B, C, D

5.

A, B

A, C

A, B

6.

A, D

A, B, C, D

7.

C, D

B, D

8.

A, C

A, D

A, D

9.

A, D

B, D

A, B, C

10.

B, D

A, B

A, D

1.

2.

3.

4.

5.

7.

8.

9.

10.

6.

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

Physics

PART I
SECTION A

1.

Using concept of relative velocity we can


solve

vA
v

B(d, )

(0, 0)
R min

3.

Use v 2 u2 2as
And impulse = change in momentum

4.

Use v

2gh

where, 1

I
Mr 2

5.

Use work energy theorem

6.

Buoyant force FB = Vegeff


If lift accelerates
geff = g + a

7.

v v0
Use, app v

v vs
v = speed of sound

8.

for isothermal process, PV = constant


For adiabatic process, PV = constant

9.

Electric field at centre = 0


So, charge q will produce same electric
field as induced charge on sphere at centre
so A & D

10.

vB vj

R
d

Using conservation linear moment and conservation mechanical energy.

SECTION C
1.

For translation position of A will be 2.

2.

formula for rod and are both are


k
k
sin sin i cos cos j
d
d

So, E 0 and b = 0

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3
AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

3
P0 V0
2
P V P1V1
U 2 2
1
3
Q P0 V0
2
k=3

6.

work done =

7.

f1 = f

30 m/s

C
330
f
1000 Hz
C 30
300
C v0
360 330
f2
fw

1000 1200 Hz
C
330 300
Frequency Band width = f2 f1 = 200 Hz
fw

8.

Fnet Fpseudo FBuoyant V 2 10 v 10 v 10


a

9.

30 m/s

IL
IC

Fnet v 10

5 m/s
n
v 2
100
50 2
100

2 A

2
50 2
Isource IL IC 0

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4
AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

Chemistry

PART II
SECTION A

1.

Dacron is a copolymer of ethylene glycol and terephthalic acid

2.

A
ZA

A 4
Z 2

A 4
Z 1

A 4
Z

- emission gives isodiapher.


3.

From kinetic theory of gases


K. E. T
MNa2CO3

4.

WB 1000
mB V

5.3 1000
0.5
106 100
W 1000
B
EB V

NNa2CO3

NH2C2O4 .2H2O

5.3 1000
1
53 100
n-factor =2
o
Eredox

change

6.3 1000
0.5
126 100
N 1000
B
EB V

5.

WB 1000
mB V

MH2 C2O4 .2H2O

6.3 1000
1
63 100
n-faction = 2

will be negative for non-spontaneous reaction

Ni2 aq Cu s Ni s Cu2 aq
o
Eo EoNi2 / Ni ECu
0.25 0.34 0.59V ve, non spon tan eous
2
/ Cu

Cu s 2H aq Cu2 aq H2 g
o
Eo EHo /H ECu
0 0.34 0.34V ve, non spon taneous
2
/Cu
2

6.
H

Ring

Exp

H O
2

OH OH

OH

OH
O

7.
i CH3MgBr
CH3 CHO

ii H2O

H3C

H SO /

HBO
2
4
CH3 CH CH2 CH3 CH2 CH2 OH
CH3

OH
B
2

8.

Compounds have all c atom sp hybridised are coplanar.

9.

B. O. of NO = 2.5, paramagnetic
NO+ = 3.0, diamagnetic

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

10.

Cr 3 , d3 configuration shows same number paired e and EAN but strength of all ligands are
different so does not slow same colour and splitting.

SECTION C
1.

[Mabcd] type square planar complex has 3 G. I.

2.

NO2 HCl HNO2 Cl


3HNO2 HNO3 2NO H2 O
2NO O2 2NO2
SO23 HCl H2O 2Cl SO2
HCO3 HCl H2O CO2 Cl

3.

Cl

Cl

Br

Br

Br

Cl

Br

Br

meso

5.

Cl

Br

Br

Br

Enatiomers

Aromatic compounds

,
N

, N

, graphite
N

A layer of graphite (graphene) contains infinite lattice of fused aromatic rings. All the valencies
are satisfied (except at the edges) and no bonds are needed between layers. (Planar layered
structure of fused aromatic rings).
6.

5 mol H2 SO 4 5 98 490 gm of H2 SO 4

5M
1000 ml of solution 1000 1.115 1115 gm solution

wt. of solvent = 1115 490 = 625 gm


moles of solute
5
m

8 mol / kg
wt. of solvent in kg 625 103
7.

1s
15 P

,2s2 ,2p6 ,3s2 3p3

For s = 0, m = 0, e = 6
-1

For p, = 1, m =

+1
0

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

-1

2e
Total e = 6 + 2 + 1 = 9
8.

0
1
1e

PCl5
PCl3 Cl2
a
a ax

0
a

Kp

2P
1

0
a 0.50

Kp
P

0.5 0.5
0.75

P
3
KP

P = 3 KP
O

9.

O
S

O
O

10.

Mn CN

6
x + 6(1) = 3
x = +3
Mn3 Ar 3d4 4S0

t 2g

eg

As CN is strong ligand hence due to splitting it will from low spin complex.

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7
AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

Mathematics

PART III
SECTION A

1.

2.

4 x1

x
1
2 1
x2
x2

1 x2

x
1
2 2
x3
x3

4 x3

x
1
2 3
x4
x4

1 x4

x
1
1
1
1
1
4
2 4 16 x1
x2
x3
x 4 2
x1
x1
x
x
x
x

2
3
4
1

2
Any point on xy = 2 is P 2t,

2 2
Normal at P is y
t x 2t
t

3.

ABC BPC APC


1
1
ar br
2
2
2
r
ab

cos

4.

A
B
C
cos cos
2
2
2

5.

s s b
ac

s s c
ab

s
abc

z4 z4
2
2

0 which is a circle x + y 4x 2y = 0
z 2i z 2i
xx1 + yy1 2(x + x1) (y + y1) = x12 y12 4x1 2y1
2
2
It passes through (0, 0), so, the locus of (x1, y1) is x + y 2x y = 0.
So, z1 = x1 + iy1, lies on this circle for which the points (2, 0) and (0, 1) are extremities of a
diameter. Also (0, 0) and (2, 1) represent extremities of another diameter
I

dx

cos x ln x

e e
7.

bc

1
. Thus P(A1 A2) = P(A1) P(A2)
2

6.

s s a

1
2
, P(A1) =
4
4

P(A1 A2) =
P(A2) =

1 x 2 dx

3
2

f(t) = t t + t + 1
f(t) > 0
max.{f(t): 0 t x} = f(x)

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

2 sin

x 3 sin x 1

8.

Put 2

9.

En = 3 + C23 + C43 + ..
On = nC13n1 + nC33n3 + ..
Adding and subtracting, we get En + On = (3 + 1)n = 4n, En On = (3 1)2 = 2n
4n 2n
Adding and subtracting again, we get 2En = 4n + 2n En
2
n
n
4

2
n
n
2On = 4 2 On
2

10.

n2

n4

dx
x 2 y 3 xy
dy
dx
xy x 2 y 3
dy

1 dx y
y3
x 2 dy x

Put

1
t
x

SECTION C
1.

c3

3 x

4 1
3
3
x
AB
4
2
cos

1
A

p 4 2 3 2 7 and c 3M

CM 7
2.

3.

M
x

7
4

B p 7
3

c1

7 3 7

4
4

c2
3

x2 + 1 = (x + i)(x i)
b = 1, a = c
Number of ways of choosing a, b, c = 10 = 10 1
k=1

Unit vector n perpendicular to OA and CB



3 7 i 4j 5 k
CB OA
n
CB OA
3 7 2 16 5 2
i
j
k

7 3 4 2 2 5
As CB OA 1 3 1 = BA n
3 7 2 16 5 2
1
2
3

Shortest distance = BA n

4.

Replacing x by

1
, we obtain
1 x

Again, replacing x by 1

1
f
f 1
1 x

1
2
2x

x
x

1
x

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AITS-CRT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15

5.

We have a =

x x6 1
2

x 1
x 2 1
x6 + 1 = a
2a
x

2a x6 1
2

6.

(x 1) = 3{1 + cos(ax + bx + c)} solution exists when L.H.S. = R.H. S. = 0


x = 1 and cos(ax2 + bx + c) = 1
When x = 1, x = 1
a + b + c = 3, a b + c =
b = and a + c = 2

7.

f x x i

100

i101 i

i 1

ln f x

100

i 101 i ln x i
i 1

100 i 101 i

1
f ' x

f x
i 1 x i

8.

For any quadrilateral,


a + b + c > d.
Now, (a b)2 + (b c)2 + (c a)2 0
a2 + b2 + c2 (ab + bc + ca)
3 (a2 + b2 + c2) 3 (ab + bc + ca)
3 (a2 + b2 + c2) a2 + b2 + c2 + 2 (ab + bc + ca)
3 (a2 + b2 + c2) (a + b + c)2
3 (a2 + b2 + c2) > d2
(a2 b2 c 2 ) 1

.
3
d2
a2 b2 c 2 1
The minimum value of
is
d2

9.

2 1

As P(, (1 + ) ) lie on y
On solving y

1
2, 5

1
1 x2

1
2,
5

1
with L1, we get
x 1
2

.. (1)

1
and with line L2, we get P2 5,
.. (2)
26
Equation (1) and (2), we get 2 5
10.

P1

5,
P2 26

y+2=0
L1 = 0

L2 = 0

f(x) = cos x 2a cos 2x cos 3x + 2a 0 x R


2 sin2 x (cos x + a) 0
a cos x 1

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