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Product Name 210 CATALYST

Update Date Mar 02,2015

Safety Data Sheet

Number 21000210

Create Date Mar 01,2014


Update date Mar 02,2015

Additive for printing ink

1.PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME

210 CATALYST

COMPANY IDENTIFICATION

Teikoku printing Inks Mfg.Co.,Ltd.

ADDRESS

8-43-2 Nishi-Ogu,Arakawa-Ku,Tokyo 116-0011,Japan

MANUFACTURER'S NAME

THE LABORATORY OFFICE.

TELEPHONE NUMBER FOR


81-3-3800-9911
INFORMATION
FAX NUMBER FOR INFORMATION 81-3-3800-9919
MAIL ADDRESS

rdtkoku@teikokuink.com

EMERGENCY TELEPHONE NUMBER +81-3-3800-6760THE LABORATORY OFFICE.)


RECOMMENDED USES AND
RESTRICTIONS ON USE
NUMBER

Additive for printing ink.


21000210

2.HAZARDS IDENTIFICATION(GHS CLASSIFICATION)


ACUTE
TOXICITY(Inhalation;Vapours) Category 4
GHS LABEL ELEMENTS
SYMBOL
SIGNAL WORD

Warning

HAZARD STATEMENT

H332 Harmful if inhaled.

PRECAUTIONARY STATEMENTS
SAFETY PRECAUTIONARY
STATEMENTS

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.


P271 Use only outdoors or in a well-ventilated area.

FIRST-AID PRECAUTIONARY
STATEMENTS
STORAGE PRECAUTIONARY
STATEMENTS
DISPOSAL PRECAUTIONARY
STATEMENTS

P312 Call a doctor if you feel unwell.


P304P340 IF INHALED: Remove person to fresh air and keep
comfortable for breathing.
P403P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with
local/regional/national/international regulations.

3.COMPOSITION/INFORMATION ON INGREDIENTS
SINGLE OR MIXTURE

MIXTURE.

Chemical Name

Wt

Cas No.

Application of Law

Hexamethylene diisocyanate

1.0

822-06-0

Functional polyisocyanate

90.0-100.0

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Product Name 210 CATALYST

Update Date Mar 02,2015

Number 21000210

Korea "Toxic Chemicals Control Law" applicable to the observational chemicals


Industrial Safety and Health LawDangerous and Harmful Substances Subject to Indicate
Industrial Safety and Health LawDangerous and Harmful Substances Subject to Notify
Ordinance on Prevention of Organic Solvent PoisoningFirst-class organic solvent
Ordinance on Prevention of Organic Solvent PoisoningSecond-class organic solvent
Ordinance on Prevention of Organic Solvent PoisoningThird-class organic solvent
Law concerning Pollutant Release and Transfer Register Class 1 Designated Chemical
Substances
Law concerning Pollutant Release and Transfer Register Class 2 Designated Chemical
Substances
Poisonous and Deleterious Substances Control Act
Chemical Substances Subject

4.FIRST-AID MEASURES
INHALATION
SKIN CONTACT
EYE CONTACT
INGESTION

Remove person immediately to fresh air. Keep warm and


comfortable for breathing. Immediately call a doctor.
Take off immediately all contaminated clothing.Wash with plenty
water. Continue rinsing. If skin irritation or rash occurs: Get
medical advice/attention.
Immediately rinse with plenty water or warm water for 15
minutes. Get medical advice/attention.
Rinse mouth. Do NOT induce vomiting. Immediately call a doctor.

5.FIRE-FIGHTING MEASURES
SPECIFIC HAZARDS

Nonhazardous materials.

Since combustion gas contain toxic gases such as carbon


monoxide, avoid smoke inhalation at the time of fire fighting.
EXTINGUISHING METHODS AND
Use Form , Dry chemical , CO2 , proper fire-extinguishers. Do
EXTINGUISHING MEDIA
not use straight stream of water for the extinguishing media.
FIRE EXTINGUISHING NOTES AND Extinguish a fire from the windward.
FIRE FIGHTING MEASURES
In case of fire in the periphery, move movable container to the
safe place immediately.
Prohibit unauthorized person's entry to the periphery of the
fire site.
Lead unauthorized persons to the safe place.
Use fire-extinguishing powder, fire-extinguishing foam, carbon
dioxide (CO2), and sand for fire fighting.
Spray water for cooling the container.
Be sure to wear suitable protective equipment (protective
gloves/eye protection/face protection, etc.) at fire fighting .

6.ACCIDENTAL RELEASE MEASURES


PERSONAL PRECAUTIONS,
PROTECTIVE EQUIPMENT, AND
EMERGENCY PROCEDURES
ENVIRONMENTAL PRECAUTIONS

Evacuate personnel to safe area. Evacuate non-essential


personnel. Shut off all sources of ignition. No flares, smoking
or flame in area. Wear proper protective equipment.
Do not wash away spills into sewer, watercourse or river.

METHODS AND MATERIALS FOR


CONTAINMENT AND METHODS AND
MATERIALS FOR CLEANING UP

For small spill, absorb spills with inert materials( e.g. dry
sand or earth), then place in a chemical waste containers.
For large spill, dike for later disposal, cover spills with
foam, then place in a chemical waste container using
non-sparking tools.
Wipe off residual spill by using paper.
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Product Name 210 CATALYST

Update Date Mar 02,2015

Number 21000210

7.HANDLING AND STORAGE PRECAUTIONS


HANDLING

STORAGE

Use only outdoors or in a well-ventilated area.Do not handle


until all safety precautions have been read and understood.Wear
protective gloves/protective clothing/eye protection/face
protection.Keep away from heat/sparks/open flames/hot surfaces.
No smoking.Use explosion-proof electrical/ventilating/lighting
equipment.Use only non-sparking tools.Do not get in eyes, on
skin, or on clothing. Avoid breathing
dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after
handling.
Store locked up.Store in a well-ventilated place. Keep cool.Keep
container tightly closed.

8.EXPOSURE CONTROLS AND PERSONAL PROTECTION


CONTROL PARAMETERS

Not Classified.

ENGINEERING MEASURE

RESPIRATORY PROTECTION

Use this product only in a totally enclosed systems or local


exhaust ventilation. Make available in the work area with
emergency shower and eyes washer. Ground/bond container and
receiving equipment.Use explosion-proof
lectrical/ventilating/lighting equipment.Use only non-sparking
tools.Take precautionary measures against static discharge.
Wear respiratory protection.

EYE PROTECTION

Wear eye protection/face protection.

SKIN AND BODY PROTECTION

Wear protective gloves/protective clothing/eye protection/face


protection.
Wear protective gloves.

HAND PROTECTION
OTHER PROTECTION

The adsorption in the masks is exchanged at regularity or each


use.

9.PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE (Form)

Liquid.

APPEARANCE (color)

Light-Yelllow

ODOUR

Odour of Organic Solvent.

pH

No information is available.

MELTING POINT

No information is available.

BOILING POINT()

No information is available.

FLASHPOINT()

225.0

UPPER/LOWER FLAMMABILITY OR
EXPLOSIVE LIMITS
VAPOUR PRESSURE

0.9-9.5Hexamethylene diisocyanate)

VAPOUR DENSITY

No information is available.

SPECIFIC GRAVITY (Relative


Density)
SOLUBILITY

1.1-1.2

No information is available.

Not soluble in water.


Soluble in organic solvents.

n-OCTANOL/WATER PARTITION
No information is available.
COEFFICIENT
AUTO-IGNITION TEMPERATURE() No information is available.
DECOMPOSITION TEMPERATURE() No information is available.

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Product Name 210 CATALYST

Update Date Mar 02,2015

Number 21000210

10.STABILITY AND REACTIVITY


STABILITY

It stabilizes under the normal temperature.

INCOMPATIBLE MATERIALS

Strong oxidizing agents.

CONDITIONS TO AVOID

Heat, flames and sparks.High temperature and humidity.

HAZARDOUS REACTIONSOCCURRING No information is available.


UNDER SPECIFIC CONDITIONS
HAZARDOUS DECOMPOSITION
The harmful gases such as CO and NOx.
PRODUCTS

11.HAZARD INFORMATION
ACUTE TOXICITY

SKIN IRRITATION/CORROSION

Hexamethylene diisocyanate
Oral LD50747mg/kg(Rat)
Dermal LD50593mg/kg(Rabbit)
Inhalation Vapours LC5020ppm(Rat)
Inhalation DustMist Classification not possible.
Hexamethylene diisocyanate Category 1A1C(Rabbit)

SERIOUS EYE DAMAGE/IRRITATION Hexamethylene diisocyanate Category 1(Rabbit)


RESPIRATORY OR SKIN
SENSITIZATION
SPECIFIC TARGET ORGAN
TOXICITY-SINGLE EXPOSURE
SPECIFIC TARGET ORGAN
TOXICITY-REPEATED EXPOSURE

Hexamethylene diisocyanate
RESPIRATORYCategory 1(Human)
SKIN SENSITIZATIONCategory 1(Cavy)
Hexamethylene diisocyanate
Category 1Respiratory organs(Rat)
Hexamethylene diisocyanate
Category 1Respiratory organs(Human)

12.ECOLOGICAL INFORMATION
ECOTOXICITY

No information is available.

PERSISTENCE AND DEGRADABILITY No information is available.


BIOACCUMULATIVE POTENTIAL

No information is available.

MOBILITY IN SOIL

No information is available.

HAZARD TO THE OZONE LAYER

No information is available.

13.NOTES ON DISPOSAL
WASTE FROM RESIDUES

CONTAMINATED CONTAINER AND


CONTAMINATED PACKAGING

Do processing such as detoxification, stabilization, and


neutralization to lower hazard level as much as possible before
disposal.
Disposal of container and contents must be entrusted to waste
disposer authorized by local authorities.
Clean the container for recycling or appropriately dispose under
the related laws and regulations and the standard of local
government.
In case of disposal of empty container, remove the contents
completely.

14.TRANSPORT INFORMATION
UN NUMBER

It is not classified in the definition.

NAME OF PRODUCT (UN PROPER


SHIPPING NAME)

It is not classified by definition.

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Product Name 210 CATALYST

Update Date Mar 02,2015

Number 21000210

UN CLASSIFICATION (TRANSPORT This product is not classified in the definition.


HAZARD CLASS)
PACKING GROUP
It is not classified by definition.
MARINE POLLUTANT (Y/N)

No

INDICATION NUMBER FOR


EXTINCTION IN JAPAN
PRECAUTIONS

171
It is necessary to retain yellow card at the time of
transport.
Do not transport with food and feed.
For transportation, avoid direct sunlight, load without
container damage, corrosion, and leakage and ensure prevention
of load shift.
Do not load heavy goods on top of it.

15.REGULATORY INFORMATION
REGULATIONS RULE

Please refers national measures that may be relevant.


All materials for this product are registered in the CAS, TSCA,
EINECS(ELINCS).
Industrial Safety and Health Law.
Law concerning Pollutant Release and Transfer Register.
Road Act (dangerous articles transportation on the tunnels under
the water,long tunnels and else for loading limitation)
Dangerous article ship transportation and storing rule
4th group Dangerous Substance 4th group petroleum under the
Japanese Fire Defense Law.
Poisonous and Deleterious Substances Control Act.

16.OTHER INFORMATION
REFERENCE

CHANGE IN CONTENTS OF
DESCRIPTION, ETC.

1)ACGIH2010)
2)Japan society for occupational health.(2012-2013)
3)ICSC CARD http//:nihs.go.jp/ICSC
4)Kanagawa environmental research center date base.
5)Nite incorporated administrative agency national institute of
technology and evaluation.
6)Raw material safety data sheet.
7)Guideline of GHS(Japan Chemical Industry Association)
8)JIS Z 7252-2009
9)JIS Z 7253-2012
10)IARCvol.185)
This information is furnished without warranty, express or
implied, except that it is accurate to the best knowledge of
Teikoku Printing Inks Mfg. Co., Ltd. It relates only to the
specific material designated herein, does not relate to use in
combination with any other material or in any process. Teikoku
Printing Inks Mfg. Co., Ltd. assumes no legal responsibility for
use of or reliance upon this information.

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