QC 1 | FINALS Q2 SPECIAL METHODS

1. Calculate the water content of Streptomycin powder using 5g sample. The water equivalent factor of the Karl Fischer Reagent was 3.6 and the
volume consumed was 9.2ml. The %water content was:
2. What is the acid value of a fatty acid sample weighing 3.5g which require 42ml of 0.1090N NaOH to bring about the endpoint.
3. If a sample of white wax is found to have an acid value of 63.1 and a saponification value of 72.3, what is the ester value of the sample?
4. Determine the iodine value of an unknown sample of oil weighing 0.26g if 33ml and 14.7ml of 0.0988N of sodium thiosulfate are required for
the blank and residual titration, respectively. Identify the sample given the USP requirement of: (Persic oil 90-108, Corn oil 102-128, Olive oil
79-88, None of the choices)
5. In phenol content determination of a volatile oil, the layer in the graduated neck of the cassia flask read 2.3ml obtained from a sample of
10ml of the oil after treatment with KOH solution. The %phenol is:
6. A crude drug weighing 10.0525g was dried in an oven for several hours yielding a residue equivalent to 3.6572g. Calculate the weight loss
on drying.
7. A sample of corn oil weighing 1.6g saponified with 25ml of 0.4N KOH required 9ml of 0.5N HCl to titrate the excess KOH. In the blank
determination 20ml of 0.5N HCl was required to titrate the alkali. Calculate the saponifiation value of the sample
8. What is the percent phenolic content of the clove oil if 10ml was used as sample and after treatment with KOH TS, the non-phenolic layer at
the neck of the cassia flask measured 1.5ml?
9. If a 2g sample of cod-liver oil required 4.5ml of 0.02N NaOH in the titration of the free fatty acids, what would be the acid number of the oil?
10. If a sample of beeswax has an acid value of 18.45 and the ester value of 89.8, what is the saponification number of the sample?
11. If a sample of white beeswax has an acid value of 18.45 and a saponification value of 74, what is the ester value of the sample?
12. Find the acid number of a rosin sample weighing 1.1000 grams which required 28 mL of 0.1100N sodium hydroxide to bring about the end
point
13. Find the saponification value of cottonseed oil if a 1.5320 grams sample required 15.7 mL of 0.5100N hydrochloric acid. A blank was run
using 26 mL of 0.5100N hydrochloric acid.
14. Determine the iodine value of oil weighing 0.2100g, if 24.5 mL and 12.0 mL of 0.1100N sodium thiosulfate solution are required for the blank
and residual titrations, respectively.
15. If a sample of beeswax is found to have an acid value of 20.4 and a saponification value of 89.8, what is the ester number of the sample?

QC 1 | FINALS Q2 SPECIAL METHODS

1. Calculate the water content of Streptomycin powder using 5g sample. The water equivalent factor of the Karl Fischer Reagent was 3.6 and the
volume consumed was 9.2ml. The %water content was:
2. What is the acid value of a fatty acid sample weighing 3.5g which require 42ml of 0.1090N NaOH to bring about the endpoint.
3. If a sample of white wax is found to have an acid value of 63.1 and a saponification value of 72.3, what is the ester value of the sample?
4. Determine the iodine value of an unknown sample of oil weighing 0.26g if 33ml and 14.7ml of 0.0988N of sodium thiosulfate are required for
the blank and residual titration, respectively. Identify the sample given the USP requirement of: (Persic oil 90-108, Corn oil 102-128, Olive oil
79-88, None of the choices)
5. In phenol content determination of a volatile oil, the layer in the graduated neck of the cassia flask read 2.3ml obtained from a sample of
10ml of the oil after treatment with KOH solution. The %phenol is:
6. A crude drug weighing 10.0525g was dried in an oven for several hours yielding a residue equivalent to 3.6572g. Calculate the weight loss
on drying.
7. A sample of corn oil weighing 1.6g saponified with 25ml of 0.4N KOH required 9ml of 0.5N HCl to titrate the excess KOH. In the blank
determination 20ml of 0.5N HCl was required to titrate the alkali. Calculate the saponifiation value of the sample
8. What is the percent phenolic content of the clove oil if 10ml was used as sample and after treatment with KOH TS, the non-phenolic layer at
the neck of the cassia flask measured 1.5ml?
9. If a 2g sample of cod-liver oil required 4.5ml of 0.02N NaOH in the titration of the free fatty acids, what would be the acid number of the oil?
10. If a sample of beeswax has an acid value of 18.45 and the ester value of 89.8, what is the saponification number of the sample?
11. If a sample of white beeswax has an acid value of 18.45 and a saponification value of 74, what is the ester value of the sample?
12. Find the acid number of a rosin sample weighing 1.1000 grams which required 28 mL of 0.1100N sodium hydroxide to bring about the end
point
13. Find the saponification value of cottonseed oil if a 1.5320 grams sample required 15.7 mL of 0.5100N hydrochloric acid. A blank was run
using 26 mL of 0.5100N hydrochloric acid.
14. Determine the iodine value of oil weighing 0.2100g, if 24.5 mL and 12.0 mL of 0.1100N sodium thiosulfate solution are required for the blank
and residual titrations, respectively.
15. If a sample of beeswax is found to have an acid value of 20.4 and a saponification value of 89.8, what is the ester number of the sample?

QC 1 | FINALS Q2 SPECIAL METHODS

1. Calculate the water content of Streptomycin powder using 5g sample. The water equivalent factor of the Karl Fischer Reagent was 3.6 and the
volume consumed was 9.2ml. The %water content was:
2. What is the acid value of a fatty acid sample weighing 3.5g which require 42ml of 0.1090N NaOH to bring about the endpoint.
3. If a sample of white wax is found to have an acid value of 63.1 and a saponification value of 72.3, what is the ester value of the sample?
4. Determine the iodine value of an unknown sample of oil weighing 0.26g if 33ml and 14.7ml of 0.0988N of sodium thiosulfate are required for
the blank and residual titration, respectively. Identify the sample given the USP requirement of: (Persic oil 90-108, Corn oil 102-128, Olive oil
79-88, None of the choices)
5. In phenol content determination of a volatile oil, the layer in the graduated neck of the cassia flask read 2.3ml obtained from a sample of
10ml of the oil after treatment with KOH solution. The %phenol is:
6. A crude drug weighing 10.0525g was dried in an oven for several hours yielding a residue equivalent to 3.6572g. Calculate the weight loss
on drying.
7. A sample of corn oil weighing 1.6g saponified with 25ml of 0.4N KOH required 9ml of 0.5N HCl to titrate the excess KOH. In the blank
determination 20ml of 0.5N HCl was required to titrate the alkali. Calculate the saponifiation value of the sample
8. What is the percent phenolic content of the clove oil if 10ml was used as sample and after treatment with KOH TS, the non-phenolic layer at
the neck of the cassia flask measured 1.5ml?
9. If a 2g sample of cod-liver oil required 4.5ml of 0.02N NaOH in the titration of the free fatty acids, what would be the acid number of the oil?
10. If a sample of beeswax has an acid value of 18.45 and the ester value of 89.8, what is the saponification number of the sample?
11. If a sample of white beeswax has an acid value of 18.45 and a saponification value of 74, what is the ester value of the sample?
12. Find the acid number of a rosin sample weighing 1.1000 grams which required 28 mL of 0.1100N sodium hydroxide to bring about the end
point
13. Find the saponification value of cottonseed oil if a 1.5320 grams sample required 15.7 mL of 0.5100N hydrochloric acid. A blank was run
using 26 mL of 0.5100N hydrochloric acid.
14. Determine the iodine value of oil weighing 0.2100g, if 24.5 mL and 12.0 mL of 0.1100N sodium thiosulfate solution are required for the blank
and residual titrations, respectively.
15. If a sample of beeswax is found to have an acid value of 20.4 and a saponification value of 89.8, what is the ester number of the sample?