Documentos de Académico
Documentos de Profesional
Documentos de Cultura
January 2015
January 2015
Publications Code IA040464
All the material in this publication is copyright
Pearson Education Ltd 2015
All candidates must receive the same treatment. Examiners must mark
the first candidate in exactly the same way as they mark the last.
Mark schemes will indicate within the table where, and which strands of
QWC, are being assessed. The strands are as follows:
i) ensure that text is legible and that spelling, punctuation and
grammar are accurate so that meaning is clear
ii) select and use a form and style of writing appropriate to purpose and
to complex subject matter
iii) organise information clearly and coherently, using specialist
vocabulary when appropriate
WCH02_01
1501
WCH02_01
1501
Correct Answer
Question
Number
2(a)
Correct Answer
Question
Number
2(b)
Correct Answer
Question
Number
3
Correct Answer
Question
Number
4
Correct Answer
Question
Number
5
Correct Answer
Question
Number
6
Correct Answer
Question
Number
7
Correct Answer
Question
Number
8(a)
Correct Answer
Question
Number
8(b)
Correct Answer
Question
Number
9
Correct Answer
Question
Number
10
Correct Answer
Question
Number
11
Correct Answer
Question
Correct Answer
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
WCH02_01
1501
Number
12
Question
Number
13
Correct Answer
Question
Number
14
Correct Answer
Question
Number
15
Correct Answer
Question
Number
16
Correct Answer
Question
Number
17
Correct Answer
Question
Number
18
Correct Answer
1
Reject
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
1
Reject
Mark
Mark
1
Reject
Mark
1
WCH02_01
1501
Section B
Question
Number
19(a)
Question
Number
19(b)(i)
Acceptable Answers
(in NH3 =) -3/3-/-III
(in NO =) +2/2+/+II
Reject
(1)
(1)
Just 2
Acceptable Answers
Reject
Mark
Just
single electron
lone electron
ALLOW non-paired
Ignore references to
reactivity/stability/orbital/charge/location
of unpaired electron
Question
Number
19(b)(ii)
Mark
Acceptable Answers
Electrons
Free electron
Reject
Mark
2
ALLOW
WCH02_01
1501
Question
Number
19(c)
Acceptable Answers
Reject
Mark
Harmful/
Dangerous
(2)
OR
Wear gloves
and
(Concentrated) ammonia is corrosive /causes burns
(2)
OR
Safety screens / students wearing safety goggles
and
Risk of explosion / very exothermic
(2)
If the linked points are not made for 2 marks, then
any of the above precautions or hazards scores 1
mark max
Fireflies
flashes
WCH02_01
1501
Question
Number
19(d)(i)
Acceptable Answers
Reject
Mark
2
Atoms
(1)
The curve must clearly start from the origin, rise to a peak
and then decrease, approaching the x axis without
crossing/touching it.
If the curve is concave at the start or rises at the end then
this mark is lost.
Question
Number
19*(d)(ii)
Acceptable Answers
Reject
Mark
Ea
catalyst
to the
RHS =0
WCH02_01
1501
Question
Number
Acceptable Answers
Reject
19(e)
Marking point 1
Catalysts weaken/break the bonds of the
reactants
OR
Increase the collision rate/number of collisions
(1)
Mark
2
Marking point 2
Any one of:
Reaction takes place on the (catalyst) surface
/active sites
(1)
The gaseous reactant molecules adsorb on the
catalyst (and then react)
(1)
Absorb
Question
Number
19(f)(i)
Acceptable Answers
Reject
Mark
(NH4)2Cr2O7
OR
Formula with balanced charges
Question
Number
19(f)(ii)
Acceptable Answers
Reject
Mark
ALLOW
Carry out in a vacuum/remove the air
Question
Number
19(f)(iii)
Acceptable Answers
Reject
Mark
Orange to green
Any other
colours in
combination
e.g.
orangeyellow
WCH02_01
1501
Question
Number
20(a)
Acceptable Answers
Reject
Mark
3
(1)
(1)
(1)
O2
Question
Number
20(b)(i)
Acceptable Answers
Reject
Mark
Primary/ 1
Secondary
Tertiary
WCH02_01
1501
Question
Number
20(b)(ii)
Acceptable Answers
Reject
Marking point 1
Ethanal...
volatile/has low boiling temperature
(compared to ethanol)
Mark
3
ethanoic
acid
ALLOW
evaporates easily/readily
(1)
Marking point 2
Ethanal...
Distils
OR
Boils out of the mixture/boils off
OR
Condenses in the right-hand flask
ALLOW
Passes through the condenser
(1)
Ignore fractional
Marking point 3
Ethanal...
Separates before being oxidized further/completely
OR
Away from the oxidizing agent
ALLOW
Reflux is needed for complete oxidation
OR
Reflux is needed for oxidation (of ethanol) to ethanoic
acid
OR
Reflux is needed otherwise only partial oxidation
occurs
(1)
Question
Number
20(b)(iii)
Acceptable Answers
Prevents pressure building up (by allowing gases to
escape)
Reject
Mark
1
WCH02_01
1501
Question
Number
20(c)(i)
Acceptable Answers
Reject
Mark
White smoke
(1)
OR
(Reagent)
Na/Sodium
(1)
(Observation)
Effervescence / bubbles
Just gas
Any incorrect gas
(1)
WCH02_01
1501
Question
Number
20(c)(ii)
Acceptable Answers
Reject
Absence of
+
sign
CH3CHO+
ALLOW
HCO+
Mark
(1)
(1)
Question
Number
20(d)(i)
Acceptable Answers
C3H8O3 + 3O2 3CO2 + 4H2O
Reject
Mark
1
OR multiples
Ignore state symbols even if incorrect
WCH02_01
1501
Question
Number
20(d)(ii)
Acceptable Answers
Reject
Mark
OR
C3H8O3 + 2O2 3CO + 4H2O
One mark for species
One mark for balancing
(1)
(1)
H2 as product
scores 0/2
Equation for
complete
combustion
scores 0/2
Just smoke
Just carbon
Just blue
flame
ALLOW
Black solid/black deposit/soot
Question
Number
20(e)(i)
(1)
Acceptable Answers
Nucleophilic
Substitution
(1)
(1)
Grey
Reject
Mark
Elimination
Addition
WCH02_01
1501
Question
Number
20(e)(ii)
Acceptable Answers
Reject
Mark
3
()
X=F
(1)
WCH02_01
1501
Section C
Question
Number
21(a)
Acceptable Answers
Reject
Marking point 1
Heat/Bunsen flame and Magnesite
(1)
Marking point 2
Suitable container and delivery tube dipping into the liquid
ALLOW the collection of gas over water/ syringe
(1)
Marking point 3
Limewater turns cloudy/milky/white precipitate
Mark
System
sealed
(1)
WCH02_01
1501
Question
Number
21(b)
Acceptable Answers
Mg(OH)2(s)
Reject
Equation
State symbols
Mark
2
(1)
(1)
(aq)
OR multiples
Symbol mark dependent on correct equation
Question
Number
21(c)
Acceptable Answers
Reject
Any from:
Ca(OH)2/Sr(OH)2/Ba(OH)2
Be(OH)2
Mark
1
ALLOW Ra(OH)2
Question
Number
21(d)
Acceptable Answers
Mg3N2
Reject
(1)
Mark
3
Just remove
nitrogen
(1)
WCH02_01
1501
Question
Number
21(e)
Acceptable Answers
Reject
Electrons are...
promoted
OR
excited
OR
moved to a higher energy level
(1)
Electrons...
return to lower energy level
OR
return to ground state
OR
fall back
(1)
Energy/Light/Radiation/Photon is
emitted/released upon return
IGNORE colour is released
Mark
4
(1)
Proton
Acceptable Answers
Reject
Mark
1
OR multiples
Ignore state symbols even if incorrect
Question
Number
21(g)
Acceptable Answers
H2SO4
Reject
Mark
1
ALLOW
As part of the following equation
MgO + H2SO4 MgSO4 + H2O
Ignore sulfuric acid and references to
concentration
WCH02_01
1501
Question
Number
21(h)(i)
Acceptable Answers
Reject
Mark
3
(1)
(1)
(1)
ALTERNATIVE METHOD
2.55 5 = 120.4 (120.4 + 18x)
(1)
(1)
(1)
WCH02_01
1501
Question
Number
21(h)(ii)
Acceptable Answers
Reject
Mark
(1)
(1)
Reject
Mark
Question
Number
21(i)
Acceptable Answers
90()
(1)
WCH02_01
1501
Question
Number
21(j)
Acceptable Answers
Reject
Mark
1
OR
magnesium oxide forms on the surface
(preventing further reaction)
TOTAL FOR SECTION C (QUESTION 21) = 23 MARKS
TOTAL FOR PAPER = 80 MARKS
WCH02_01
1501
WCH02_01
1501