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abstract
Article history:
The straight use of vegetable oils as fuel in diesel engines entails adjusting several physical
properties such as density and viscosity. By adequately heating the vegetable oil before
entering the injection system, its physical parameters can reach values very close to that of
27 January 2012
diesel fuel. Consequently, by properly adjusting the temperature of vegetable oils used as
engine aging due to incomplete burning. In this study the density and viscosity of several
vegetable oils are studied within a wide variety of temperatures. The optimal range of
Keywords:
temperatures at which each vegetable oil should operate in order to adjust its properties to
Viscosity
those of automotive diesel and biodiesel is then found. Additionally an empirical rela-
Density
tionship between the dependence of viscosity with density is presented. Thus, by means of
the above-described relationship, through measuring the density of a given oil, its viscosity
Diesel engine
Combustion
1.
Introduction
b i o m a s s a n d b i o e n e r g y 4 2 ( 2 0 1 2 ) 1 6 4 e1 7 1
165
2.
Methodology
2.1.
166
b i o m a s s a n d b i o e n e r g y 4 2 ( 2 0 1 2 ) 1 6 4 e1 7 1
Rapeseed
Sunflower
Soybean
Palm
Corn
Grapeseed
Biodiesel
Dodecanoic (lauric)
Tetradecanoic (myristic
Hexadecanoic (palmitic)
Hexadecenoic (palmitoleic)
Octadecanoic (estearic)
Octadecenoic (oleic)
Octadecadienoic (linoleic)
Octadecatrienoic (linolenic)
Eicosenoic (gadoleic)
Docosenoic (erucic)
e
<0.1%
4.7%
0.3%
1.3%
65.3%
19.2%
8.3%
0.7%
<0.3%
e
<0.1%
6.7%
0.3%
2.9%
38.7%
51.3%
<0.1%
<0.1%
e
e
<0.1%
11.2%
0.2%
2.9%
25.2%
55.4%
5.0%
0.1%
e
0.1%
0.9%
45.6%
0.4%
3.8%
38.5%
10.5%
0.1%
e
e
e
<0.1%
11.4%
0.3%
1.7%
32.8%
53.3%
0.5%
<0.1%
e
e
<0.1%
7.2%
0.1%
3.9%
20.2%
68.4%
0.2%
<0.1%
e
e
0.3%
18.6%
0.8%
4.5%
32.0%
39.7%
4.0%
e
e
2.1.1.
Density
(1)
3
where r is the density expressed in g cm , T is the temperature expressed in C, a is the intercept and b is a negative
slope.
2.1.2.
Viscosity
h A1 ,expRT
(2)
(3)
(4)
(5)
(6)
2.1.3.
As both, density and viscosity are highly temperature sensitive, it is possible to find out the dependence between them.
This dependence is often used in the oil industry [30]. The
measurement of density is very simple and quick because it
requires a low-cost hydrometer that is quite easy to use. On
the other hand, the measurement of the viscosity is more
complex and time consuming, requiring a more complex and
expensive assessment instrument employed by qualified
laboratory technicians. If the relationship between density
and viscosity is known, one only needs to measure the density
of a given oil to deduce its viscosity. According to Rodenbush
et al. [27], when dealing with vegetable oils the dependence
between density and viscosity can be expressed as illustrated
in Equation (7).
r D E=h1=2
(7)
Fuel
EN 590
Diesel fuel
EN 14214 Biodiesel
DIN 51605 Rapeseed oil
40 C
0.820e0.845
0.860e0.900
0.910e0.925
2.00e4.50
3.50e5.00
Max. 36.00
167
b i o m a s s a n d b i o e n e r g y 4 2 ( 2 0 1 2 ) 1 6 4 e1 7 1
2.2.
3.
Experimental
Table 3 e Dependence of density with temperature for automotive diesel fuel, pure biodiesel and the analyzed vegetable
oils. SVO density values below 0.860 g cmL3 are in bold.
Density (g cm3)
Temp. ( C)
10
20
30
40
50
60
70
80
90
100
110
120
130
140
Diesel
BD100
Rapeseed
Sunflower
Soybean
Palm
Corn
Grapeseed
0.8376
0.8308
0.8242
0.8181
0.8114
0.8043
0.7970
0.7890
0.7825
0.7759
0.7708
0.7636
0.7577
0.7516
0.8859
0.8798
0.8717
0.8641
0.8583
0.8513
0.8433
0.8372
0.8287
0.8229
0.8150
0.8075
0.8002
0.7912
0.9210
0.9145
0.9080
0.9027
0.8963
0.8911
0.8848
0.8777
0.8724
0.8658
0.8593
0.8537
0.8469
0.8395
0.9251
0.9169
0.9114
0.9043
0.8994
0.8926
0.8877
0.8798
0.8743
0.8670
0.8602
0.8536
0.8472
0.8408
0.9254
0.9185
0.9127
0.9061
0.8998
0.8941
0.8879
0.8817
0.8750
0.8689
0.8626
0.8566
0.8498
0.8430
e
e
e
0.8996
0.8922
0.8845
0.8789
0.8721
0.8664
0.8595
0.8536
0.8457
0.8407
0.8325
0.9237
0.9167
0.9113
0.9046
0.8979
0.8920
0.8864
0.8801
0.8740
0.8678
0.8610
0.8555
0.8489
0.8424
0.9259
0.9188
0.9126
0.9060
0.8998
0.8941
0.8874
0.8813
0.8754
0.8695
0.8626
0.8570
0.8505
0.8440
168
b i o m a s s a n d b i o e n e r g y 4 2 ( 2 0 1 2 ) 1 6 4 e1 7 1
b (104)
r2
Fcalc (104)
Ftab
0.8442
0.8938
0.9273
0.9310
0.9315
0.9250
0.9295
0.9314
6.7009
7.2073
6.1837
6.4145
6.2790
6.5612
6.2053
6.2343
0.99911
0.99932
0.99945
0.99920
0.99985
0.99900
0.99983
0.99982
1.3466
1.7554
2.1884
1.4907
8.0160
9.0182
6.9725
6.7749
4.7472
4.7472
4.7472
4.7472
4.7472
5.1174
4.7472
4.7472
3.1.
(8)
Density
Table 5 e Dependence of kinematic viscosity with temperature for automotive diesel fuel, pure biodiesel and the analyzed
vegetable oils. SVO viscosity values below 6 mm2 sL1 are in bold.
Kinematic viscosity (mm2 s1)
Temp. ( C)
10
20
30
40
50
60
70
80
90
100
110
120
130
140
Diesel
BD100
Rapeseed
Sunflower
Soybean
Palm
Corn
Grapeseed
5.39
4.15
3.30
2.70
2.26
1.92
1.64
1.43
1.27
1.14
1.03
0.93
0.85
0.78
9.00
6.78
5.30
4.26
3.51
2.94
2.51
2.16
1.90
1.69
1.51
1.36
1.23
1.13
119.48
74.19
48.88
34.06
24.68
18.62
14.48
11.58
9.45
7.89
6.70
5.86
5.09
4.47
118.72
73.45
48.46
33.78
24.48
18.52
14.44
11.53
9.44
7.78
6.50
5.62
4.91
4.37
107.62
67.12
44.69
31.42
23.00
17.47
13.67
11.17
9.13
7.71
6.58
5.68
4.99
4.45
e
e
e
45.34
28.19
20.84
15.60
12.35
9.94
8.21
6.88
5.85
5.02
4.38
113.39
70.29
46.54
32.53
23.74
17.96
14.01
11.39
9.34
7.83
6.65
5.70
4.93
4.34
100.63
64.32
42.94
30.19
22.29
17.04
13.34
10.88
8.96
7.53
6.42
5.49
4.77
4.21
169
b i o m a s s a n d b i o e n e r g y 4 2 ( 2 0 1 2 ) 1 6 4 e1 7 1
5
Diesel fuel
BD100
Rapeseed
Sunflower
Soybean
Palm
Corn
Grapeseed
loge(kinematic viscosity)
-1
0.0024
0.0026
0.0028
0.0030
0.0032
0.0034
0.0036
1/Temperature (K-1)
3.3.
Relationship between the kinematic viscosity and
the density
As explained in Section 2.1.3, it is valuable to have a mathematical expression linking density and viscosity of a given fuel
or vegetable oil. Using this approach, by measuring the vegetable oil density, which is simple and fast, its viscosity can be
estimated.
For characterizing the density-viscosity dependence,
a least-squares linear fit should be carried out according to
Equation (7), resulting in the dependencies shown in Fig. 3
From Fig. 3b it is deduced that there exists a linear relationship between density and the inverse of the square root of
the kinematic viscosity, as stated in Equation (7). Table 7
shows a summary of the most relevant parameters related
to density-viscosity1/2 fit obtained by means of Equation (7)
for the whole set of samples analyzed.
Results shown in Fig. 3 and Table 7 indicate that Equation
(7) is accomplished when dealing with the studied vegetable
oils, diesel fuel and pure biodiesel obtained notably high r2
(9)
3.2.
Kinematic viscosity
Table 6 e Important parameters of the loge (kinematic viscosity) versus temperature-1 fit.
Sample
Diesel fuel
Biodiesel
Rapeseed
Sunflower
Soybean
Palma
Corn
Grapeseed
r2
Fcalc (104)
Ftab
1.2202
0.8412
2.5315
1.9493
2.7247
4.5613
2.1769
1.7625
499.62
598.31
2724.34
2358.16
2801.29
4444.00
2469.25
2154.47
373853.59
412410.30
951274.72
893322.03
948792.52
1313500.49
902448.54
837480.85
0.999949
0.999957
0.999965
0.999928
0.999929
0.998765
0.999838
0.999856
23.3391
27.7126
34.5676
16.6119
16.9468
0.7277
7.3942
8.3568
4.7472
4.7472
4.7472
4.7472
4.7472
5.1174
4.7472
4.7472
170
b i o m a s s a n d b i o e n e r g y 4 2 ( 2 0 1 2 ) 1 6 4 e1 7 1
150
Rapeseed
Sunflower
Soybean
Palm
Corn
Grapeseed
-1
125
100
75
Error (%)
Max.
Min.
Average
Rapeseed
Sunflower
Soybean
Palm
Corn
Grapeseed
7.62
8.41
4.44
4.54
4.35
5.27
0.24
0.03
0.14
0.38
0.22
0.10
2.33
2.46
1.84
1.79
1.62
1.40
50
25
4.
0
0.82
0.84
0.86
0.88
0.90
0.92
Density (gcm-3)
b
1.0
0.9
(Kinematic viscosity)
-1/2
(mm s )
-1 -1/2
1.1
0.8
0.7
Diesel fuel
BD100
Rapeseed
Sunflower
Soybean
Palm
Corn
Grapeseed
0.6
0.5
0.4
0.3
0.2
0.1
0.750
0.775
0.800
0.825
0.850
0.875
0.900
0.925
Density (gcm-3)
r2
Fcalc (104)
Ftab
7.1833
6.1125
4.5331
4.4707
4.4546
4.6144
4.5604
4.5744
8.0456
6.5067
4.8285
4.7447
4.7147
4.9634
4.8440
4.8436
0.9989
0.9971
0.9990
0.9988
0.9993
0.9990
0.9993
0.9991
1.1331
0.4123
1.2986
0.9804
1.8284
0.9283
1.8063
1.3833
4.7472
4.7472
4.7472
4.7472
4.7472
5.1174
4.7472
4.7472
references
b i o m a s s a n d b i o e n e r g y 4 2 ( 2 0 1 2 ) 1 6 4 e1 7 1
[26]
[27]
[28]
[29]
[30]
[31]
[32]
[33]
[34]
[35]
[36]
[37]
[38]
[39]
[40]
[41]
171