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Log o, *,Goo
INTRODUCTION
liquid
solid
*
G
10
10
10
10
G'
G''
*
10
10
4
10
Minimum viscosity
10
10
80
100
120
140
160
Temperature T [C]
Equilibrated stoechiometry
6
EFFECT OF MOISTURE
10
PDMS r=1
tc
10
tc+2
tc-2
tc-6
,
Frequencies
1 rad/s
4 rad/s
, 16 rad/s
8
,
10
0.5
t-t c log A
10
10
G'
G''
-6
-2
0
+2
+6
+2
+1
0
-1
-2
tan
10
4
10
Precise
Gel Point
,
,
10
-4
10
-3
10
-2
10
-1
10
10
10
10
10
10
10
10
10
25
Frequency A+ aT [rad/s]
30
35
40
Frequency = 10 rad/s
Initial temperature = 50C
1E+03
3C/min 2C/min
Viscosity
1E+04
1E+02
1000
1E+01
1E+00
0
1C/min
2000
3000
4000
5000
6000
Time t [s]
Figure 6: Measurement of the viscosity profile of an epoxy
resin as a function of the heat-up rate
2 AN003
Viscosity * [Pas]
10
10
10
10
good resin
resin with higher moisture content
-1
10
50
100
150
200
Temperature T [ C]
10
Viscosity * [Pas]
10
at mold temperature:
Sample A
Sample A + 1% Znst.
sample B
at barrel temperature:
sample A
sample A + 1% Znst.
sample B
4
10
10
12
lll
l
$
l
l$
l$
lllll lll
l l ll
l
' l lll
ll
ll
ll
llllllll
l
'
l
l
l
l
l
l
l
llllll llllll
'
)
lllll
l
'l
'
'l
1E+08 ll
l
1E+07
-150 -100
-50
50
100
$
150
200
tan
At the boiling point of water, some of the excess Figure 9: Effect of Zn-stearat on the viscosity profile during
moisture evaporated, leaving voids in the material cure at barrel and mold temperature
and causing the resins viscosity to rise. But as the EFFECT OF CURE TEMPERATURE
temperature increased further, the remaining excess
Beyond the gel point, the modulus increases to
give the adhesive its ultimate strength. Adhesive
strength is evaluated from dynamic modulus
1E+11
1E+01
measurements as a function of frequency and
temperature. Figure 8 shows the dynamic elastic
93C
modulus G and tan versus temperature. For 3
l
135C
1E+10
1E+00
l
ll
l
ll l
different cure temperatures of 93, 135 and 350 oC,
l
l
l
l
l
l
l
l
l
l
l
ll
350C
l
ll ll
ll
ll
l
ll
ll
ll
the Tg of the cured epoxy resin shifted from 130oC
l
ll
ll
ll
l
l
ll
ll
ll
ll
ll
l
l
ll
l
l
ll
ll
l
l
l
l
ll
'
l
l
l
l
ll
l
l
l
l
1E+09
l
l
1E-01
'l lll
ll
l
to over 250oC.
lll
lll
l l l
EFFECT OF ADDITIVES
1E-02
1E-03
250
Temperature T [C]
100
Frequencz 1Hz
10
0.1
1E8
-150
-100
-50
50
100
150
200
250
300
0.01
1E-3
350
Temperature T [C]
200
10
10
10
10
Temperature
Neat Resin
Prepreg
180
160
140
1E7
Temperature T [ C]
1E9
tan
1E10
Viscosity * [Pas]
1E11
120
100
80
10
-1
10
-2
60
40
50