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1.0 INTRODUCTION
1.1 Relevance of work
Ethylene is one of the most important and largest volume petrochemicals in the world
today. It is used extensively as a chemical building block for the petrochemical industry.
The importance of ethylene results from the double bond in its molecular structure that
makes it reactive. Ethylene can be converted industrially into a variety of intermediate and
end products [41]. The major use of ethylene is conversion to low and high-density
polyethylene. Other significant uses of ethylene include chlorination to ethylene dichloride,
used in the manufacture of the polyvinyl chloride (PVC), oxidation to the ethylene oxide,
an intermediate in the manufacture of polyester fibres and films, and the conversion to ethyl
benzene, an intermediate in the manufacture of polystyrene [23].
Ethylene has become an important industrial intermediate and various technologies have
been utilized in ethylene production. Recently, ethylene has taken the place of acetylene in
virtually all large-scale chemical synthesis. However, acetylene itself is a by-product of
modern ethylene production [50].
More than 97% of ethylene around the world is produced by pyrolysis of hydrocarbons,
which is the thermal cracking of petrochemicals in the presence of steam. This process can
be described as the heating of a mixture of steam and hydrocarbon to the necessary
cracking temperature depending on the hydrocarbon used. This mixture is then fed to a
fired reactor or furnace and heated. As a result, the original saturated hydrocarbon cracks
into smaller unsaturated molecules. This process is extremely endothermic, and the product
must be cooled back to the original feed temperature upon leaving the reactor in order to
minimize secondary reactions. [2]
Chemical companies have a variety of options for feedstock as well as processes to produce
ethylene. Economics and environmental issues are the dominant factors considered in the
choice of feedstock and processes of ethylene production.
The focus in this report will be on the steam pyrolysis of hydrocarbons mainly ethane.
There are several reasons for this choice which include the cost of production, availability
of raw materials and the viability of process.
1.2 Objectives
The main objective of this project is to develop a simplified plant design for the production
of ethylene and acetylene which includes a thermal cracking section, quenching section, gas
compression/separation, ethylene purification, and an integrated refrigeration section.
The design is aimed at estimating the production of ethylene and acetylene using ethane as
a feedstock and also to determine the yield of ethylene and acetylene using the steam
pyrolysis process. The design is also aimed at determining the feasibility of the steam
pyrolysis process on an industrial scale.
CHAPTER 2
It is colourless
It is flammable
It has a slightly sweet smell at normal condition, that is ambient temperature and
one atmosphere
2.1.2 Acetylene
Acetylene (IUPAC name: ethyne) with the chemical symbol C2H2 is a hydrocarbon
consisting of two hydrogen atoms and two carbon atoms. As an alkyne, acetylene
is unsaturated because its two carbon atoms are bonded together in a triple bond. The
3
carbon-carbon triple bond places all four atoms in the same straight line, with CCH bond
angles of 180. [16]
Acetylene is an extremely reactive hydrocarbon. It is moderately soluble in water or alcohol
and markedly soluble in acetone. Acetylene has a melting point temperature of -81.5C and
a boiling point temperature of -84C. Physical properties include:
It is a combustible gas
Acetylene is colourless
Once the gas is compressed, liquefied, mixed or heated with air, it becomes very explosive.
inorganic materials with organic synthetics and the further development of radically new
synthesis materials [26].
Our target market is producers of polyethylene products, PVC, and the likes. Some of the
current global market prices of ethylene are as follows: $900/tonne in Asia, 970/tonne and
840/tonne in Europe. [9]
2.4 Feedstock
A variety of feedstock can be used in a steam pyrolysis process. The feedstock for an
ethylene plant could be methane, ethane, propane and heavier paraffin. With the
development of cracking technology, it can also be cracked from crude oil fractions:
naphtha, kerosene and gas oil. Sometimes, raffinates from aromatics extraction facilities
can also be used as feedstock. The choice of feedstock is a compromise of availability,
price and yield. In selecting a process for ethylene production, the most important factor is
the hydrocarbon feedstock. Although this is controlled by conditions like quantity, quality,
and economics, studies have shown that as the molecular weight of the feed hydrocarbon
increases, ethylene yield decreases.
Methane is the first member of the alkane series and is the main component of natural gas.
It is also a by-product in all gas streams from processing crude oils. It is a colourless,
odourless gas that is lighter than air. Methane is mainly used as a clean fuel gas. It is also
an important source for carbon black. Methane may be liquefied under very high pressures
and low temperatures. Liquefaction of natural gas (methane), allows its transportation to
long distances through cryogenic tankers. [17]. Methane, though an important and abundant
fuel, has not been an attractive raw material for ethylene production, because it is thermally
stable and has no carbon-carbon bonds. The carbon-hydrogen bond requires more energy to
break than the carbon-carbon bond. The C-H bond energy is 93.3 Kcal, whereas C-C
energy bond is 71.0 Kcal [6]. The net reaction for methane dehydrogenation is
2CH4
C2H4 + H2 (2)
7
C3H8
2C3H8
2C3H8
2.4.4 Naphtha
Naphtha, an important feedstock for ethylene production, is a collective of liquid
hydrocarbon intermediate oil refining products. It is a mixture of hydrocarbons in the
boiling point range of 30-200 C. For the naphtha cracker process, typical feedstock are
light naphthas (boiling range of 30-90 C), full range naphthas (30-200 C), and special cuts
(C6-C8 raffinates) [29]. Naphtha is obtained in petroleum refineries as one of the
intermediate products from the distillation of crude oil. The processing of light naphtha to
ethylene is similar to the ethane and propane processes.
2.4.5 Kerosene
This is a distillate fraction heavier than naphtha, and is normally a product from distilling
crude oils under atmospheric pressures. It may also be obtained as a product from thermal
and catalytic cracking or hydrocracking units. Kerosene is usually a clear colourless liquid
which does not stop flowing except at very low temperature (normally below -30C).
However, kerosene containing high olefin and nitrogen contents may develop some colour
(pale yellow) after being produced. Currently, kerosene is mainly used to produce jet fuels,
after it is treated to adjust its burning quality and freezing point. Before the widespread use
of electricity, kerosene was extensively used to fuel lamps, and is still used for this purpose
in remote areas. It is also used as a fuel for heating purposes. [17]
Much of the natural gas appears in regions that are remote from markets or pipe lines, and it
is called stranded gas, which is a natural gas field that has been discovered, but remains
unusable for either physical or economic reasons. Most of this gas is flared, re-circulated
back into oil reservoirs, or not produced. In addition, natural gas has a major disadvantage
in transportation. Because of the low density of natural gas, pipeline construction is very
expensive. [2]
Table 2.1 Approximate material balance of pyrolysis with different feed stock
Products,% mass
Gaseous feed
Liquid feed
Ethane
gas-oil
H2 and methane
13.0
28.0
24.0
26.0
23.0
Ethylene
80.0
45.0
37.0
30.0
25.0
Propylene
1.1
14.0
16.4
14.1
14.4
Butadiene
1.4
2.0
2.0
4.5
5.0
Butene mixture
1.6
1.0
6.4
8.0
6.0
C5+
1.6
9.0
12.6
18.5
32.0
Ratio propylene/ethylene
0.003
0.3
0.5
0.4
0.6
58.3
99.0
98.3
96.7
11
The first step in ethylene production is thermal cracking of the hydrocarbon feedstock.
Thermal cracking of natural gas liquids (NGL) or crude oil fractions in the presence of
steam is still the dominant method for the production of ethylene. This thermal
decomposition results from adding heat to the feed to break its chemical bonds. The steam
does not enter directly into the reaction, but it enhances the product selectivity and reduces
coking in the furnace coils. The product of this thermal cracking process is a mixture of
hydrocarbons, which extends from hydrogen and methane to gasoline and gas oil [28].
Most current ethylene processes are basically similar to each other. Ethylene plants use
similar separation units.
In the following sections, each step of ethylene production will be discussed.
12
Thermal cracking of hydrocarbons by indirect heating include the pebble bed reactors, the
fluidized bed reactors, and regenerative furnace. Even though construction costs seem to be
more expensive and the operation to be more complex, ethylene yield by indirect heating is
higher than that obtained in the fired tubular heaters. One of the advantages of the indirect
heating reactors is that crude oil and heavy fuel oil can be used as feedstock because the
coke by-product can be removed continuously or intermittently in the process [6].
The pyrolysis gas leaving the cracker usually has a temperature in the range of 375C to
500C in the case of naphtha pyrolysis and typically from 500C to 600C in the case of
gas oil pyrolysis. The outlet temperature depends upon the amount of the carbon deposits in
the transfer line exchanger [26]. Quenching of the conversion product or rapid temperature
reduction is important to prevent the decrease of ethylene yields caused by secondary
reactions. This is carried out either by transfer line exchangers or by injecting water and oil.
compression stages, the cracked gas is usually cooled in water-cooled exchangers. Water
and hydrocarbons condensed between stages are separated from the pyrolysis gas in interstage separators.
Hydrogen sulphide and carbon dioxide are removed from pyrolysis gas between the third
stage and fourth stage of the compression system. This location is optimum because the
actual gas volume has been reduced significantly in the first three stages of compression
while acidic components are still present in the gas stream [26]. Acid gas produced in
thermal cracking must be removed before the first major fractionation step. In removing
acid gases such as carbon dioxide and hydrogen sulphide, non-regenerative caustic washing
followed by water washing is employed in the most of the existing plants and proves to be
most economic. The pyrolysis gas leaving the caustic scrubber contains less than 1 ppm of
acid gases and hence assures that the final products of the plant will meet specification in
this respect.
Compressed cracked gas usually is dried to reduce the moisture content to 1 ppm or less
and avoid problems with freezing and hydrate formation in downstream low temperature
equipment. In drying the cracked gases, alumina, silica gel, and molecular sieves are used
commercially. Among them, molecular sieves seem to have an economic advantage over
conventional desiccants because of their higher desiccant activities and lower regeneration
temperatures [17]. Recovery of acetylene and removal of acetylenic materials from the
process gas is very important in manufacturing polymer-grade ethylene.
be present. Low temperature straight fractionation, absorption, and selective adsorption are
three different methods to recover and purify ethylene. The aim of this section is to separate
ethylene and acetylene from hydrogen and methane fractions, ethane and propane fractions,
and heavier hydrocarbons. Commercial separation processes operate at four ranges of
pressure: 450-600 psia, 100-150 psia, 70-90 psia, and 30-40 psia. The most popular is the
450-600 psia because it offers an attractive combination of purity, recovery, efficiency, and
investment for large ethylene plants. [41]
In ethylene purification section, demethanized process streams are introduced to the deethanizer in most cases. The de-ethanizer is a simple tower refrigerated by propane or
propylene to make reflux. The net overhead from the de-ethanizer flows to an ethyleneethane separator. This is the second most costly separation step in an ethylene plant because
the volatility is low and a large amount of reflux is required.
15
CHAPTER 3
Feedstock
CRACKING
SECTION
Pyrolysis
gas
QUENCH
SECTION
Water
16
SEPARATION
SECTION
Final
product
heavy hydrocarbons that are contacted with a pillared inter layered clay
molecular sieve or other high silica zeolite containing catalysts in a riser or down flow
transfer line reactor in the presence of steam. It is catalytically pyrolysed at a temperature
of 650 C to 750 C and a pressure of 0.15 to 0.4 MPa for a contact time of 0.2 to 5
seconds. The weight ratio of catalyst to feedstock ranges from 15:1 to 40:1 and the weight
ratio of steam to feedstock is about 0.3:1 to 1:1.
Catalytic pyrolysis combines catalytic cracking and steam pyrolysis and has the advantages
of both catalytic cracking and steam pyrolysis. It can raise the yields of light olefins,
expand the flexibility of products distribution, and simultaneously lower reaction
temperature and decrease energy consumption for the whole system; so it has broad
application prospect. The raw material is usually crude oil.
Considering that the feed that is used in catalytic pyrolysis is crude oil, this process is not
exactly feasible in Ghana for the production of ethylene and acetylene. This is due to the
shortage in supply of Ghanas crude oil. Furthermore, the crude oil which is imported
mainly from Nigeria and Equatorial Guinea is chiefly refined to produced petroleum,
diesel, kerosene, etc. which is highly useful on the market. Furthermore, this process
requires the use of catalysts in large quantities, and which would require frequent plant shut
down in case of short catalyst life.
hydrocarbon feedstock, air, or oxygen and fuels are preheated to about 593C to reduce the
oxygen consumption and increase the yield. The process of ethylene production by
autothermic cracking is based upon the thermal cracking of crude oil using fluidized beds.
[2]
Fluidized bed reactors are relatively new tools in the chemical engineering field developed
for the oil and petrochemical industries. Here catalysts are used to reduce petroleum to
simpler compounds through cracking. Today fluidized bed reactors are still used to produce
gasoline and other fuels, along with many other chemicals. Many industrially produced
polymers are made using FBR technology, such as rubber, vinyl chloride, polyethylene,
and styrene. A major advantage of this process is the ability to operate the reactor in a
continuous state. However because of the expansion of the materials in the reactor, a larger
vessel is often required, which increases the cost of production. Again, the fluid-like
behaviour of fine solid particles within the bed eventually results in the wear and tear of the
reactor vessel. This requires expensive maintenance which adds to the cost of production.
reaction involves some form of catalyst. [8] There are two main types of these membrane
reactors (1) the inert membrane reactor and (2) the catalytic membrane reactor.
The inert membrane reactor allows catalyst pellets to flow with the reactants on the feed
side (usually the inside of the membrane). In this kind of membrane reactor, the membrane
does not participate in the reaction directly; it simply acts as a barrier to the reactants and
some products. [14]
Catalytic Ceramic Membrane is a system for the dehydrogenation of ethane to produce
ethylene and hydrogen through the use of a catalytic ceramic membrane having selective
permeability, thus permitting the separation of hydrogen from the reaction zone which
causes further dehydrogenation of ethane. The catalytic ceramic membrane tube is enclosed
within an alloy tube of suitable composition to permit heating to the temperature range of
300 to 650 C. The reactor is connected to a recovery system which permits separation of
pure ethylene and unconverted ethane. A steady stream of H2O or argon continuously
sweeps away the H2 coming out through the selective membrane, thereby further
facilitating the conversion process. [14]
The membrane reactors major advantage is its combination of reaction and separation to
produce a good amount of conversion and yield. However, the membranes (ceramic and
metallic) are poor in mechanical strength and need to be replaced at regular intervals.
Another major disadvantage is the cost of the membranes and its low resistance to harsh
environments. Also, the membrane reactors are usually used for production on small scale
(g to kg). [11] Considering the amount of ethylene and acetylene we want to produce,
which runs into thousands of tonnes, this process is not recommended.
19
extracting solvent. The gas is then finally sent to the ethylene column where high purity
polymer grade ethylene is recovered as product. The bottoms product containing mainly
acetylene is sent to the acetylene stripper where acetylene is recovered by further
separation.
3.8 Capacity
Our plant is likely to have a capacity of 100,000 tonnes per year of ethylene and about 550
tonnes per year of acetylene. This is because we are operating in a continuous process. Our
main product is ethylene. Acetylene is only a by-product, which is recovered in our quest to
produce 99.95% polymer-grade ethylene to meet market demands. The percentage yield for
acetylene is about 0.2% when using ethane.
22
CHAPTER 4
23
Fresh ethane
Component mass
flowrate
(kg/hr)
Ethane
29189.55
29189.55
TOTAL
Temperature: 70C
Component
mass
flowrate
(kg/hr)
CO2
44
O2
9.6
N2
242.2
H2O(v)
36
331.85
TOTAL
Temperature: 250C
Mass,
%
100
100
Mass,
%
13.3
2.9
73
10.8
100
Material Steam 1
Component
mass
flowrate
(kg/hr)
H2O
5259.6
5259.6
TOTAL
Temperature: 180 C
mass,
%
Pyrolysis furnace
Material stream 2
100
100
Component
mass
flowrate
(kg/hr)
Methane
1062.4992
Ethane
10216.35
Propane
2643.5992
H2O
5201.3132
Hydrogen
1018.2284
Acetylene
82.2172
Ethylene
14166.656
CO2
139.1368
34530.00
TOTAL
Temperature: 840.8 C
Pressure : 107kPa
Fuel/air
Component
mass
flowrate
(kg/hr)
Methane
1544
Air
25890.0922
27390.5322
TOTAL
Temperature: 25 C
Pressure: 101.325kPa
Mass,
%
5.48
94.52
100
24
mass (%)
3.08
29.59
7.66
15.06
2.95
0.24
41.03
0.40
100.00
mass
flowrate
(kg/hr)
Methane
1062.4992
Ethane
10216.35
Propane
2643.5992
H2O
5201.3132
Hydrogen
1018.2284
Acetylene
82.2172
Ethylene
14166.656
CO2
139.1368
34530.00
TOTAL
Temperature: 840.8 C
Pressure : 101kPa
mass (%)
Cooling water 1
3.08
29.59
7.66
15.06
2.95
0.24
41.03
0.40
100.00
Component
Mass
flowrate
(Kg/hr)
H2O
10620
10620
TOTAL
Temperature: 25C
Pressure: 4177 kPa
Mass %
100
100
Transfer-line exchanger
Material stream 3
Steam at 500 C
Component
Mass
flowrate
(Kg/hr)
H2O
10620
10620
TOTAL
Temperature: 500C
Pressure: 16690 kPa
Component mass
flowrate
(kg/hr)
Methane
1062.4992
Ethane
10216.35
Propane
2643.5992
H2O
5201.3132
Hydrogen
1018.2284
Acetylene
82.2172
Ethylene
14166.656
CO2
139.1368
34530.00
TOTAL
Temperature: 350 C
Pressure : 150kPa
Mass %
100
100
25
mass
(%)
3.08
29.59
7.66
15.06
2.95
0.24
41.03
0.40
100.00
mass
(%)
Cooling water 2
Component Mass
flowrate
(Kg/hr)
H2O
26864.82
26864.82
TOTAL
Temperature: 30C
Pressure: 4177 kPa
3.08
29.59
7.66
15.06
2.95
0.24
41.03
0.40
100.00
Mass %
1.0
1.0
Quench tower
Material stream 4
Component mass
flowrate
(kg/hr)
Methane
1062.4992
Ethane
10216.35
Propane
2643.5992
H2O
5.25402
Hydrogen
1018.2284
Acetylene
82.2172
Ethylene
14166.656
CO2
139.1368
29333.940
TOTAL
8
Temperature: 34 C
Pressure : 1930 kPa
Water out
mass
fraction
(%)
3.62
34.83
9.01
0.02
3.47
0.28
48.29
0.47
100
Component mass
flowrate
(kg/hr)
H2O
141737.094
141737.094
TOTAL
Temperature: 80 C
Pressure : 6987 kPa
26
mass
fraction
100
100
mass
fraction
(%)
3.62
34.83
9.01
0.02
3.47
0.28
48.29
0.47
100
Caustic solution
Component Mass
flowrate
(Kg/hr)
NaOH(aq)
45068.4
45068.4
TOTAL
Temperature: 30C
Pressure: 101.325 kPa
Mass
fraction
100
100
Caustic tower
Material stream 6
Component mass
flowrate
(kg/hr)
Methane
1062.4992
Ethane
10216.35
Propane
2643.5992
H2O
5.25402
Hydrogen
1018.2284
Acetylene
82.2172
Ethylene
14166.656
CO2
trace
29194.70971
TOTAL
Temperature: 38 C
Pressure : 3500 kPa
Mass
flowrate
(Kg/hr)
Na2CO3 9631.954
H2O
38520.498
TOTAL 48152.452
Temperature: 40C
Pressure: 101.325 kPa
Mass %
20
80
100
27
Mass, %
3.64
34.99
9.06
0.02
3.49
0.28
48.52
0.00
100
mass
(%)
3.64
34.99
9.06
0.02
3.49
0.28
48.52
0.00
100
Cooling water 3
Component mass
flowrate
(kg/hr)
H2O
87.9234
87.9234
TOTAL
Temperature: 21.5 C
Pressure : 101 kPa
mass %
100
100
Spray tower
Material stream 8
Water out
Component
mass
flowrate
(kg/hr)
H2O
87.9234
87.9234
TOTAL
Temperature: 80 C
Pressure : 101kPa
Component mass
flowrate
(kg/hr)
Methane
1062.4992
Ethane
10216.35
Propane
2643.5992
Hydrogen
1018.2284
Acetylene
82.2172
Ethylene
14166.656
CO2
trace
29194.70971
TOTAL
Temperature: 40C
Pressure : 3500 kPa
mass %
100
100
28
mass
(%)
3.64
34.99
9.06
3.49
0.28
48.52
0.00
100
4.1.6 DEMETHANIZER
Material stream 9
Component mass
flowrate
(kg/hr)
Methane
1062.4992
Ethane
10216.35
Propane
2643.5992
Hydrogen
1018.2284
Acetylene
82.2172
Ethylene
14166.656
28910.6902
TOTAL
Temperature: -120.0 C
Pressure : 2000 kPa
mass %
Material stream 10
Component
mass
flowrate
(kg/hr)
Methane
1062.4992
Hydrogen
1018.2284
Ethylene
141.29108
2267.6624
TOTAL
Temperature: -127 C
Pressure : 3200 kPa
3.97
34.28
9.06
3.60
0.27
49.00
100
Demethanizer
Material stream 11
Component mass
flowrate
(kg/hr)
Methane
11.448
Ethane
9909.4343
Propane
2621.0494
Acetylene
76.7424
Ethylene
14024.7251
26643.4
TOTAL
Temperature: 6.05 C
Pressure : 2600 kPa
29
mass %
0.04
37.20
9.84
0.29
52.63
100
mass
%
48
46
6
100
4.1.7 DE-ETHANIZER
Material stream 11
Component mass
flowrate
(kg/hr)
Methane
11.448
Ethane
9909.4343
Propane
2621.0494
Acetylene
76.7424
Ethylene
14024.7251
26643.4
TOTAL
Temperature: 6.05 C
Pressure : 3006 kPa
mass %
Material stream 12
0.04
37.20
9.84
0.29
52.63
100
Component mass
flowrate
(kg/hr)
Methane
5.048
Ethane
9909.435
Acetylene
76.7416
Ethylene
13954.6
23945.82
TOTAL
Temperature: -34.95 C
Pressure : 3000 kPa
De-ethanizer
Propane product
Component mass
flowrate
(kg/hr)
Ethylene
110.31
Propane
2623.79
2734.1
TOTAL
Temperature: 40.00 C
Pressure : 3000 kPa
30
mass %
0.04
0.96
100
mass
%
0.02
41.4
0.32
58.28
100
4.1.8 C2 SPLITTER
Material stream 12
Component mass
flowrate
(kg/hr)
Methane
5.048
Ethane
9909.435
Acetylene
76.7416
Ethylene
13954.6
23945.82
TOTAL
Temperature: -34.95 C
Pressure : 3080 kPa
Mass %
Material stream 13
0.02
41.4
0.32
58.28
100
Component mass
flowrate
(kg/hr)
Ethylene
13919.217
Acetylene
76.7416
13995.96
TOTAL
Temperature: -10.7 C
Pressure : 3200 kPa
C2 splitter
Material stream 14
Component mass
flowrate
(kg/hr)
Methane
10.6528
Ethane
9909.435
Ethylene
35.385
9955.47
TOTAL
Temperature: -7.901 C
Pressure : 2000kPa
31
mass %
99.53
0.11
0.36
100
mass %
0.55
99.45
100
Material stream 17
mass %
Component mass
flowrate
(kg/hr)
Acetone
127.201
127.201
TOTAL
Temperature: 35 C
Pressure: 101.325 kPa
99.45
0.54
100
Acetylene absorber
Material stream 16
Material stream 15
Component mass
flowrate
(kg/hr)
Acetylene
1.5977
Ethylene
13900
13901.535
TOTAL
Temperature: 20 C
Pressure: 1722.44kPa
mass %
0.011
99.98
100
Component mass
flowrate
(kg/hr)
Acetylene
75.2066
Acetone
127.201
202.4076
TOTAL
Temperature: 30 C
Pressure : 1000 kPa
32
mass %
37.16
62.84
100
mass %
100
100
mass %
37.16
62.84
100
Acetylene stripper
Material stream 18
Material stream 17
Component mass
flowrate
(kg/hr)
Acetone
127.201
Acetylene
127.201
TOTAL
Temperature: 31.30 C
Pressure: 40.09 kPa
Component mass
mass %
flowrate
(kg/hr)
Acetylene
79.8872 100
Acetone
79.8872 100
TOTAL
Temperature: 34.09 C
Pressure : 6000 kPa
mass %
100
100
33
mass %
0.011
99.98
100
Ethylene Column
Material stream 20
Component mass
flowrate
(kg/hr)
Ethylene
13888.89
Acetylene
0.0135
13888.9
TOTAL
Temperature: -10 C
Pressure: 2500 kPa
mass %
99.9
0.1
100
Material stream 19
Component mass
flowrate
(kg/hr)
Acetylene
1.5842
Ethylene
11.1
12.68
TOTAL
Temperature: -30 C
Pressure : 2500 kPa
34
mass %
12.49
87.51
100
Enthalpy
(kJ)
Ethane
2445111.3
2445111.3
TOTAL
Temperature: 70 C
Pyrolysis furnace
Component
Steam (stream 2)
Methane
Ethane
Propane
H2O
Hydrogen
Acetylene
Ethylene
CO2
TOTAL
Component
enthalpy
(kJ)
H2O
1551719.1
1551719
TOTAL
Temperature: 180 C
35
Enthalpy
(kJ)
3101484.4
26843935.6
6885500.9
8968631.9
11856702.8
154495.7
31518168.1
140909.5
89469828.9
Quench tower
Componen
t
Methane
Ethane
Propane
H2O
Hydrogen
Acetylene
Ethylene
CO2
TOTAL
Enthalpy
(kJ)
-44726466.4
82218800.9
6877143
6977.6
22107265.9
654218
96107084
4167.8
138791702.6
Material stream 8
Component Enthalpy
H2O
18176207.5
18176207.5
TOTAL
Temperature: 80 C
Pressure : 6987 kPa
36
Enthalpy
(kJ)
-44726466.4
82218800.9
6877143
6977.6
22107265.9
654218
96107084
4167.8
138791702.6
Caustic soda
Component
NaOH
159261400
159261400
TOTAL
Temperature: 30C
Pressure: 4.177 kPa
Caustic tower
Component Enthalpy
(kJ)
Methane
-350957.8
Ethane
-6953247.8
Propane
96371.2
H2O
711.3
Hydrogen
20846495.5
Acetylene
-66039.6
Ethylene
597934.1
CO2
5414.2
13578747
TOTAL
Enthalpy (kJ)
37
4.2.4 DEMETHANIZER
Component Enthalpy
(kJ)
Methane
-1058204.1
Ethane
5382174.6
Propane
-863333.2
Hydrogen
-6524474.9
Acetylene
-5711589.7
Ethylene
8242969.9
TOTAL
Demethanizer
Component
Methane
Hydrogen
TOTAL
Component Enthalpy
(kJ)
Ethane
-704981.6
Methane
420434.0
Propane
-130952.4
Acetylene
-7726.2
Ethylene
8086124.9
7662898.7
TOTAL
Enthalpy
(kJ)
1094052.6
-1009895.2
84157.4
38
4.2.5 DE-ETHANIZER
Component Enthalpy
(kJ)
Methane
4650.7
Ethane
-706674.8
Propane
-131409.9
Acetylene
-6957.5
Ethylene
-1145519.4
-1985910.9
TOTAL
De-ethanizer
Component Enthalpy
(kJ)
Methane
10154.4
Ethane
-1980235.4
Acetylene
-19722.6
Ethylene
-3058549.5
-5048353.1
TOTAL
Component Enthalpy
(kJ)
Propane
110680.1
Ethylene
5306.8
115986.9
TOTAL
39
4.2.6 C2 SPLITTER
Component Enthalpy
(kJ)
Methane
-4909.6
Ethane
-2026150.9
Acetylene
36772.2
Ethylene
-2986782.9
-4981071.2
TOTAL
C2 splitter
Component Enthalpy
(kJ)
Acetylene
30135.8
Ethylene
-2318046.8
-2287911
TOTAL
Component Enthalpy
(kJ)
Methane
-2323.5
Ethane
3174817.8
3172494.3
TOTAL
40
Ethylene column
Component
Enthalpy
(kJ)
Ethylene
Acetylene
TOTAL
-430.4059
-155.096
-585.5019
Acetylene
-76.4246
Ethylene
TOTAL
-2836982.474
-2837058.903
41
CHAPTER 5
42
Number: 4-stage
Material of construction: Carbon steel
5.1.8 De-methanizer
Duty: To separate and remove methane and hydrogen from the ethylene gas stream
Temperature: 120C
Pressure: 30bar
Height: 15m
Diameter: 1.4m
Material of construction: carbon steel
5.1.9 De-ethanizer
Duty: To separate the C2s and C3s
Temperature: 6C
Pressure: 32bar
Height: 25 m
Diameter: 1.5 m
Number: 1
Material of construction: carbon steel
5.1.10 C2-splitter
Duty: To separate or split the C2 into ethylene and acetylene as overhead and ethane as
bottom stream to be recycled back to the furnace.
45
Diameter: 3.248m
Material of construction: stainless steel
Internal diameter =
Length = 48in = 1.22m
Thickness of tank = 25mm
Material of construction: Carbon steel
2)
Schedule number
3)
Material of construction
4)
Wall thickness
1000
S
49
According to Sinnott, the optimum diameter of a stainless steel pipe is given as:
d,optimum = 230G 0.52-0.37
where, G = Mass flow rate in kg/s and = density in kg/m3
Reynolds number, Re
4G
(2) [43]
d
Re
43.77075
0.0010.428
50
Re = 11217
Re is greater than 4000 and hence flow is turbulent.
From Wallas (1990) Table A5
For optimum pipe diameter of 16.85 in
Nominal size = 16 in
Pipe schedule number = 30s
Outer diameter (do) = 16.00 in
Inner diameter (di) = 15.25 in
2
2 2
2
D 0.423 m 0.1405m
4
4
0.471ms1
51
Entry loss =
2
0.6782
umax
0.4 KPa
1.73
2
2
52
Table 5.1 Summary of pipe line specifications for our ethylene plant
Locatio Optim
n
um
diamet
er
(mm)
From
Furnace
to TLE 655.53
From
TLE to
quench
tower
423.24
From
quench 733.00
tower
to
compre
ssor
From
compre 467.6
ssor to
caustic
tower
From
737.96
caustic
tower
to dryer
From
729.29
dryer to
cooler
From
cooler
721.28
to demethani
zer
From
de696.56
methani
zer to
deethaniz
er
From
deethaniz
er to C2
splitter 659
Nomi
nal
Size(i
n)
Sched
ule
Numb
er
25.83
Nor
mal
fluid
veloc
ity
(m/s)
Maxim
um
design
fluid
velocit
y (m/s)
Material
of
Construct
ion
Outer
diamete
r
(in)
Inner
diamet
er
(in)
Crosssectio
nal
area(i
n2)
20
Stainless
steel
24
23.25
0.3375
2.297
3.3082
16.66
40
Stainless
steel
16.00
15.25
0.2277
2.713
3.906
28.87
20
29
28.80
0.422
1.464
2.108
18.00
17.25
0.252
2.452
3.53
29.20
28.70
0.425
1.453
2.094
28.70
28.40
0.421
1.434
2.077
28.40
28.20
0.418
1.413
27.45
27.00
0.403
1.353
1.95
26
25.50
0.3806
1.43
1.206
Stainless
steel
18.40
40
Stainless
steel
29.05
20
Stainless
steel
28.65
20
Stainless
steel
2.035
28.40
20
Stainless
steel
27.42
30
Stainless
steel
25.95
30
Stainless
steel
53
From
C2
splitter
to
acetyle
ne
absorbe
r
From
acetyle
ne
absorbe
r
to
acetyle
ne
stripper
From
acetyle
ne
absorbe
r
to
ethylen
e still
From
ethylen
e still to
storage
tank
495.15
19.5
30
19.5
0
19.25
0.193
1.89
2.73
16.6
0
16.00
0.1405
0.471
0.678
19.3
0
19.00
0.190
0.64
0.920
17.7
0
17.00
0.0152
4.00
5.76
Stainless
steel
428
16.85
30
Stainless
steel
491
19.33
30
Stainless
steel
44.95
17.70
30
Stainless
steel
55
0.0097688
2.873ms1
0.0034
0.0001084
3.284ms1
0.000033
P
V2
The total discharge head, H dc dc Z dc dc
2g
g
Pdc
Vdc2
g
2
g
P P
V 2 V 2
Therefore, H dc sc Z dc sc
2g
g
Where, Z Z dc Z sc 2m
that is the height difference at the centre line of the pump between the suction and
discharge pipe. [44]
Pdc Psc 365KPa
56
= 790kg/m3; g = 9.81m/s2
Hence, H
365000
0.411
2
49.11m
790 9.81
2 9.81
Ns
N Q
H
3
4
.. (11)
Ns
1750 586.2
161.122
3
4
936.903
Specific speeds for centrifugal pumps usually lie the range 900-15000 but values above
12000rpm are considered impractical .Since the calculated value lies within the range it
suggest that the calculated value is correct.
57
Pi Pvap
(12)
279272.589 12330
34.444m
790 9.81
58
Qty Power
Net
positive Specific
Efficiency
requirement
suction
head speed
(w)
(m)
(r/min)
1637
21
293
65
1142.82
15.095
192
60
3718.433
34.44
862
72
Tower
For pumping caustic 1
solution
into
the
caustic tower
For pumping acetone 1
into
the
acetylene
absorber
59
CHAPTER 6
Stack
Stack damper
Stea
m
Ethane feed
Convection section
sesection
Cracked gas
Radiant section
Fuel
Air
Design constraints
Stack height
61
C2H6
Reaction 1
2C2H6
C3H8 + CH4
Reaction 2
C3H8
C2H2 + CH4 + H2
Reaction 3
C + 2H2O
CO2 + 2H2
Reaction 4
62
Substance
Nin 10
Nout
Hin KJ/mol
103
Hin KJ/mol
mol/hr
CO2
3.555
H3
C2H2
3.199
H4
C2H4
505.869
H5
C3H8
60.79
H6
CH4
66.477
H7
H2O
291.896
H1
291.265
H8
C2H6
972.985
H2
340.564
H9
H2
509.068
H10
64
Total heat absorbed = Heat for preheating the feed + Heat absorbed for cracking of feed
6.2
[2]
Where: N
tube
tube
tube
66
Where Qabsorbed in the convective tubes = heat absorbed in the convection section (MJ/hr)
Hout = Enthalpy of the stream entering the radiant section (KJ/mol)
Hin= Enthalpy of the feedstock (KJ/mol)
Qabsorbed in the convective tubes
103+0.688105 +0.76041012 2)
T = 312 C
6.2.8.2 Temperature of flue gas entering the convective section
By rule of thumb the temperature of the flue gas entering the convective section should be
150 C above the process temperature. This mean the temperature of the gas is 990.8 C.
6.2.8.3 Temperature of flue gas entering the stack section
(Waals 1990,pg. 214)
Where Ts temperature of flue gas leaving the convection section oF
a = 0.22048 - 0.35027z + 0.92344z2, b = 0.016086 + 0.29393z - 048139z2
Where z = fraction excess air =0.1
Therefore substitute into the equation above: a= 0.1946874, b=0.0406653
Where:
P = the suction available from a natural draft system, Pa
C = 0.0342
a = atmospheric pressure in Pa, h = height of the stack (m).,Ti=inlet temperature in K
To =ambient temperature in K (25 oC)
Setting the P = the suction available from a natural draft system to 400 Pa which is in the
acceptable range [2]
=80.04 m
=80.04 m
, Re
=Reynolds number =
, hi= inside coefficient (W/m2 oC), di= tube inside diameter (m),
=
6.2.10.1.2 For the radiative tubes
69
= 26.152 KPa
6.2.11.2 Pressure drop in the Convective tubes:
At Reynolds number of 2.446
, jf = 1.7 10-3 [2], w=1.69810-3, Np=3, L=11m
=5.743KPa
LHVfuel
( Mullinger et al.2008)
70
71
UNITS
Heat Duty
20.862
MW
Temperature in/out
70/840.8
Pressure drop
5.737
KPa
0.417
Kg/s
7.192
Kg Air /s
10
3.858
Kg/s
Steam required
1.461
Kg/s
9.588
Kg/s
Operating pressure
107
KPa
72
73
74
respect to plain carbon steel. Stainless steel is to be used for this design (Coulson et al,
Volume 6).
Longitudinal stress,
Circumferential stress,
Pi Di
2t
Pi Di
4t
112.095 6.0
62681.267 KPa
2 0.005365
112.092 6.0
31340.634 KPa
4 0.005365
The density of high alumina refractory bricks is given as 2579kg/m3 (Rotary kiln transport
phenomena and transport processes)
Where,
75
Where,
R= external radius of steel shell, r = internal radius of steel shell
Mass of content:
76
VALUE
Design Temperature
400 oC
Design Pressure
112.095 KPa
0.005365 m
Longitudinal stress
62681.267 KPa
Circumferencial stress
31340.634 KPa
1827.722 kN
77
CHAPTER 7
78
to
and
.
Where equations (5) and (6) are the dimensionless temperature ratios of the correction
factor.
79
80
81
82
83
The Reynolds (Re) and Prandtls number (Pr) of the cracked gas at the tube side is given
by,
84
85
The shell side linear velocity is appreciable since it falls in the standard range 0.3 1.0 m/s.
Equivalent Diameter (De) of the triangular pitch is given by,
86
The Reynolds (Re) and Prandtls number (Pr) of the cooling water at the shell side is given
by,
87
88
For
The total tube side pressure drop is less than 70 kPa, hence within specification.
89
As this pressure drop on the shell side is less than 70 kPa, the design is acceptable from the
pressure drop point of view.
91
Nozzles
Assume that inlet and outlet nozzles = 100 mm
92
Head
Take Torispherical heads for both ends and the following parameters are determined
bellow.
93
Flange Design
Flange is ring type with plain face.
94
95
Flange Thickness
96
97
98
Gasket size
99
Under atmospheric conditions, the bolt load due to gasket reaction is given by,
After the internal pressure is applied, the gasket which is compressed earlier, is released to
some extent and the bolt load is given by,
100
Using the larger of the above areas, determine the size of bolts,
Thickness of Nozzle
Assume that inlet and outlet nozzles = 100 mm
101
Flange Thickness
102
103
104
105
106
107
CHAPTER 8
Design of a quench tower to condense the steam coming out of the furnace in a packed
tower
Residence time
Data: The packing used is 50mm metal pall ring random packing
Cp = is a packing constant, 0.763, a = specific surface area of packing, 112.6 m2/m3,
= packing void fraction, 0.951, FP = packing factor, 27m2/m3,
Ch = is a characteristic of the particular type and size of packing, 0.784
108
Temperature =34C
Flowrate =7589.283 kmol/hr
Gas out
1. -- Column
shell
2. -- Inlets
and
outlets for
gas and
liquids
3. -- Packing
material
2
Liquid
in
Flowrate =1492.490 kmol/hr
Temperature
=30C
3
2
Gas in
Temperature
=350C
Flowrate
=1777.473 kmol/hr
Liquid out
Temperature =80C
Flowrate =7874.283
kmol/hr
109
110
Where, L = liquid mass flow rate, 39.3714Kg/s
G = gas density, 0.570832Kg/m3
V' = gas mass flow rate, 9.571890 Kg/s
L = liquid density, 1000Kg/m3 (Sinnot, 1999)
QG = is the volumetric flow rate of the gas,m3/s
The ratio of the liquid mass flow rate to the gas mass flow rate is given by
Flooding data for quench columns with countercurrent flow of gas and liquid can be
correlated in terms of the flow parameter(X) given by
Flooding curve in quench tower can be accurately described by the polynomial regression
111
112
113
D =2.49865m 2.5m
Hence the diameter of the column is 2.5m
The area of the column can be calculated as:
The wall factor can be important for columns with an inadequate ratio of effective particle
diameter to inside column diameter, and is given by:
114
KW = 0.9805309
The Reynolds number of the gas can be calculated as
Where,
, is given by the
empirical expression:
115
= 0.7464431
=7.931453316Kg/m2.s
The Reynolds number of the liquid can be calculated as:
= 7.2206272810-4
region
can
be
calculated
from
the
dimensionless
expression:
hL= 0.047606969
Hence the liquid holdup in the column is 0.047606969
For the case of quench tower use in condensing of the steam the value of
0.8 for purpose of design (Colburn, 1939)
Therefore the number of overall gas-phase transfer units is calculated as
NOG = 10.156
Hence the overall gas-phase transfer units is 10.156
8.4 Calculation of the height of gas and liquid film transfer units
The height of the gas and liquid film transfer units is given as:
is taken as
= HG factor
= HL factor
= liquid mass flow-rate per unit area column cross-sectional area, kg/m2s,
f1 = liquid viscosity correction factor
f2 = liquid density correction factor
f3 = surface tension correction factor
The liquid Schmidt number can be calculated as:
121
The liquid mass flow-rate per unit area column cross-sectional area is given by:
Therefore the mass flow-rate per unit area column cross-sectional area is 8.020676 Kg/m2s
For 70%flooding,
= 80,
Z* =8m, f1=f2=f3=1
(Sinnot,2005)
122
Z = 10.1561.4238 = 13.897m
Hence the packed height Z =14m
Table 8.1 Summary of chemical engineering design for quench tower
Parameter
value
4.8257
2.5
325
0.0476
499
10.156
0.852
0.726
1.4238
14
28
123
Where, ts = Minimum thickness of the shell cylinder required for pressure loading, mm
P = the design pressure, bar
Di = Internal diameter of the column, m
124
C = corrosion allowance, mm
J = weld joint factor
ts = 28mm
Hence Minimum thickness (ts,) of the shell cylinder required for pressure loading is taken
as 28mm
The minimum thickness of ellipsoidal heads is given as
Therefore, 28mm plating is chosen for the column heads (for uniformity).
DO = Di+2ts
DO = 2.5 + 2(0.028)
DO = 2.556m
Where, DO = Mean diameter, mm
m = total mass of the column and contents, Kg
g = acceleration due to gravity, 9.81m/s2
Wind loading
Wind velocity (max) V, = 160 km/h (Sinnott, 2005)
Wind velocity which correspond to Dynamic wind-pressure loading of 1280Pa (Sinnott,
2005)
Bending moment (Mx) at bottom tangent line
129
8.8.2 Downwind
Total stress = bending stress +Hoop stress Radial stress
Total stress = 4MPa+54MPa 3MPa
Total stress = 55MPa
Therefore the maximum stress is 55MPa
130
The maximum stress is more than 43% below the design stress of 125 MPa, and therefore
the shell design is considered acceptable.
Where,
bS
WS
ts = skirt thickness, m
Bending moment at base of skirt,
Ms = 778.365kNm
bS=
5.6N/mm2
The maximum dead weight load on the skirt will occur when the vessel is full of water.
Where,
WS
WS(operating)
WS(test)
= 3.26N/mm2
= 3.90N/mm2
Ab= 466.8mm2
Using M30 bolts (BS 4190:1967) root area = 561 mm2
Ab =561mm2
134
Db = 27mm
The bolt root diameter is therefore 27mm.
The base ring must be sufficiently wide to distribute the load to the foundation. The total
compressive load on the base ring is given by:
Fb = 362kN/m
Where, Fb = the compressive load on the base ring, Newtons per linear metre,
DS = skirt diameter, 2m.
The minimum width of the base ring is given by:
135
Where,
= 20mm.
Value
28
27
54
28
55
Table 8.3 Summary of mechanical design of the skirt support for the quench tower
Parameter
Value
Skirt thickness, mm
30
5.60
3.27
2.34
9.50
137
Table 8.4 Summary of mechanical design for base ring and anchor bolt
Parameter
Value
156
Bolt diameter, mm
27
362000
20
138
CHAPTER 9
L2 = 2233.073 kmol/hr
X2 = 0.0
G2 = 1481.664kmol/hr
y2 = 3ppm
G1 = 1488.71549 Kmol/hr
y1 = 0.0021
L1 = 2236.195 Kmol/hr
X1 = 0.0014
139
Amount
in Mole
kmoles
fraction
Methane
66.4062
0.0446
Ethane
340.545
0.2287
Propane
60.0818
0.0404
H2O
0.29189
0.0002
Hydrogen
509.1142
0.3420
Acetylene
3.1622
0.0021
Ethylene
505.952
0.3399
CO2
3.1622
0.0021
TOTAL
1488.71549
1.0000
140
0.0021044,
y1 = 0.0021
y2 = 3ppm
Y2 =
X2 = 0
pCO2 = 7350917.175 Pa, where pCO2 is the partial pressure of CO2 at 31C
Pt = 3500000pa, where Pt is the total pressure of the gas
Y*=
2.1
Min Ls =
For 1.5 times the minimum, Ls= 1.50.4129 = 0.619 kmol/s
X1=
0.0014
141
L2
2231.52Kmol/hr
G2
1481.664kmol/hr
x2
0.0
y2
3ppm
L1
2228.4Kmol/hr
G1
1488.71549 Kmol/hr
x1
0.0014
y1
0.0021
9.2.3 Calculating for the mass velocity of the gas and the liquid
Average molecular weight of the gas = [1666.4062 + 30340.545 + 4460.0818 +
180.29189 + 2509.1142 + 263.1622 + 28505.952 + 443.1622]/1488.71549
MwG= 19.704 Kg/Kmoles
Now considering 20wt% of NaOH solution
Finding the mole fraction of NaOH(XNaOH) in this solution using the relation
X NaOH
X NaOH
Wi M W i
Wi M W i 1 Wi)
M W H2 0
0.20 / 40
0.20 40 0.80 18
X NaOH 0.1011
X H2O 0.8989
142
FLV
L1 g
1
G l
0.5
12.519 26.92
8.148 1213.5
0.5
0.229
From the generalized pressure drop correlation given in Richardson and Coulson, pg 603
K4 = 2.1
=
= 2.137 Kg/ m2s
Then, the cross section area required,
Diameter, d =
144
D=
2.203m
% loading =
= 58.7%
LW
liquid
rate
per
unit
12.519kg/s
1213.5kg/m 128m 2 /m 3 3.813m 2
3
L W 2.11 10 -5 m 3 /m 2 s
145
cross-sectional
area
Absorption and stripping tower by Morris and Jackson, recommends wetting rate of
2.010-5m3/m2s and above for packing size between 25mm and 75mm.
18.528)/ 0.0103
Hoy =
Hoy = 0.229m
Noy =
Where a= top of column, b= bottom of column
x a= 0
xb = 0.0014
ya = 310-6
yb = 0.0021
y* = 2.1x
yb* = 2.10.0014 = 0.00294
ya* = 0
y = yb-ya = 0.0021-310-6 = 0.00297
At the bottom of the column, yb-yb* = 0.0021-0.00294 = -0.00084
At the top, ya-ya* = ya = 0.000003
Noy =
= 1.49610-4
Noy = 19.852
ZT = 0.22919.852 = 4.546m
Height of packing = 4.546m
147
Distance
Purpose
Distributor
Between beds and top distributor and bed40cm Prevent excessive carryover of liquid
Between top of inlet gas nozzle and
50cm Prevent excessive carryover of liquid
bottom support plate
Source: (Rase, 1977)
Total height of free spaces in column = 230cm = 2.3m
Table 9.3: Summary of Chemical Engineering Design
Parameter
Value
Column diameter
2.203m
4.546m
Height of column
6.846m
4.87910-4mol/m3hPa
Wetting rate
2.1110-5 m3 /m 2s
Liquid hold up
0.182 m3/m3
% Loading
58.7%
Residence time
5.4min
Choice of packing
Packing size
38mm
Type of installation
Random
148
= 4.076 m2
150
s (Tensile) = bs ws
s (Comprehensive) = bs ws
Where
bs
4Ms
( Ds ts )tsDs
ws
W
(Ds ts)ts
151
Where
Ms = maximum bending moment, evaluated at the base of the skirt
W = total weight of the vessel and contents
Ds = inside diameter of the skirt, at the base
ts = skirt thickness
Dynamic wind pressure = 1280 N/m2
Mean diameter = 2.203 + 2(0.0543) = 2.3116m
Loading per linear mater (Fw) = 1280N/m22.278m
= 2915.84 N/m
Fw h 2 2915.84 (6.846) 2
Ms
= 68329.38051Nm
2
2
Ds = 2.278m = 2278mm
Weight of vessel, W= 27133.939kg 9.81ms-2 = 266183.9416N
The maximum dead weight load on the skirt would occur when the drum is full of the
solvent NaOH.
Approximate weight = (
= 332156.6897N
152
bs
4Ms
4(598340.63) x 103
ws
W
598340.63
s (tensile) = bs - ws
= 3.855 2.1952 = 1.6598 N/mm2
s (comprehensive) = bs + ws
3.855+2.1952 = 6.0502N/mm2
s
s
153
fs = maximum allowable design stress for the skirt material, normally taken at ambient
temperature, 20oC
J = weld joint factor
s (tensile) fs J sin
PDi
2t
PDi
L
4t
154
Where
= circumferential stresses
L=
longitudinal stresses
3.850 2203
113.18 N / mm2
2 37.47
3.850 2203
L
56.59 N / mm2
4 37.47
2. Direct stress due to the weight of the vessel, its contents and any attachments.
W
266183.9416
1.009 N / mm2
( Di t )t (2203 37.47)37.47
1500
7.8 8
600
Scheiman gives the following guide rules which can be used for the selection of the anchor
bolts:
1. Bolts smaller than 25 mm (1 in.) diameter should not be used.
2. Minimum number of bolts 8.
3. Use multiples of 4 bolts.
155
Value
Equipment(shell) thickness
37.47mm
Weight of tower
140952N
Weight of packing
125231.9N
Vessel volume
27.904m3
Skirt thickness
20mm
Longitudinal stress
56.59N/mm2
Circumferential stress
113.18N/mm2
Direct stress
1.009N/mm2
No. Of bolts
Bending moment
68329.38Nm
Type support
Straight skirt
156
CHAPTER 10
10.2 JUSTIFICATION
The mixture of gases ready to undergo separation into their individual has water in it. The
exposure of the gas mixture to water sprayed at Tdp over a period of time will allow all the
water to be collected downstream. In this way about 96% of the water is sure to be
removed. By this process, the gas mixture is ready to be separated into individual gases.
Water cooler
Inlet air(Gas mixture)
157
Gin
Lout
Gin = 29438.1762
Therefore the amount of water entering the spray tower = 87.9234 kg/hr
Therefore to find the flowrate of the exit gas stream = 29241.1306kg/hr
But water of 2ppm is the least that can be allowed in the mixture without effect on the
result.
2ppm which is 0.0002% of the total amount present;
..(tosun, 2007)
159
l=
The velocity of the gas is assumed to be the same as the mass velocity since the gas mixture
is in vapour form(perry cha 6 pg 6-7)
V = 1485.36kmol every hour
D = 3.878m
and applying the force balance between buoyancy and drag forces.
But;
160
d = 0.09551 m
Ut = 0.005283 m/s
3133)
Cpl = 18.2964+147.7730-130.9630+40.3002
161
d = 1.31424 10-6
Cpl = 75.4066J/mol.K
Therefore
Therefore
ps = 2556.89 Pa
162
to find the dew point; the temperature at which the water in the gas mixture begins to
condense.
(tosun, 2007)
tdp = 21.4922=21.5 C
thus a temperature below this will condense the water in the mixture.
(40-21.5) C = 24.5 C/2=9.25 C 12.5
12C is assumed to be the temperature(modeling in transport)
therefore
..(tosun, 2007)
163
= 5.1878 10-5m3/m2s
= 49.20mJ/m2
10.6.1.1 Summary of chemical engineering design
Table 10.1 Chemical engineering design of spray tower
Parameter
Value
Column diameter
3.878m
Column height
9.94m
Terminal velocity
0.005283m/s
Dew point
21.5 C
Water temperature(inlet)
12 C
Residence time
31.34minutes
5.1878 10-54mol/m3hPa
34
200 nozzles
166
= 6.0915 m2
s (Tensile) = bs ws
s (Comprehensive) = bs ws
Where
167
bs
4Ms
( Ds ts )tsDs
W
(Ds ts)ts
Where
Ms = maximum bending moment, evaluated at the base of the skirt
W = total weight of the vessel and contents
Ds = inside diameter of the skirt, at the base
ts = skirt thickness
Dynamic wind pressure = 1280 N/m2
Mean diameter = 3.878 + 2(0.0543) = 3.9866m
Loading per linear mater (Fw) = 1280N/m22.278m
= 2915.84 N/m
The weight of the spray nozzles is approximated to be 500kg
Thus total dead weight = 67851.63+500
= 68351.63kg
Approximate weight = (
= 1230427.61N
Therefore total weight, W = 669845.97+ 1230427.61= 1900273.31N
= 1900.27kN
ts = 66mm
4Ms
4(1900273.31) x 10 3
bs
ws
W
1900273.31
s (tensile) = bs - ws
=3.242 2.148= 1.094 N/mm2
s (comprehensive) = bs + ws
3.242+2.148 = 5.390/mm2
s
fs = maximum allowable design stress for the skirt material, normally taken at ambient
temperature, 20oC
J = weld joint factor
1500
7.8 8 (closest
600
Direct stress due to the weight of the vessel, its contents and any attachments.
W
665624
0.762 N / mm 2
( Di t )t (4010.3 68.17)68.17
Value
Equipment(shell) thickness
68.17mm
Weight of tower
665624N
Vessel volume
60.549m3
Direct stress
0.762
No. Of bolts
Bending moment
98854.38Nm
Type support
Straight skirt
171
CHAPTER 11
Condenser
Splitter
Distillate, D
D = 577.7694 kmol/hr
Feed, F
F = 1448.2614 kmol/hr
V
L
Re-boiler
172
Bottoms product, B
B = 870.4920 kmol/hr
Mole fraction
Hydrogen, H2
0.350
Methane, CH4
0.046
Ethane, C2H6
0.222
Acetylene, C2H2
0.002
Ethylene, C2H4
0.340
Propane, C3H8
0.040
Mole fraction
Ethane, C2H6
0.3693
173
Acetylene, C2H2
0.0033
Ethylene, C2H4
0.5600
Propane, C3H8
0.0666
Methane, CH4
0.0008
Mole fraction
Hydrogen, H2
0.8773
Methane, CH4
0.1142
Ethylene, C2H4
0.0085
N min
x D , LK x B , HK
ln
x B , LK x D , HK
ln LK , HK
HK
= relative volatility of the light key component with respect to the heavy key
component
From the stream composition tables above,
XB, LK = 0.0008
XD, LK = 0.114
XB, HK = 0.56
XD, HK = 0.0085
Pmeth/ Pethyl
175 K
1573.072 Pa
813.309 Pa
1.93
200 K
2018.18 Pa
1096.51 Pa
1.84
230 K
2555.48 Pa
1434.98 Pa
1.78
253 K
2969.00 Pa
1696.86 Pa
1.75
175
Realize that, LK , HK
Therefore,
Pmrthane
and
Pethylene
N min
Average LK , HK
0.56
0.114
ln
ln 9388.2353
0.0008 0.0085
1
1
ln LK , HK
ln 1.83
Rm 1
x
V
i , HK D ,i
D
i i , HK
Where:
i, HK is the relative volatility of a component i, with respect to the heavy key component at
feed conditions
xd, I is the mole fraction of a component i, in the distillate
Rm is the minimum reflux ratio
i xi , f
1 q
176
Component Xi,f
i, HK
i, HK Xi,f
Try = 1.75
Try = 2.2
Try = 2.21
Methane
0.046
2.37
0.11
0.18
0.65
0.68
Ethane
0.222
1.33
0.30
-0.71
-0.345
-0.34
Propane
0.040
0.18
0.0072
-0.0046
-0.0036
-0.0036
Hydrogen
0.350
345.86
121.05
0.35
0.35
0.35
Acetylene
0.002
0.40
0.0008
-0.0006
-0.00044
-0.00044
Ethylene
0.340
1.00
0.340
-0.45
-0.283
-0.28
= -0.64
= 0.367
= 0.406
XD,i
i,HK
S = i,HK -
Methane
0.1142
2.37
0.16
0.27
1.68
Ethane
1.33
-0.88
Propane
0.18
-2.03
Hydrogen
0.8773
345.86
343.65
303.423
0.88
Acetylene
0.40
-1.81
Ethylene
0.0085
1.00
-1.21
0.0085
-0.007
177
Rm 1
i , HK x D,i
V
For R = 2.19,
R
2.33
0.70
R 1 2.33 1.00
and hence
N min
R
f
N
R 1
14
22.6 23
0.62
The minimum reflux ratio is 1.46; the actual reflux ratio is 2.33; the minimum number of
theoretical stages is 14, and the actual number of theoretical stages is therefore 23.
23 - 1
37
0.6
Note that the number of plates is same as the number of real stages.
N S xF , LK
xB , LK
x
D , HK
2
B
0.206
Where:
B = molar flow rate of bottom product, D = molar flow rate of top product
178
Therefore,
N R x F , HK
N S x F , LK
x B , LK
x
D , HK
2
B
0.206
NR
0.206
7.39130.0088581.50664
0.62
NS
Solving N R 0.62 N S
N S 14.20 14
N R 8.80 9
14.20
23.67 24
0.6
8.80 1
13
0.6
Hence, feed enters the column at the 24th tray from the top.
0.206
Again, R
L
D
V
R 1
D
V 593.6602.19 1 1893.78kmol / hr
vap 2.06kg / m 3
liq 221.67kg / m 3
180
The contribution of the feed stream to the internal flow of liquid is described by the
equation below:
L = L + qF
V = V (1 q) F
Where:
L = liquid flow rate at the bottom of the column
V = vapour flow rate at the bottom of the column
vap 1.43kg / m 3
liq 433.20kg / m 3
V hV + QC = DhD + L hL
Where: hV = enthalpy of vapour at the top of column = 4694.491 KJ/kgmol
V = vapour flow rate = 1893.78 kgmol/hr
QC = condenser duty
D = flow rate of distillate = 593.660 kgmol/hr
hD = enthalpy of distillate = 7662.846 kJ/kgmol
L = flow rate of liquid at the top of the column = 1300.12 kgmol/hr
hL = enthalpy of liqiud at the top of the column = -517480.041 kJ/kgmol
11.4 Determination of liquid-vapour flow factor, FLV at the bottom and top
The liquid-vapour flow factor, FLV is given by:
FLV
Lw
Vw
V
L
Where:
Lw = liquid flow-rate
FLV , bottom
FLV , top
Vw = vapour flow-rate
2192.98 1.43
0.097 0.10
1298.54 433.20
1300.12 2.06
0.06618 0.07
1893.78 221.67
Therefore, the liquid-vapour flow factor at the bottom and top are 0.10 and 0.07
respectively.
uf =
K1 ( L V ) 0.5
V 0.5
Where:
uf = is the flooding vapour velocity in m/s or maximum permissible velocity based on the
net column cross-sectional area
K1 = empirical constant
V = vapour density
183
L = liquid density
From fig. 11.27 (R.K. Sinnot, 1986), and using a plate spacing of 0.5m at bottom and top
and their respective flow factors:
K1= 8 x 10-2 ..bottom
K1 = 8.5 x 10-2 .top
11.5.1 Surface tensions:
Bottom surface tension = 0.045 N/m
= 0.022 N/m
0.2
0.022
K1 = 0.085
0.02
0.094 ..bottom
0.2
0.094 .top
Hence,
Bottom uf =
Top
The flooding condition fixes the upper limit of the vapour velocity. A high vapour velocity
is needed for high plate efficiencies, and the velocity will normally be between 70 to 90 per
cent of that which will cause flooding. For design, a value of 80 to 85 per cent should be
used. (R.K. Sinnot, 1986)
184
Hence design for 85 per cent flooding at maximum flow rate (uf) will be:
Bottom uf = 1.63 x 0.85 = 1.39 m/s
Top uf
The maximum volumetric flow rate can be calculated from the correlation,
..(10)
Bottom
Top
1298.54 20.80
5.25m 3 / s
1.43 3600
1893.78 3.82
0.98m 3 / s
2.06 3600
A = net area
Bottom A
5.25
3.78m 2
1.39
Top A
185
0.98
1.2m 2
0.84
Bottom =
1.2
1.4m 2
0.88
Top =
A 4
Bottom
4.3 4
2.34m
Top
1.4 4
1.34m
LB
L
Where:
Bottom L
2192.98 20.80
2.9 10 2 m 3 / s
3600 433.20
Top
L= liquid density
1300.12 3.82
6.22 10 3 m 3 / s
3600 221.67
The plate diameter is within the range of Figure 11.28 (R.K. Sinnot, 1986) and it is clear
from the flow pattern that a single pass plate can be used for both the top and the bottom.
186
0.3m is taken as the spacing between the draw off tray and the bottom of the
product. (Coulson et al, 1983)
Hence, height of column = (number of plates x plate spacing) + 0.4 m = (37 x 0.5) + 0.4 =
19 m
Table 11.7 Summary of Property Values Used
Parameter
Enriching Section
Stripping Section
1300.12
2192.98
1893.78
1298.54
221.67
433.20
2.06
1.43
0.022
0.045
0.07
0.10
0.84
1.39
0.98
5.25
187
Enriching Section
Stripping Section
Temperature, oC
-98
-20
3000
3000
Number of trays
24
13
Column diameter, m
1.34
2.34
Parameter
2.33
Height, m
19
-677127
-6203
Pressure, kPa
Ad
0.17
100%
100% 12% corresponds to
Ac
1.4
lw
0.76
Dc
Where lw is the weir length
Weir length = D C 0.76 1.34 0.76 1.02m
Take:
Hole diameter = 3 mm
Plate thickness = 3 mm
L
750 w
Llw
2/3
hw
1.38
750
221.67 1.02
2/3
25mm liquid
0.97
hw 750
221.67 1.02
2/3
At minimum rate, hw + h
19mm liquid
= 50 + 19 = 69 mm
From the weep-point correlation Eduljee (1959), Fig. 11.30 (R K Sinnot), K2 = 30.4
Minimum vapour velocity through the holes at weep point is given by:
u h min
2.06 0.5
6.86 7m / s
Ah
0.1
This implies that the minimum operating rate is well above the weep point, and hence no
weeping occurs.
0.98
9.8 10m / s
0.1
The pressure drop through the dry plate can be estimated using expressions derived for flow
2
u
hd 51 h V
CO L
Where the orifice coefficient CO is a function of the plate thickness, hole diameter and the
hole to perforated area ratio.
From discharge coefficient (CO) plot, fig 11.34 (R.K Sinnot, 1986), Liebson et al, (1957),
for plate thickness/hole diameter =1 and Ah/Ap Ah /Aa = 0.1, CO = 0.84.
190
10 2.06
Hence hd can be estimated as: hd 51
67mm liquid
0.84 221.67
Residual head
Methods have been proposed for estimating the residual head as a function of liquid surface
tension, froth density, and froth height. However as this correction term is small the use of
an elaborate method for estimation is not justified and the simple equation proposed by
Hunt et al (1957) can be used. (R.K.Sinnot 1986)
hr
12.5 10 3
12.5 10 3
56mm liquid
221.67
ht hd hw hw hr 67 50 19 56 192mm liquid
Downcomer liquid back-up
Downcomer pressure loss; assume the height of apron, hap = hw 10 = 40mm
Then area under apron, Aap = lw x hap = 1.02 x 0.04 = 0.041 m2
As this is less than Ad = 0.17 m2, the head loss in the downcomer, hdc can be estimated
using the equation given by Cicalese et at, (1947)
L
hdc 166 wd
L Am
1.38
hdc 166
3.83 4mm
221.67 0.041
Back-up in Downcomer
In terms of clear liquid the downcomer back-up, hb, is given by:
hb hw how ht hdc ...................................................................................(21)
0.22
1
plate spacing weir height and hence the tray spacing is acceptable.
2
Ad hb L
0.17 0.27 221.67
tr
7.4s
Lwd
1.38
The residence time, tr = 7.4s is well above 3 seconds and hence indicative of a satisfactory
result.
Percentage flooding
uv
0.82m / s
net area
1.2
Percentage flooding =
0.82
0.83 83%
0.99
FLV = 0.07
lw
0.76 ,
Dc
99 0
81
1.82m
180
193
Hole Pitch
The hole pitch (distance between the hole centres) lp should not be less than 2.0 hole
diameters, and the normal range will be 2.5 to 4.0 diameters. Square and equilateral
triangular patterns are used; triangular is used in this design.
d
A
For an equilateral triangular pitch: h 0.9 h
Ap
l p
3
0.9 32 0.802
0.1
8.06mm
Where lp denotes the hole pitch
0.9 l p
0.1
0.802
l p
lp = 8.06 mm is in the range 2.5 4.0 hole diameter and hence a satisfactory result.
dh2
4
3 10 3
hole area
0.1
14147.113 14148
area of one hole 7.06858 10 6
10
3000 300kPa
100
Hence, the design pressure = 3000 kPa + 300 kPa = 3300 kPa
194
Design temperature
The strength of the materials decreases with temperature. The maximum operational
temperature used was -20oC (253 K). For design purposes, a tolerance of about 20oC is
allowed. The maximum operational temperature could therefore be pegged at 0oC (273 K).
For carbon and low alloy steel, a minimum allowance of 2.0mm should be used. (R.K.
Sinnot). Where more corrosion is expected a minimum of 4mm is allowed.
Wall thickness
If Di is internal diameter; e the minimum thickness required; f the design stress and Pi the
internal pressure, then:
Pi Di
2 f Pi
Design stress (f) for carbon steel at the design temperature is 135 N/mm2 = 135000 kPa
(Table 13.2, Sinnot, 1993)
At bottom of the column, minimum thickness required is:
3000 2.34
0.026 26mm
2135000 3000
3000 1.34
0.015 15mm
2135000 3000
195
Pi Di
3000 1.34
0.015 15mm
2 Jf 0.2 Pi 2 1 135000 0.2 3000
At the bottom, e
3000 2.34
0.026 26mm
2 1 135000 0.2 3000
ek
Pi Dc
1
30001.34
1
0.0152 15.2mm
2 fJ Pi cos 2135000 3000 cos 8.7
At the bottom,
ek
30002.34
1
0.0263 26.3mm
2135000 3000 cos 8.7
Lk
Di
2.34
0.77m
4 cos
4 cos 8.7
Weight of shell
According to Sinnot, 1993, the approximate weight of the column, Wv is given by:
Wv 240Cv Dm H c 0.8Dm t
Where:
Wv = Total weight of column excluding internal fittings such as plates
Cv = a factor to account for the weight of nozzle, manways and plate support ring or
equivalent fittings and it is equal to 1.15 for distillation columns. (R.K sinnot, 1993)
Hc = height of cylindrical section
t = wall thickness
Dm = mean diameter of column = t + diameter of column
Since the column diameter at the top is different from that at the bottom, the total weight of
the column is determined as below:
Total weight of shell = weight of bottom + weight of top
weight of top 240Cv Dm H c 0.8Dm t 240 1.15 1.35712.1 0.81.357 0.017 84kN
weight of bottom 240 1.15 2.3686.9 0.82.368 0.028 161kN
Weight of Plate
Since the plate diameter at top is different from that the bottom, the weight of the plates is
determined as shown below:
Weight of plates = weight of plates at the top + weight of plates at the bottom
Weight of plates at the top = 1.2 kN x 1.4 x 24= 40.32 kN
Weight of plates at the bottom = 1.2 kN x 4.3 x 13= 67.08 kN
Total weight of plates = 40.32 + 67.08 = 107.4 kN
Weight of insulation
Mineral wool is used for the insulation because it is relatively cheap and also widely used
for insulating distillation columns (Nelson, 1963).
Density of mineral wool = 130kg/m3 (Nelson, 1993)
Thickness of insulation = 75mm (Nelson, 1993)
Approximate volume of insulation
198
Wind Loading
Take dynamic wind pressure as 1280 N/m2
Mean diameter, including insulation (using average diameter and average thickness)
Mean diameter = 1.84 + 2(23 + 75) x 10-3 = 2.04 m
Loading (per linear metre) Fw = 1280 x 2.04 = 2611 N/m
2611
19 2 471285.5 Nm
2
Analysis of Stresses
Pressure stresses
PDi
2t
60000kPa 60 N / mm 2
4t
4 0.023
199
The stress due to the weight of the vessel and the attachments are referred to as the dead
weight stress and is calculated as follows:
W
, where W is the total weight of the column
Di t t
371.78
2761.8kN / m 2.77 N / mm 2
1.84 0.0230.023
Bending Stress
As a result of bending moments on the column, the column would definitely be subjected to
bending stress. The bending stress will be compressive or tensile, depending on the location
and it is given by:
M
Iv
Di
Iv
D
64
Di
Iv
1.886
64
471285500 1840
23 7.6 N / mm 2
10
5.84 10 2
z,
and
h.
The greatest difference between the principal stresses will be on the down-wind side.
Thus 120 49.63 = 70.37 N/mm2.
The value is well below the allowable design stress of 115 N/mm2 and hence satisfactory.
Elastic Stability
The critical buckling stress
t
Do
c 2 10 4
c is
given by:
23
2
2 10 4
244 N / mm
1886
The maximum compressive stress will occur when the vessel is not under pressure.
Thus maximum compressive stress = 2.77 + 7.6 = 10.37 N/mm2 and this value is well
above the critical and hence acceptable.
Column Supports
The supports must be designed to carry the weight of the vessel and contents, and any
superimposed loads such as wind loads. Supports should also be designed to allow easy
access to the vessel and fittings for inspection and maintenance. The height of the skirt is
usually between 2-3m. For this design a height of 2m is used.
In this design, a straight cylindrical skirt (s = 90o) is adopted. The material of construction
shall be carbon steel.
201
Skirt thickness
The skirt thickness must be sufficient to withstand the dead-weight loads and bending
moments imposed on it by the vessel; it will not be under the vessel pressure.
The resultant stresses in the skirt will be: s (tensile) bs ws
s (compressive) bs ws
Where
bs
ws
4M s
Ds t s t s Ds
W
Ds t s t s Ds
Where:
Ms = maximum bending moments evaluated at the base of the base of the skirt
W = total weight of the vessel and its contents
Ds = inside diameter of the skirt at the base
ts = skirt thickness
The maximum dead weight load on the skirt would occur when the column is full of the
feed in liquid form at top and bottom conditions.
Approximate weight = 1.34 2 12.1 221.67 9.81 2.34 2 6.9 433.20 9.81
4
4
202
212
575.50kNm
Using a skirt height of 2 m, bending moment at the base of skirt, 2.61
2
As a first trial, take skirt thickness to be 20 mm
ws (test)
163.21 10 3
1.40 N / mm 2
1840 2020
ws (operating)
371.78 10 3
3.18 N / mm 2
1840 2020
f s J sin
2
135N / mm2 is greater than the maximum stress (tensile) = 7.52 N/mm
t
0.125E s
Ds
20
2
sin 0.125 200000
sin 90 271.8 N / mm
1840
203
t
0.125E s
Ds
Both criteria are satisfied, adding 2 mm for corrosion gives a skirt thickness of 22 mm.
Base ring and anchor bolts
The anchor bolts are assumed to share the overturning load equally, and the bolt area
required is given by:
Ab
4M s
W
N b f b Db
Where:
Ab = area of one bolt at the root of the thread
Nb = number of bolts
Fb = maximum allowable bolt stress also equal to the design stress
Ms = bending moments at the base
Db = bolt circle diameter
2040
11
600
Number of bolts = 12
Bolt spacing =
Ab
2040
534mm
12
1 4M s
1 4 575.5 10 3
W
371.78 752mm 2
N b f b Db
2.04
12 125
4 752
31mm
The total compressive load, Fb on the base ring per unit length is given by:
Fb
4 575.5 10 3 371.78 10 3
281 10 3 N / m
2
1
.
84
1.84
Lb
Fb
1
281 10 3
3
56.2mm
f c 10
5 10 3
205
Value
Weight of shell, kN
245
Weight of plates, kN
107.4
19.38
Total weight, kN
371.78
244
10.37
64.83
49.63
60
2.77
Skirt height, m
Skirt thickness, mm
22
Number of bolts
12
752
31
206
CHAPTER 12
, ....................................................................................................................................1
where,
PA = vapour pressure of heavier key component (propane).
PB = vapour pressure of lighter key component (ethylene).
= Relative volatility.
207
Table 12.1 Vapour pressure and relative volatility of propane and ethylene
Temperature (K)
C2H4(Pa)
248.05
2.2608106
3.7808106
1.6723
313
3.3714106
7.2785106
2.1592
Where:
Nmin = Minimum number of ideal plates
208
Nmin =
Nmin =
Therefore the minimum number of stages, Nmin = 21
,..4
where , = the relative volatility of component i with respect to some reference component,
usually the heavy key,
Rm = the minimum reflux ratio,
xD = concentration of component i in the tops at minimum reflux
and is the root of the equation:
, .5
xF = the concentration of component i in the feed, and q depends on the condition of the
feed.
209
But,
-1 = 1.75597
Most columns are designed to operate between 1.2 and 1.5 times the minimum reflux ratio
because this is approximately the region of minimum operating cost.
The Erbar-Maddox correlation which gives the ratio of number of stages required to the
number at total reflux, as a function of the reflux ratio, with the minimum reflux ratio as a
parameter was used here. Estimates of the number of stages at total reflux and the minimum
reflux ratio gives
, ...............................................................................................5
Where;
NR = number of stages above the feed, including any partial condenser,
NS = number of stages below the feed, including the reboiler,
B = molar flow bottom product,
D = molar flow top (distillate) product,
XF, MK =concentration of the heavy key in the feed,
XF, LK = concentration of the light key in the feed,
XD, HK = concentration of the heavy key in the top product,
XB, LK = concentration of the light key if in the bottom product.
2
N R 0.0666 0.04035 62.0737
0.206
= 4.552196 .........................................................................................................................6
........................................................................................................................7
Solving equation A and B simultaneously,
NR = 6.484 = 7 and NS = 29
211
Therefore the number of plates below the feed is 29. Hence the feed plate is at the 28th
plate from the top.
, 8
Where;
N = Number of trays
Ts = tray spacing ( 0.6 m is specified)
Kd = safety factor = 1.3
H = (36-1) 0.61.3 = 27.3 = 27m.
Where:
212
R = reflux ratio
V = 3.1072857.2043 =2663.5052kmol/hr
Also
/hr
Therefore vapour and liquid rate at the top of the column are 2663.5052kmol/hr and
1806.3892kmol/hr respectively.
213
kJ/kgmol
] - [-5468.588 (2663.5052)]
QC = -195.4954138MJ/hr
From equation (16), QR = DHD + BHB - FHF - QC
Where:
QR = reboiler heat duty
HF = the enthalpy of feed = -6458kJ/kgmol
HD = enthalpy of distillate = -2.405
kJ/kgmol
QR = 688.1685452MJ/hr
215
12.1.12 Determination of vapour and liquid density at the top and bottom
From calculations the vapour and liquid density of the column are as shown below
Table 12.2: Vapour and liquid density at the top and bottom
Property
Vapour
Top
Bottom
density
(V, 434.2564
450.9902
Density
(L, 460.0943
482.8811
Kg/m3)
Liquid
Kg/m3)
Where
Lw = liquid mass flow-rate, kg/s,
Vw = vapour mass flow-rate, kg/s.
= 0.98913
Therefore, the liquid-vapour factor at the bottom and top are 0.98913 and 0.6566
respectively.
216
,....18
Where:
uf = is the flooding vapour velocity in m/s or maximum permissible velocity based on
bubbling of active area,
K1 = empirical constant,
V = vapour density
L = liquid density
Using a plate spacing of 0.6m [1] and the flow factors at the top and bottom; thus
for FLV = 0.98913, K1= 0.035 (bottom) and
for FLV =0.6566, K1 = 0.046 (top)
Corrections for surface tensions:
Bottom surface tension = 0.1333N/m
Top surface tension
= 0.000801N/m
Therefore:
Bottom, K1 =
= 0.0541
217
Top,
K1 = 0.048
0.0252
Hence,
Bottom uf =
Top
= 0.0144m/s
uf =
The flooding condition fixes the upper limit of the vapour velocity. A high vapour velocity
is needed for high plate efficiencies, and the velocity will normally be between 70 to 90 per
cent of that which will cause flooding. For design, a value of 80 to 85 per cent should be
used. [1]
Hence design for 85 per cent flooding at maximum flow rate (uf) will be:
Bottom uf = 0.0144
Top
0.85 = 0.01224m/s
..19
V = vapour density
= maximum volumetric vapour flow rate
Top;
218
Bottom;
...20
Where:
AC = column area
= maximum volumetric flow rate
uf = maximum flooding flow rate
Top;
Bottom;
Column diameter:
21
Where:
AC = column area
Top;
219
Bottom ;
..22
Where:
LB = liquid rate at the bottom of the column, kg/s
L=
liquid density
6.005
3006
3000
3000
Reflux Ratio(R)
2.1072
1.7560
R/Rmin
1.2
Feed Stage
28
220
21
36
Tray Efficiency
59%
Height of column(m)
27
-195.4954138
688.1685452
Column diameter, m
top
2.8265
Bottom
3.4584
The sieve tray is chosen for the purpose of this design because of its efficiency, wide
operating range, and ease of maintenance and cost factors.
An = Ac Ad, 23
For the top, An = 6.2745
0.075 = 6.1995m2
Using
Where;
lw = length of weir
Dc = column diameter
0.805 = 2.2753m
2(0.075) = 9.7893m2
222
,26
where:
Lw = liquid flow rate, kg/s
Lw = weir lenght weir crest, mm liquid
= 43.1960mm liquid.
= 56.71893mm liquid.
223
=34.0546 mm liquid.
Bottom,
= 41.1666mm liquid.
Minimum rate =
Top, 50 + 39.0546 =89.0546 mm liquid.
Bottom, 50 + 39.1332 =58.1332 mm liquid.
The weep-point correlation,
K2 of the top is 30.8 and that of the bottom is 30.9 [1]
, .............................................................................................................27
vapour density
hole diameter
=0.5970m/s
= 0.6018m/s
= 24.3853m/s
224
Bottom, =
= 22.7953m/s
This means minimum operating rate will be well above weep point.
); and a term to account for other, minor, sources of pressure loss, the
ht =
, ........................................................................................................29
k1 = 0 and
Cv = 0.7419
k2 = 50.8 / 0.74192 = 92.77
For the top, uh = 0.1254m/s
225
Thus
mm liquid
, .30
mm liquid
Bottom, hr =
mm liquid
Hence ht =117.6008mm liquid for the top and 84.2379mm liquid for the bottom
, ..................................................................................................................31
Bottom,
+
For the top,
89.0546+177.6008+9.8335=276.4889mm liquid
, ............................................................33
= 0.7001sec
227
At
lw
Dc
Number of holes
0.0148
753.95 754
1.963 105
6.1245m2
Length of weir, lw
Bottom 9.7893m2
Top
2.2753m
Bottom 2.7842m
Weir height
50mm
Downcomer area, Ad
0.075m2
Plate thickness
3mm
Hole area, Ah
0.61245m2
117.6 mm liquid
Top
Hole diameter,
Bottom 0.97893m2
Net area, (An)
Top
6.1995m2
5mm
dh
754
Downcomer area
0.07m2
Bottom 9.8643m2
Plate spacing
0.6m
Plate material
228
carbon steel
3000kPa
100
Maximum weight of the vessel and contents under hydraulic test conditions.
Wind loads
240Cv Dm Hc
0 8 Dm t ,.......................................................................................34
Where:
W v = Total weight of column or shell; N
Cv = a factor to account for the weight of nozzle, manways and plate support ring or
equivalent fittings and it is equal to 1.15 for distillation columns. [1]
Hc = Column height = 27m
g = acceleration due to gravity = 9.81N/m2
t = wall thickness, mm = 5mm
Dm = mean diameter of column = t + Hc = 0.005 + 2.8265 = 2.827m for the top and
3.4589m for the bottom
Wv
240
1 15
2 827
27
2 827 0 005
21077 83286N for the top and 34763 44462N for the bottom. Therefore total weight of
column =21077.8386 + 34763.444462 = 55.8412831MN.
Plate area = 4
0 62
0 28m2
230
The total weight of a plate are found by multiplying the plate area by 1.2kN/m
weight of plate = 1.2 0.28 = 0.34kN
Pw = 0.05Uw 2,...35
Pw = wind pressure, N/m2
Uw = wind speed, km/h.
Average Uw = 150km/h [6]. To allow for tolerance, a value of 160km/h will be used.
Pw
0 05
1602
1280N/m2
1280
2 9865
3822 72N m for the top and 4426.753N/m for the bottom. Hence
Mx
Wx2
2
, .37
x = column height
Mx
3822 72 272
2
To ensure that column is sufficiently rigid to withstand its own weight, a minimum wall
thickness is allowed. For column with diameter between 3-3.5m a minimum thickness of
12mm is required.[2] Since the column diameter is approximately between 3 and 3.5, wall
thickness of 12mm is used.
2t
, ..38
Where:
h=
Di= internal diameter of column = 2.8265m for the top and 3.4584m for the bottom.
t = wall thickness = 0.005m
3300 2 8265
h
2 0 005
PDi
4t
, ...39
3300 2 8265
L
4 0 005
The stress due to the weight of the vessel and the attachments are referred to as the direct
stress,
is calculated as:
233
W
w
, 40
Di t t
21077 8386
w
Iv
t ,.41
where:
M is the total bending moment at the plane being considered
Iv is the second moment of area of the vessel about the plane of bending moment
Iv
64
Do 4
Di 4 , .42
Do = 2.8265 + (20.005) = 2.8365m for the top and 3.4684 for the bottoms.
Iv = 0.0446m for the top and 0.0816m for the bottoms
b
upwind
negative
3108434536 N m2
234
b .....................43
downwind
2072721518N m2
and
k.
The greatest
difference between the principal stresses will be on the down-wind side and this should be
below the maximum allowable of 141.92 N/mm2.
Therefore the metal can withstand the stresses imposed on it during operation since the
stresses are well below the maximum allowable stress.
bs
ws
...44
Where:
bs =
bs
4Ms
Ds ts ts Ds
.45
Where,
bs =
bending stress,
1 52
28
1081 736
525074 2508
wx2
2
9 81
481038 2
525074 2508 N
1006112 451 N
.................................................................................46
bs
29 52
2131 2
4Ms
4 927338 4 103
Ds ts ts Ds
1500 15 15 1500
927338 4 Nm
34 64 N mm2
Also
W
ws
Ds ts ts
Where,
ws
......................................................................................................
47
1500 15 15
14 09 N mm2
bs
ws
bs
34 64
ws
34 64
14 09
14 09
48 73 N mm2
20 55 N mm2
maximum
0 125
190000
0 015
sin90
3 4584
103 01N m2
This is far higher than the calculated design stress. The criterion is therefore satisfied.
Maximum tensile stress = fsJsin [1].
Where fs = maximum allowable design stress for skirt material = 103.01 N m2
J = weld joint factor = 0.85 [1]
237
103 01
0 85
sin90
87 559N m2
4Ms
Nb fb
Db
W .. 49
Where:
Ab = area of one bolt at the root of the thread
Nb = number of bolts
fb = maximum allowable bolt stress = 125 N/m2
Ms = bending moment at the base = 1613551 469 Nm
Db = bolt circle diameter = 2.2 m
238
2200
600
11 519
Ab
12
4
125
4 453 3
Bolt spacing =
1613551 469
22
2 2 103
12
9042
1895 54m2
49 127mm
575 95
576 mm
The total compressive load, Fb on the base ring per unit length is given by:
4
Fb
1613551 469
15
90420
15
973363 35 N m
Lb
1195507 822
103
103
194 673m
Lf
ts
15
50 mm
50
165 mm
fc
Fb
LR
1195507 822
165
10
7 25 N mm2
The minimum thickness of base ring is found by the ring as a cantilever beam and it is
given by:
tb
Lr
tb
3fc
fr
.50
150
7 25
140
59 mm
Weight of
shell, Wv
Resultant
longitudinal
stress
(upwind),
Design
temperatur
e
3108434536N/
m2
Resultant
longitudinal
stress
(downwind),
2072721518N/
m2
Weight of 12.241kN
plates
Circumferenti
al stress
1037008.5kN/m
Skirt
height
2.5m
Direct stress
1114316.53kN
Number of
bolts
12
8249.473Nm
Total weight
column
55.841283MN
-45C(top)
85C(botto
m)
Wind
pressure
1280Pa
Bolt area
1895.54mm
Bolt spacing
576mm
Total
compressiv
e load, Fb
125N/m2
Minimum
width of base
ring, Lb
194.673m
Bolt
diameter
49.127mm
Actual
pressure,
Minimum
thickness
of
base
ring, tb
59mm
Design
pressure
241
3000kPa
3300kPa
CHAPTER 13
D=500.0665Kmol/hr
x(C2H6) =0.3970
x(CH4)=0.0008
x(C2H4) =0.994
x(C2H2)=0.0035
x(C2H2)=0.006
x(C2H4)=0.5987
T=262.3K
P=3200kPa
F=832.3662Kmol/h
T=238.05K
B=332.24407kmol/hr
P=3080027kPa
x(C2H6)=0.9942
x(C2H4)=0.0038
x(CH4)=0.002
T=265.099K
P=2000kPa
Relative volatility()
To determine the relative volatility between the two substances,a formula is employed from
(R.K. Sinott,1986) to determine their vapour pressures.The relative volatility is taken as the
geometric mean of the values at the top column and the bottom temperature.
=PBo/PAo
where PBo = vapour pressure of the light key
PAo= vapour pressure of the heavy key
Using the formula,
expC1+(C2/T)+C3x ln(T)+ C4x TC5,(1)
PBo (C2H4) = 31.44
PAo (C2H6) =25.28
Therefore , = 31.262/25.28=1.24
Using the McCabe Thiele theory,
y= x/1+(-1)x..(2)
Choosing sample values for x between 0.1 to 1.0(values are used to construct the
equilibrium curve and operating lines)
0.1
0.12
0.6
0.65
0.2
0.23
0.7
0.74
0.3
0.36
0.8
0.83
0.4
0.45
0.9
0.91
0.5
0.56
1.0
1.00
Figure 3 shows the Equilibrium curve relation between Ethylene and Ethane
244
For the McCabe Thiele theory, only one component is being considered (predominantly
the lighter component) throughout the entire section.
By the aid of figure 1 above,
For ethylene compositionXD in top stream,
=0.994 1.00
For ethylene composition,XB in bottom stream,
=0.0038 0.004
For the construction of the equilibrium curve, the compositions are :
XF=0.6 XB=0.003 XD=1.00
For construction of the q line,
q=(HV HF)/ .(3)
where :
CP=heat capacity
HV=enthalpy of vapour flow
HF=enthalpy of feed
=latent heat of vapourisation of ethylene
HV=mvCpT
but m=Mn=28x1.0=28kg(M(ethylene)=28)
Hv=28x0.994x87.461x262.3=638494.47
245
HF= mFCpT
Cp=82.04
HF= 28x0.5987x82.04x238.05=327386.771
q=(638494.47-327386.771)/2182578.473=0.15 0.2
For minimum reflux(Rm)
Rm/Rm+1=(XD-yI)/(XD-xI)
= 1-0.92/1-0.9
0.8=Rm-0.8Rm
0.80=0.2Rm
Rm=0.8/0.2=4.0
L=RxD=6x500.0665=3000.399Kmol/hr
Also,V=L+D , where V vapour flow rate
V=3000.399+500.0665
=3500.4655Kmol/hr
For Rectification section,
Calculate for :
XD/(R+1)=1/(6+1)=0.14
From correlation,
N-Nm/N+1=0.35
N-Nm=0.35N+0.35
but Nm=48.35
N-48.35=0.35N+0.35
0.65N=48.7
N=74.92 stages
Feed stage location
By the feed stage location is given by;
2
N R 0.5987 0.0038 332.244
0.206
Where;
NR = number of stages above the feed, including any partial condenser,
NS = number of stages below the feed, including the reboiler,
B = molar flow bottom product,
D = molar flow top (distillate) product,
XF, HK =concentration of the heavy key in the feed,
XF, LK = concentration of the light key in the feed,
XD, HK = concentration of the heavy key in the top product,
248
0.206
= 4.47 .................................................................................................................................5
................................................................................................................................6
Solving equation A and B simultaneously,
NR = 63 and NS = 14
Therefore the number of plates below the feed is 14. Hence the feed plate is at the 13th
plate from the top.
Tray Spacing
Chosen as 0.5m using theory from Handbook of Chemical engineering calculations
249
H=(75-1)x0.5x1.3
=48.1m
by conversion,W=8.542Ib/s
From theory, v=2.085kg/m3.By conversion,v=1.402Ib/ft3
AF=(8.542Ib/s)/1.58x(1.402)1/2
=4.56ft2
FLOODING VELOCITY(at the top and bottom columns)
Flooding velocity can be estimated from the correlation given by Fair(1961)
Uf=K1(L- v)0.5/ v0.5 ..(8)
where :
Uf=flooding vapour velocity in m/s or maximum permissible velocity based on bibbling of
active area
K1=empirical constant
v=vapour density
L=liquid density
From fig.11.27(R.K. Sinnot,1986)
Using a plate spacing of 0.5m(18in) and the flow factor,FLV from figure 11.27(Coulson and
Richardson.Vol. 6)
FLV=Lw/VW v/ L where
LW=liquid mass flow rate ,kg/s=332.24407kmol/hr=2.58kg/s
Vw=vapour mass flow rate ,kg/s=501.0665kmol/hr=3.89kg/s
251
v=density of vapour(ethylene)
L=density of liquid(ethane)=
v=vapour density
L=liquid density
From figure 11.27(Sinnot 2003) using a plate spacing of 0.5m(18in) and the flow factors at
the top,
K1=0.06.bottom
K1=0.08top
Correlations for surface tensions ( =0.02N/m multiply K1 by( /0.02)0.23)
Bottom surface tension=128x10-3N/m
Top surface tension=171.28x10-3N/m
Therefore
Bottom K1=(128/20)0.2x10x10-2=0.14
Top K1=(171/20)0.2x9x10-2=0.13
Hence
Bottom,Uf=0.14(328.33-1.37)/1.37
=2.16m/s
Top Uf=0.13(494.14-1.3)/1.3
=2.53m/s
The flooding condition fixes the upper limit of the vapour velocity.A high vapour velocity
is needed for high plate efficiencies, and the velocity will normally be between 70 to 90%
254
of that which will cause flooding.For design, a value of 80 to 85% should be used(R.K.
Sinnot,1986).Hence design for 80% flooding at maximum flow rate(Uf) will be as follows:
Bottom Uf=2.16x0.80
=1.728m/s
Top Uf=2.53x0.80=2.024m/s
Maximum volumetric flow rate
The maximum volumetric flow rate can be calculated from the correlation,
..(10)
V = vapour density
= maximum volumetric vapour flow rate
Base =3.89/1.37=2.84m3/s
Top
=2.58/1.3=1.98m3/s
Area required
The net area required can be estimated from the equation:
AC / f ...(11)
Where:
AC = column area
255
Ac=2.84/1.728=1.64m2
Top
Ac=1.98/2.024=0.98m2
4 AC .. (12)
DC
Where:
AC = column area
Top Dc=((4x0.98)/3.142)0.5=1.117m
Bottom Dc=((4x1.64)/3.142)0.5=1.44m
Liquid flow pattern
Maximum volumetric liquid rate,
L =
LB
..(13)
Where:
LB = liquid rate at the bottom of the column, kg/s
L = liquid density
256
L = 2.58/328.338=7.86x10-3m3/s
From Fig. 11.28 (R.K. Sinnot, 2003) the flow pattern is chosen to be cross flow (single
pass) based on the value of L.
257
-34.95
3080027
3200
2000
Reflux Ratio(R)
6.00
4.00
R/Rmin
1.5
Feed Stage
13
48.35
75.0
Tray Efficiency
78%
Height of column(m)
48.1
-1.5x104
Column diameter, m
Top
1.117
Bottom
1.44
258
Using
Ad
100 12 , Ad/ Ac x 100 = 6.12
AC
equivalent
lw
0.76 is read from Fig.11.31 (R.K. Sinnot, 1986).
DC
259
Dc = column diameter
For top column
lw = 0.76 x 1.117 = 0.848m
For bottom column
lw= 0.76x1.44=1.09m
Value of hole diameter, d h and plate thickness are 5mm and 5mm respectively.
Active area, Aa= Ac -2Ad = 0.98 2(0.06) = 0.86m2
Hole area, Ah = 0.1Aa= 0.1x 0.86 = 0.086m2
lw =weir length
how=weir crest,mm liquid
Maximum how
For top column=750(3.91/(264.615x0.848))2/3=50.4mm liquid
For bottom column=750(3.91/(264.615x1.09))2/3=42.6mm liquid
Also minimum how
For top column= 750(2.74/(264.615x0.848))2/3=39.76mm liquid
For bottom column=750(2.74/(264.615x1.09))2/3=33.64mm liquid
Hence at minimum rate, hw + how
For top column = 50 + 39.76= 89.76mm
For bottom column=50+33.64=83.64mm
From Fig. 11.30, the weep-point correlation Eduljee (1959), K2 = 30.4
Also;
uh=(K2- 0.9(25.4-dh))/ v0.5.(15)
uh= minimum vapour velocity through the holes at weep point
v=vapour density
dh= hole diameter,mm
uh=(30.4-0.90(25.4-0.0055))/1.6800.5=5.8m/s
261
u
hd 51 h V . (17)
CO L
Where the orifice coefficient CO is a function of the plate thickness, hole diameter, and the
hole to perforated area ratio.
262
From discharge coefficient (CO) plot, fig 11.34 (R.K Sinnot, 1986), Liebson et al, (1957),
for plate thickness/hole diameter =1 and Ah/Ap Ah /Aa = 0.06 0.1, CO = 0.84. Hence hd
can be estimated as:
=51(37.2/0.84)2x(0.974/264.61)
=368mmliquid
=0.3mliquid
Residual Head
Methods have been proposed for estimating the residual head as a function of liquid surface
tension, froth density, and froth height. However as this correction term is small the use of
an elaborate method for estimation is not justified and the simple equation proposed by
Hunt et al (1957) can be used. (R.K.Sinnot 1986)
hr=12.5x103/L
hr=12.5x103/264.61=47.23mmliquid(18)
Total plate pressure drop, ht
ht hd hw how hr .(19)
Downcomer design
Downcomer pressure loss
Assume the height of apron, hap = hw 10 = 40mm
Then area under apron, Aap = lw x hap
For top column= 0.848 x 0.04 = 0.03m2
For bottom column=1.09x0.04=0.04m2
As these values are less than Ad 0.06m2 , the head loss in the downcomer, hdc can be
estimated using the equation given by Cicalese et at, (1947)
L
hdc 166 wd .................................................................................................(20)
L Am
where:
L wd liquid flow rate in downcomer, kg/s
A m either the downcomer area Ad or the clearance area under the downcomer A ap :
whichever is the smaller, m 2
hdc= 166(3.91/(264.615x0.06))=40.88mm
Downcomer liquid back-up
In terms of clear liquid the downcomer back-up, hb, is given by:
hb hw how ht hdc ...................................................................................(21)
= 0.42m.
For bottom column hb=(50+33.64) +283.84+40.88
=408.36mm
=0.41m
tr
Ad hbc L
.....................................................................................................(22)
Lwd
where:
tr residence time
h bc clear liquid back-up
tr=( 0.06x0.4x264.615)/3.91=1.62s
Determination of entrainment
Entrainment must therefore be reduced to a minimum amount such that it will not exceed
0.1 moles liquid per mole of gas. This can be estimated from the correlation given by Fair
(1961), which gives the fractional entrainment (kg/kg gross flow) as a function of liquidvapour factor FLV, with percentage approach to flooding as a parameter.
The percentage flooding is given by:
Percentage flooding =
un
5.59
3.63m / s un= 3.91/1.54=2.54m/s
1.54
3.63
87, FLV 0.05 =2.54/4.24=60 FLV =0.03
4.24
From Fig. 11.28 (R.K. Sinnot, 2003), fractional entrainment =0.06 which is less than
the upper limit of 0.1, hence satisfactory.
Estimation of perforated area
lw
0.76
DC
Where
990
266
lp
dh
Where:
lp = the hole pitch (distance between the hole centers)
lp=dh x2.7=5x2.7=13.5mm
Calculation of the Number of Holes
Area of one hole = 1.963 x 10-5m
Number of holes
0.0148
753.95 754
1.963 105
Weir height
1.48m
0.005m
0.848m
1.09m
Hole diameter, d h
5mm
Plate thickness
5mm
1.112m2
Active area, Ac
0.98m2
Hole area, Ah
0.086m2
Hole pitch, lp
13.5mm
Plate spacing
0.5m
Active holes
754
Turn-down
287.33Pa
Mild steel
Downcomer material
267
Mild steel
10
101.3 10.13kPa
100
(24)
Where:
Cv = a factor to account for the weight of nozzle, manways and plate support ring or
equivalent fittings and it is equal to 1.15 for distillation columns. (R.K sinnot, 1993)
Hc = Column height = 48.1m
g = acceleration due to gravity = 9.81N/m2
t = wall thickness, mm = 5mm
Dm = mean diameter of column = t + diameter of column(top) = 0.005 + 1.117 = 1.122m
= t + diameter of column(bottom)=0.005+1.44=1.445m
Wv(top)=240x1.15x1.122(48.1+(0.8x1.122))x5 = 75.87kN
Wv(bottom)=240x1.15x1.445(48.1+(0.8x1.445))x5=98.22 kN
Weight of plates
Plate area =
0.6 0.28m2
2
The total weight of a plate are found by multiplying the plate area by 1.2kN/m
weight of plate = 1.2 0.28 = 0.34kN
Weight of insulation
269
Mineral wool is used for the insulation because it is relatively cheap and also widely used
for insulating distillation columns. (Nelson, 1963).
Density of mineral wool = 130kg/m3 (Nelson, 1993)
Thickness of insulation = 75mm (Nelson, 1993)
Approximate volume of insulation = = x0.6 x48.1x0.075=6.7m3
Weight of insulation =6.7x130x9.81=8.544kN
The weight of insulation is doubled to allow for attachment of fittings and moisture
absorption. (Nelson, 1963)
Therefore weight of insulation together with fittings is taken as 2x8.54=17.08
Sum of Weights = weight of shell + weight of plates + insulation weight
= 44.13 + 25.5 + 17.08
= 86.71kN
Wind loading
Wind pressure for smooth cylindrical columns is estimated from the relation;
Pw = 0.05Uw 2
Pw = wind pressure, N/m2
Uw = wind speed, km/h.
Average Uw = 150km/h (Meteorological Department, KNUST). To allow for tolerance, a
value of 160km/h will be used.
270
The load per unit length of the column, Fw, is obtained from the wind pressure multiply by
the effective diameter, Deff, (i.e. the outside diameter + an allowance for the thermal
insulation).
Fw = Pw Deff..(25)
Deff = 2.04 + 2(0.075 + 0.005) = 2.2m
Mx =
Wx 2
2
(26)
PDi
(27)
2t
271
Where:
0.14 2040
28.56 N / mm2
25
PDi
.............................................................................................( Sinnot , 1993)
4t
2040 0.14
L
14.28 N / mm2
45
The stress due to the weight of the vessel and the attachments are referred to as the direct
stress, w , is calculated as:
W
....................................................................................( Sinnot , 1993)
( Di t )t
57010
1.77 N / mm 2
(2040 5) 5
As a result of bending moments on the column, the column would definitely be subjected to
bending stress. The bending stress will be compressive or tensile, depending on the location
and it is given by:
272
M Di
where:
M = Total bending moment at the plane being considered
I v = The second moment of area of the vessel about the plane of bending and it is given by:
Iv
64
5 16.84 N / mm 2
10
1.68 10 2
2
N / mm ...................................................................(Sinnot, 1993)
5
2
c 2 104
48.78 N / mm
2050
c 2 104
The maximum compressive stress that would occur when the column is not under pressure
would be equal to the dead weight stress plus the bending stress.(Sinnot, 1993).
273
The maximum compressive stress = 5.95 + 19.17 = 25N/mm2. This is far below the critical
and therefore acceptable.
Column Supports
The method used to support a vessel depends on the size, shape and weight of the vessel;
the design temperature and pressure; the vessel location and arrangement and the internal
and external fittings. Horizontal vessels are usually mounted on two saddle supports whilst
tall vertical vessels like distillation columns are mounted on skirt supports. The supports
must be designed to carry the weight of the vessel and contents, and any superimposed
loads such as wind loads. Supports should also be designed to allow easy access to the
vessel and fittings for inspection and maintenance. The height of the skirt is usually
between 2-3m. For this design a height of 2m is used.
Skirt thickness
The skirt thickness must be sufficient enough to withstand the dead weight loads and
bending moments imposed on it by the vessel.
The resultant stresses, in the skirt will be:
s bs ws (28)
Where: bs = the bending stress in the skirt given by
bs
4M s
.............................................................................(Sinnot, 1993)
( Ds ts )ts Ds
ws
W
..........................................................................(Sinnot, 1993)
Ds ts ts
Where:
Ms = maximum bending moments evaluated at the base of the base of the skirt
W = total weight of the vessel and its contents
Ds = inside diameter of the skirt at the base
Ts = skirt thickness
The skirt thickness should be such that under worst combination of wind and dead weight
loading the following design criteria should not be exceeded;
ts
Ds
ws 0.125E
Where:
E = Youngs modulus = 200,000N/mm2
s
The maximum dead weight load on the skirt that would occur when the column is full of
water. (Sinnot, 1993)
275
=(/4x2.042x48.1)
Weight of column = 57.01kN
Total weight 57.01 448.90 505.91kN
(14 2)2
Bending moment at base of skirt=2.82
360.96kN
2
bs
ws (test )
505.91103
4.61N / mm2
2040 17 17
ws ( operating )
The
57.01103
0.51N / mm2
2040 17 17
maximum
stress
(compressive),
is
calculated
as:
This is far higher than the calculated design stress. The criterion is therefore satisfied.
276
2mm is added to the skirt thickness to cater for corrosion. Design skirt thickness is
therefore taken as 19mm.
Base ring and anchor bolt
The anchor bolts are assumed to share the overturning load equally, and the bolt area
required is given by:
Ab
1 4M s
W ........................................................................ Scheiman, 1963
N b f b Db
Where:
A b area of one bolt at the root of the thread, N/mm 2
N b number of bolts
f b maximum allowable bolt stress also equal to the design stress opf 115N/mm 2
M s bending moments at the base, Nm
D b bolt circle diameter, m
According to Scheiman (1963), bolt spacing should not be less than 600mm and the total
number of bolts should be in multiples of 4.
Bolt spacing =
2.2 103
12
575.96mm 576mm
277
2200
12
600
Ab
1 4 360.96 103
57.01103 399.52mm2 400mm2
12 125
2.2
399.52 4
22.55mm 23mm
The total compressive load, Fb on the base ring per unit length is given by:
110kN / m
2
2.04
2.04
The minimum width of the base ring, Lb is given by:
Lb
Fb 1
...................................................................................( Scheiman,1963)
f c 103
Lb
110 103
22mm
5 103
Where Lr is the distance from the skirt to outer edge of the ring.
Actual width = 76 + 13+50 = 139mm
Actual pressure on the concrete foundation,
f c'
Fb
...............................................................................................( Scheiman, 1963)
LR
f c'
110 103
0.79 N / mm2
139 103
The minimum thickness of base ring is found by the ring as a cantilever beam and it is
given by:
278
tb Lr
3 f c'
.......................................................................................( Scheiman, 1963)
fr
tb 79
3 0.79
10.28mm 10mm
140
279
Critical
stress, c
44Kn
buckling 49 N/mm2
29N/mm2
Resultant
longitudinal
(upwind), z
stress
Resultant
-4 N/mm2
longitudinal stress
(downwind), z
14N/mm2
Weight of plates
25.5kN
Circumferential
stress
Skirt height
2m
Number of bolts
12
Weight of column
57kN
Bending
Mx
Wind pressure,N/m2
1280
Total weight
506kN
Maximum
stress(compressive),
s
11N/mm2
Maximum
stress(tensile), s
7N/mm2
Bolt area
400mm2
23mm
moment, 3257.56kNm
Actual pressure,
Total weight
column
280
0.8N/mm2
of 506kN
CHAPTER 14
Components specification
Height of packings
Type of packing
Diameter calculation
Support design
14.1.2 CONSTRAINTS
Flooding limits
Loading Limits
Absorption factor
14.20 ASSUMPTIONS
Once the process is followed by air stripping, the value of X2 will approach zero
Since we're considering a new design with no serious pressure drop constraint, we'll
choose the more economical random packings.
14.3 Justification
Random packing absorber is chosen over the other types because
It is cheaper in terms of cost of the type of packings used.
It is economical as far as this pilot project is concern.
It is simple to construct.
mass
(kg/hr)
Amount
kmole/hr
Acetylene
76.7416
0.0059
2.9516
Ethylene
13919.217
0.9941
497.1149
TOTAL
13,995.958
1.0000
500.0665
282
in
mass
Amount
(kg/hr)
in
kmole
Acetylene
1.535
1.18
0.0059
Ethylene
13900.00
0.999882
496.423
TOTAL
13,901.535
1.0000
496.4345
mass fraction
Amount in kmole/s
Acetone
127.201
2.190
Mass
Amount in kmole/s
(kg/s)
Acetone
127.20
0.628
2.190
Acetylene
75.2066
0.372
2.8925
Total
202.4076
5.0825
acaaaa
Where:
Gm = total gas molar flow rate (mole/hr)
y = mole fraction of acetylene in gas stream
Lm = total liquid molar flow rate (mole/hr)
x = mole fraction of the acetone in pure liquid
The flow of gas and liquid does not change in the absorber
284
Henrys correlation (Hy) = 0.0082atm.m3/mol at 200C and 17 atm (Ray and Johnson)
285
Multiply the slope of the minimum operating line by 1.5 to get the slope of the actual
operating line: (sinott 2005)
AF = absorption factor
L2 = molar flow rate of liquid
m = slope of the equilibrium line on a mole fraction basis = Hy
G1 = molar flow rate of gas
= 87%
286
Kg/s
= 0.4545 Kg/m2s
Designing for a Pressure Drop of 32 mm acetone per m of packing, we have
K4 = 1.25
Then, Cornells method for determining percentage flooding (sinnot 2005, page 618).
Percentage flooding at selected diameter:
% Flooding =
= 71.55%
And,
(Sinnott 2005)
Di =
288
289
0.415 m/s
(Kister (1992))
The Methodology adopted for the calculation of Height of the Packing is referred from the
literature by NORMAN W.S (ABSORPTION, DISTILLATION AND COOLING
TOWERS), Pg 214.
The Average Properties of the gas at the temperature are given as follows,
The Density of gas mixture
290
(sinott 2005)
kG
(sinott 2005)
Now,
With (P/PBM) =1(approx), we have,
=203.257 Pa
Acetylene absorbed =
Area of Packing =
=550.96 m
) + 2.81 = 19.09775 m
292
(1.50)
VALUE
Height of Packings
9.2677m
Column Height
19.0977m
Wetting rate
Choice of packing
Packing size
76 mm
Type of installation
Random
Absorption factor
87%
Percentage Flooding
71. 55%
1722.525KPa
Diameter of Column
293
= 2m
Where,
Inner Diameter of vessel, Di =
Most design codes and standards specify minimum allowance of 3.0 mm. (sinnott2005, pg
826)
Corrosion allowance(c) = 3mm = 0.003m
Hence,
= 11.733mm
For column of diameter 2m-3m, the minimum thickness should be 10mm. (sinnott2005, pg
828)
11.756 mm
21 MPa
295
14.6.4OUT OF ROUNDNESS
Figure 2.0
So outer diameter of shell Do = 3.248 m + 2 x 0.03m = 3.308 m
Ovality (out-of-roundness) of a cylinder is measured by:
%
For vessels under external pressure this should normally exceed 1.5%. (Sinnot 2005, pg
841)
MPa
296
297
W=
= 188 KN
The bending stresses will be compressive or tensile, depending on location, and are
given by:
The forces due to wind load acting on the lower and upper parts of the vessels are
determined as
Plw = k 1 h1 Do
Puw = k
h2 Do
. (1)
(2)
Data:
Choosing cylindrical skirt support as the support for the absorber
Skirt support is used to support the absorber column.
Material to be used = Structural steel (ISO 800)
1 = density structured steel = 7700 kg /m3
h1=2m
D0=3.308m
Iv the second moment of area of the vessel about the plane of bending
299
Where
the effective column diameter is: This includes the outside diameter plus an
allowance for the thermal insulation and attachments, such as pipes and ladders.
D0=3.308 m
An allowance of 0.4 m is mostly added for expansion
300
71.076
301
= 596696.65
Ab
1 4Ms
Nb fb Db
Where:
Ab = area of one bolt at the root of the thread
Nb = number of bolts
fb = maximum allowable bolt stress
Ms = bending moment at the base
Db = bolt circle diameter
W = weight of column
Bolt spacing should not be less than 600 mm and the total number of bolts should be in
multiples of 4.[Sinnott pg860]
302
00
600
Ab
4
125
Bolt spacing =
1613551 469
22
4
2 2 103
9042
mm
mm
303
m2
VALUE
cylindrical skirt
11.733mm
Critical Pressure
21MPa
Weight of Support
188 KN
3.248m
3.308m
Carbon Steel
Elastic stability
71.076
Earthquake loading
15040 N
0.37MPa
Bending stress (
2.6 MPa
11.756 mm
304
CHAPTER 15
Where:
F = feed
D = distillate or top product
B = bottom product.
Component Balance:
FX F DX D BX B ....................................................... 2
N min
ln[ xD (1 xB ) / xB (1 xD )]
1 .. (3)
ln
Where:
Nnim = Minimum number of ideal plates
306
Therefore Nnim =
Rmin =
1
X / X 1 X D /1 X F (4)
1 D F
Where:
is the relative volatility of the two components
Rmin is the minimum reflux ratio
XD and XF are the mole fraction of methanol in the distillate and feed
respectively.
Rmin
1
0.99999 / 0.11838 10^6 1.231 0.99999 /1 0.11838 10^6 3662
1.23 1
From studies, the optimum reflux ratio to use for lowest cost per year is between the
minimum Rmin and the total reflux. This has been shown for many cases to be at an
operating reflux ratio between 1.2 Rmin and 1.5 Rmin. (Geankopolis, 198.)
Therefore, the optimum reflux ratio, R is chosen as
R = 1.2(Rmin) = 4394
308
R Rmin
N N min
f
N 1
R 1
......................................................................................(5)
R Rm
1.83
R 1
For plate efficiency, Eo = 85%
N=Nmin/0.85
N=129
Location of feed plate
KIRKBRIDES equation is used for the estimation of the number of plates above and
below the feed plate. The equation is given by:
B X
m
log 0.206 log FF
p
D X MF
X FD
(6)
X MD
Where:
B = mass flow rate of bottom product
D = mass flow rate of top product
309
13494.83
m
0.99999
1.0 10^ _ 6
log 0.206 log
0.9998
p
1.5977 0.11838 10^ 6 0.99999
m
0.9998
p
m = 0.9998p... (7)
Total number of plates, T = p + m.................................... (8)
Substituting equation (7) into (8) gives:
T = p + 0.9998p
129 = 1.9998p
P= 65
Therefore the number of plates below the feed is 69. Hence the feed plate is at the 11th
plate from the top.
310
0.5m is taken as the spacing between the draw off tray and the bottom of the
product. (Coulson et al, 1983)
Now
V
R 1 (Mc Cabe et al, 1986)
D
Where:
R = reflux ratio
V
4394 1 4395 , but D = 1.5842kg /hr
D
V=6962.6147kg/hr
Also
L
R
4394
0.9459 L=6961.0305kg/hr
V R 1 4394 1
311
Therefore vapour and liquid rate at the top of the column are 6962.6147kg/hr and
6961.0305kg/hr respectively.
Vapour and liquid rates at the bottom of the column
Assume a constant molal overflow at the bottom of the column, the total material balance
gives:
LB = VB +B (10)
Where:
LB = liquid rate at the bottom of the column
VB = vapour rate at the bottom of the column
B = bottom product
F= feed rate
But
LB = L + F.. (11)
LB =20457.4482kg/hr
VB=LB-B
VB=6962.6182kg/hr
Therefore liquid and vapour rate at the bottom of the column are 20457.4482kg/hr and
6962.6182kg/hr respectively.
Balances around entire column
312
QC 32614MJ / hr
From equation (11), QR = DhD + BhB - FhF - QC
Where:
QR = reboiler heat duty
313
QR 29833MJ / hr
Determination of vapour and liquid density at the top
Molecular weight of vapour MV = 0.99999(26.06) + 1.0*10-6(28.05) = 26.06g/mol
Assume the ideal gas law is applicable to vapour,
Then
PV = nRT PV =
M
RT
MV
M
PMV = RT , PMV V RT
V
PM V
RT
Where:
T = Boiling point temperature of Acetylene = 357K
314
V vapour density
V (5030 x 26.06)/(8.314 x 357) =44.1636kg/ m3
V 0.999999(7.61)+(5.5909)(1.x10-6)=7.61kg/m3
Liquid density = (1.0 x10 -6)(11.03329) +(0.999999 x17.2133)=17.2132kg/ m3
Determination of vapour and liquid density at the bottom
Molecular vapour, MV = 0.999999(28.05) + 1.0 x 10 -6(26.06) = 28.0499g/mol
Assume the ideal gas law is applicable to vapour,
then PV = nRT PV =
M
RT
MV
M
PMV = RT
V
PM V
RT
Where:
T = Boiling point temperature of Ethylene= 377K
P = pressure of column = 5030kPa
315
V vapour density
V (5030 x 28. 0499)/(8.314 x 377)=45.0140kg/ m3
Hence the gas mixture is not ideal.
FLV
Lw
Vw
V
L
Where:
Lw = liquid mass flow-rate, kg/hr
Vw = vapour mass flow-rate, kg/hr
At bottom;
=2.091
At the top
=0.665
316
Therefore, the liquid-vapour factor at the bottom and top are 2.091 and 0.665 respectively.
Determination of flooding velocity at the top and bottom
The flooding velocity can be estimated from the correlation given by Fair (1961):
uf =
K1 L V
0.5
V 0.5
.. (9)
Where:
uf = is the flooding vapour velocity in m/s or maximum permissible velocity
based on bubbling of active area,
K1 = empirical constant,
V = vapour density
L = liquid density
From fig. 11.27 (R.K. Sinnot, 1986), using a plate spacing of (24inch)
K1= 0.09.bottom
K1 = 0.10.top
Corrections for surface tensions:
Bottom surface tension = 56x10-3N/m
Top surface tension
= 21x10-3N/m
Therefore:
317
0.2
Bottom K1 =
56
2
9 10 0.11
20
Top
21
2
10 10 0.10
20
0.2
K1 =
Hence,
Bottom
uf=0.11((11.033-5.59)/(5.59)^0.5)
uf b= 13.5398 m/s
Top
uft =11.2352 m/s
The flooding condition fixes the upper limit of the vapour velocity. A high vapour velocity
is needed for high plate efficiencies, and the velocity will normally be between 70 to 90 per
cent of that which will cause flooding. For design, a value of 80 to 85 per cent should be
used. (R.K. Sinnot, 1986)
Hence design for 85 per cent flooding at maximum flow rate (f) will be:
Bottom fb 13.5398 x 0.8500=11.5088m/s
Top
ft =11.2352 x 0.8500=9.55m/s
318
..(10)
V = vapour density
= maximum volumetric vapour flow rate
Base = (6962.6182/5.59)
=124.55488 m3 / hr
Top
= (6961.0305/7.61)
=91.7215 m3 / hr
AC / f ...(11)
Where:
AC = column area
= maximum volumetric flow rate
f = maximum flooding flow rate
Bottom
319
AC (124.5548/11.5088)=10.8225m2
Top
AC (91.7215/9.55)
=9.5120m2
DC
4 AC .. (12)
Where:
AC = column area
Top
=(4 x9,51220/3.124)^0.5
=3.4801m =3.5m
Bottom
=(4 x 10.8225/3.142)^0.5
3.7120m
=3.7m
For the design
320
Dc =3.6m
Liquid flow pattern
Maximum volumetric liquid rate,
L =
LB
..(13)
Where:
LB = liquid rate at the bottom of the column, kg/s
L = liquid density
L =(20457.4482/11.033)
=1854.2054 m3 /hr
=0.5151m3s-1
321
-30
1atm
0.999atm
1.001atm
Reflux Ratio(R)
4394
3662
R/Rmin
1.2
Feed Stage
65
110
129
Tray Efficiency
85%
Height of column(m)
78.2m
29833
Ethylene purity
99.9999%
Column diameter, m
3.6
322
at 12 per cent
Using
Ad
l
100 12 , equivalent w 0.76 is read from Fig.11.31 (R.K. Sinnot, 1986).
AC
DC
323
dh
=0.05m
V = vapour density
dh
= hole diameter.mm
=(31.4-0.90(25.4 -0.05)/(5.59) 0.5)
=8.63m/s
=18ms-1
This means minimum operating rate will be well above weep point.
325
=38m/s
The pressure drop through the dry plate can be estimated using expressions derived for flow
through orifices given as:
2
u
hd 51 h V . (17)
CO L
Where the orifice coefficient CO is a function of the plate thickness, hole diameter, and the
hole to perforated area ratio.
From discharge coefficient (CO) plot, fig 11.34 (R.K Sinnot, 1986), Liebson et al, (1957),
for plate thickness/hole diameter =1 and Ah/Ap Ah /Aa = 0.1, CO = 0.84. Hence hd can be
estimated as:
2
37.8 0.74
= 51
69.5mm liquid
0.84 1100
Residual Head
hr
hr
12.5 103
L
12.5 103
11.4mm liquid...........................................................................(18)
1100
326
Downcomer design
Downcomer pressure loss
Assume the height of apron, hap = hw 10 = 40mm
Then area under apron, Aap = lw x hap = 1.22 x 0.04 = 0.049m2
As this is less than Ad =0.5084m2 the head loss in the downcomer, hdc can be estimated
using the equation given by Cicalese et at, (1947)
L
hdc 166 wd .................................................................................................(20)
L Am
where:
L wd liquid flow rate in downcomer, kg/s
A m either the downcomer area Ad or the clearance area under the downcomer A ap :
whichever is the smaller, m 2
3.91
hdc 166
12.0mm
1100 0.049
hb 50 15 145.9 12
222.9mm
= 0.22m
Residence time
Downcomer residence time is given by:
tr
Ad hbc L
.....................................................................................................(22)
Lwd
where:
tr residence time
h bc clear liquid back-up
tr
Determination of entrainment
The percentage flooding is given by:
Percentage flooding =
un
5.59
3.63m / s
1.54
328
3.63
87, FLV 0.05
4.24
From Fig. 11.28 (R.K. Sinnot, 1986), fractional entrainment 0.08 which is less than the
upper limit of 0.1, hence satisfactory.
Estimation of perforated area
lw
0.76
DC
Where
990
81
2.81m
180
Ah 0.148
0.121
Ap 1.222
lp
dh
Where:
329
3.6m
Length of weir, lw
2.772m
Weir height
0.5m
Hole diameter, d h
50mm
Downcomer area, Ad
0.5084m2
Plate thickness
5mm
9.6588m2
Active area, Ac
10.1672m2
Hole area, Ah
0.00196m2
Hole pitch, lp
13.5mm
Plate spacing
0.6m
Active holes
48989
Turn-down
146mm
liquid=32.92Pa
Plate material
Mild steel
330
10
101.3 10.13kPa
100
For carbon and low alloy steel, a minimum allowance of 2.0mm should be used. (R.K.
Sinnot). Where more corrosion is expected a minimum of 4mm is allowed.
Design load
The column must be designed to overcome gross plastic deformation and collapse under all
conditions of loading. Two main categories of loads are identified. The major loads
include:
Design pressure: including any significant static head of liquid.
Maximum weight of the vessel and content under operating conditions.
Maximum weight of the vessel and contents under hydraulic test conditions.
Wind loads
Weight Loads
According to Sinnot, 1993, the approximate weight of the column, Wv is given by:
W v 240Cv Dm H c 0.8( Dm ) t
Where:
Cv = a factor to account for the weight of nozzle, manways and plate support ring or
equivalent fittings and it is equal to 1.15 for distillation columns. (R.K sinnot, 1993)
Hc = Column height = 78.2m
g = acceleration due to gravity = 9.81N/m2
t = wall thickness, mm = 5mm
Dm = mean diameter of column = t + diameter of column = 0.005 + 3.6 = 3.605m
WV =240 X 1.15 X 3.605[78.2 +(0.8 X 3.605)] X 5 =403.3847kN
Weight of plates
Plate Area = d2/4
=10.1788m2
The total weight of a plate are found by multiplying the plate area by 1.2kN/m
Weight of a plate =1.2kN/m x 10.1788m2
=12.2146N
Therefore for 129 plates;
Total weight of plates =129 X 12.2146 =157.56782kN
Weight of insulation
333
Mineral wool is used for the insulation because it is relatively cheap and also widely used
for insulating distillation columns. (Nelson, 1963).
Density of mineral wool = 130kg/m3 (Nelson, 1993)
Thickness of insulation = 75mm (Nelson, 1993)
Approximate volume of insulation =3.142 X 3.6 X 78.2 X 0.075
=66.34m3
Weight of insulation =66.3400 x 130 x 9.81 =84.60364kN
The weight of insulation is doubled to allow for attachment of fittings and moisture
absorption. (Nelson, 1963)
Therefore weight of insulation together with fittings is taken as 2 X 84.6036 =169.2073kN
Sum of Weights = weight of shell + weight of plates + insulation weight
= 403.3847 +157.5682 + 169.2073
= 730.1602kN
Wind loading
Column loading is a very important factor which must be considered since the column
would be sited in an open. Usually, columns are free standing and mounted on skirt
support. The column under these conditions under wind loading acts as a cantilever beam.
Wind pressure for smooth cylindrical columns is estimated from the relation;
Pw = 0.05Uw 2
334
The load per unit length of the column, Fw, is obtained from the wind pressure multiply by
the effective diameter, Deff, (i.e. the outside diameter + an allowance for the thermal
insulation).
Fw = Pw Deff
Deff = 3.6 + 2(0.075 + 0.005) = 3.76m
FW = PW Deff
1280 x 3.76 = 4812.8N/m
Since the column would be free standing and mounted on skirt supports it would act as a
cantilever under wind loading.
Now for a uniform loaded cantilever, the bending moment at any plane is given by:
Mx =
Wx 2
2
x = column height
335
Wx =Fx
Mx =(4812.8 )2 /2 =11581521.92Nm
Wall thickness
To ensure that column is sufficiently rigid to withstand its own weight, a minimum wall
thickness is allowed. For column with diameter between 0.5-2m a minimum thickness of
10mm is required. (R.K. Sinnot, 1993) Since the column diameter is 3.6m, wall thickness
of 10mm is used.
Design stress
It is necessary to decide a value for the maximum allowable stress that can be acceptable in
the material of construction.
It is determined by applying a suitable design stress factor (factor of safety) to the
maximum stress that the material is could be expected to withstand failure under standard
test conditions. The design stress factor allows for any uncertainty in the in the design
methods, the loading, the quality of the materials and the workmanship.
For materials not subject to high temperatures, the design stress is based on the yield stress
(proof stress) or the tensile strength of the material at design temperature.
Primary stress
PDi
2t
is calculated as;
(sinnot,1993)
As a result of bending moments on the column, the column would definitely be subjected to
bending stress. The bending stress will be compressive or tensile, depending on the location
and it is given by:
337
IV = Seccond moment of area of te vessel obout the plan of bending and is given as
338
= -214.939N/mm2
According to Sinnot, 1993; the greatest difference between the principal stresses will be on
the down-wind side and this should be below the maximum allowable of 11581N/mm2.
The greatest difference between principal stresses =239.5542-(-214.939)= 454.4932N/mm2.
This far below the maximum and it is therefore allowable.
Elastic Stability
The critical buckling stress c is given by:
The maximum compressive stress = 5.95 + 19.17 = 25N/mm2. This is far below the critical
and therefore acceptable.
15.8Column Supports
Horizontal vessels are usually mounted on two saddle supports whilst tall vertical vessels
like distillation columns are mounted on skirt supports. The supports must be designed to
carry the weight of the vessel and contents, and any superimposed loads such as wind
loads. Supports should also be designed to allow easy access to the vessel and fittings for
inspection and maintenance. The height of the skirt is usually between 2-3m. For this
design a height of 2m is used.
339
Skirt thickness
The resultant stresses, in the skirt will be:
s bs ws
Where: bs = the bending stress in the skirt given by
bs
4M s
.............................................................................(Sinnot, 1993)
( Ds ts )ts Ds
ws
W
..........................................................................(Sinnot, 1993)
Ds ts ts
Ms = maximum bending moments evaluated at the base of the base of the skirt
W = total weight of the vessel and its contents
Ds = inside diameter of the skirt at the base
Ts = skirt thickness
The skirt thickness should be such that under worst combination of wind and dead weight
loading the following design criteria should not be exceeded;
ts
sin s .....................................................................(Sinnot, 1993)
Ds
ws 0.125E
340
The maximum dead weight load on the skirt that would occur when the column is full of
water. (Sinnot, 1993)
Approximate weight =7808.5544kN
Weight of column = 730.160kN
Total weight =8538.7146kN
Wind loading = 48.128kN
341
=934.4826.N/mm2
Maximum stress (tensile), s = 44.2023 +3.7798 =47.9821N/mm2
This is far higher than the calculated design stress. The criterion is therefore satisfied.
2mm is added to the skirt thickness to cater for corrosion. Design skirt thickness is
therefore taken as 19mm.
Where
Ab=Area of the Bolt at the root of the thread,mm2
Nb =number of Bolts
Fb=maximum allowable bolt stress also equal to the design stress of 11581.521N/m
Db =bolt circle diameter,m
Ms =bending moment at the base,Nm
342
The total compressive load, Fb on the base ring per unit length is given by:
Where Lr is the distance from the skirt to outer edge of the ring.
Actual width = 76 + 13+50 = 139mm
Actual pressure on the concrete foundation,
The minimum thickness of base ring is found by the ring as a cantilever beam and it is
given by:
tb Lr
3 f c'
.......................................................................................( Scheiman, 1963)
fr
344
403.4000kN
Resultant
longitudinal 240N/mm2
stress (upwind), z
Resultant
longitudinal -13 N/mm2
stress (downwind), z
Weight of plates
8kN
Circumferential stress
Skirt height
2m
Number of bolts
20
Weight of column
703kN
Bending moment, Mx
154780.6kNm
Wind pressure,N/m2
1280
Total weight
731kN
Maximum
stress(compressive), s
934.4826N/mm2 Maximum
s
Bolt area
724mm2
23N/mm2
stress(tensile), 48N/mm2
30.4mm
Actual pressure,
0.8N/mm2
731kN
Minimum thickness
base ring, tb
22mm
of 9mm
345
CHAPTER 16
transport: road, rail, waterway (canal or river), or a sea port. The towns proximity to the
port serves as a good means of easily transporting the raw materials and products by sea.
The western region also has good road networks for transport of materials, products and
equipments to and from the site. Rail transport is also available in the region.
16.2.4 Availability of Suitable land
Sufficient suitable land must be available for the proposed plant and for future expansion.
The land should ideally be leveled, well drained and have suitable load-bearing
characteristics. The western region has a vast array of land and its gentleness in level or
topography becomes an added advantage. There is also good drainage system.
16.2.5 Availability of labour
Labour will be needed for construction of the plant and its operation. There must be an
adequate pool of labour available locally, and labour suitable for training to operate the
plant. Unemployment among the youth in most developing areas in Ghana is high, thus
labour especially unskilled labour will not be a problem in our chosen plant site. Skilled
labour can also be brought in for special purposes.
16.2.6 Availability of utilities
Ethylene plants require large quantities of water for quenching, washing, and for the
production of steam as well as other non-production related purposes such as drinking and
sanitary purposes among others. Power and steam requirements are high, as in most
industrial plants, and fuel is ordinarily required to supply these utilities. In view of this,
power and fuel can be combined as one major factor in the choice of a plant site. Takoradi
has a reliable water supply from the Ghana Water Company and electricity supply from the
348
Electricity Company of Ghana since there exist a power line network connecting Takoradi
to the national hydroelectric source of energy (Akosombo). Thus uninterrupted electricity is
assured.
16.2.7 Environmental Impact and Waste Disposal
Many legal restrictions have been placed on the methods for disposing of waste materials
from the process industries. The disposal of toxic and harmful effluents will be covered by
local regulations, and the appropriate authorities must be consulted during the initial site
survey to determine the standards that must be met. All industrial processes produce waste
products and full consideration must be given to the difficulties and cost of their disposal.
The site selected for a plant should have adequate capacity and facilities for correct waste
disposal. The location of our plant meets all the specifications and conditions afore
mentioned.
Even though the area has minimal restrictions on pollution, it should not be assumed that
this condition will continue to exist. In choosing our plant site, the permissible tolerance
levels for various methods of waste disposal have been considered carefully, and attention
will be given to potential requirements for additional waste-treatment facilities.
16.2.8 Local community consideration
The proposed plant must fit in with and be acceptable to the local community. Full
consideration must be given to the safe location of the plant so that it does not impose a
significant additional risk to the community. The local community must be able to provide
adequate facilities for the plant personnel such as schools, banks, housing, and recreational
and cultural facilities. Our chosen plant location is favoured by this factor.
349
350
CHAPTER 17
17.0 SAFETY AND POLLUTION CONTROL
Any organization has a legal and moral obligation to safeguard the health and welfare of its
employees and the general public. Safety is also good business; the good management
practices needed to ensure safe operation will also ensure efficient operation.
All manufacturing processes are to some extent hazardous, but in chemical processes there
are additional, special hazards associated with the chemicals used and the process
conditions. The designer must be aware of these hazards, and ensure, through the
application of sound engineering practice, that the risks are reduced to acceptable levels.
[43]
Plant engineers must ensure the quality of the environment both inside and outside the
facility as well as the safety and health of the employees and the reliability of its systems
and equipment. And they are expected to do all of this in a cost-effective manner.
17.1 PLANT SAFETY
Fire, toxic chemicals, mechanical equipments and electrical faults are the major health and
safety hazards usually encountered in the process industries. To avert these, the following
measures will be taken;
1. All electrical wires are to be insulated with PVC while the use of fuses and earth
leakage breakers would be employed to break off power automatically in times of
overload.
2. Periodic and regular maintenance or checks will be made on mechanical equipment
and electrical installation.
351
352
Spent caustic is derived from scrubbing ethylene gas and typically contains a range of
various components namely NaOH, Na2CO3 and some soluble oil. In addition to soluble
components, insoluble polymers resulting from the condensation of olefins during
scrubbing are present in the liquor. Spent caustic is intensely malodorous, toxic, and highly
alkaline. It contains high chemical oxygen demand (COD), some total organic carbon
(TOC), and high total dissolved solids (TDS). These insoluble polymers have a lower
specific gravity than the spent caustic and can be removed from the spent caustic stream by
gravity separation and decanting from a quiescent tank or separator. (Wet Air Oxidation of
Ethylene Plant Spent Caustic, Ellis et al). A spent caustic oxidation unit, which is a wet air
oxidation (WAO) system, will therefore be built to treat the wastewater by oxidizing a
majority of the COD. This allows the oxidized spent caustic to be further treated by
conventional biological treatment prior to discharge.
17.3.2 Gas emissions
Gaseous and particulate emissions to air that are produced primarily come from the flue
gases from the furnace during the steam cracking of the hydrocarbon feedstock. Typical
gases include carbon dioxide (CO2) and oxygen (O2). The temperature of the furnace is
regulated so that NOx emission is reduced to the barest minimum. Methane (CH4) is burnt
completely to avoid CH4 emission.
17.4 NOISE POLLUTION
Excessive noise is a hazard to health and safety. Long exposure to high noise levels can
cause permanent damage to hearing. At lower levels, noise is a distraction and causes
fatigue. Permanent damage to hearing can be caused at sound levels above about 90 dB
(A), and it is normal practice to provide ear protection in areas where the level is above 80
354
dB(A).(sinnott).Noise from the plant will result from the operations and movement of
equipment such as the quench tower, absorbers, strippers, and the furnace.
17.4.1 NOISE POLLUTION CONTROL
The plant will be sited well away from residential areas to prevent the unavoidable noise
levels generated by some of the process units. Ear plugs will be worn by all employees
operating any of the heavy equipments to prevent the harmful effect of noise on the human
ear. Sound absorbing materials will be used in constructing all plant buildings for
equipments that cause a lot of noise, thus minimizing significantly the noise levels in the
plant.
355
CHAPTER 18
18.0 INSTRUMENTATION AND PROCESS CONTROL
In the chemical processing industry, controllers play a crucial role in keeping the plants
running by controlling process variables.
A typical control system consist of
Sensor
Transmitter
controller
The primary objective of any control system in the operation of the plant is to monitor and
stabilize process parameters. The objectives in installing control devices and other
instrument in the plant are;
1. It keeps the process variables within safe operating mode.
2. To ensure that effluents are within acceptable limits as prescribed by environmental
regulations.
3. To attain the production rate and product quality in terms of product specification.
4. To minimize operational cost as much as possible
5. Dangerous situations are detected as they develop and alarms and automatic
shut-down systems are provided.
18.1 INSTRUMENTATION
A central control computerized panel will be located in the plant and it will be responsible
for indication, recording, and regulation of process variable and indication of a signal when
a process variable exceeds its set point.
356
The following process variables will be measured and monitored by the control systems.
1. Temperature
2. Pressure
3. Flow
4. Level
5. Concentration
These variables play vital roles in their respective places and recording continuously will
enable personnel to control them within limit.
18.2 Process Variable Control System
18.2.1 Flow meters
Flow rate is checked by the help of a valve and flow meters. Overflowing is undesirable in
any chemical plant hence the control valve and flow meters are to ensure that the set flow
of material moves from one equipment to another. The flow meters in this case acts as the
measuring device which measures the errors in the flow. Error signal is sent through the
transmitter to a controller. An actuating signal from the controller then causes a variance in
the orifice of the valve. The flow meters will therefore be used to indicate the volume of
liquid pumped from the different units. It will also be used to control their flow rates as is
required in the process. The flow control system will thus operate by closing and operating
valves to check overflowing and emptying of holding vessels.
18.2.2 Temperature control system.
Temperature control is quite essential in process design for some equipment such as the
furnace, heat exchanger, stripper and distillation column temperatures. The reason is that
357
any deviation from the required temperatures will result in the production of undesirable
by-products or products that do not meet specifications.
18.2.3 Pressure Control system
Excessive pressure can lead to explosion and destruction of equipment and it is usually
necessary for equipments handling vapour or gas. The pressure control system will
maintain operating pressures within required limits so that any excessive pressure that
builds up will be relayed to pressure releasing valves to open in order to let out excessive
pressure. This will specifically be employed to check the pressure of the compressor,
different absorbers, stripper, and the various distillation columns in order to obtain good
products.
18.2.4 Level control system
This will be used to monitor the settling tank, flash drum, stripper, vacuum distillation
column and storage tanks to prevent entrainment in the case of columns.
358
CHAPTER 19
19.0 ECONOMIC ANALYSIS
Ideal for every investment, the chemical engineering process must be economically viable.
To access the profitability of a project, an estimate of the required investment and cost of
production must be made. An acceptable plant design must present a process that is capable
of operating under conditions which will yield a profit.
Basis of economic analysis:
Start of construction: January, 2012
Completion of construction: December, 2014
Commencement of processing: January, 2015
Plant operation: 3 shifts per day
Process: continuous
Plant life: 19 years
Plant production rate: 100,000 tons per annum
Working period: 300 days
Production capacity: 333 tonnes per day
Selling price of ethylene: $0.53/Kg
Exchange rate of dollar: GH1.5
19.1 Project cost estimation
Once the process plant has designed and approved for construction then the chemical
engineer has to estimate the amount of capital required for the construction, operation of
the plant and sale of products.
359
360
.. (Eqn 19.1)
The latest Marshall and Swift cost index available is for the year 2010.
Table 19.1 Cost Index
Year
2006
2007
2008
2009
2010
1373.3
1449.3
1468.6
1457.4
Unit
Cost Gross
Equipment
Quantity Cost($)2007
($)2010
($)2010
Cracking furnace
4,400,000.000
4,669,453.142
4,669,453.142
exchanger
120,000.000
127,348.722
127,348.722
Storage tank
90,000.000
95,511.542
382,046.166
Quench tower
130,000.000
137,961.116
137,961.116
Caustic tower
160,000.000
169,798.296
169,798.296
Reboiler
90,000.000
95,511.542
382,046.166
Condenser
84,000.000
89,144.105
356,576.422
Compressor
120,000.000
127,348.722
509,394.888
cooler
100,000.000
106,123.935
212,247.870
Dryer
105,000.000
111,430.132
111,430.132
Trasfer
line
361
cost
Demethanizer
110,000.000
116,736.329
116,736.329
Ethylene column
150,000.000
159,185.903
159,185.903
Deethanizer
110,000.000
116,736.329
116,736.329
C2- splitter
95,000.000
100,817.738
100,817.738
centrifugal pump
10,000.000
10,612.394
31,837.181
Asorber
90,000.000
95,511.542
95,511.542
Truck
70,000.000
74,286.755
74,286.755
Pick up
30,000.000
31,837.181
31,837.181
Bus
60,000.000
63,674.361
191,023.083
stripper
95,000.000
100,817.738
100,817.738
PCE
6,584,990.170
987,748.525
7,572,738.695
items such as shop, first aid and cafeteria equipment among others. This component is
estimated to be 30% of the purchased equipment cost.
19.2.8 Cost of land
The plant will be sited in the western region. As a rough average, land cost for industrial
plants amounts to 6% of purchased equipment cost.
19.3 ESTIMATION OF INDIRECT FIXED CAPITAL INVESTMENT
19.3.1 Engineering and supervision cost
This cost consist of the cost for construction design and engineering, drafting, purchasing
accounting, construction and cost engineering, travel, reproductions, communications and
home office expenses including overhead. This component is estimated as 25% of the total
direct costs of the process plant.
19.3.2Construction expenses
This cost component involves the cost for construction or field expenses. It involves
temporal construction and operation, construction tools and rentals, construction payroll,
taxes, insurance and other overheads. This component is estimated as 10% of the total
direct cost.
19.3.3 Contractors fee
The contractors fee can be taken as 5% of the total direct cost.
19.3.4 Contingency fees
364
A contingency fee is included in the total capital investment in recognition of the fact that,
experience show that, there will be unexpected events and changes that will inevitably
increase the cost of the project. These events may include strikes, price changes, small
design changes, storms, floods etc. this component is estimated as 10% of the total direct
cost.
Table 19.3 Total capital investment
1
7,572,738.695
0.400
0.200
Piping
0.700
0.100
Utilities
0.500
Storages
0.150
0.150
Site Development
0.050
3.250 24,611,400.759
0.300
11
Contractors Fee
0.050
12
Contingency
0.100
1.450 35,686,531.101
60,297,931.860
18,089,379.558
365
78,387,311.418
Number
Annual
Salary
head, $
Plant manager
35,000
35,000
Production manager
20,000
20,000
366
Chemical Engineer
15,000
45,000
Mechanical Engineer
15,000
30,000
Supervisors
13,500
67,500
Electrical Engineer
15,000
30,000
Occupational
health
and 2
20,000
10,000
safety specialists
Quality Controller
10,000
30,000
Chemist
13,000
39,000
9,000
216,000
532,500
equipment 24
Chemical
operators
Number
Annual
($)
($)
Managing Director
30,000
30,000
Personnel Manager
20,000
20,000
Human Resources
18,500
37,000
Sales Manager
18,000
18,000
Accountant
18,000
18,000
Accounts Clerk
10,000
10,000
Store Keeper
9,000
9,000
Secretary
4,000
12,000
Receptionist
3,200
3,200
367
Drivers
3,000
15,000
Cleaners
1,600
4,800
Security men
1,600
4,800
181,800
Total (ILC)
714,300
753,587
368
Annual Quantity kg
Unit Cost,$
Ethane
11,470,625.000
0.864
9,910,620.000
Methane
566,347.860
4.000
2,265,391.440
Acetone
13,646,835.400
1.000
13,646,835.400
NaOH
645,681.220
0.870
561,742.662
Material
26,384,589.502
Total
369
AD
C f S1
S
19.6.2 Insurance
The insurance cost paid on the plant and general site is estimated as 1% of the fixed capital
investment (peters et al).
19.6.3 Local taxes and royalties
Local taxes are estimated as 1% of the fixed capital investment (Peter et al, 1990).
Description
Manufacturing Costs
Direct Production Costs
Variable costs
1
Raw Materials
26,384,589.52
Miscellaneous
361,787.591
materials
3
Power
757,273.870
Utilities
Fixed costs
4
Operating
753,586.500
150,717.300
Labour
5
Operating
Supervision
3,617,875.912
Repairs
7
Laboratory
150,717.300
Charges
8
Royalties
602,979.319
Local Taxes
1,205,958.637
10 Insurance
602,979.319
11 Capital Charges
6,029,793.186
12 Total
Overhead Costs
0
General Expenses
15% of the Total Manufacturing Costs
6,431,902.244
4,287,934.829
12 Administrative
expenses
Marketing
14 Research
2,143,967.415
Development
Total General Expenses (G)
12,863,804.47
55,743,152.77
0.463
42,879,348.290
62,420,221.360 27,503,650.96
19.8.2 Turn over ratio
This is a rapid method suitable for order of magnitude estimates. In other words, it could be
the ratio of gross annual sales to the fixed capital investment.
That is,
374
62,420,221.360
0.796
78,387,311.418
19.8.3 Annual Cash Flow
The average selling price for ethylene is $0.53 per kilogram (VAT exclusive). The aim of
our project is to produce high quality product at a lower cost. The tax rate now is at 15%.
19.8.4 Rate of Return (ROR)
Rate of return which is a ratio of annual profit to investment is a simple index of the
performance of the money invested. It does not consider the time value of money and it
does not account for the fact that profit and cost may vary significantly over the life of the
project. [43]
CNCF
100%
LP OI
Where
CNCF is the cumulative net cash flow at the end of project
LP is the life of the project
OI is the original investment
383,808,042.486
100% 30.60%
16 78,387,311.418
19.8.5 Discounted Cash Flow
The net cash flow in each year of the project is brought to its present worth at the start of
the project by discounting it at some chosen compound interest rate.
375
( NFW )n
(1 r ) n
Where
(NFW) n is the net future worth in year n
r is the discount rate (interest rate) per cent /100 and
n t
NFW
(1 r )
n 1
The discount rate is chosen to reflect the earning power of money. It would be roughly
equivalent to the current interest rate that the money could earn if invested. (Coulson and
Richardson, Volume 6). From the figure 19.2 the discounted rate is 22.12%
19.8.6 Pay-back Time
Payout period is the minimum length of time theoretically necessary to recover the original
capital investment in the form of cash flows to the project based on total income minus all
cost except depreciation. The Figures 19.1a,b below depict that, break even will occur at
the end of the 5.3 rd year.
376
$50.00
$40.00
$30.00
$20.00
$10.00
$0.00
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Time, yrs
-$10.00
377
Interest rate
0.300
0.250
0.200
0.150
0.100
0.050
0.000
0.000
0.200
0.400
0.600
0.800
Ratio: PV/TCI
378
1.000
1.200
1.400
1.600
CHAPTER 20
20.0 CONCLUSION AND RECOMMENDATIONS
20.1 DISCUSSION
The prevailing price of the raw materials needed to operate the plant allows for a oneyear break-even point and is an exciting investment prospect. From the economic
analysis, the rate of return is a profitable 30.6% on the invested value. The issue of
fluctuating market prices of some of the process inputs can however alter the
profitability of this project. Challenges as to the constant profitability can be accurately
overcome by continued vigorous research and extensive market surveillance.
Environmental analysis shows that sodium carbonate sludge is one of the predominant
and problematic wastes produced. This is sent to a wet-air oxidation unit or regeneration
unit for regenerating NaOH from the sludge. Noise, thermal and gaseous pollution are
present but minimal.
The major feedstock being used in this project is ethane. This was chosen after
considering its availability, and high yield and selectivity of ethylene. Its processing is
relatively simple, involving lower capital costs. Also ethane is again produced in large
quantities as a by-product from the process and can be reused as a feedstock. This is of
key importance to the project. This is because failure to get your constant supply
(needed quantity) would cripple the project.
Again, cape three points in the western region was considered to be the area where the
project would take place. After considering factors such as availability of needed raw
materials, cost of labour, roadwork, and tax rate among others, it was prudent to
establish the industry at the said place.
379
20.2 CONCLUSION
From the economic analysis, our ethylene plant is economically viable. The ethylene
plant will have an enormous impact on the Ghanaian economy. Among such positive
impacts are the creation of capital for investors, reduction in unemployment, and
provision of foreign exchange for Ghana.It also does not pose very serious threats to the
environment. The steam pyrolysis process using ethane as feedstock to obtain our
product is also very economical since it does not involve the use of catalysts and other
expensive raw materials. Due to the location of the plant, our raw materials can be
easily acquired or imported. The products of the plant also have an already established
market in the country and in the world at large.
The conclusion drawn is that, the establishment of an emerging ethylene-producing
plant that uses steam pyrolysis process is feasible under the current technological and
economic development of Ghana, and would come with a lot of advantages.
20.3 RECOMMENDATION
From the economics, the plant is feasible, and we recommend that this plant design
should be given a favorable consideration. We also recommend that, the issue of safety
and control should be enforced at all levels and times to ensure the safe and smooth
running of the plant, to protect lives and the environment as a whole. It is again
recommended that the possibility of mixing ethane and propane as feedstock is
considered since propane will be produced as a by-product and can be reused.
380
REFERENCES
1) Albright, L.F., Crynes B.L., and Corcoran W.H. (1983) Pyrolysis: Theory and
Industrial Practice. Academic Press, Inc., New York
2) Ali Abdulhamid A. (2007) Economic analysis of a new gas to ethylene
technology. MSc. Thesis, Texas A&M University Anonymous, (2007) Process
analytics in ethylene production plants, oil and gas industry. Siemens AG
3) Bird, Steward and Lightfoot, (1960) Transport Phenomena, John Wiley and
sons
4) Bennett, C.O. and Myers, J.E. 2nd ed., (1974) Momentum, Heat, and Mass
Transfer, McGraw-Hill, New York.
5) Benitez, J. (2009) Principles and Modern Applications of Mass Transfer
Operations, 2nd ed, John Wiley & Sons, Inc., Hoboken, New Jersey. Pg 22
6) Chemical Market Association, Inc. Chemical prices Available on the web at
<http://www.cmaiglobal.com>. [Accessed October 28, 2010].
7) Davis H.G., Keister R.G. The Advanced Cracking Reactor (ACR): A Process for
Cracking Hydrocarbon Liquids at Short residence Times, High Temperatures,
and Law Partial Pressure, Presented at ACS Meeting, Philadelphia, 1975; April
6-11.
8) Distillation and Absorption Towers via Correlations, Chemical Engineering, 28
December, pp. 77-82 (1981).
9) Gondolfe, J and Mueller C, The Definitive Solution: Gasoline Fractionator
Retrofit Techniques , Presented at the 14th Ethylene Producers Conference,
AIChE 2002 Spring National Meeting, New Orleans, Louisiana, March 10 - 14,
2002
10) Hall K.R. A new gas to liquids (GTL) or gas to ethylene (GTE) technology,
Catalysis Today. 106:243-246(2005).
381
[Accessed
September
18,2010]
382
38) Reid, R. C., J. M. Prausnitz, and B. E. Poling, The Properties of Gases and
Ludwig, E. E., Applied Process Design for Chemical and Petrochemical Plants,
vol. 2, 2nd ed(1992).
39) Shah R.K. and Dusan S, (2003) Fundamentals of Heat Exchanger Design John
Wiley & Sons
40) Sherwood, P. W. Production of ethylene from petroleum sources, Part I. Petrol.
Refiner. 30: September: 220-5. (1951).
41) Shigeyoshi
Takaoka.
Ethylene
Stanford Research
Institute.
Process
Accessed
385
APPENDIX A
CALCULATIONS FOR MATERIAL BALANCES
Molecular weights
Component
Molecular weight
Ethylene
28
Acetylene
26
Water (steam)
18
Methane
16
Hydrogen
Ethane
30
Propane
44
From our stated capacity, ethylene to be recovered at the end of the process is 100 000
tonnes/year.
1x10 8 kg
1yr
1day
x
x
Ethylene to be produced = 100,000TPA = 1 x 10 kg/yr =
1yr
300day 24hr
8
=13888.89kg/hr
Basis: 1hr of operation
Total weight of ethylene produced = 13888.89kg
Assuming 2% of the ethylene is lost during the production and coke was also assume to
be negligible but CO2 formed is assume to be 0.05% of the ethane that reacted
386
2
x 13888.89 = 277.778kg
100
Acetylene produced =
505.952
= 632.4405 kmol/hr
0.8
0 .5
ethane reacted
100
0 .5
632.4405 = 3.1622 kmol/hr
100
Ethane supplied =
632.4405
= 972.985 kmol/hr
0.65
C2H4 + H2
............................... (a)
2C2H6
C3H8 + CH4
................................ (b)
C3H8
C + 2H2O
CO2 + 2H2
............................ (d)
C2H4 out
1 .......................................................... (2)
H2 out
1 + 3 + 4.............................................. (3)
C3H8 out
2 - 3...................................................... (4)
CH4 out
2 + 3...................................................... (5)
C2H2 out
3........................................................... (6)
CO2 out
4........................................................... (7)
388
Hence:
C2H6 out = 340.545 kgmole/hr
C2H4 out = 505.952 kgmole/hr
H2 out = 509.1142 kgmole/hr
C3H8 out = 60.0818 kgmole/hr
CH4 out = 66.4062 kgmole/hr
C2H2 out = 3.1622 kgmole/hr
CO2 out =0.3162 kgmole/hr
Steam to Ethane (supplied) ratio = 0.3: 1
Steam used = 0.3 x Ethane supplied = 0.3 x 972.985 = 291.8955 kgmole/hr
Total output from furnace = 340.545 + 505.952 + 509.1142 + 60.0818 + 66.4062 +
3.1622 + 291.8955+0.3162 = 1777.4731 kgmole/hr
The mole percentages of the individual components leaving the furnace are as follows:
C2H6 =
340.545
x 100% = 19.16%
1777.4731
C2H4 =
505.952
x 100% = 28.46%
1777.4731
H2 =
509.1142
x 100% = 28.64%
1777.4731
C3H8 =
60.0818
x 100% = 3.38%
1777.4731
389
CH4 =
66.4062
x 100% = 3.74%
1777.4731
C2H2 =
3.1622
x 100% = 0.18%
1777.4731
H2O =
291.8955
x 100% = 16.42%
1777.4731
CO2 =
0.3162
100
1777.4731
=0.02 %
390
APPENDIX B
CALCULATIONS FOR ENERGY BALANCE
Reactions in the furnace:
.Reaction 1
C2H6
C2H4 + H2
2C2H6
C3H8
C + 2H2O
391
Substance
Nin 103
Nout
Hin KJ/mol
103
Hin KJ/mol
mol/hr
CO2
3.555
H3
C2H2
3.199
H4
C2H4
505.869
H5
C3H8
60.79
H6
CH4
66.477
H7
392
H2O
291.896
H1
291.265
H8
C2H6
972.985
H2
340.564
H9
H2
509.068
H10
,
mol
CAUSTIC TOWER
Reference: CO2, C2H2, C2H4, C3H8, CH4, H2O, C2H6, H2 at 35oC for gas and 25oC for
NaOH solution 1 atm
393
Substance
Nin 10
Nout
Hin KJ/mol
103
Hin KJ/mol
mol/hr
CO2
3.1622
3.1662
H8
C2H2
3.1622
3.1660
H5
C2H4
505.952
505.952
H6
C3H8
60.0818
60.0818
H3
CH4
66.4064
66.4064
H1
H2O
0.29189
0.29189
H7
C2H6
340.545
340.545
H2
H2
509.1142
509.1142
H4
NaOH
3981.535
H9
3987.1098
H10
394
H= 212827.5891
QUENCH TOWER
A balance around water
Reference: H2O, at 25oC 1 atm
Substance
Nout
Nin 103
Hin KJ/mol
103
Hin KJ/mol
mol/hr
H2O
1492.490
H1
7874.283
H=323794.543
DEMETHANIZER
Reference: C2H2, C2H4, C3H8, CH4,C2H6, H2 at 25oC 1 atm
Substance
Nin 103
Hin KJ/mol
C2H2
2.9762
H1
C2H4
505.9520
H2
395
H2
C3H8
59.5238
H3
CH4
68.4523
H4
C2H6
330.3569
H5
H2
520.833
H6
Flows
Distillate (D)
Bottoms (B)
Hout KJ/mol
Hout KJ/mol
2.9762
H11
505.9520
H9
59.5238
H10
68.4523
H8
H14
330.3569
H13
520.833
H7
,
mol
,
mol
396
H= -11244.9174
C2 SPLITTER
Reference: C2H2, C2H4, CH4, C2H6, at 35oC, 25oC 1 atm
Substance
Nin 103
Hin KJ/mol
C2H2
2.9516
H1
C2H4
498.3786
H2
CH4
0.6658
H3
C2H6
330.3148
H4
397
Flows
Distillate (D)
Bottoms (B)
Hout KJ/mol
Hout KJ/mol
497.1149
H5
2.9516
H6
0.6558
H7
330.3145
H8
398
H=1609.18309
ACETYLENE ABSORBER
A balance around the gas Reference: C2H2, C2H4, 25oC,1 atm
Substance
Nin 10
Nout
Hin KJ/mol
103
Hin KJ/mol
mol/hr
C2H2
3.0725
H1
3.1660
H3
C2H4
481.9578
H2
505.952
H4
399
H=
400
APPENDIX C
CALCULATIONS ON TANK DIMENSIONS
Tank volume 1
The volume of the tank is determined by the volume of fluid stored
Where,
= volume of acetylene required for a days operations
= the mass of acetylene for a day = 1896 kg/day (material balance calculations)
= density of acetylene = 1.091 kg/m3 at 21oC and 1 atm (Perry, 1999)
The total storage volume for at most 7 days of supply cut off
Ullage =
m3 = 3,374,331.513 gal (US)
401
TABLE 18.2. Storage Tanks, Underwriter or API Standard, Selected Sizes (wallas, pg
622)
Internal diameter of acetylene storage tank =
Length of acetylene storage tank = 42.05 in =106.807cm =1.068 m
Thickness of tank = 25mm
Tank volume 2
The volume of the tank is determined by the volume of fluid stored
Where,
= volume of ethylene required for a days operations
= the mass of ethylene for a day = 333,333.36 kg/day (material balance calculations)
= density of ethylene = 1.115 kg/m3 at 20oC and 1 atm (Perry, 1999)
The total storage volume for at most 7 days of supply cut off
Ullage =
= 4,063,274.222 gal (US)
TABLE 18.2. Storage Tanks, Underwriter or API Standard, Selected Sizes (wallas, pg
622)
Internal diameter of ethylene storage tank =
Length of ethylene storage tank = 43.43in =110.3122cm = 1.103m
Thickness of tank = 25mm
Tank volume 3
The volume of the tank is determined by the volume of fluid stored
Where,
= volume of propane required for a days operations
= the mass of propane for a day = 63254.28 kg/day (material balance calculations)
= density of propane = 1.83 kg/m3 at 94oC and 1.0130bar (Perry, 1999)
The total storage volume for at most 7 days of supply cut off
403
There should always be a small ullage (the air space between the water surface and the
top of the tank) remaining when the contents gauge registers full. Thus equivalent to 5%
of the total contents of the tank (Mobley, 2001).
Volume of the storage tank
Ullage =
= 3,537,431gal (US)
TABLE 18.2. Storage Tanks, Underwriter or API Standard, Selected Sizes (wallas, pg
622)
Internal diameter of propane storage tank =
Length of propane storage tank = 42.376in =107.64cm = 1.076m
Thickness of tank = 28.18mm
Tank volume 4
The volume of the tank is determined by the volume of fluid stored
Operation storage volume
Where,
= volume of ethane required for a days operations
= the mass of ethane for a day = 700,549.20 kg/day (material balance calculations)
= density of ethane = 1.282 kg/m3 at 21oC and 1atm (Perry, 1999)
The total storage volume for at most 7 days of supply cut off
404
Ullage =
= 7,427,160.362gal (US)
TABLE 18.2. Storage Tanks, Underwriter or API Standard, Selected Sizes (wallas, pg
622)
Internal diameter of ethane storage tank =
Length of ethane storage tank = 50.1667 in =127.423cm = 1.274m
Thickness of tank = 25mm
405