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Bestell-Nr.: LXS-FCC17D, Ausgabe: 2005-10
GENERAL PRODUCTINFORMATION
CONTENT
INTRODUCTION
P. 4
P. 5
SYNTHESIS
P. 7
STRUCTURES
P. 7
I M I TAT I N G N AT U R E
P. 9
- B AY P U R E D S 1 0 0
P. 9
- B AY P U R E C X 1 0 0
P. 11
B I O D E G R A D AT I O N I N H A R M O N Y W I T H T H E E N V I R O N M E N T
P. 1 2
TOXICOLOGY
P. 1 4
B AY P U R E D S 1 0 0
P. 1 7
- S U P P LY F O R M S
P. 17
- S TA B I L I T Y
P. 18
- VISCOSITY
P. 19
- S TA B I L I T Y C O N S TA N T S
P. 19
- COMPARISON POLYASPARTATE
OTHER POLYCARBOXYLATES
P. 20
B AY P U R E C X 1 0 0
P. 2 3
- DELIVERY FORMS
P. 23
- DENSITY
P. 25
- VISCOSITY
P. 25
- p H A N D p K a D ATA
P. 27
- S TA B I L I T Y
P. 27
- I M I N O D I S U C C I N AT E M E TA L C O M P L E X E S
P. 28
- C A L C I U M B I N D I N G C A PA C I T Y
P. 29
- S TA B I L I T Y C O N S TA N T S
P. 30
B AY P U R E D S P
P. 3 3
- PRODUCT CHARACTERISTICS
P. 33
A P P L I C AT I O N S O V E R V I E W
P. 3 5
Baypure
E F F I C I E N T B Y N AT U R E
INTRODUCTION
E F F I C I E N T B Y N AT U R E - E C O N O M I C A L LY A N D E C O L O G I C A L LY I M P O RTA N T
dominantly used are removed in water treatment plants, they are only
customers.
Chemistry and nature do not conflict with each other: on the con-
With the new Baypure range, LANXESS is now able to offer its cus-
trary, chemical substances are the building blocks of both our living
try and for water treatment. The world market is currently estimat-
cern.
What can be more natural than to learn from nature? That is the
result of it.
* Baypure is a registered
tradename of
Bayer AG, Leverkusen
SYNTHESIS
All Baypure products are made of maleic acid anhydride, ammonia water and occasionally sodium hydroxide. These raw materials
are easily accessible.
In the process of manufacturing Polyaspartic Acid, Polysuccinimide is generated first. This is converted into salts of Polyaspartic Acid by subsequent hydrolysis. The Baypure CX 100 is directly synthesized of the above mentioned raw materials.
Baypure DSP
Polysuccinimide
, NH3
NaOH, NH3
NaOH
Baypure DS 100
Baypure CX 100
Sodiumpolyaspartate
Tetrasodium Iminodisuccinate
STRUCTURES
O
O
ONa
H
N
N
H
H2N
O
H
N
O
ONa
ONa O
O
N
H
ONa
O
N
H
O
ONa
NaO
ONa
NaO
O
ONa
ONa
N
ONa
O
n
Baypure DS 100
Baypure CX 100
D,L-asparatic acid,
N-(1,2-dicarboxyethyl)-,
tetranatrium salt;
CAS-No. 144538-83-0
Polyaspartates
Polyaspartates
2. New seed crystals are formed on the polymer chains so that ulti-
growth not only in vivo, but also in vitro. The protein chain interacts
mately many small crystals are produced which can shift with
ASP
ASP
ASP
ASP
ASP
ASP
the aqueous solution cannot easily be inserted into the crystal lat-
crystal morphology.
tional polymers.
ASP
Polycarboxylate
ASP
ASP
ASP
ASP
ASP
ASP
ASP
ASP
ASP
COO- O
COO- O
N
H
Having an effect
on the crystal
morphology of
minerals
COO-
N
H
biodegradation.
Polyasparate
F R O M T H E P O LY M E R T O T H E M O N O M E R :
B AY P U R E C X 1 0 0
Chelation is also a widespread process in nature. Processes involving complexants are photosynthesis in plants, and oxygen transport
in all animals right up to humans. Porphyrin complexes of magnesium, iron or copper, are key substances in living organisms. Synthetic chelants act in just the same way as biological complexing
agents, which hold firmly on to their essential metal ions when they
bond to troublesome metal ions and thus mask them.
The use of nitrogen atoms in combination with oxygen functions as
complex-forming centers is a very old idea in nature. The skillful linking of these functional groups in Baypure CX100, the Tetrasodium
salt of Iminodisuccinic Acid, also give rise to a superior property of
this molecule: its outstanding biodegradability.
This means that this compound is much better, from an ecological
point of view, than conventional complexing agents. Complexing
agents from the Baypure range do their work where they are actually used, during application.
IMINODISUCCINIC ACID:
A BIODEGRADABLE COMPLEXING AGENT
O
O
ONa
C-Terminus, Polyaspartate
ONa
N
I
H
O
O
H 2O
OH
NaOH
NaO
OH
NH 3
NaO
O
O
ONa
10
ONa
O
N
I
H
Biodegradation in %
over 28 days
100
80
60
40
20
0
0
14
21
Biodegradation in %
over 28 days
28
time [d]
100
80
60
40
20
0
0
14
21
28
time [d]
60-
50-
40-
within a very short time, like their natural templates. The degradation
30-
Most conventional complexing agents find their way into rivers and
20-
10-
drinking water.
00
10
time [d]
glucose
polyaspartic acid
polycarboxylate
12
15
20
25
30
not classified
not classified
non-irritant
non-irritant
four weeks
not classified
skin sensitization
non-sensitizing
negative
not classified
not classified
not classified
not classified
not classified
readily degradable
not classified
not classified
not classified
not classified
non-irritant
non-irritant
skin sensitization
non-sensitizing
negative
negative
The Baypure product range is safe to use in household and industrial applications. They dont irritate or sensitize the skin.
not classified
not classified
not classified
not classified
not classified
not classified
readily degradable
BAYPURE DS 100
B AY P U R E D S 1 0 0 - S U P P L I E D I N T H R E E F O R M S :
Product Name
Baypure DS100/40%
Delivery Form
solution
solid
solid
Appearance
orange to brown
Odor
very low
odorless
odorless
9.5 10.5
ca. 10.5
ca. 10.0
ca. 1.30
---
---
---
0.55 0.90
0.83 0.97
20 - 60
---
---
ca. 12C
---
---
each ratio
80
80
ca. 330
ca. 480
ca. 540
Solubility in Water
B AY P U R E D S 1 0 0 - C O N S T I T U E N T S :
16
Productname
Baypure DS100/40%
> 38.0
> 80.0
> 87.0
< 2.0
< 4.0
< 4.0
< 0.3
< 0.5
<
< 0.3
< 0.5
< 0.7
< 0.2
< 0.3
< 0.5
Water [% w/w]
ca. 60
<
< 10.0
15
0,5
STABILITY
T H E R M O S TA B I L I T Y A N D p H S TA B I L I T Y
O F B AY P U R E D S 1 0 0
In many applications especially in cleaning agents and detergents, any ingredient must be stable in both strong alkaline conditions and within a wide range of temperatures.
Stability [%]
Washing machines, dishwashers and membrane cleaning operations can run for hours. Baypure DS 100 therefore needs ade-
100
60
40
20
1
12
24
Time [hrs.]
100
43
39
23
100
8
96
96
83
10
12
13
14
pH
CHELATION CONSTANTS
VISCOSITY
S TA B I L I T Y T O O X I D A N T S
ionic strength: 0,1 mol/L. They give evidence of the strong com-
10000-
1000-
Stability [%]
50C
80C
100
ing to graying of the fibers. In addition iron interferes with the bleach-
100-
80
60
10-
20
65
95
Temperature
[C]
I
35
I
40
Concentration in [% w/w]
64
77
80
99
100
100
8,5
pH-Value
stability at 65C
stability at 95C
18
1- I
30
100
9
98
9,5
97
10
92
73
12
14
I
45
I
50
I
55
I
60
I
65
Metal ions
Mg2+
Ca2+
Mn2+
Fe2+
Fe3+
Cu2+
logK
2.0
2.7
2.1
10.0
18.5
4.8
COMPARISONS
Calcium Carbonate Dispersing Capacity (CCDC) at pH =10
water) and 25C. After 30 minutes the solution was filtered with a
partic acid (active substance) was then added and the chronologi-
The washing process depends, however, on the dispersion performance of the polymer as the function of binding metal ions is
assumed by other constituents of the formulation.
To determine the calcium binding capacity, fully demineralized water
Polycarboxylate
Polycarboxylate
Polyaspartate
Polyaspartate
I
0
I
20
I
40
I
60
20
I
80
I
100
I
120
I
140
I
160
I
180
I
200
I
0
I
20
I
40
I
60
I
80
I
100
I
120
I
140
I
160
I
180
I
200
I
220
I
240
BAYPURE CX 100
B AY P U R E C X 1 0 0 - S U P P L I E D I N T H R E E F O R M S :
Product Name
Baypure CX100/34%
Delivery Form
solution
solid
solid
Appearance
colorless to
white powder
white granules
yellowish, clear
Odor
very low
no odor
no odor
Color no.[Hazen]
< 300
---
---
approx. 11.0
approx. 11.0
< 1.34
---
---
---
0.5 0.7
0.78 - 1.02
< 50
---
---
<5
---
---
56
56
Solubility in water
at 20C [g/100g H2O]
Solubility in glycol
at 20C [g/100g glycol]
very low
very low
Ammonia [ppm]
< 70
---
---
approx. 225
approx. 480
approx. 540
> 120
> 260
B AY P U R E C X 1 0 0 - C O N S T I T U E N T S :
22
Productname
Baypure CX100/34%
> 33.0
> 65.0
> 78.0
< 7.0
< 15.0
< 15.0
< 2.5
< 8.0
< 5.0
< 2.0
< 0.7
< 0.3
< 2.0
< 0.5
> 41.0
> 85.0
> 96.0
Water [% w/w]
< 59.0
< 15.0
< 4.0
raised.
byproducts being responsible for this are the sodium salts of (sum
Baypure CX100 solid and Baypure CX100 solid G are the spray-
are natural compounds that are used as additives in animal feeds and
a bulk density of 0.5 0.7 kg/l. If they are dissolved in water, a clear
edible acids. Normally, only traces of maleic acid disodium salt are
found.
centrations:
(68F).
Density [g/ml]
1.300
1.360
1.250
1.350
1.200
1.340
1.150
1.330
1.100
1.320
1.050
1.310
1.000
0
10
15
20
25
30
35 40
45
1.300
0
50
10
20
30
40
50
Temperature[C]
Concentration [w/w %]
concentration [total sodium salts]
IDS Na-salt
Total sodium salt
45.0 %
42.2 %
44.8 %
40.6 %
43.1 %
The results show that the solutions remain pumpable even if they are
of concentration
Viscosity
[mPa*s]
100
125
80
100
60
75
40
50
20
0
0
different concentrations
25
5
10
15
20
25
30
IDS Na-salt
Total concentration of sodium salt
35
40
45
50
0
0
15
20
25
30
35
40
Temperature [C]
Concentration [w/w %]
24
10
pH- AND pK a
By using the plotted neutralization curve it is possible to determine
pKa1
pKa2
pKa3
pKa4
2.8
3.6
4.7
10.2
12
10
8
6
4
2
0
0,0
2,0 2,5
3,0
3,5
4,0 4,5
5,0
NaOH [mole-equivalents]
STABILITY
Stability of sodium salts of Iminodisuccinic Acid
Chelants are used in various conditions in many applications. It may
Stability
[%]
100
80
60
40
20
0
0
1,5
7,0
4,0
11,0
Time [5h]
Time [20h]
13,5
pH
within a pH range from 4 to 13.5, which reflects conditions in practice, stability is sufficient in the applications mentioned. After 5 hours,
90 to 98% of the active ingredient still remains undecomposed. The
highest stability is at pH 7.
IDS Na4 salt is also stable in the presence of large amounts of caus-
80
tic soda. A solution containing approx. 13.5% of IDS Na4 salt and
60
40
20
0
0
12
16
20
24
Time [weeks]
26
50C
complexes with metal ions. In this case, the chelation involves the
nitrogen atom and all four carboxyl groups. As a result of the octa-
Me
dination geometry.
Computer calculations show that the imino-disuccinic acid iron III
The results obtained were approx. 230 mg CaCO3/g Na salt for IDS
lows:
Iminodisuccinic acid iron III complex
Na4 salt, compared with 210 and 280 mg CaCO3/g Na salt for
DTPA Na5 salt and EDTA Na4 salt. Overall, IDS Na4 salt has good
DTPA Na5 salt
IDS Na4-salt
The calculation shows that the iron III complex has a higher stability than the
manganese II complex because of the bond length and bonding angle. This has
been confirmed by measuring the complexing constants.
EDTA Na4-salt
I
0
I
50
I
100
I
150
I
200
I
250
I
300
28
STABILITY CONSTANTS
The stability of metal complexes with Iminodisuccinic Acid is
tration of the metal complex formed and the product of the concen-
depend on the equilibrium reaction between the metal cation and the
tration of the free IDS anion and the metal cation. If the metal ions
mum
IDS anion on the one hand and the metal complex on the other:
tions, the proportion of IDS anions that can form complexes declines
K
IDSm- + Men+ == IDSMe
(m-n)-
[IDSMe
(m-n) -
KIDS =
[IDSm-] [Men+]
log K
Ba2+
Ag1+
Sr2+
Ca2+
Mg2+
Mn2+
Fe2+
Cd2+
Cr3+
Co2+
Zn2+
Pb2+
Ni2+
Cu2+
3.4
3.9
4.1
5.2
6.1
7.7
8.2
8.4
9.6
10.5
10.8
11.0
12.2
10 13
10 12
10 14
6 14
9 12
4 14
8 12
4 12
--6 12
3 12
6 11
3 14
13.1
14.1
14.9
15.2
3 14
4 7
2 11
2 10
AI3+
Hg2+
Fe3+
30
log K
Metal ion
range
kond.
BAYPURE DSP
O
S T R U C T U R E O F P O LY S U C C I N I M I D E
O
O
O
N
N
O
O
M A I N F I E L D S O F A P P L I C AT I O N :
P R O D U C T P R O P E RT I E S B AY P U R E D S P
Product name
Product form
solid
Appearance
orange-beige powder
Odor
odorless
Bulk density
[kg/liter]
0.50 0.60
Solubility in water at 20 C
[g/100 g H2O]
insoluble
[g/100 g glycol]
30 - 35
B AY P U R E D S P C O N S I S T S O F T H E F O L L O W I N G C O M P O N E N T S :
Product name
Polysuccinimide
[% by wt]
> 90%
[% by wt]
< 4%
[% by wt]
< 2%
[% by wt]
< 2%
*(cp. e.g. Mosig et al, Ind. Eng. Chem. Res.; 1997, 2163-2170)
32
agents and we shall continue to expand this in the interests of our customers and for the wellbeing of the environment.
Baypure is a package provided for the more efficient use of water.
The properties of the dispersing agent Baypure DS 100 and the
Baypure CX100
Baypure DS100
Baypure DSP
A P P L I C AT I O N
FUNCTIONS, i.e.
tions.
Detergens
I
I
I
I
Watersoftening
Disperson of soiling
I&I
I
I
I
Watersoftening
Dispersion of soiling
Membrane cleaning
Cosmetics
Oil Field
Antiscaleant
Mining
Antiscaleant
Ceramic Industry
I
I
I
I
Fluidification of concrete
Retarder
Water Treatment
I
I
I
I
I
Watersoftening
Antiscaleant
Corrosion Inhibition
Prevention of incrustations
Paper-, Leather-,
Textile auxiliaries
I
I
I
I
I
I
I
I
I
Dispersion of Slurries
Bleaching Additives
Antiscaleant
Dyes, Pigments,
Lakes, Inks
Sugar
34
Dispersion of Colorants
Antiscaleant