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Note: The source of the technical material in this volume is the Professional
Engineering Development Program (PEDP) of Engineering Services.
Warning: The material contained in this document was developed for Saudi
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Any material contained in this document which is not already in the public
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of the Vice President, Engineering Services, Saudi Aramco.
Chapter : Chemical
File Reference: CHE-206.02
Engineering Encyclopedia
CONTENT
PAGE
INTRODUCTION...........................................................................................................................8
TEMPERATURE CONTROL METHODS AND EQUIPMENT
USED TO INHIBIT HYDRATE FORMATION IN A NATURAL GAS STREAM ......................9
Downhole Regulators.....................................................................................................10
Downhole Regulator Design.............................................................................10
Indirect Heaters ..............................................................................................................11
Indirect Heater Design.......................................................................................11
Indirect Heater Sizing.........................................................................................13
Advantages and Disadvantages of Temperature Control Methods .........................14
Downhole Regulators.........................................................................................14
Indirect Heaters ..................................................................................................15
Comparison of Temperature Control Methods ...............................................15
CALCULATING METHANOL INJECTION RATE REQUIRED
TO INHIBIT HYDRATE FORMATION IN A NATURAL GAS STREAM.................................17
Chemical Injection..........................................................................................................17
Equation for Calculating Required Depressions
of Hydrate-Formation Temperatures................................................................17
Hammerschmidt Equation.................................................................................18
Methanol..........................................................................................................................19
Methanol Applications .......................................................................................21
Methanol Injection System.................................................................................22
Hammerschmidt Equation Modified
for High Concentrations of Methanol................................................................25
Determining Methanol Injection Rates (General Applications)..................................26
Calculating Water Content of Gas Stream (W)...............................................27
Determining Hydrate-Formation Temperature (TH) .......................................27
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SUMMARY..................................................................................................................................65
Temperature Control Methods......................................................................................65
Chemical Injection..........................................................................................................65
Methanol..............................................................................................................66
Glycol...................................................................................................................66
Calculating Inhibitor Injection Rates Summary............................................................68
WORK AID 1: PROCEDURES AND RESOURCES FOR CALCULATING
METHANOL INJECTION RATE REQUIRED TO INHIBIT
HYDRATE FORMATION IN A NATURAL GAS STREAM..........................69
Work Aid 1A: Procedures and Resources for Calculating
Methanol Injection Rates (General Applications).............................69
Required Depression of Hydrate-Formation Temperatures .........................69
Hammerschmidt Equation.................................................................................69
Hammerschmidt Equation (Eqn. 3)
Solved for the Weight Percent of Inhibitor .......................................................70
Free Water Condensed Out of Gas Stream ...................................................70
Methanol Injection Rate Required to Compensate for Vapor Losses..........71
Methanol Injection Rate Required
to Achieve Aqueous Methanol Concentration.................................................71
Total Methanol Injection Rate ............................................................................71
Work Aid 1B: Procedures and Resources for Calculating
Methanol Injection Rates (Cryogenic Applications) ..........................76
Depression Of Hydrate-Formation Temperatures......................................................76
Hammerschmidt Equation Modified
for High Concentrations of Methanol................................................................76
Flow Rate of Free Water ...................................................................................77
Depressed Hydrate-Formation Temperature (THdepressed) ......................78
Safety Margin......................................................................................................78
Methanol Injection Rate: Vapor Losses ...........................................................78
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List of Figures
Figure 1: Typical Indirect Heater..............................................................................................12
Figure 2: Typical Wellhead Heater Installation.......................................................................12
Figure 3: Comparison Of Temperature Control Methods.....................................................16
Figure 4: Effect Of Methanol On Hydrate Formation In Propane .........................................20
Figure 5: Methanol Injection System .......................................................................................22
Figure 6: Methanol Injection And Recovery System ..............................................................24
Figure 7: Mass Balance Around Separator ...........................................................................33
Figure 8: Flow Of Gas Stream In Methanol Injection Sample Problem (Cryogenic)..........35
Figure 9: Mass Balance Around Separator In Methanol Injection Sample Problem
(Cryogenic) .........................................................................................................38
Figure 10: Comparison Of Chemical Injection Inhibitors ......................................................41
Figure 11: Freezing Points Of Aqueous Glycol Solutions.....................................................43
Figure 12: Allowable Glycol Dilutions......................................................................................44
Figure 13: Dow Chemical Glycol Recommendations ...........................................................45
Figure 14: Glycol Injection And Recovery System .................................................................47
Figure 15: Glycol Injection And Recovery System (Three-Phase) .......................................49
Figure 16: Boiling Point Of Meg ..............................................................................................51
Figure 17: Glycol Sprayed Onto The Tube Sheet Of A Heat Exchanger ............................54
Figure 18: Increase In Pressure Drop Because Of Hydrate Formation..............................55
Figure 19: Nozzle Placed At Three Locations: One Flow Rate...........................................55
Figure 20: Nozzle Placed At One Location: Three Flow Rates...........................................56
Figure 21: Comparison Of Hydrate Inhibition Methods.........................................................66
Figure 22: Comparison Of Chemical Inhibitors .....................................................................67
Figure 30: Summary Of Method For Calculating Methanol Injection Rates
(Steps 1 To 4).....................................................................................................72
Figure 31: Summary Of Method For Calculating Methanol Injection Rates
(Steps 5 To 9).....................................................................................................73
Saudi Aramco DeskTop Standards
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INTRODUCTION
The previous module, ChE 206.01, covered predicting hydrate
formation.
This module covers the following methods of
preventing, or inhibiting, the formation of hydrates.
Temperature control
Methanol injection
Glycol injection
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Downhole Regulators
The use of downhole regulators to inhibit hydrate formation by
controlling gas stream temperatures is generally feasible when the
gas well has the following conditions:
Excess pressure
High capacity
Well depth
Wellbore configuration
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Indirect Heaters
Two types of indirect heaters are used to inhibit hydrate formation:
wellhead and flowline. The expansion of gas streams at or near
wellheads often results in the formation of hydrates. Wellhead
heaters keep the temperatures of these gas streams above their
hydrate-formation temperatures.
Flowlines in other parts of the world often lose enough heat to the
surrounding air and ground to lower the temperature of the gas
stream below its hydrate-formation temperature. Flowline heaters
inhibit hydrate formation by replacing this lost heat and keeping
the temperature of the gas stream above its hydrate-formation
temperature. Flowline heaters also inhibit hydrate formation by
heating gas streams expanded or choked downstream from the
wellhead.
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12
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Downhole regulators
disadvantages:
have
the
following
limitations
or
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Indirect Heaters
The advantages of using indirect heaters to inhibit the formation of
hydrates include the following:
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DESIGN FACTORS
DOWNHOLE
REGULATORS
Investment
Very low
Very high
None
Very high
Fuel
Low
Low
Chemicals
None
Very low
Plot Area
None
Very high
Hazards
High
High
Downtime
Low
Low
Operating Maintenance
Source:
WELLHEAD HEATERS
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(Eqn. 1)
where:
T
TH
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Hammerschmidt Equation
The flow rate of the chemical inhibitor required to depress the
hydrate-formation temperature of a gas stream can be calculated
by hand or with computer programs. Computer programs (PRO/II
and HYSIM) use thermodynamic equations (Eqn. 2) that describe
the freezing point depression of an ideal solution.
T =
n
RT02
In 1+ inhibitor
Hf
n solvent
(Eqn. 2)
where:
T
= Gas constant
T0
Hf
T =
KHwI
100M - MwI
(Eqn. 3)
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(T)(M)
(100)
KH + (T)(M)
(Eqn. 4)
where:
wI
KH
Methanol
Methanol works well as a hydrate inhibitor because of the following
reasons:
It is not corrosive.
It is reasonable in cost.
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Source:
Katz, Donald L. and Robert L. Lee; Natural Gas Engineering: Production and Storage. McGraw-Hill.
1990. With permission from the Gas Processors Suppliers Association.
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Methanol Applications
Because methanols material cost is so low and its vapor losses
so high, methanol is often not recovered. Not requiring a recovery
system significantly reduces capital costs. Therefore, methanol
injection is generally economical for temporary installations,
situations with low gas volumes, or situations with mild, infrequent,
or seasonal hydrate problems.
For instance, the Uthmaniyah Gas Plant uses methanol injection in
case its solid desiccant dehydration system fails. Because of its
high volatility, methanol is also injected to inhibit hydrate formation
in pipelines.
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Source:
Dehydration and Hydrate Inhibition. Exxon Production Research Company, Production Operations
Division. July 1986. With permission from Exxon Production Research Company.
22
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Washed
propane
To fractionation
HC
gas
Methanolhydrocarbon
separator
Gas-gas
exchanger
Water
wash
tower
Propane
product from
depropanizer
Vent gas
Chiller
Feed
gas
Spray
Nozzle
Dissolved
gas
Freewater
knockout
Flash
drum
Reflux
pump
Methanol
still
Water
surge
drum
Excess water
Methanol
injection pump
Source:
Methanol
storage
Nielsen, R. B. and R. W. Bucklin. "Use of Methanol for Hydrate Control in Expander Plants." Fluor
Engineers and Constructors, Inc. Presented at 1981 Gas Conditioning Conference. With permission
from Fluor engineers and Constructors, Inc.
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T = -
RT0
Hf
ln xwater
(Eqn. 5)
where:
T
= Gas constant
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T0
Hf
xwater
(Eqn. 6)
where:
xMeOH
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The amount of free water condensed from the natural gas after
chilling or expanding
Gravity graphic
HYSIM
K-value
SimSci
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Sample Problem:
Calculating Methanol Injection Rates
(General Applications)
Calculate the methanol injection rate required to inhibit the
formation of hydrates in a saturated gas stream being cooled in a
chiller. Refer to Work Aid 1A.
Given:
Gas specific gravity = 0.67
Inlet temperature=70F
Chiller temperature = 40F
Operating pressure = 700 psia
Solution:
1.
2.
=
=
=
=
=
3.
4.
=
=
=
TH - Tminimum + S
58F - 40F + 5F
23F
(Eqn. 1)
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5.
(T)(M)
wI
(100)
= KH + (T)(M)
(Eqn. 4)
(23F) 32.0
lb
mole
(100 )
lb
mole
=
= 24 wt % MeOH
6.
(Eqn. 9)
(W )(w MeOH )
w water
q MeOHaq =
12 lb H2O/MMSCF 24 wt % MeOH
76 wt % H2O
=
= 3.8 lb MeOH/MMSCF
8.
(Eqn. 10)
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q MeOHtotal
= q MeOHvapor + q MeOHaq
= 28.1 lb MeOH/MMSCF + 3.8 lb MeOH/MMSCF
= 31.9 lb MeOH/MMSCF
9.
(Eqn. 11)
More precise
temperatures
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Work Aid 1B groups the steps of this procedure into the following
sequential tasks:
1.
2.
3.
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Source:
33
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Because
of the units of measurement used in Figure 41, the calculation of
the injection rate to account for solubility hydrocarbon liquid
requires multiplication of the solubility of methanol by the flow rate
of the hydrocarbon liquid and the molecular weight of methanol (32
lb/mole).
Injection Rate to Account for Solubility Hydrocarbon Liquid -
Sample Problem:
Calculating Methanol Injection Rates
(Cryogenic Applications)
Referring to Work Aid 1B, calculate the methanol injection rate
required to inhibit hydrate formation in a separator. Figure 8
shows the flow of the gas stream. A gas-gas exchanger and a
chiller cool the gas stream before it is separated.
Given:
Source:
Nielsen, R. B. and R. W. Bucklin. "Use of Methanol for Hydrate Control in Expander Plants." Fluor
Engineers and Constructors, Inc. Presented at 1981 Gas Conditioning Conference. With permission
from Fluor Engineers and Constructors, Inc.
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Solution:
1. The water content of the inlet gas is given.
2. The methods described in the ChE 206.01 are used to
determine that the amount of free water condensed out of the
gas stream (W) is 2.24 lb H2O/MMSCF.
From ChE 206.01:
Woutlet
W
3.
= 0.012 lb H2O/MMSCF
= Winlet - Woutlet
(Eqn. 7)
= 2.25 lb H2O/MMSCF - 0.012 lb H2O/MMSCF
= 2.24 lb H2O/MMSCF
qwater =
1 day
) 24 hr
day
24 hr
= MMSCF
lb H 2O
168
=
hr
4.
5.
= TH - ? T
= 45F - 234F
= -189F
(Eqn. 13)
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6.
(Eqn.14)
7.
8.
mole MeOH
100 mole HC liquid
0.24
Adding a 20% safety margin:
mole MeOH
100 mole HC liquid
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Source:
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9.
q MeOHvapor
=
(vapor-to-liquid composition ratio)(xMeOH)
SCF
379. 5
lb -mole
10 6
(qHCvapor)
(Eqn. 15)
0.83 lb MeOH
MMSCF
0.835 mole fraction MeOH
q MeOHvapor = mole fraction MeOH
173,000 mole HC vapor 379.5 SCF
lb-mole
6
hr
10
45 lb MeOH
hr
=
10. The methanol injection rate required to account for methanol
dissolved in hydrocarbon liquid is 1,940 lb MeOH/hr. From
Figure 46, the molecular weight of methanol (MMeOH) is 32
lb/mole.
q MeOHliquid =
=
(Eqn. 16)
32 lb MeOH
mole MeOH
= 1,940 lb MeOH/hr
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q MeOHaq =
w MeOHaq q water
w water aq
(Eqn. 17)
90 lb MeOH
168 lb H 2 O 100 lb aqueous solution
hr
10 lb H 2O
= 100 lb aqueous solution
= 1,510 lb MeOH/hr
12. The total methanol injection rate required for this system is
3,500 lb MeOH/hr.
q MeOHtotal
1hr
q MeOH = (q MeOHtotal) densityMeOH
(Eqn. 19)
60 min
gal MeOH
hr
lbMeOH 6.47 lb MeOH 60 min
= 3,500
hr
= 9.0 gpm
Answer: The methanol injection rate required for this system is
9.0 gpm.
Source:
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INHIBITOR
Glycol
ADVANTAGES
Usually lower operating cost than
methanol when both systems recover
injected chemical
Low vapor losses (low volatility)
DISADVANTAGES/ LIMITATIONS
High initial cost
Possibility of glycol contamination
Limited use (only noncryogenic
applications)
Cannot dissolve hydrates already
formed
Methanol
Simple system
Low viscosity
When injected, distributes well into gas
streams
Can dissolve hydrates already formed
FIGURE 10: COMPARISON OF CHEMICAL INJECTION INHIBITORS
Temperature increase
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KEY:
Source:
MEG
DEG
TEG
TREG
=
=
=
=
Monoethylene glycol
Diethylene glycol
Triethylene glycol
Tetraethylene glycol (not generally used for hydrate inhibition)
GPSA, Tulsa.
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SITUATION
Source:
ALLOWABLE OR
RECOMMENDED DILUTION OF
GLYCOL
If distribution of glycol is a
problem, limit to about 5%
Up to about 20%
Francis S. Manning and Richard E. Thompson's Oilfield Processing of Petroleum, Volume One: Natural
Gas. Copyright PennWell Books, 1991.
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MEG
DEG
TEG
SITUATION/CONDITION
RECOMMENDATION
45
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46
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Source:
Francis S. Manning and Richard E. Thompson's Oilfield Processing of Petroleum, Volume One: Natural
Gas. Copyright PennWell Books, 1991.
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Glycol injection just before the heat exchanger and just before
the choke.
The separated cold, dry gas to pre-cool the gas stream in the
gas-gas heat exchanger.
The rich glycol to cool the regenerated glycol in the glycolglycol heat exchanger.
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Source:
Dehydration and Hydrate Inhibition. Exxon Production Research Company, Production Operations
Division. July 1986. With permission from Exxon Production Research Company.
The injection nozzle injects the lean glycol into the gas stream.
The reboiler boils off excess water from the rich glycol, and
thereby prepares it to be injected again.
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Reboiler
The temperature in the reboiler depends on the type and
concentration of the glycol used. Reboilers in hydrate inhibition
systems do not regenerate glycols to the same high levels of purity
used in dehydration systems.
Figure 16 plots boiling temperatures of MEG. For example,
Figure 16 shows that the temperature of the reboiler should be set
at about 250F to achieve a lean MEG concentration of 75 wt % at
1 atm (absolute). It is important not to exceed the boiling point of
pure glycol because doing so causes thermal degradation.
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KEY:
B = Boiling curve
C = Condensing curve
Source:
Dehydration and Hydrate Inhibition. Exxon Production Research Company, Production Operations
Division. July 1986. With permission from Exxon Production Research Company.
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Inhibitor Pump
A drum on top of a typical power-gas-driven pump contains the
inhibitor: methanol or glycol. The drum connects directly to the
pump (generally, a positive displacement pump). Methods for
monitoring the inhibitor injection rate include inserting a calibrated
dipstick through the top of the drum or pumping the inhibitor into a
measured vessel. Drums are replaced when empty.
Glycol Losses
Glycol injection systems that involve both hydrocarbon liquids and
gases generally lose glycol to the following:
Leakage
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Capacity
Spray angle
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Source:
Rosen, Ward; Manual P-8: Hydrate Inhibition, 2nd ed. Petroleum Learning Programs, Ltd. Houston.
1991. With permission of Petroleum Learning Programs, Ltd.
FIGURE 17: GLYCOL SPRAYED ONTO THE TUBE SHEET OF A HEAT EXCHANGER
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Source:
Rosen, Ward; Manual P-8: Hydrate Inhibition, 2nd ed. Petroleum Learning Programs, Ltd. Houston.
1991. With permission of Petroleum Learning Programs, Ltd.
Rosen, Ward; Manual P-8: Hydrate Inhibition, 2nd ed. Petroleum Learning Programs, Ltd. Houston.
1991. With permission of Petroleum Learning Programs, Ltd.
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Figure 20 shows one nozzle location but three flow rates. Too low
a nozzle flow rate produces the same result as a nozzle located
too close to the tube sheet. Too high a nozzle flow rate produces
the same result as a nozzle located too far from the tube sheet.
Glycol
Glycol
Spray pattern at
proper glycol
flow rate
Source:
Spray pattern at
high glycol
flow rate
Glycol
Spray pattern at
low glycol
flow rate
Rosen, Ward; Manual P-8: Hydrate Inhibition, 2nd ed. Petroleum Learning Programs, Ltd. Houston.
1991. With permission of Petroleum Learning Programs, Ltd.
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Concentration of Glycol
As with methanol, the Hammerschmidt equation (Eqn. 4) is used
to calculate the minimum glycol concentration that depresses the
hydrate-formation temperature of the gas stream.
wI =
where:
(T) (M)
KH + (T) (M)
(100)
(Eqn. 4)
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If the glycol concentration required to depress the hydrateformation temperature is lower than the minimum glycol
concentration recommended by the vendor (usually greater than
60 wt % glycol), the glycol concentration recommended by the
vendor should generally be used.
In addition to the restrictions on the
concentrations of the lean and rich glycol solutions, the dilution of
the lean glycol may need to be limited. The concentration of the
rich glycol solution should be calculated by subtracting the allowed
amount of dilution recommended in Figure 12 or recommended by
a vendor from the concentration of the lean glycol.
Dilution of Rich Glycol Solution -
Once the
concentrations of the lean and rich glycol solutions have been
determined, an inhibitor injection rate that maintains both
concentrations should be calculated. Equation 22 calculates
inhibitor injection rates.
Equation
for
Calculating
W
q injection =
where: q injection
W
Inhibitor
1
100 100
wrich w lean
Injection
Rate
qgas stream
(Eqn. 22)
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w rich
w lean
=
=
=
=
=
900 psia
45F
90F
10 MMSCFD
0.7
Solution:
1.
=
=
=
WTsaturation = 48 lb H2O/MMSCF
WTminimum = 9.6 lb H2O/MMSCF
WTsaturation - WTminimum
(Eqn. 8)
48 lb H2O/MMSCF - 9.6 lb H2O/MMSCF
38.4 lb H2O/MMSCF
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2.
=
=
=
W (q gas stream)
(Eqn. 20)
lb H 2 O
38.4
10 MMSCF
MMSCF
day
lb H 2 O
384
day
3.
4.
5.
TH - Tminimum + S
64F - 45F + 5F
24F
(Eqn. 1)
(100)
K
+
(T)(M)
wI = H
(Eqn. 4)
(24)(62.10)
(100)
(4,000) + (24)(62.10)
=
= 27 wt % MEG
6.
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7.
8.
9.
1
100 100
wrich w lean
qgas stream
q injection =
38.4 lb H2 O
1
MMSCF
100 lb solution - 100 lb solution
=
65 lb MEG
75 lb MEG
lb
MEG
1,870
day
=
(Eqn. 22)
10 MMSCF
day
11. The value calculated in Step 9 and the density of MEG (from
Figure 49 assuming an injector solution temperature of 90F)
are used to determine that the system requires a lean glycol
injection rate of 276 gpd.
lb MEG 100lb lean glycol solution
galleanMEG
x
x
day
75lb MEG
9.07 lblean MEG
275 galleanMEG solution
=
day
q injection = 1870
Answer:
This system requires a minimum injection rate of 276 gallons of 75
wt % MEG (at 90F) per day.
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=
=
=
=
=
85F
-10F
10 MMSCFD
800 psig
0.75
Solution:
1.
WToperating
=
46 lb H2O/MMSCF
= 1.5 lb H2O/MMSCF
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=
=
=
W (q gas stream)
(Eqn. 20)
44.5 lb H2O/MMSCF (10 MMSCFD)
445 lb H2O/day
3.
4.
The chiller temperature is subtracted from the hydrateformation temperature and a safety margin is added, with the
result that the required depression of the hydrate-formation
temperature is 79F.
T = TH - Tchiller + S
= 64F - (-10F) + 5F
= 79F
(Eqn. 1)
5.
6.
7.
8.
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9.
10. Using the injection rate from Figure 51 and multiplying by the
flow rate of the gas stream, the system requires 2,225 lb of
MEG per day.
From Figure 51:
q MEG = 5
lb MEG
lb H2O
Answer:
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SUMMARY
Hydrates can be inhibited in gas streams by controlling the
temperature of the gas stream or by injecting a chemical inhibitor.
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DESIGN
FACTORS
GLYCOL
INJECTION
METHANOL
INJECTION
DOWNHOLE
REGULATORS
WELLHEAD
HEATERS
Investment
High*
Medium*
Very low
None
Very low
None
Very high
Very high
Low
Low
Low
Low
High
Very high*
High*
Low
Very high
Very low
Medium
Low
None
None
High
Low
Very low
Very high
High
Low
Fuel
Operating
Maintenance
Chemicals
Plot Area
Hazards
Downtime
* If glycol is recovered.
Source:
Dehydration and Hydrate Inhibition. Exxon Production Research Company, Production Operations
Division. July 1986. With permission from Exxon Production Research Company.
Methanol
Methanol works well as a hydrate inhibitor because its
characteristics are as follows:
It is not corrosive.
It is reasonable in cost.
Glycol
Glycol does not evaporate as easily as methanol. In some
applications, glycol does not dissolve into liquid hydrocarbons as
easily as methanol. Recovering glycol, therefore, is generally
more economical than recovering methanol. Economical recovery
of glycol often compensates for its higher material cost, lowering
its operating cost below that of methanol.
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INHIBITOR
Glycol
ADVANTAGES
DISADVANTAGES/
LIMITATIONS
Simple system
Methanol
Dehydration and Hydrate Inhibition. Exxon Production Research Company, Production Operations
Division. July 1986. With permission from Exxon Production Research Company.
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(Eqn. 1)
TH
Tminimum
Hammerschmidt Equation
(W )(w MeOH )
(w water )
where:
(Eqn. 3)
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where: w I =
(Eqn. 4)
T =
KH =
(Eqn. 7)
(Eqn. 8)
WTminimum =
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(Eqn. 9)
(W )(w MeOH )
q MeOHaq =
where: q MeOHaq
(w water )
(Eqn. 10)
(Eqn. 11)
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Source:
Underground Storage of Fluids, 1968. With permission from Ulrich's Book Store.
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STEP
5
QUANTITY
Concentration of MeOH in
aqueous solution (wt %
MeOH)
1
100 100
wrich w lean
qgas stream
(Eqn. 4)
Qt
q MeOHaq = (U) (LMTD )
If necessary, convert
q MeOHtotal to appropriate
units
(Eqn. 10)
Katz, Donald L. and Robert L. Lee, Natural Gas Engineering: Production and Storage, McGraw-Hill,
1990, p. 220, Table 5.5.
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Source:
Katz, Donald L. and Robert L. Lee. Natural Gas Engineering: Production and Storage. McGraw-Hill.
1990. With permission from McGraw-Hill.
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Source:
Katz, Donald L. and Robert L. Lee. Natural Gas Engineering: Production and Storage. McGraw-Hill.
1990. With permission from McGraw-Hill.
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Work Aid 1B: Procedures and Resources for Calculating Methanol Injection Rates
(Cryogenic Applications)
The procedure outlined below is based on the
assumption that pure methanol is injected.
Note:
(Eqn. 1)
where: T
TH
where:
(Eqn. 6)
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(Eqn. 7)
WToperating
WTminimum
(Eqn. 8)
where:
WTsaturation
WTminimum
1 day
q water = (W) (q gas stream) 24 hr
where:
q water
W
(Eqn. 12)
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Engineering Encyclopedia
(Eqn. 13)
= Depression of hydrate-formation
temperature, F
Safety Margin
S =Tminimum - (TH - T)
where:
(Eqn. 14)
= Safety margin, F
= Depression of hydrate-formation
temperature, F
SCF
379. 5
lb -mole
10 6
(q HCvapor )
(Eqn. 15)
where: q MeOHvapor=
x MeOH
q HCvapor
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Engineering Encyclopedia
(Eqn. 16)
MMeOH
wMeOH aq qwater
w water aq
(Eqn. 17)
where: q MeOHaq
wMeOHaq
qwater
wwateraq
(Eqn. 18)
79
Engineering Encyclopedia
q MeOHliquid
q MeOH = q MeOHtotal
1 hr
densityMeOH 60 min
where: q MeOH
(Eqn. 19)
hydrate-formation
80
Engineering Encyclopedia
STEP
QUANTITY
Saturation temperature of
gas stream, Tsaturation
Minimum temperature of
the system, Tminimum
2
(Eqn. 8)
Hydrate-formation
temperature, TH
1 day
q water = (W) x (q gas stream) x 24 hr
81
Engineering Encyclopedia
STEP
5
QUANTITY
(Eqn. 6)
Safety margin, S
(Eqn. 13)
(Eqn.14)
Solubility of MeOH in
hydrocarbon vapor
(vapor-to-liquid
composition ratio)
Solubility of MeOH in
hydrocarbon liquid
82
Engineering Encyclopedia
STEP
9
10
11
12
QUANTITY
q MeOHvapor =
(vapor-to-liquid composition ratio)(x MeOH)
SCF
379. 5
lb -mole
(qHCvapor)
(Eqn. 15)
10 6
q MeOHaq =
w MeOHaq q water
w water aq
(Eqn. 17)
If necessary, convert
injection rate units
1
1 hr
q MeOH = q MeOHtotal
60 min (Eqn.
density MeOH
19)
To determine the density of methanol, either use
Figure 42 or assume the density of methanol equals
6.56 lb/gal.
83
Engineering Encyclopedia
Source:
MEOH, MOLE
FRACTION
MeOH, WT %
T, F
0.0
0.0
0.0
0.1
16.5
13.7
0.2
30.8
28.9
0.3
43.2
46.2
0.4
54.2
66.2
0.5
64.0
89.8
0.7
80.6
156
0.8
87.7
209
0.835
90.0
234
Nielsen, R. B. and R. W. Bucklin. "Use of Methanol for Hydrate Control in Expander Plants. Fluor
Engineers and Constructors, Inc" Presented at 1981 Gas Conditioning Conference. With permission
from Fluor Engineers and Constructors, Inc.
Source:
84
Engineering Encyclopedia
Source:
Source:
Reproduced with permission from Hydrocarbon Processing, April 1983.
85
Engineering Encyclopedia
Source:
86
Engineering Encyclopedia
8.5
5%
10%
20%
8.0
30%
40%
50%
7.5
60%
70%
80%
7.0
90%
100%
wt % MeOH
6.5
6.0
-80
-60
-40
-20
20
40
60
Temperature, F
80
100
120
Source:
Nielsen, R. B. and R. W. Bucklin. "Use of Methanol for Hydrate Control in Expander Plants. Fluor
Engineers and Constructors, Inc." Presented at 1981 Gas Conditioning Conference. With permission
from Fluor Engineers and Constructors, Inc.
87
Engineering Encyclopedia
Source:
Nielsen, R. B. and R. W. Bucklin. "Use of Methanol for Hydrate Control in Expander Plants. Fluor
Engineers and Constructors, Inc" Presented at 1981 Gas Conditioning Conference. With permission
from Fluor Engineers and Constructors, Inc.
88
Engineering Encyclopedia
(Eqn. 1)
Depression of hydrate-formation
temperature, F
TH
Tminimum =
where:
n
RT02
In 1+ inhibitor
Hf
n solvent
(Eqn. 2)
= Depression of hydrate-formation
temperature, F
= Gas constant
T0
Hf
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Engineering Encyclopedia
Hammerschmidt Equation
T=
KHwI
100M - M wI
(Eqn. 3)
(T)(M ) (100 )
KH + (T )(M)
(Eqn. 4)
wI
Depression of hydrate-formation
temperature, F
KH =
(Eqn. 7)
90
Engineering Encyclopedia
(Eqn. 8)
(Eqn. 20)
(Eqn. 21)
91
Engineering Encyclopedia
W
q injection =
1
qgas stream
100 - 100
wrich wlean
where: q injection
(Eqn. 22)
w rich
w lean
92
Engineering Encyclopedia
QUANTITY
(Eqn. 8)
(Eqn. 20)
Hydrate-formation
temperature, TH
Required depression of
hydrate-formation
temperature, T
T = TH - Tminimum + S
(Eqn. 1)
93
Engineering Encyclopedia
STEP
7
QUANTITY
10
1
qgas stream
100
100
(
)
wrich wlean
If necessary, convert
glycol injection rate to
appropriate units
94
Engineering Encyclopedia
PROPERTY
MeOH
MEG
DEG
TEG
TREG
Molecular Weight
32.04
62.10
106.10
150.20
194.23
148.10
387.10
427.60
532.90
597.2
94
0.12
<0.01
< 0.01
< 0.01
0.7868
1.110
1.113
1.119
1.120
--
1.085
1.088
1.092
1.092
6.55
9.26
9.29
9.34
9.34
Freezing Point, F
-144
17
19
22
Pour Point, F
--
< -75
-65
-73
-42
0.55
16.5
28.2
37.3
39.9
Absolute Viscosity at
140F, Centipoise (cP)
0.36
5.1
7.6
9.6
10.2
22
47
44
45
45
0.27
0.58
0.55
0.53
0.52
Flash Point, F
--
240
280
320
365
Fire Point, F
--
245
290
330
375
Decomposition
Temperature, F
--
329
328
404
460
Heat of Vaporization at
14.7 psi, Btu/lb
473
364
232
179
--
Source:
Dehydration and Hydrate Inhibition. Exxon Production Research Company, Production Operations
Division. July 1986. With permission from Exxon Production Research Company.
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Engineering Encyclopedia
SITUATION
Up to about 20 %
Source:
Francis S. Manning and Richard E. Thompson's Oilfield Processing of Petroleum, Volume One: Natural
Gas. Copyright PennWell Books, 1991.
Source:
Engineering Data Book, Vol. 2, 10th ed. GPSA, Tulsa. 1987. With permission from the Gas
Processors Suppliers Association.
96
Engineering Encyclopedia
Source:
Francis S. Manning and Richard E. Thompson, Oilfield Processing of Petroleum, Volume One: Natural
Gas. Copyright PennWell Books, 1991.
97
Engineering Encyclopedia
98
Engineering Encyclopedia
lb H 2O
12
14
10
0
100
80
60
40
Concentration of inject ed lean MEG , wt %
20
99
Engineering Encyclopedia
GLOSSARY
aqueous solution
borehole
See wellbore.
dilution
choke
DEG
Diethylene glycol.
downhole
emulsion
enthalpy
expansion loop
fire tube
free-water knockout
100
Engineering Encyclopedia
heater coil
high-pressure flowline
immiscible
lean glycol
Monoethylene glycol.
reboiler
reboiling
relief valve
residue gas
rich glycol
101
Engineering Encyclopedia
safety-drilled
shut in
still
TEG
Triethylene glycol.
three-phase separator
TREG
Tetrathylene glycol.
tubing string
wellbore
wellhead
wireline
wireline operations
102
Engineering Encyclopedia
DEFINITION
Hf
KH
Flow rate
Gas constant
T0
T
TH
Operating temperature, F
Hydrate-formation temperature of gas stream, F
Water content
103
Engineering Encyclopedia
NOTE:
(Eqn. 1)
n
RT02
In 1+ inhibitor
Hf
n solvent
(Eqn. 2)
KHw I
100M Mw I
(Eqn. 3)
Hammerschmidt Equations
T =
(T)(M)
(100)
KH + (T)(M)
(Eqn. 4)
T = -
RT0
Hf
ln xwater
(Eqn. 5)
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Engineering Encyclopedia
(Eqn. 6)
(Eqn. 7)
(Eqn. 8)
(Eqn. 9)
(W )(w MeOH )
(w water )
(Eqn. 10)
(Eqn. 11)
1 day
24 hr
(Eqn. 12)
105
Engineering Encyclopedia
(Eqn. 13)
S = Tminimum - (TH - T)
(Eqn. 14)
Safety Margin
SCF
379. 5
lb -mole (Eqn. 15)
(qHCvapor)
10 6
(Eqn. 16)
w MeOHaq q water
w water aq
(Eqn. 17)
(Eqn. 18)
1 hr
q MeOH = q MeOHadjusted x densityMeOH x 60 min
(Eqn. 19)
(Eqn. 20)
106
Engineering Encyclopedia
(Eqn. 21)
1
100 100
wrich w lean
qgas stream
(Eqn. 22)
107
Engineering Encyclopedia
2.
3.
Determine the heater load (Qg) of the gas for the above
inlet and outlet conditions.
108
Engineering Encyclopedia
4.
Qt
(U) (LMTD )
109
Engineering Encyclopedia
110