Documentos de Académico
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CAPITULO 10
Termodinmica y
Cintica
a)
b)
c)
d)
Hf0 SiO2(s) = -910.9 kJ/mol; Hf0 Na2CO3(s) = -1131 kJ/mol; Hf0 CO2(g) = -393.5
kJ/mol
Hf0 H2SiF6(ac) = -2331 kJ/mol; Hf0 HF(ac) = -320.8 kJ/mol; Hf0 SiF4(g) = -132 kJ/mol
Hf0 N2O5(s) = -43.1 kJ/mol; Hf0 NO2(g) = 33.2 kJ/mol; Hf0 NO(g) = 90.25 kJ/mol Hf0
N2O(g) = 82.05 kJ/mol; Hf0 H2O(g) = -241.8 kJ/mol; Hf0 Na2SiO3 (g) = -1079 kJ/mol
Rta: a) 570 kJ; b) 74.4 kJ; c) 109.5 kJ; d) 340.25 kJ
10) El fosgeno, COCl2, es importante en la fabricacin de polmeros. Por ser un veneno
respiratorio muy peligroso se emple como gas venenoso. Demostrar que la
preparacin del fosgeno a 25 C es exotrmica. CO(g) + Cl2(g) COCl2(g)
0
Hf CO(g) = -110.5 kJ/mol; Hf0 COCl2(g) = -223 kJ/mol
11) A continuacin se da la ecuacin de la reaccin que se emplea para separar silicn
ultra puro para semiconductores. Calcular H de la reaccin SiBr4(l)
H0 = -72.8 kJ
FSICA - EXACTAS COLEGIO CHAMPAGNAT
H0reaccion = -102.3
H0reaccion = 624.6 kJ
A+2BC+2D
Experimento
1
2
3
4
[A]
[mol/L]
0.1
0.3
0.3
0.4
[B] [mol/L]
0.1
0.3
0.1
0.20
2 A + B + 2C D + 2 E
Experimento
1
2
3
4
[A] [inicial]
0.1 M
0.2 M
0.3 M
0.4 M
[B] [inicial]
0.2 M
0.2 M
0.2 M
0.6 M
[C] [inicial]
0.1 M
0.3 M
0.1 M
0.3 M
A+BC
Experimento
1
2
3
[A]
[inicial]
0.1 M
0.2 M
0.1 M
[B] [inicial]
0.1 M
0.2 M
0.2 M
[A]
[inicial]
0.2 M
0.3 M
0.4 M
[B] [inicial]
0.1 M
0.1 M
0.2 M
[A]
[inicial]
0.2 M
.... M
0.8 M
[B] [inicial]
0.05 M
0.05 M
.... M
0.1 M/seg
0.2 M/seg
0.8 M/seg
Experimento
1
2
3
[A]
[inicial]
1.0 M
2.0 M
2.0 M
[B] [inicial]
0.2 M
0.2 M
0.4 M
0.25 M/seg
____ M/seg
____ M/seg
1
0
1
1
1
2