Physical Properties For Heat Exchanger Design

GBH Enterprises, Ltd.
Process Engineering Guide:

GBHE-PEG-HEA-500
Physical Properties for Heat

Exchanger Design
Information contained in this publication or as otherwise supplied to Users is

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Process Engineering Guide:
Physical Properties for Heat

Exchanger Design
CONTENTS
SECTION
INTRODUCTION/PURPOSE
SCOPE
FIELD OF APPLICATION
DEFINITIONS
COMPONENT PROPERTIES
4.1
4.2
General
Use of Component Properties for Mixtures
3
3
INPUT OF MIXTURE CURVES
5.1
5.2
5.3
5.4
General
Generation of the Mixture Curves
Selection of Temperature Points
Extrapolation
4
4
5
6
IMMISCIBLE CONDENSATES
FIGURES
1
TEMPERATURE POINTS SELECTED FOR

EQUAL ENTHALPY CHANGE
TEMPERATURE POINTS SELECTED FOR GOOD

FIT TO CURVE
INTRODUCTION/PURPOSE
This Guide is one of a series on heat transfer produced for GBH Enterprises.
SCOPE
This Guide discusses how to provide physical property data for the computer
aided thermal design of heat exchangers.
It is NOT a guide to sources of property data, nor to methods of estimating such
data. If information is required on such items, a physical properties expert should
be consulted.
FIELD OF APPLICATION
This Guide applies to all process engineers in GBH Enterprises worldwide.
DEFINITIONS
For the purposes of this Guide, the following definitions apply:

HTFS
.
HTRI
Heat Transfer and Fluid Flow Service. A cooperative research

organization, based in the UK, involved in research into the
fundamentals of heat transfer and two phase flow and the
production of design guides and computer programs for the design
of industrial heat exchange equipment.
Heat Transfer Research Incorporated. A cooperative research
organization, based in the USA, involved in research into heat
transfer in industrial sized equipment, and the production of design
guides and computer programs for the design of such equipment.
COMPONENT PROPERTIES
4.1
General
As an alternative to using in-built data banks of commercially available programs

, property data for individual components can be input. Data are normally given
at two temperatures, however programs are now available to allow for up to 12
temperatures.
4.2
Use of Component Properties for Mixtures
Component or automatic properties for mixtures should not be used unless it is

ensured that they are reasonably ideal.
In general, if data are given for several components, either by use of automatic
property codes in commercially available programs or by direct input, or a
combination of these, the programs will use ideal mixing rules to determine the
mixture properties (non-ideal VLE behavior can be allowed for in some
commercially available programs, using equilibrium constants, but all other
properties are based on ideal mixing).
INPUT OF MIXTURE CURVES
5.1
General
The use of mixture profiles is the preferred way to input physical property data for
mixtures, as it allows for the user to model non-ideal behavior with more
precision. However, it does require the generation of a large quantity of data.
Some commercially available programs, (i.e., thermal rating programs) will
accept physical properties in the form of a matrix of values for all properties,
calculated at different temperatures, and in some cases also at different
pressures. Versions exist that will allow up to three sets of data at different
pressures. . Versions exist that will allow data at two pressures;
5.2
Generation of the Mixture Curves
If all the components of a mixture are available, the recommended method of

generating the MIXTURE curves is by means of commercially available
programs.
If not all data are available, it may be possible to insert the coefficients for the
missing components when running the program. For further help, consult a
physical properties expert.
If the additional data are not available in a suitable form, it may be necessary to
generate the data by hand.
5.3
Selection of Temperature Points
The properties at the chosen temperature points, when linked linearly, should be
a reasonable approximation to the actual curves. This is particularly important for
the weight fraction vapor and the specific enthalpy or heat load from entry, as
these properties often vary in a significantly non-linear manner with temperature.
Obviously, the more data points provided by the user, the better the
representation of the data will be.
Commercially available programs will interpolate linearly between values
supplied. The programs in general use a spline method of interpolation for
specific enthalpy and weight fraction vapor which will give better results than the
simple linear interpolation.
For two phase systems, condensing or boiling, the dew point and the bubble
point should always be included as points on the profile if they occur within the
temperature range selected. Usually, only one extra point will be required for the
superheated region, and one for the subcooled region unless there is a large
superheated or subcooled zone and the properties vary in a non-linear manner.
The majority of the points should be selected in the two-phase region, where,
because of composition changes, properties are changing rapidly.
One commercially available program, - has an option that first locates the dew
and bubble points, if they occur within the input temperature range, and then
divides the two-phase region into zones of equal enthalpy change.
For many mixtures, the equal enthalpy change approach is adequate. However,
it can lead to significant errors for mixtures with temperature/enthalpy curves with
regions of high curvature, for example, mixtures of mainly condensables, but with
a small quantity of inerts. In these cases, it is desirable to have more points in the
region of high curvature, if necessary at the expense of regions where properties
vary in a linear manner. See Figures 1 and 2. The difference between these two
approaches can lead to differences in performance prediction of more than 10%.
Following a preliminary run, the estimated weight fraction vapor and stream
enthalpy values should be plotted against temperature.
This may be done using the graph plotting option of commercially available
programs.
Further runs may be necessary at different temperatures to obtain the full shape
of the curves. Having obtained the full curve, a final set of temperatures can be
selected, including dew and bubble point if they occur within the temperature
range, and processed through the 'Manual' option to obtain the data files
for running the exchanger program.
5.4
Extrapolation
Mixture curves given should span the range of temperatures expected. If they do
not, the program will extrapolate from the points given, often in a linear manner,
which can result in significant errors or program crashes in some cases.
FIGURE 1 TEMPERATURE POINTS SELECTED FOR EQUAL ENTHALPY

CHANGE
FIGURE 2 TEMPERATURE POINTS SELECTED FOR GOOD FIT TO CURVE
MMISCIBLE CONDENSATES
Some vapor mixtures condense forming two wholly or partially immiscible liquid
phases. A typical example is a mixture of steam and hydrocarbons. In general,
such a system will have two 'dew points'. As the vapor is cooled, the first dew
point will be reached where one liquid phase will condense. Further cooling will
produce a second dew point, below which two liquid phases will be present. At
present none of the heat exchanger programs available will handle this situation
rigorously. Indeed, there is some doubt as to how such a system does perform in
condensation. The recommended method for rating such exchangers, which is
believed to underestimate the heat transfer coefficient, and hence will generally
be safe, is as follows:
(a)
The two dew points should be selected as two of the temperature points
on the condensation curve.
(b)
Other temperature points should be selected to give a good representation

of the curve shape.
(c)
For temperatures between the two dew points there is only one liquid
phase. Use the liquid physical properties of this phase.
(d)
Below the lower dew point, where there are two liquid phases, the liquid
phase used by the heat transfer program should be assumed to have the
transport properties of the phase with the worse properties, i.e. higher
viscosity and lower thermal conductivity. For a water/organics system, this
will almost certainly be the organics rich phase. For other systems, it may
not be obvious which will give the worse results, and it may be necessary
to try both options.
(e)
Below the lower dew point the specific heat and enthalpy of the liquid
phase has to be taken as the weighted mean of the two phases, to
conserve the heat balance.
Commercially available programs can be used to generate the values of
the properties, assuming that the non-ideality can be modeled. The
'Automatic' temperature point method cannot be used in these
circumstances, and the location of the two dew points and the bubble
point will need to be determined by trial and error.
Data for both liquid phases can be generated in tabular form

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GBH Enterprises, Ltd.

Process Engineering Guide:

Physical Properties for Heat

Information contained in this publication or as otherwise supplied to Users is

Process Engineering Guide:

Physical Properties for Heat

INPUT OF MIXTURE CURVES

TEMPERATURE POINTS SELECTED FOR

TEMPERATURE POINTS SELECTED FOR GOOD

This Guide applies to all process engineers in GBH Enterprises worldwide.

For the purposes of this Guide, the following definitions apply:

Heat Transfer and Fluid Flow Service. A cooperative research

As an alternative to using in-built data banks of commercially available programs

Use of Component Properties for Mixtures

Component or automatic properties for mixtures should not be used unless it is

INPUT OF MIXTURE CURVES

Generation of the Mixture Curves

If all the components of a mixture are available, the recommended method of

Selection of Temperature Points

FIGURE 1 TEMPERATURE POINTS SELECTED FOR EQUAL ENTHALPY

FIGURE 2 TEMPERATURE POINTS SELECTED FOR GOOD FIT TO CURVE

Other temperature points should be selected to give a good representation

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