Documentos de Académico
Documentos de Profesional
Documentos de Cultura
K : Kimia
I : Itu
M : Mudah
I : In Sya Allah / Pasti
A : A+
NAMA:..............................................
TINGKATAN:...................................
1|Page
Atomic Structure
HAND OUT 1
HANDOUT 2
ELEMENT
ATOM
FREEZING
POINT
MOLECULE
2|Page
MATTER
ION
MELTING
POINT
DIFFUSION
COMPOUND
HANDOUT 3
Choose correct sentences to describe the arrangement and movement of particles in solids,
liquids and gases according to the kinetic theory of matter.
3|Page
KINETIC THEORY OF MATTER
1.
2.
3.
4.
Cannot be compressed
5.
Particles are far apart from each other and in random motion
6.
SOLID, LIQUID
OR GAS?
4|Page
HANDOUT 4
HAND OUT 5
5|Page
WE LEARN THAT THERE ARE 3 STATES OF MATTER. BUT DO YOU KNOW
THAT ACTUALLY THERE ARE 5 STATES OF MATTER?
PLASMA AND BOSE- EINSTEIN CONDENSATE ARE THE 4TH AND THE 5TH
STATES OF MATTER
PLASMA
Plasmas are a lot like gases, but the atoms are different because they are made up of free
electrons and ions of the element. Northern Lights or ball lightning, are types of plasmas.
FINDING A PLASMA
Inside the long tube of fluorescent light bulb is a gas. Electricity flows through the tube
when the light is turned on. The electricity acts as that special energy and charges up the
gas. This charging and exciting of the atoms creates glowing plasma inside the bulb.
Another example of plasma is a neon sign. The electricity charges the gas, possibly neon,
and creates plasma inside of the tube. The plasma glows a special color depending on what
kind of gas is inside.
Stars are big balls of gases at really high temperatures. The high temperatures charge up
the atoms and create plasma.
BOSE-EINSTEIN condensate
In 1995, two scientists, Cornell and Weiman, finally created this new state of matter. Two
other scientists, Satyendra Bose and Albert Einstein, had predicted it in the 1920. If
plasmas are super hot and super excited atoms, the atoms in a Bose-Einstein condensate
(BEC) are total opposites. They are super-unexcited and super-cold atoms.
The BEC happens at super low temperatures. When temperatures get that low, you can
create a BEC with a few special elements.
When you get to a temperature near absolute zero something special happens. Atoms
begin to clump .A group of atoms takes up the same place, creating a "super atom." There
are no longer thousands of separate atoms. They all take on the same qualities and for our
purposes become one blob.
6|Page
HANDOUT 6
Using the kinetic theory of matter, explain what happens when the solid is heated
Fill in the blanks with right words in the sentences below.
more energy
overcome
energy supplied during heating
the temperature
liquid
gains energy
A-B
When the solid is heated, the solid particles .and
vibrate faster .
B-C
As the temperature is further increases, the particles vibrate faster until they
gain enough energy to the forces of attraction between solid particles.
At this point, the solid changes to The energy absorbed by the
particles is used to overcome the forces of attraction between particles.More heating
does not increase ..because the energy absorbed by the particles is equal
to the ..
C-D
7|Page
The following graph shows the COOLING CURVE of a substance
Using the kinetic theory of matter, explain what happens when liquid is cooled. Fill in the blanks
with right words in the sentences below.
get closer to one another
release energy
kinetic energy
bonds are formed
lose energy
loss to the environment
A-B When the liquid is cooled, the particles ..and move slower
As the temperature continue to drop, the particles continue to lose energy and begin to
..
B-C
C-D
The substance is in solid form. The temperature drops because the solid particles
released more ..and move slower.
8|Page
SUMMARY
HANDOUT 7
1. Fill in the table below
( Note that the order of discovery is not arranged according to the correct sequence)
Students are requested
1) to draw the atomic models suggested by each scientist 2) To rearrange the ideas according to the correct order of discovery
Scientists
Democritus
Ideas/discovery
J.J. Thomson
Arrangement of
discovery
9|Page
John
Dalton
Werner
Heisenberg
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year
1. Democritus
BC460-371
BC
Ideas/discovery
model
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John
1766-1844
Dalton
J.J. Thomson
1856-1940
1871-1937
Lord Ernest
Rutherford
Negative
electron
Positive
sphere
12 | P a g e
scientists
year
discovery
Niels Bohr
1913-1963
James
Chadwick
1891-1974
1901-1976
Werner
Heisenberg
Model
13 | P a g e
HANDOUT 8 ( MATCHING DISCOVERIES AND NAME OF SCIENTISTS)
Democritus
James Chadwick
John Dalton
Niels Bohr
Werner Heisenberg
Lord Ernest Rutherford
J.J. Thomson
Match the following ideas with the names of scientists in the box above
Atoms are of different size, shape and weight .
Atom is a small indivisible matter like a tiny ball ..
Discovered electrons
Proposed that atom is a sphere of positive charges that that contains tiny negative particles like plum pudding model
.
5. Discovered protons
6. Most of an atom consists of an empty space ..
7. Positive charge only concentrated in a small , central region .
8. Proposed that protons are small central nucleus with electrons revolve around
14 | P a g e
HANDOUT 9
Below are atomic model of atoms . Write down names of the scientists who proposed the ideas of the models.
ATOMIC MODELS
1
SCIENTISTS
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5
16 | P a g e
HANDOUT 10
PROTON
SYMBOL
RELATIVE
ELECTRIC CHARGE
RELATIVE
MASS
+1
NEUTRON
ELECTRON
1/1840
17 | P a g e
2. Fill in the blanks with appropriate words to describe properties of subatomic particles of an atom. Use words in the box to help you
QUARKS
SPIN AND ROTATE ELEMENT COMPOUNDS
CHEMICALLY
CHEMICAL FORMULA
GAIN OR LOSE
SUBATOMIC PARTICLES
ATOM
NEUTRONS
1.
2.
3.
4.
5.
6.
7.
8.
AN ISOTOPE
..................................................is
of protons
in the nucleus of an atom
PROTON NUMBERthe number
NUCLEON
NUMBER
....................................................is the number of protons and neutrons in the nucleus of an atom
An is the smallest particle of an element that remain identical to all other particles.
The atoms of one .are different from those of all other element.
are made when atoms of different elements are combined together.
..are used to describe the types of atoms and their numbers in an element or compound.
Protons and neutrons are composed of smaller particles called ..
While an atom is tiny, the nucleus is ten thousand times smaller than the atom and the quarks and electrons are at least ten thousand times
smaller than the nucleus.
9. ..are particles that are smaller than the atom.
10. Atoms of a particular element must have the same number of protons but can have different numbers of
11. When two atoms have the same number of protons but different number of neutrons, they are called .
18 | P a g e
12. Element's or isotope's mass number or nucleon number tells how many
..in its
atoms.
13. Electrons around the outside of the nucleus.
14. As the electrons circle the nucleus they travel at certain energy levels but can "jump" between different energy levels if they
energy.
If this were the proton in a
hydrogen atom, it would take a
screen 1 mile across to display
the electron's orbit.
If an electron weighed the same as a 1 cent ,
a proton would weigh the same as a gallon of milk.
HANDOUT 11
SYMBOL
ELEMENT
Sodium
Helium
Magnesium
Calcium
Aluminium
Potassium
Silicon
SYMBOL
Al
19 | P a g e
Argon
Phosphorous
Chlorine
Neon
Sulphur
Fluorine
S
Lithium
Oxygen
Beryllium
Zinc
Boron
Iron
Carbon
Silver
C
Nitrogen
Gold
Lead
Nitrogen
Au
Note 1
What is the function of electron to an atom?
Answer:
Absorbs or give out energy. Also valence electron able to form bond with other atoms so to make compounds
What is the function of proton to an atom?
Answer:
The number of protons in an atom defines what element the atom is. Also provides an attractive force for orbiting electrons.
What is the function of neutron to an atom?
Answer:
neutrons hold the nucleus together.
Neutrons in an atom's nucleus decide the isotopes of an atom
20 | P a g e
Worksheet 1.1:
Question:
1. Helium-6 and Helium-7 are isotopes. The nucleon number of helium-6 is 6 and Helium-7 is 7. Given the proton number for each isotope
is 2, answer the following question.
(a) What is meaning of the term isotopes?
____________________________________________________________________
(b) Write the symbol for helium-6 and helium-7 , showing proton number and nucleon number.
(c) Compare the number of electrons, protons and neutrons in one atom of helium-6 and one atom of helium-7
______________________________________________________________________________________________________________
______________________________________________________________________________________________________________
(d) What are the similarities and difference between isotopes helium-6 and helium-7.
21 | P a g e
Fill in the table below
Isotopes
No. of protons
No. of electrons
No of neutrons
10
17
22 | P a g e
Carbon-14
Cobalt-60
Phosphorous -32
Radio isotopes
Sodium-24
plutonium
23 | P a g e
9. inhibit budding in potatoes
10. pest control in agriculture
Worksheet 1 (complete the table below)
Element
Proton
number
Nucleon
Hydrogen
Helium
Lithium
Beryllium
number
Number
of
neutrons
Number
of
protons
Number
of
electrons
Electron
arrangement
Number of
valence electrons
1
24 | P a g e
Boron
11
Carbon
12
Nitrogen
Oxygen
2.4
25 | P a g e
Fluorine
10
Neon
10
10
Sodium
11
12
Magnesium
12
12
Aluminium
13
27
26 | P a g e
Silicon
14
28
Phosphorus
15
31
Sulphur
16
32
Chlorine
17
18
Argon
18
22
27 | P a g e
Potassium
19
20
Calcium
20
20
28 | P a g e
LO 3.3 ANALYSING THE RELATIONSHIP BETWEEN THE NUMBER OF MOLES OF A SUBSTANCE WITH ITS MASS
Activity 1 : Relate molar mass of a substance to its NA constant and RAM / RMM / RFM
No
Name
1. Potassium, K
2. Oxygen, O2
3. Water, H2O
RAM/RMM/RFM
(39)
(32)
(18)
No of particles
(atom/molecule/ion)
6.02 x 1023
6.02 x 1023
6.02 x 1023
5. Magnesium
oxide, MgO
6.02 x 1023
6. Sodium
chloride, NaCl
6.02 x 1023
8. Aluminium
sulphate,
Al2(SO4)3
9. Sulphur
dioxide, SO2
10. Copper(II)
nitrate, Cu(NO3)2
(39g/mol)
6.02 x 1023
4. Zinc, Zn
7. Nitrogen
dioxide, NO2
Molar mass
(g/mol)
(65g/mol)
(40g/mol)
(58.5)
6.02 x 1023
(46)
6.02 x 1023
(342)
(342g/mol)
6.02 x 1023
6.02 x 1023
(64g/mol0
Mass of
1 mole
(g)
39g
29 | P a g e
(188)
11. Methane,
CH4
12. Iron(III)
chloride, FeCl3
(16)
6.02 x 1023
6.02 x 1023
(162.5)
13. Carbon, C
6.02 x 1023
6.02 x 1023
(12g/mol)
(63)
Activity 2 : Solving numerical problems to convert the number of moles of a given substance to its mass and vice versa
1. The molar mass of a substance ,
= the mass of _________________ mole of the substance.
= the mass of (NA) number of particles
= the mass of ____________________ particles
x Molar mass
Number of moles
Mass in g
Molar mass
30 | P a g e
mass of 1 mole of the substance/molar mass
Therefore :
Mass of substance
Example 1 :
Example 2 :
16 ]
31 | P a g e
g) 1 mole of carbon dioxide ( CO2)
Mass =
b) 6g of carbon atoms
Number of moles =
d) 4g of sulphur atoms
32 | P a g e
Number of moles =
Number of moles =
33 | P a g e
q) 15.8g of potassium manganate (VII) KMnO4
Number of moles =
Molar mass
Calculate
formulae
Copper
Cu
RAM= 64
(a)Mass of 1 mol = g
(b) Mass of 2 mol = . g
(c)Mass of mol = .g
(d)Mass of 3.01x1023 Cu atoms
=
Sodium hydroxide
NaOH
RFM= 40
34 | P a g e
(b) Number of moles of sodium hydroxide in
20 g =
Zinc nitrate
Zn(NO3)2
RFM =
LO 3.4 ANALYSING THE RELATIONSHIP BETWEEN THE NUMBER OF MOLES OF A GAS WITH ITS VOLUME
Activity 1 : Calculate the volume of gases at STP or room conditions from the number of moles and vice versa,
1. The molar volume of a gas is defined as the
.
2. One mole of any gas always has the under the same temperature and pressure.
3. The molar volume of any gas is
24 dm3 at or
22.4 dm3 at .
Example :
1 mol of oxygen gas, 1 mol of ammonia gas, 1 mol helium gas and 1 mol sulphur dioxide gas occupies the same volume of 24 dm3 at room
condition.
35 | P a g e
x 22.4 / 24 dm3
Number of moles of gas
Volume of gas
22.4/24 dm3
e) 0.1 moles of N2
Volume =
f) 1.5 mol of N2
Volume =
36 | P a g e
5. Complete the diagram below .
Volume of gas (dm3)
Mass in gram
Number of moles
No of particles
Activity 2 : Solve numerical problems involving number of particles, number of moles, mass of substances and volume of gases at STP or room
conditions.
Solve these numerical problems
1.
What is the volume of 0.3 mole of sulphur dioxide gas at STP? [Molar volume: 22.4 dm3 mol-1 at STP]
2.
37 | P a g e
3.
4.
5.
Calculate the number of water molecules in 90 g of water, H2O. [Relative atomic mass: H, 1; O, 16. Avogadro constant, NA: 6.02 x 1023
mol-1]
38 | P a g e
6.
Calculate the number of hydrogen molecules contained in 6 dm3 of hydrogen gas at room conditions. [Molar volume: 24 dm3 mol-1 at
room conditions Avogadro constant, NA: 6.02 x 1023 mol-1]
39 | P a g e
SOLVING NUMERICAL PROBLEMS INVOLVING EMPIRICAL FORMULA
1. 24g of element X combines with 32 g of sulphur to form a compound. Determine the empirical formula of the compound? [RAM: X; 6,
S; 32 ]
2. 1.72g of M oxide contains 0.8g oxygen. Determine the empirical formula of M oxide.
[RAM : M; 46, O; 16 ]
3. A sample of carbon disulfide, CS2, contains 16g of sulphur. Determine the mass of carbon in the sample. [RAM: S; 32, C; 12 ]
40 | P a g e
4. 11g of element A combines with 6.4g of element B to form a compound AB2, Calculate the relative atomic mass of element A. [RAM :
B; 16 ]
5.
An oxide of sulphur contains 40% sulphur. Calculate its empirical formula. [RAM: S; 32, O; 16 ]
6. Element M combines with fluorine to form MFx. Determine the value of x if 2.28g of fluorine combines with 3.8g of element M.[RAM :
M; 190, F; 19 ]
41 | P a g e
EXERCISE 1 : EMPIRICAL FORMULA AND MOLECULAR FORMULA
a)
Write the empirical formula of the following compounds in the table below.
Molecular Formula
Empirical Formula
C2H4
C4H8
C6H12O6
H2SO4
MgO
b)
A compound has empirical formula of C4H9 and relative molecular mass is 114. Determine the molecular formula of the compound.[
RAM: C; 12, O; 16]
42 | P a g e
c)
A compound has the empirical formula CH and relative molecular mass is 78. Determine its molecular formula. [RAM : C; 12, H; 1 ]
1.
Diagram 1
Mass of combustion tube
Mass of combustion tube + metal X
Mass of combustion tube + oxide of X
a.
b.
=
=
=
24.56 g
25.16 g
25.56 g
43 | P a g e
c.
d.
How do you determine that all metal X has completely reacted with oxygen?
............................................................................................................................................................................................................................
............................................................................................................................................................................................................................
i.
Determine the empirical formula for the oxide of metal X.
ii.
Write the chemical equation for the above reaction
................................................................................................................................................
CHEMICAL FORMULA OF COMPOUNDS
Write the formula for the ionic compounds listed below.
sodium chloride
ammonium sulphate
calcium carbonate
zinc sulphate
Magnesium sulphate
sulphuric acid
calcium nitrate
sodium hydride
silver nitrate
magnesium hydroxide
44 | P a g e
iron (II) nitrate
Lead(II) nitrate
zinc sulphide.
Potassium sulphate
Copper(II) sulphate
barium hydroxide
aluminium oxide
calcium carbonate
K2 Cr2 O7
NH4 NO3
Al2 (OH) 3
NaBr
BaCO 3
PbI2
CaSO4
MgH2
Fe (OH) 3
45 | P a g e
ZnSO4
CuCO3
Li2 SO4
Ag2 CrO4
SnO
(NH4) 2 SO4
CH3 COOH
Na2 CO3
QUESTION
2 Li + 2 H2O 2 LiOH + H2
Lithium atom has 0.5 mol, find the number of mole for :
a) water
b) lithium hydroxide
c) hydrogen gas
ANSWER
a)
b)
c)
46 | P a g e
2
Zn + 2 HCl ZnCl2 + H2
a) How many moles of hydrochloric acid are needed to
react with 0.2 mol of zinc ?
b) How many moles of hydrogen gas are produced from
0.6 mol of HCl?
a)
b)
2 H2O2 2 H2O + O2
When 0.02 mol of H2O2 decomposes, calculate
a) the mass of water formed[Ar H = 1 , O =16]
b) the volume of O2 gas evolved at s.t.p
[1 mol of gas occupied 22.4 dm3 at s.t.p]
a)
b)
2 Mg + O2 2 MgO
Calculate the mass of magnesium oxide which is formed
when 1.2 g of magnesium is burn in oxygen .
[Ar O = 16 , Mg = 24 ]
Ans : 1.0 g
47 | P a g e
WORKSHEET 1 -IONIC BOND
ANSWER ALL QUESTIONS.
Exercise 1 : Write the half equation for the:
a) Formation of cation from a metal atom
i)
Li : _____________________
ii)
Na:_____________________
iii)
K : _____________________
iv)
Mg:_____________________
v)
Ba:_____________________
i)
Pb:______________________
48 | P a g e
Exercise 3: Explain the formation of ionic bond in magnesium chloride.(Proton no: Mg;12, Cl; 17)
Covalent Bonds
Activity 1 : Formation of covalent bonds
Fill in the blanks with the correct words.
1 Covalent bonds are formed when .. atoms .. electrons to achieve . electron
arrangements .
2 Types of covalent bonds:(i)
(ii)
(iii)
3
49 | P a g e
5
(a)
both atoms
Complete the diagram below.
50 | P a g e
(b) Illustrate the formation of oxygen molecule using the Lewis structure.
(b) Illustrate the formation for nitrogen molecule using the Lewis structure.
51 | P a g e
Appendix 1
Complete the following table for the electrolysis of 0.5 mol dm-3 sodium nitrate, NaNO3 solution using carbon electrode.
Set up of apparatus
Half equation
Name of the products
Observations
Confirmatory test (method
and observation)
Anode
Cathode
52 | P a g e
Changes in electrolyte
Appendix 2
Complete the following table for the electrolysis of 0.5 moldm-3 copper (II) nitrate, Cu(NO3)2 solution using carbon electrode.
Set up of apparatus
Half equation
Anode
Cathode
53 | P a g e
Name of the products
Observations
Confirmatory test (method
and observation)
Changes in electrolyte
Appendix 3
Complete the following table for the electrolysis of 0.5 moldm-3 sodium sulphate, Na2SO4solution using carbon electrode.
Set up of apparatus
Anode
Cathode
54 | P a g e
donate electron)
Half equation
Name of the products
Observations
Confirmatory test (method
and observation)
Changes in electrolyte
55 | P a g e
Appendix 4
EXERCISES
1
Diagram 1 shows the electrolysis of copper (II) sulphate solution using carbon electrodes.
(a)
(b)
(c)
(d)
Diagram 1
Determine the cathode and the anode electrodes.
(i) State all the ions present in the dilute copper (II) sulphate solution.
(ii) Write down the half equation for the reaction at electrode L.
..
(i) Name the product at electrode K in the cell.
56 | P a g e
Appendix 1
Complete the following table for the electrolysis of 0.001moldm-3 hydrochloric acid and 1 moldm-3 hydrochloric acid using carbon electrode.
Set up of apparatus
Electrolyte
57 | P a g e
Ion discharged (accept or
donate electron) at cathode
Set up of apparatus
Electrolyte
Ions present in electrolyte
Ion that are attracted to
anode
58 | P a g e
Ion discharged (accept or
donate electron) at anode
59 | P a g e
Appendix 3
Complete the following table for the electrolysis of 1 moldm-3 copper (II) sulphate solution with carbon electrode and copper electrode.
Set up of apparatus
Electrode
Carbon
Copper
60 | P a g e
Ion discharged (accept or
donate electron) at cathode
Appendix 4
1
Diagram 1 shows the apparatus set up to investigate the electrolysis of 1.0 mol dm-3 sodium chloride solution using carbon electrodes.
Diagram 1
(a)
61 | P a g e
(b)
(c)
(d)
The experiment is repeated using 0.0001 mol dm-3 sodium chloride solution as the electrolyte.
(i) Name the gas produced at electrode X.
.......................................................................................................................
(ii) Write the half equation for the reaction in d(i).
......................................................................................................................
(iii) Describe a chemical test to confirm the presence of gas named in d(i).
................................................................................................................................................................................................
62 | P a g e
2.
The Diagram 2 shows the apparatus set-up for the electrolysis of silver nitrate solution using silver electrodes X and Y.
Bulb
Silver
Silver
electrode X
electrode Y
Silver nitrate
solution
Diagram 2
Based on Diagram 2, answer the following questions.
(a)
(i)
What is meant by cation?
..........
(ii)
List the ions present in silver nitrate solution
..................................................................................................................
(iii) Name the ions attracted to
anode : .............................................................................................
cathode : ................................................................................................
(b)
(i)
Name the product formed at the silver electrode X.
..........
(ii)
Write the half equation for the reaction that take place at silver electrode X.
......
(c)
(i)
The electrolysis is repeated by replacing both silver electrodes with carbon electrodes. What can be observed at anode and
cathode?
At anode: .......
At cathode: ..........
(ii)
Write the half equation
63 | P a g e
At anode: ......
At cathode..............
Topic : Electrochemistry
Sub topic : 6.6 Construct the electrochemical series using voltaic cell
Diagram 1 shows a chemical cell. / Rajah 1 menunjukkan satu sel kimia.
Diagram / Rajah 1
(a)
(i)
(ii)
(b)
(i)
(ii)
Write the half equation for the reaction that occurs at the zinc plate.
Tuliskan setengah persamaan bagi tindak balas yang berlaku pada kepingan zink.
..................................................................................................................
64 | P a g e
[1 mark]
(c)
(d)
[1 mark]
(e)
(f)
[1 mark]
The copper plate in the chemical cell above is replaced by magnesium metal and copper(II) sulphate solution is replaced by
magnesium sulphate solution.
Kepingan kuprum dalam sel kimia di atas ditukar dengan logam magnesium dan larutan kuprum(II) sulfat ditukar dengan
larutan magnesium sulfat.
(i)
What will happen to the direction of electron flow?
Apakah yang akan berlaku kepada arah pengaliran elektron?
..
[1 mark]
(ii)
Give a reason for your answer.
Berikan satu sebab untuk jawapan anda.
..
[1 mark]
Another experiment is carried out by replacing zinc plate with metal P and Q.
Table 1 shows the results.
Satu eksperimen lain dijalankan dengan menggantikan kepingan zink dengan logam P dan Q. Jadual 3.2 menunjukkan keputusan
yang telah diperolehi.
Pair of metal
Voltage / V
Negative terminal
P and Cu
2.0
P
Q and Cu
0.5
Q
Table / Jadual 1
(i)
Arrange metals P, Q and Cu in ascending order of electropositivity.
Susunkan logam P, Q dan Cu mengikut tertib menaik keelektropositifan.
..................................................................................................................
65 | P a g e
[1 mark]
(ii)
Predict the voltage for chemical cell using pair of metal P and Q.
Ramalkan voltan bagi sel kimia yang menggunakan pasangan logam P dan Q.
..................................................................................................................
[1 mark]
Topic
: Electrochemistry
Sub topic : 6.6 Construc electrohcemical Series : Predict the ability of a metal to displace another metal from its salt solution
An experiment is carried out to determine the relative position of three metals, silver,L and M, in the electrochemical series. Diagram 8.2 shows
the results of the experiment.
I
II
Grey deposit
Colourless solution
Grey deposit
Light blue solution
III
experiment
Observation
(i)
(ii)
No change
Diagram 8.2
Based on the results, arrange the three metals in order of increasing electropositivity. Explain your answer.[6 marks]
If M is copper, name the product formed in experiment II. [2 marks]
66 | P a g e
EXAMPLE OF ESSAY QUESTION.
A student is given a piece of impure silver plate. Design an experiment to
produce a sample of very pure silver metal in the laboratory.
Your answer should consist of the following:
Chemicals required
Procedures of the experiment
Diagram showing the set-up of apparatus
Chemical equation involved in the reaction
Observation
10 marks
67 | P a g e
(a)
(b)
Concentration in g dm-3
Concentration in ...................
Molar mass
5.0 g of copper(II) sulphate is dissolved in water to form 500 cm3 solution. Calculate the concentration of copper(II) sulphate solution
in g dm-3 ?
What is the mass of sodium carbonate required to dissolve in water to prepare 200 cm3 solution that contains 50 g dm-3 ?
[Answer: 10 g]
(Refer to page 123 -124 - F4 Chemistry textbook )
68 | P a g e
5
4.0 g of sodium carbonate powder, Na2CO3 , is dissolved in water and made up to 250 cm3. What is the molarity of the sodium
carbonate solution?
[Relative atomic mass: C, 12; O, 16; Na, 23]
n =
M =
V =
If the volume is in cm3 convert the volume of solution from cm3 to dm3
n= MV
1000
or
n = M x
V
1000
Calculate the number of moles of ammonia in 150 cm3 of 2 mol dm-3 aqueous ammonia.
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6
A student pipetted 20.0 cm3 of potassium hydroxide , KOH solution into a conical flask. The concentration of the alkali was 1.5 mol
dm-3 . Calculate the number of moles of potassium , KOH in the flask.
Preparation of standard solutions by Weighing method (mass of solute) :Step 1 : Calculate the mass of solute needed .
mass = n
X molar mass
= MV
X molar mass
1000
n = mass
molar mass
n = MV
1000
Example: To prepare 100 cm3 of 2.0 mol dm-3 sodium hydroxide solution.
Calculate the mass of NaOH needed. [Relative atomic mass: Na, 23 ; O, 16 ; H, 1]
mass
molar mass
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=
MV
X molar mass
1000
= 2.0 X 100 X 40
=
1000
8g
Try this:
(a) To prepare 250 cm3 of 1.0 mol dm-3 sodium carbonate solution. Calculate the mass of Na2CO3 needed. [Relative atomic
mass: Na, 23 ; O, 16 ; C, 12]
[Answer : 26.50g]
(b) 0.25 mol dm-3 solution of sodium hydroxide was prepared by dissolving x g of sodium hydroxide in 750 cm3 of water. What is
the value of x ? [Relative atomic mass: Na, 23 ; O, 16 ; H, 1]
[Answer : 7.5 g]
(Refer to page 126 - F4 Chemistry textbook )
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Step 2 :
Match the descriptions / procedures with the correct diagram below.
(a)
Wash and rinse the weighing bottle
or small beaker and filter funnel to
ensure no solute remains in any of
the apparatus used.
Transfer the dissolved solute into a
suitable volumetric flask.
(b)
(c)
(d)
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Handout : Preparation of Standard solutions by Dilution method
1
Dilution method
Step 1 : Calculate the volume of stock solution required by using the equation:M1V1 = M2V2
Example: 50 cm3 of 0.1 mol dm-3 sodium hydroxide, NaOH solution from 2.0 mol dm-3 sodium hydroxide,NaOH solution
Before dilution
M1
2.0 mol dm-3
2.0 x V1 = 0.1 x 50
V1 = 0.1 x 50
2.0
V1
?
After dilution
M2
V2
-3
0.1 mol dm
50 cm3
= 2.5 cm3
Try this: 100 cm3 of 0.5 mol dm-3 potassium manganate(VII) ,KMnO4 solution is prepared from 1.0 mol dm-3 potassium
manganate(VII) ,KMnO4 solution. Calculate the volume of the solution
[Answer : 50 cm3]
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(a)
Step 2
Match the diagram with the correct descriptions below.
Add water slowly by using a dropper to bring the level of the solution to the
calibration mark.
The volumetric flask is closed tightly and inverted several times to get a
uniform or homogenous solution.
(b)
(c)
(d)
decreases
concentration
higher
hydroxide alkali
hydrogen
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1
2
3
4
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Fill in the blanks for appropriate substances to be used to prepare insoluble salts
( Remember!!!! All insoluble salts must be prepared from two soluble substances )
Write balanced chemical equation for each reaction from 1)
a) ..+ calcium carbonate +
chemical equation:
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SALT
Precipitation
Mix solutions of two soluble substances /salts
to precipitate the insoluble salt
IS IT
SOLUBLE?
Yes
Is metal hydroxide /
metal carbonate soluble?
yes
Titration method
Mix acid and alkali to produce salt
Eg: HCl +NaOHNaCl + H2O
No
Mix acid and excess metal/ metal oxides/
metal carbonate
Eg: CuO+ H2SO4 CuSO4 + H2O
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EXIT TICKET INSOLUBLE SALT
TO PREPARE INSOLUBLE SALT (EG BARIUM SULPHATE)
Rearrange the procedures below according to the correct order of method
The mixture is filtered
The insoluble salt is then pressed between 2 filter papers to dry
50 cm3 of 1.0 mol dm-3 barium nitrate solution is poured into 50 cm3 of 1.0 mol dm-3 of sodium sulphate in a beaker
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Write a balanced chemical equation for the preparation of insoluble salt.
copper(II) sulphate
sodium hypochlorite
sodium chloride
potassium nitrate
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Calcium sulphate
MEDICAL USE
FOOD INDUSTRY
USES OF SALTS
AGRICULTURE
CHEMICAL INDUSTRY
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1) Fill in the blanks for word equation below to prepare soluble salts ( Remember!!!! All soluble salts must be prepared from acids)
a) . + magnesium magnesium sulphate + .
b) Hydrochloric acid + zinc chloride + water
c) Nitric acid + .. copper (II) nitrate+carbon dioxide + ............
d) .. + potassium hydroxide potassium nitrate +
e) Ethanoic acid + zinc ethanoat + hydrogen
f) . + calcium oxide calcium nitrate +
2) Write balanced chemical equations for reactions which make the following salts .(Remember, soluble salts must start from acids)
a) Magnesium chloride from magnesium metal
..
b) copper(II) sulphate from copper(II) oxide
..
c) sodium nitrate from sodium hydroxide
..
d) lead(II) nitrate from lead(II) carbonate
.
TO PREPARE SOLUBLE SALT ( EG SODIUM CHLORIDE) BY TITRATION METHOD
CONSISTS OF 2 STAGES
Stage 1- Determine the volume of alkali needed to neutralize acid solution by titration method
Rearrange the procedures below according to the correct order of method
Fill a burette with hydrochloric acid and record the initial burette reading
Use a pipette to draw up 25.00 cm3 of sodium hydroxide solution
1
Add hydrochloric acid drop by drop into the alkali solution . Swirl the contents of the flask.
Continue adding the acid until the indicator just turns from pink to colourless Record the final burette reading
Transfer the sodium hydroxide solution into a conical flask . Add 2 to 3 drops of phenolphthalein
Rearrange the pictures below according to the correct order of procedures
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stage 2 : TO PREPARE SALT( SODIUM CHLORIDE) FROM THE NEUTRAL SOLUTION OBTAINED FROM TITRATION METHOD
Rearrange the procedures below according to the correct order of method
The experiment is now repeated as stage 1 above but no indicator is used
1
Pour the solution of sodium chloride in an evaporating basin
Filter the sodium chloride crystals and dry them by squeezing them between sheets of filter paper
Allow the solution to cool .Crystals of sodium chloride will appear in the cool solution
Heat to evaporate most of the water. This produce a hot saturated solution of sodium chloride
The hydrochloric acid is placed in a burette and the same volume of acid is added to the flask as before. If, for example 30.5 cm3 of the
acid was used in the first experiment to just react with the alkali, then 30.5 cm3 of acid is added to the second experiment. The flask will
then contain a solution of sodium chloride without excess of acid or alkali
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Rearrange the pictures below according to the correct order of procedures
TO PREPARE SOLUBLE SALT (EG ZINC SULPHATE) BY REACTION OF ACID WITH EXCESS METAL/OXIDE
METAL/CARBONATE METAL
Rearrange the procedures below according to the correct order of method
Filter the zinc sulphate crystals and dry them by squeezing them between sheets of filter paper
Heat to evaporate most of the water. This produce a hot saturated solution of zinc sulphate.
Allow the solution to cool .Crystals of zinc sulphate will appear in the cool solution
Pour the solution of zinc sulphate in an evaporating basin
Remove the excess zinc metal by filtering
1
Add zinc powder bit by bit with stirring to hot dilute sulphuric acid until some of it no longer reacts, The acid is then used up .There is
excess zinc present
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Rearrange the pictures below according to the correct order of procedures
sodium sulphate
sodium nitrate
sodium ethanoat
potassium ethanoat
copper(II)
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Sulphuric acid
Nitric
acid
SALTS
Ethanoic acid
Hydrochloric acid