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INTRODUCTION
Since the discovery of the Bi-Sr-CaCu-O superconducting compounds [Maed
et al., 1988]1, a great deal of work has been
done to prepare the high critical temperature
(Tc) phases. The most common method used
to synthesize these superconducting oxides
is the solid state reaction method [Koyoma
et al., 1988]2, which consist of the mixing
nominal composition of high purity
compounds such as Bi2O3, SrCO3, CaCO3
and CuO. The Bi-2223 phase has attracted
considerable interest due to its higher Tc and
the potential for applications. One of the
reasons for the low critical current densities
J is the granular nature of this sintered high
Journal of Pure Applied and Industrial Physics Vol.4, Issue 1, 31 January, 2014, Pages (1-56)
36
H. S. Singh, et al., J. Pure Appl. & Ind. Phys. Vol.4 (1), 35-38 (2014)
Bi2Sr2Ca2Cu3O10+4CO2 2)
Bi2Sr2Ca2.5Cu3.5O11+4.5CO2 3)
Bi2Sr2Ca3Cu4O12+5CO2 4)
Bi2Sr2Ca3.5Cu4.5O13+5.5CO2
Therefore entropy is a
temperature and volume. So
S = S (T,V)
v T
function
of
(1)
,
v T
Journal of Pure Applied and Industrial Physics Vol.4, Issue 1, 31 January, 2014, Pages (1-56)
(3)
H. S. Singh, et al., J. Pure Appl. & Ind. Phys. Vol.4 (1), 35-38 (2014)
Substituting the value of dE in equation (2)
and we get,
v T +
v
T + P dV
v = v
(5)
and
T v
(7)
v = Tv
(8)
Differentiating equation (8) with respect to
V at constant temperature T.
(9)
T = v
(9a)
T
dT
v
(9a)
+ v dV
(10)
This equation is applicable to
layered high temperature superconductors of
2223 system.
P dT + T dP
(11)
(4)
37
P dP
(14)
Substituting the value of d from equation
(14) in to (13).
T P dT + T dP V dP
(15)
Comparing the coefficients of equations (15)
and (13)
TP = P
(16)
And
TT = T V T = TT + V(17)
T P
(18)
From equation (18) and (19)
T = P
(19)
(20)
Journal of Pure Applied and Industrial Physics Vol.4, Issue 1, 31 January, 2014, Pages (1-56)
38
H. S. Singh, et al., J. Pure Appl. & Ind. Phys. Vol.4 (1), 35-38 (2014)
P
P
(21)
3.
4.
5.
6.
7.
8.
REFERENCES
1. Maeda H, Tanaka Y, Fukutomi M,
Asano T. A new high-Tc oxide
superconductor without a rare earth
element, Jpn. J. Appl. Phys. 27:L209L210 (1988).
2. Koyoma S, Endo U, Kawai T.
Formation of high Tc phase of Bi-Pb-
9.
Journal of Pure Applied and Industrial Physics Vol.4, Issue 1, 31 January, 2014, Pages (1-56)