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local composition, and k is the solute partition coecient. Assuming that the material from the four dissolving secondary arms around the dendrite periphery is
re-deposited on the trunk surface over the height, h,
gives
p/h d/
dL
4pr2
2 dt
dt
Fig. 1Transverse micrograph of a directionally solidied Al6 wt pct Si alloy with the primary dendrite trunk diameters indicated. V=301 lm s1, GL=150 K cm1[9].
2
d/
Dl C
32
dt
ml CL 1 k
3
Dl C
t:
ml CL 1 k
4
Equation [4] now represents the primary trunk diameter in terms of its initial diameter, /0.
Noting that the composition, CL, along the length
varies from the dendrite tip (approximately the bulk
composition, Co) to the composition at the eutectic, CE,
another representation of the coarsening of the trunk
diameter can be obtained. Here CL= Co+VGt/ml,
where V is growth speed and G is the thermal gradient in
the mushy zone. Substituting into Eq. [3] results in
/2
dt ml CL 1 kr2
1
d/
Dl C
32
:
dt
ml 1 kCo 1 mVGt
l Co
5
Dl C
VGt
ln 1
:
VG1 k
ml Co
6
Fig. 4Plot of the initial trunk diameter to the tip radius as a function of material properties and phase diagram parameters as determined from Esakas[21] directional solidication experiments with
succinonitrile-acetone alloys.
ml Co
Dl C
/30 :
ln
7
/3 96
VG1 k : 1 VGt0 ;
ml Co
be predicted by the Hunt-Lu model for cells. Somboonsuk et al. [22] have shown that the tip radius increases as
the growth velocity decreases and the cell-dendrite
transition is approached. Given that the trunk diameter
calculations presented here are based on Kirkwoods
model, deviation should be expected in the absence of
dissolving secondary arms. Using a larger initial tip
radius would yield a larger /0 and bring the calculated
trunk diameters for 4 wt pct Si alloys closer to the
experimental measurements. Since the microstructure
tends to be more cellular and less branched at low
growth speeds, often containing both morphologies in
the same sample cross-section, it would also result in an
increased scatter in the measured trunk diameter, as seen
in Figures 5 and 6. In addition, similar to hypoeutectic
Al-Cu alloys,[23] hypoeutectic Al-Si alloys also have a
tendency to develop convection-induced dendrite steepling[24] during DS, especially at low thermal gradient
and low growth speeds. This results in a non-uniform
distribution of primary dendrites across the sample
cross-section. This would also cause increased scatter in
the measured trunk diameter at low growth speeds and
low thermal gradient seen in Figures 5 and 6. In
summary the models agreement with the data validates
using the trunk diameter as a representative microstructural measure of the processing parameters during
controlled DS, particularly when the growth is clearly
dendritic.
The authors appreciate and acknowledge the support provided by NASA Grant NNX08AN49G, and
the NASA Microgravity Materials Science program.
One of the authors (RNG) wishes to acknowledge
Professor W. Kurz of the Ecole Polytechnique Federal
de Lausanne for the time in his laboratory which generated the data shown in Figures 5 and 6.
REFERENCES
1. M. McLean: Directionally Solidied Materials for High Temperature Service, Book 296, Metals Society, London, 1983, pp. 1139.
2. R. Elliott: Eutectic Solidication Processing: Crystalline and Glassy
Alloys, Butterworths, London, 1983, pp. 23275.
3. W. Kurz and D.J. Fisher: Fundamentals of Solidication, Trans
Tech Publications, Switzerland, 1992, pp. 6389.
4. R. Trivedi and K. Somboonsuk: Mat. Sci. Eng., 1984, vol. 65, pp.
6574.
5. D.J. Allen and J.D. Hunt: Metall. Trans. A, 1979, vol. 10A, pp.
138997.
6. R.N. Grugel: J. Mat. Sci., 1993, vol. 28, pp. 67783.
7. K.A. Jackson, J.D. Hunt, D.R. Uhlmann, and T.P. Steward, III:
Trans. Met. Soc. AIME, 1966, vol. 236, pp. 14956.
8. S.-Z. Lu and J.D. Hunt: J. Cryst. Growth, 1992, vol. 123, pp. 1734.
9. R.N. Grugel: Mater. Charact., 1992, vol. 28, pp. 21319.
10. R.N. Grugel: Metall. Mater. Trans. A, 1995, vol. 26A, pp. 49699.
11. R. Trivedi: J. Cryst. Growth, 1980, vol. 49, pp. 21032.
12. W. Kurz and D.J. Fisher: Acta Metall., 1981, vol. 29, pp. 1120.
13. R. Trivedi: Metall. Trans. A, 1984, vol. 15A, pp. 97782.
14. S.N. Tewari: Mat. Sci. Eng., 1990, vol. A130, pp. 21929.
15. J.D. Hunt and S.-Z. Lu: Mat. Sci. Eng., 1993, vol. A173, pp. 79
83.
16. J.D. Hunt and S.-Z. Lu: Metall. Mater. Trans. A, 1996, vol. 27A,
pp. 61122.
17. R.A. Pratt and R.N. Grugel: Mater. Charact., 1993, vol. 3, pp.
22531.
18. M.A. Tschopp, J.D. Miller, A.L. Oppedal, and K.N. Solanki:
Metall. Mater. Trans. A, 2014, vol. 45A, pp. 42637.
19. R.N. Grugel: Unpublished research, Michigan Technological University, Houghton, 1981.
20. D.H. Kirkwood: Mat. Sci. Eng., 1985, vol. 73, pp. L1L4.
21. H. Esaka: Ph.D. Thesis, No. 615, Swiss Federal Institute of
Technology, Lausanne, Switzerland, 1986.
22. K. Somboonsuk, J.T. Mason, and R. Trivedi: Metall. Trans., 1984,
vol. 15A pp. 96775.
23. M. Burden, D. Hebditch, and J.D. Hunt: J. Cryst. Growth, 1973,
vol. 20, pp. 12124.
24. M.A. Lauer, L. Johnson, M. Ghods, D.R. Poirier, S.N. Tewari,
and R.G. Erdmann: Unpublished research, The University of
Arizona, Tucson, Arizona 85721.