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This document discusses properties of natural gas and condensate reservoir systems. It describes how retrograde condensation can occur when reservoir pressure declines below the dew point pressure, causing liquid to condense out of the gas phase. This leaves the produced gas with a lower liquid content. The condensation reduces the value of the reservoir fluids that can be recovered. For retrograde condensation to occur, the initial reservoir conditions must exist in the area marked with an X on a pressure-temperature phase diagram.
This document discusses properties of natural gas and condensate reservoir systems. It describes how retrograde condensation can occur when reservoir pressure declines below the dew point pressure, causing liquid to condense out of the gas phase. This leaves the produced gas with a lower liquid content. The condensation reduces the value of the reservoir fluids that can be recovered. For retrograde condensation to occur, the initial reservoir conditions must exist in the area marked with an X on a pressure-temperature phase diagram.
This document discusses properties of natural gas and condensate reservoir systems. It describes how retrograde condensation can occur when reservoir pressure declines below the dew point pressure, causing liquid to condense out of the gas phase. This leaves the produced gas with a lower liquid content. The condensation reduces the value of the reservoir fluids that can be recovered. For retrograde condensation to occur, the initial reservoir conditions must exist in the area marked with an X on a pressure-temperature phase diagram.
22 Properb'es of Nslorsl Gases and Condensate Syslems
Oil rerervoirr Candenrate Gas rerervoin
I i Fig. 2.2 Pressure-temperature phase diagram of a reservoir fluid Fig. 2 3 Phase daagrarns of a cap gas and oil lone fluid showing ( a) retrograde capgas and (b) nanretrograde cap gas. (After Craft and Hawkins.) begins from the reservoir and pressure declines, no change in the state of the reservoir fluids occurs until the dew point pressure is reached at 2700 psia, point r). - . Below this pressure a liquid condenses out of the reservoir fluid as a fog or dew. This is not considered to be a normal situation since, for most hydrocarbon fluids, a pressure reduction tends to increase the amount of gas. Therefore, this behavior is usually referred to as retrograde condensation, signifying that vapor- ization generally occurs during isothermal expansion rather than condensation. The condensation leaves the-gas phase with a lower liquid content. As the condensed liauidadheres to thewallsofthe wresoacesof the rock. it isimmobile. * . Thus, the gas produced at the surface will have a lower liquid content, and the producing GOR will rise. As the liquefiable portions of the reservoir fluids are usually the most valuable components, the loss of part of these fluids could substantially reduce the ultimate income from the property, which must be considered in an economic evaluation. Exmination of Fig. 2.2 will show that for a reservoir fluid to exhibit the phenomenon of retrograde condensation, the initial conditions of pressure and iemperature must exist outside the phase envelope to the right of themitical point C and to the left of ooint Tor within the ohase envelo~e in the reeion marked X. - The point T is cal i d the cricondentherm and is the'maximum temperature at which two phases can exist in equilibrium (300F for the example). The process of retrograde condensation continues until a point of maximum liquid volume is reached, 10% at 2250 psia (point E). In some cases, a sufficient volume of liqu~d will be condensed in the reservoir to ~rovide mobilitv of the liauid ~hase. In such cases the surface fluid comoosition depends on the relative mobilities of the vapor and liquid in the reservoir. As production continues from point E to the abahdonment pressure 3., vaporization of the retroarade liauid occurs. This revaoorization aids liauid recoverv and mav be evidenceh by decreasing GOR on th; surface. This example assumesihat the reservoir fluid composition remains constant. Unfortunatelv. as retroaade condensation occurs. the reservoir fluid comwsi- tion changes and the P-?envelope shifts, increasing retrograde liquid condinsa- tion. Generally, for a particular initial hydrocarbon fluid, retrograde loss in- creases at lower reservoir temperature, higher abandonment pressure, and for greater shifting of the phase envelope to the right. As a finalillustration, considera reservoir;nitiall) at 350F and 3600 psia, revresented bv voint 4, in Fia. 2.2. Since theinttialreservoirconditionsexist tothe . - right of the criti'calpoint Cand outside the phase envelope, the reservoir fluid will be 100% gas. Furthermore, since the reservoir temperature exceeds the cricon- dentherm T, at no point in the isothermal depletioncycle (alongpath4,-4.) is the phase envelope crossed. Therefore, the fluid in the reservoir never changes composition; it is always in the gaseous state. However, after the reservoir fluid leaves the reservoir and enters the well- bore, the temperature, as well as the pressure, will decline until surface tempera-