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5070/11
CHEMISTRY
Paper 1 Multiple Choice
May/June 2011
1 hour
Additional Materials:
*2659209702*
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1
Copper(II) sulfate crystals are separated from sand using the four processes listed below.
In which order are these processes used?
1st
2nd
3rd
4th
filtering
dissolving
crystallising
evaporating
filtering
dissolving
evaporating
crystallising
dissolving
evaporating
filtering
crystallising
dissolving
filtering
evaporating
crystallising
A drop of liquid bromine is placed in the bottom of a gas jar. Brown fumes of bromine vapour
slowly spread through the covered gas jar.
Why does this happen?
Bromine molecules and the molecules in air are always moving around.
moist litmus
paper
poured in
solution X
aqueous
ammonium
chloride
mixture
heat
A gas, Y, is produced and the litmus paper changes colour.
What are solution X and gas Y?
solution X
gas Y
ammonia
chlorine
ammonia
chlorine
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3
4
16 g
32 g
64 g
70 g
A student tested a solution by adding aqueous sodium hydroxide. A precipitate was not seen
because the reagent was added too quickly.
What could not have been present in the solution?
A
Ca2+
NH4+
Zn2+
Which molecule has the largest number of electrons involved in covalent bonds?
A
Al 3+
C2H4
CO2
CH3OH
N2
sand
solid graphite
solid magnesium
Which statement about both chlorine atoms and chloride ions is correct?
A
Element X has the electronic structure 2,8,5. Element Y has the electronic structure 2,8,7.
What is the likely formula of a compound containing only X and Y?
A
XY3
X2Y3
X3Y
X3Y2
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11 The equation for the reaction between calcium carbonate and hydrochloric acid is shown.
CaCO3(s) + 2HCl (aq) CaCl 2(aq) + H2O(l) + CO2(g)
How many moles of calcium carbonate will give 24 cm3 of carbon dioxide when reacted with an
excess of the acid?
(Assume one mole of carbon dioxide occupies 24 dm3.)
A
1 mol
0.1 mol
0.01 mol
0.001 mol
13 The diagram shows the electrolysis of molten lead(II) bromide using inert electrodes.
brown gas
silvery metal
molten lead(II) bromide
heat
What happens during this electrolysis?
A
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14 Which pair of metals X and Y will produce the highest voltage when used as electrodes in a
simple cell?
V
metal X in a
solution of a
salt of X
metal Y in a
solution of a
salt of Y
porous membrane
metal X
metal Y
copper
silver
magnesium
silver
magnesium
zinc
zinc
copper
15 The energy profile diagram for the reaction between hydrogen and chlorine is shown.
H2 + Cl 2
reactants
energy
2HCl
products
reaction pathway
What information about this reaction does the diagram show?
type of reaction
endothermic
negative
endothermic
positive
exothermic
negative
exothermic
positive
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16 The following changes could be made to the conditions in the reaction between zinc and
hydrochloric acid.
1
1 and 2
1 and 4
2 and 3
3 and 4
17 The equation shows what happens in a redox reaction between iron(II) chloride and chlorine gas.
2FeCl 2 + Cl 2 2FeCl 3
Which equation describes the reduction process in this reaction?
A
2Cl Cl 2 + 2e
Cl 2 + 2e 2Cl
Fe2+ Fe3+ + e
Fe3+ + e Fe2+
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19 A solution of fertiliser was tested as shown.
fertiliser
solution
green
precipitate
forms
warm the
mixture
Which ions must be present in the fertiliser?
A
calcium carbonate
calcium hydroxide
calcium oxide
calcium sulfate
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22 Which deduction about the element astatine, At, can be made from its position in Group VII?
A
It is a gas.
23 Which pair of properties are both correct for a typical transition element?
property 1
property 2
soluble in water
high density
low density
24 The diagram represents the manufacture of sulfuric acid by the Contact process.
sulfur
sulfur
trioxide
sulfur
dioxide
sulfuric
acid
vanadium(V) oxide
water only
25 What happens when zinc foil is placed in an aqueous solution of copper(II) sulfate?
A
There is no reaction.
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26 In the apparatus shown, gas P is passed over solid Q.
Q
P
heat
No reaction occurs if P and Q are
P
hydrogen
lead(II) oxide
hydrogen
magnesium oxide
oxygen
carbon
oxygen
sulfur
27 Which element can only be extracted from its ore using electrolysis?
A
calcium
copper
lead
silver
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30 Aluminium is higher than copper in the reactivity series so the following displacement reaction
should be feasible.
2Al (s) + 3CuSO4(aq) Al 2(SO4)3(aq) + 3Cu(s)
The reaction does not take place at room temperature.
What is the reason for this?
A
carbon monoxide
chlorofluorocarbons
methane
sulfur dioxide
alkane
alkane
alkene
alkene
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34 Useful fractions are obtained by the fractional distillation of petroleum.
Which fraction is matched by its use?
fraction
use
bitumen
fuel in cars
lubricating oils
paraffin (kerosene)
petrol (gasolene)
aircraft fuel
It is insoluble in water.
CO
C=O
NC
NH
37 Compounds X and Y are both alkanes. Compound X has a higher boiling point than compound Y.
What could be the formulae of compounds X and Y?
compound X
compound Y
C8H16
C9H18
C8H18
C9H20
C9H18
C8H16
C9H20
C8H18
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38 Four hydrocarbon structures are shown.
H
H H
H H
H
1
H
H
H
H
H
H
4
1, 2 and 3
1, 2 and 4
1 and 2 only
3 and 4
39 With which substance will ethene react to form more than one product?
A
bromine
hydrogen
oxygen
steam
40 When a compound X is reacted with sodium carbonate, carbon dioxide gas is evolved.
What could be the formula of compound X?
A
C2H5CO2CH3
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C3H7CO2H
CH3CO2C2H5
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C4H9OH
13
BLANK PAGE
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BLANK PAGE
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BLANK PAGE
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UCLES 2011
Magnesium
Sodium
Calcium
5070/11/M/J/11
Strontium
Key
X = atomic symbol
Actinium
Ac
89
Ra
Radium
88
Fr
Francium
87
Hafnium
72
Lanthanum
57
178
Hf
40
Zirconium
Zr
91
Titanium
139
Yttrium
22
48
Ti
La
39
89
Scandium
21
227
Barium
56
Caesium
45
Sc
226
55
137
Ba
133
Cs
38
Rubidium
37
88
Sr
85
Rb
20
Potassium
19
40
Ca
39
12
24
Mg
23
Na
Beryllium
Lithium
11
Be
II
Li
93
Ta
181
Niobium
Nb
90
58
73
52
96
Mo
184
Protactinium
Thorium
55
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
27
59
28
59
29
64
30
65
Ru
101
Iron
190
Pm
Osmium
Os
Np
93
Neptunium
61
Promethium
76
44
Ruthenium
26
56
Fe
Sm
150
Iridium
Pu
94
Plutonium
62
Eu
152
Platinum
Am
95
Americium
63
Europium
78
195
Pt
192
46
Palladium
Pd
106
Nickel
Ni
Ir
Samarium
77
45
Rhodium
Rh
103
Cobalt
Co
Gd
157
Gold
Au
197
Silver
96
64
Curium
Cm
Gadolinium
79
47
Ag
108
Copper
Cu
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
70
Dy
162
Thallium
Tl
204
Indium
Cf
98
Es
Holmium
Ho
165
Lead
Pb
207
Tin
99
Einsteinium
67
82
50
119
Sn
32
115
Californium
66
Ge
73
Silicon
Si
28
Carbon
Germanium
14
12
In
Gallium
Ga
Dysprosium
81
49
31
13
Aluminium
Al
27
Boron
11
75
Sb
122
Arsenic
As
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
14
Se
79
Sulfur
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
32
Oxygen
16
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
VII
Hydrogen
VI
He
IV
III
1
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
Ce
Tantalum
41
23
Vanadium
51
Group
DATA SHEET
The Periodic Table of the Elements
16
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University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.