APPENDIX I

Crystallographic Data for Various Polymers. III

The following table has been compiled by R. L. Miller and L. E. Nielsen and is a further revision and extension of
their previous data tables.* The various entries are mostly self-explanatory. Unless otherwise noted all entries in a
given row were obtained from the reference noted in column 2. The compilers of the table have made no attempt to
assess the completeness of the table nor the validity of the data. The references listed in the table are not included in
the author index.

References for Crystallographic Data Table

Note that these abbreviations have been used: Atti (Mem) = Atti accad. nazl. Lincei Mem., Classe sci. fis. mat. e
nat; Atti = Atti accad. nazl. Lincei Rend., Classe sci. fis. mat. e nat.

1. H. Tadokoro, K. Kozai, S. Siki, and I. Nitta, J. Polymer Sci., 26, 379 (1957).
2. W. P. Slichter; J. Polymer Sci., 35, 77 (1959).
3. D. R. Holmes, C. W. Bunn, and D. J. Smith, J. Polymer Sci., 17, 159 (1955).
4. W. J. Dulmage, J. Polymer Sci., 26, 277 (1957).
5. A. Prietzschk, Kolloid-Z., 156, 8 (1958).
6. R. L. Miller, unpublished results.
7. G. Natta and P. Corradini, J. Polymer Sci., 20, 251 (1956); Atti, 19, 229 (1955).
8. G. Natta, I. W. Bassi, and P. Corradini, Makromol. Chem., 18-19, 455 (1956).
9. G. Natta, P. Corradini, and I. W. Bassi, Atti, 19, 404 (1955).
10. G. Natta, SPE Journal, 15,373 (1959).
11. C. W. Bunn and E. R. Howells, Nature, 174, 549 (1954).
12. G. Natta, L. Porri, P. Corradini, and D. Morero, Atti, 20, 560 (1956).
13. G. Natta, P. Corradini, and G. Dall Asta, Atti, 20, 408 (1956).
14. C. W. Bunn, Trans. Faraday Soc., 35, 482 (1939).
15. E. R. Walter and F. P. Reding, J. Polymer Sci., 21, 561 (1956).
16. M. L. Miller and C. E. Rauhut, J. Polymer Sci., 38, 63 (1959).
17. G. Natta, J. Polymer Sci., 16, 143 (1955).
18. C. C. Price, M. Osgan, R. E. Hughes, and C. Shambelan, J. Am. Chem. Soc., 78, 690 (1956).
19. G. Natta, P. Corradini, and M. Cesari, Atti, 21, 365 (1956).
20. C. Legrand, Acta Cryst., 5, 800 (1952).

* R. L. Miller and L. E. Nielsen, "Crystallographic Data for Various Polymers," J. Polymer Sci., 44, 391
(1960) and 45, 643 (1961).

513

(continued)
Crystallographic Data for Various Polymers


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
A. HYDROCARBONS
Polyethylene 14 Ortho

!
D
2h
16
7.40 4.93 2.534 2 1.00 0.852
57
110 1.88
85
Z
*28.05*
g

15 7.36 4.92 2.534 1.014
137
85
1.84
86

138 0.855
141
206
1.86
156


(second form) 68
Pseudo-
mono
4.05 4.85 2.54 1 0.965
(single crystal) 72 Tri 7.84 5.56 120 # = 105 48
1.013
f

Polypropylene: 63, 71, 82
Isotactic 19, 127 Mono

!
C
2h
6
6.65 20.96 6.50 12 0.936 0.85
45
176
10
2.37
82
3-1
67

6 6.666 20.87 6.488 " =!99.3 0.937
2.60
83

131 6.64 20.88 6.51 " =!98.2
136 Mono

!
C
2h
5
6.69 20.98 6.50* " = 98.7 12 0.9323 0.8535 3-1
170 Tri

!
C
i
1
13.36 6.50* 10.99 " = 99.5 12
II. 166 Hex 12.74 12.74 6.35 87, 108, 99
0.88
167


196 Rho

!
D
3
4
or

!
D
3
6
6.38 6.38 6.33 3
Syndiotactic 67 Ortho 14.50 5.81 7.3 8
0.91
f

169 Ortho

!
D
2
5
14.5 5.8 7.4 8 0.90 H
Polyethylidene 178 12.38 6.28 2.5
Polystyrene 67 Rho

!
C
3v
6
21.90 21.90 6.63 18 1.12
45
1.04 to 240
10
2.15
89
3-1
*104.14* 128 6.65 1.126
1.065
17
250
90
2.00
174


6

!
D
3d
6
22.08 22.08 6.626 1.111
139 1.024
Polybutene-1
I 35, 126 Rho

!
D
3d
6
17.7 17.7 6.50 18 0.95
12
0.87
45
126
12
3.33
82
3-1
67
II 9 Tet 7.49 7.49 6.85 0.96 4-1
207 Tet 14.89 14.89 20.87 44 0.89 11-3
Polypentene-1 80 8.60
75
48

*70.13*
80
9

Polyhexene-1 48 -55
*84.16*

(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Polyheptene-1 48 -40
*98.18*
Polyoctene-l 48 -38
*112.21*
Polydodecene-l 48 45
*168.31*
Polyoctadecene-1
80
6


*252.47*
100
90


Polyisobutene 34 Ortho

!
D
4

6.04 11.96 18.83 16 0.937
0.912
52
128
9
2.87
82

H
*56.10* 115 8-5
139 0.842
Polyisopropylethylene 82 310 4.130
Polyisobutylethylene 82 235 4.710
Poly-alternating-ethylene-
butene-2
191 9.15 0.87 135
*84.16*
1,2-Polybutadiene,
Syndiotactic *54.09* 7 Ortho

!
D
2h
11
10.98 6.60 5.14 4 0.063 114 Z
Isotactic 12 Rho

!
D
3d
6
17.3 17.3 8.5 18 0.96 120 3
152

1,4-trans-Polybutadiene 37
Pseudo-
hex
4.54 4.54 4.9 1 1.02
148
44
Z
(Above 65) 154
Pseudo-
hex
4.88 4.88 4.88
*54.00*
1,4-cis-Polybutadiene 36 Mono

!
C
2h
5
4.60 9.50 8.60 "!= 100 4 1.01 Z
*54.09* 124 1
1,4-trans-Poly-2,3-
dimethyl-1,3- butadiene
104 4.35 260
*82.14*
1,4-trans-Poly-1,1,4,4-
tetramethyl-1,3- butadiene
183 4.8 265
1,4-cis-Polyisoprene 40 Mono

!
C
2h
6
12.48 8.80 8.10 "! = 92 8 1.001
f
0.906
53
28
81
1.05
81
Z
*68.11*
1,4-trans-"-Polyisoprene 23 Ortho

!
D
2
4
7.78 11.78 4.72 4 1.11
f
65
46
3.04
81
H
*68.11*
74
81



(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
"! "!
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
1,4-trans-Polypentadiene 37
Pseudo-
hex
5,25 5 25 4.82

1 0.98 Z
*68.11* 199 Ortho 19.73 4.85 4.8
4 95
Poly-3-methylbutene-1 9 Mono 9.55 8.54 6.84 # = 116.5 4 0.93
300
48


4
152

*70.13*
310
90


Poly-4-methylpentene-l 55 Tet

!
S
4
1
18.66 18.66 13.80 28 0.813
235
48
7-2
67

*84.10* 67 18.60 18,60 13.84
0.816
f

94 0.828 0.838 250
Poly-4-methylhexene-1 9 14.00 200
*98.18* 67 Tet 19.64 19.64 16 0.912
52
7-2
Poly- 5-methylhexene-1 9 Hex 10.2 10.2 6.50 0.84 130
3-1
67

*98.18*
Poly-5-methylheptene-1 67 6.40 3-1
*112.21* 129 52
Poly- 3-
cyelopentylpropene
0.87
225
90


*110.19*
Poly-3-eyclohexylproprne
230
90


*124.22*
Poly-4,4-dimethylpentene
350
90


*98.18* 1
Poly- 4,4-dimethylhexene
*112.21*
Polyacetylene 69
Pseudo-
hex
4.2 4.2 2.43 4 1.15 Z
*26.04*
Polyvinylcyclopropane 175 6.5 230 H
*68.11*
Polyvinylcyclnpentane 95 Tri 10.5 7.4 6.6 92, 108, 99 3 0.986
*180.15*
Polyvinyleyclohexane 60 Tet

!
C
4h
6
21.9 21.9 6.5 16 0.95
305
90

*110.19* 67 21.76 21.76 6.50 0.906
53
4-1
95 Tri 11.6 7.8 6.6 92, 108, 98 3 0.982
Poly-o-methylstyrene Tet

!
C
4v
12
19.01 19.01 8.10 16 1.071
f


360
74
4-1
*130.18* 67, 125


(continued)

Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, "!", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Poly- m-methylstyrene 67,80 Tet

!
S
4
1
19.81 19.81 21.74 44 1.010
f
215
7
11-3
*130.18* 163 57.1 29-8
103 57.0
Poly-p-methylstyrene 103 12.9
*130.18*
Poly- 2,4-dimethylstyrenc 75 310
*144.21* 74 350
Poly- 2,5-dimethylstyrenc 75 330
*144.21* 74 340
Poly-3,5-dimethylstyrenc 75 290
*144.21*
Poly-3,4-dimcthylstyrene 75 240
*144.21*
Poly-3-phenylpropene-1 67
230
90

3-1
*118.17*
Poly- 3-phenylbutcne
360
90


*133.20*
Poly- 4-phenylbutenc 67
160
90

3-1
*132,20*
Poly- !-vinylnaphthalene 67, 122 Tet

!
S
4
1
21.20 21.20 8.10 16 1.124
f
300
75
4-1
*154.20*
Poly-p-xylene 142 1.14 375 7.20
*82.14*
Polyallylbenzene 187 208
Poly-o-allyltolnenc 187 290
Poly-m-allyltoluene 187 180
Poly-p-allyltoluene 187 240
Poly-2-allyl-p-xylene 187 338
Poly-4-allyl-o-xylene 187 275
Poly-5-allyl-m-xylene 187 252
Poly-4-phenyl-1-butene 187 68

(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Poly-4- (o-tolyl)-1-butene 187 235
Poly-4- (p-tolyl)-1-butene 187 196
B. VINYL POLYMERS
Polyvinyl chloride 7 Ortho

!
D
2h
11
10.6 5.4 5.1 4
f
1.44 1.39
41
190 Z
*62.50* 64 Ortho 10.11 5.27 5.12
1522
f


212
142
0.66
145


140 Mono 10.65 5.15* 5.20 " = 90 4 1.455
Polyvinylidene chloride 32 Mono 13.69 4.67* 6.296 " = 55.2 4 1.949
1.66
43
190
46
4
*95.95* 33 Mono 22.54 4.68* 12.53 " = 84.2 16 1.959
Polytetrafluoroethylene
below 20 C 11, 154
Pseudo-
hex
5.54 5.54 16.8 # = 119.5
2.40
f

*100.02* 209 H
Tri 5.59 5.59 16.88 # = 119.3 13-6
above 20 C 11 Hex 5.61 5.61 16.8
2.36
f

330
0.685
91

15-2
209 Hex 5.66 5.66 19.50
2.304
66


330
101
15-7
Polychlorotrifluoroethylene 21 Hex 6.5 6.5 35 14 2.10 14-1
208 Hex 5.34 5.34 35
2.19
49
2.08
49
220
49
1.20
88


116 2.032
139 1.925
205 43 16 16-1
Polyvinyl alcohol 29 Mono

!
C
2h
2
7.81 2.52** 5.51 " = 91.7 2
f
1.35
f
1.291
1
Z
132 7.805 2.533 5.485 " = 92.2
1.26
53


184 1.345 1.269
Polymethylmethacrylate
Isotactic 30
Pseudo-
ortho
21.08 12.17 10.55 20 1.23
1.22
31
160
31
5-2
*50051*
Syndiotactic 30
1.19
31
200
31
10-4
Polyisopropylacrylate
Isotactic 67 6.5
162
120
3-1
*114.14*

(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Poly-n-butylacrylatc 202 47
Poly-t-butylacrylatc 67 6.45 193
16
3-1
*125.17* 192 6.49 3-1
202 17.92 10.50 6.48 104 200 3-1
Polyisobutylacrylate 192 6.42
202 17.92 17.92 6.42 1.24 81 3-1
Poly-sec-butylacrylatc 192 6.49
202 17.92 10.34 6.49 1.06 130 3-1
Poly-n-propyl thiolacrylate 200 6.4
Polyisopropyl thiolacrylate 200 6.42
Pnlyisnbutyl thiolacrylatc 201 6.42
Poly-sec-butyl
thiolacrylate 201 6.35
Polyvinyl fluoride 62 Hex 4.93 4.93 2.53 1 1.44 200
79
1,80
79
Z
*46.04*
Pnlyvinylidene fluoride 171 Mono 5.02 25.4* 4.62 " = 107 H
*64.02*
Polyacrylonitrile
Syndiotactic 76 Hex 5.99 5.99 317
77
1.16
77

*53.06* 133 Ortho

!
C
2v
16

10.20 6.10 5.10 4 1,11 z
162 Ortho 18.1 6.12 5.00 8 1.27
210 Ortho 10.55 5.80 4 1.135
Isotactic 133 Tri 4.74 4.74 2.55 1.54
Polyvinylidene bromide 33 Mono 25.88 4,77* 13.87 " = 70.2 16 3.065 Z
*185.87*
Pnlychloroprene 109 Ortho 9.0 8.23 4.79 4 1.657
f
80
81
2.00
81

*88.54*
Poly- 1-mcthoxybutadiene 112 118 Z
*54.11*
Pnlytetrafluoroallene 38 Tet

!
C
4
2
-

!
D
4
3

6.88 6.88 15.4 8 2.02 126 Z
*113.03*

(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Poly-o-fluorostyrene 70 Rho 20.4 20.4 6.63 18
1.526
f


270
75


73

!
C
3v
6
22.1 22.1 6.65 1.296
f

123 Rho 22.15 22.15 6.63 1.29
168 3-1
Poly-p-fluorostyrene 70 8.30
265
75


*122.14* 168 4-5
Poly-o-methyl-p-
fluorostyrene
70 8.05
3-1
67

*136.16*
Polyrrimethylsilyl styrene 103 60.4 284
Polytrimethylallylsilane 70 6.50
360
71

H
Polyallylsilane 70 6.45
128
71

H
Poly-5(trimethylsilyl)-
pentene-1
70 6.55
133
71

H
Poly-2-methyl-4-
fluorostyrene
168
360
75

4-1
*136.16*
Poly-n-isopropyl
acrylamide
102 1.118 1.070 200
*113.16*
Poly- (N,N-di-n-butyl
aerylamide)
93 Hex, 26.3 26.3 6.3 12 1.06 3-1
*183.29*
C. POLYESTERS
Polyethylene terephthalate 27 Tri
!

!
C
i
1
4.56 5.94 10.75 98, 118, 112 1 1.455
1.335
7

265
5.82
87


*192.16* 195 5.54 4.14 10.86 107, 112,92 1.498 1.337
3.98
155


Polytrimethylene
terephthalate
99 233
5.40
157


*206 l8*
Polytetramethylene
terephthalate
99
1.08
111

232
7.6
111


*220. 21*
Polypentamethylene
terephthalate
99 134
*334 23
Polyhexamethylene
terephthalate
68 Tri 4.57 6.10 15.40 105, 98, 114 1
1. 131
f

160
81
8.3
81


*248.27* 99 154
8.44
159



(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Polyoctamethylene
terephthalate
99 132
*276.31*
Polynonamethylene
terephthalate
99 85
*290.34*
Polydecamethylene
terephthalate
68 Tri 4.62 6.30 20.10 107, 96, 113 1
1.012
f


138
81
11.00
81


*304.37* 99 129
Poly- 1,4-
cyclohexylenedimethylene
199 Tri 6.37 6.63 14.2 89, 47, 111 1 1.265
terephthalate-cis
Poly- 1,4-
cyclohexylenedimethylene
199 Tri 6.02 6.01 13.7 89,53,112 1 1.303
terephthalate-trans
Polyethylene isophthalate 111 1.358 1.346 240
*192.16*
Polytrimethylene
isophthalate *206.18*
111 132
Polytetramethylene
isophthalate *220.21*
111 1.309 1.268 152.5 10.1
Polyhexamethylene
isophthalate
111 140
*248.27*
Polyethylene succinate 105 9.05 11.09 8.32 " = 102.8 4
1.175
f

H
*144.12* 108 Mono 5.0 7.4 8.32
Polyethylene adipate 105 25.7 30.7 11.71 " = 103.8 40
1.274
f


52
27

Z
*172.18* 108 5.0 7.4 11.71
203 Mono

!
C
2h
5
5.47 7.23 11.72 " = 113.5 2 1.34
211 Mono 7.26 5.40 10.85 ! = 67.7
Polyethylene suberate 108 Mono 5.0 7.4 14.1
55
27


*200.23* 203 Mono

!
C
2h
5
5.51 7.25 14.28 " = 114.5 2
Polyethylene sebarate 105 25.7 30.7 16.67 " = 103.8 40
1,187
f

6.11
158

Z
*228.28* 100 Mono 5.5 15 16.9 " = 65 4
1.120
f

108 Mono 5.0 7.4 16.83
76
137
695
137

Z
Polyethylene azelate 105 25.7 30.7 31.2 " = 103,8 80
1.190
f

Z
*214.25* 108 Ortho 7.45 4.97 31.5 4
1.220
f


(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Polytrimethylene succinate 107 Mono 5.0 7.4 15.2 47 Z
*158.15*
Polytrimethylene glutarate 107 Mono 5.0 7.4 15.4 39 Z
*172.18*
Polytrimethylene adipate 107 Mono 5.0 7.4 21.5 38 Z
*180.20*
Polyti'iinethylene pimelate 107 Mono 5.0 7.4 23.6 37 Z
*200 .23*
Polytrimethylene suberate 107 Mono 3.0 7.4 20.1 41 Z
*214,25*
Polytrimethylene azelate 107 Mono 5.0 7.4 27.7 50 Z
*228. 28*
Polytrimethylene sebacate 105 Tet 31.2 31.2 33.5 1.090 Z
*242,31* 107 Mono 31.3 53
Polytrimethylene-1,9-
dicarboxylate
107 Mono 5.0 7.4 32.4 59 Z
Polytrimethylene-l,10-
dicarboxylatc
107 Mono 5.0 7,4 35.8 61 Z
Polytrimethylene-1,16
dicarhoxylate
107 Mono 5.0 7.4 51.6 76 Z
Polydecamethylene
oxylate
106 Mono 5.28 7.00 17.0 Z
*228.38*
Polydecamethylene
succinate
106 Mono 5.0 7.4 19.6 Z
*256.33*
Polydecamethylene
glutarate
106 Mono 5.0 7.4 41,6 Z
*270.36*
Polydecamethylene
adipate
106 Mono 5.0 7.4 22.1
80
81
10.2
81

Z
*284.38*
Polydecamethylene
suberate
106 Mono 5.0 7.4 24.6 Z
*312.44*
Polydecamethylene azelate 106 Mono 5.0 7.4 51.7
69
137
10.0
81

Z
*326.46*
Polvdecamethylene
sebacate
106 Mono 5.0 7.4 27 1
80
137
12 0
81

Z
*340.49*
12.3
160



(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Polyethylene $-
hydroxydeconoate 108 Ortho 7.45 4.97 27.1 4
Pnlydiethylene oxide
sebacate 105 Tet 17.6 17.6 38.0 1.128
Poly-trans-
methylmethoxyethylene 141 210
*72 10*
Poly- trans-
methylethoxyethylene 141 243
*86.13*
Poly- trans-
methylisobutoxyethylene 141 13.8 226
*114.18*
Poly- trans-ethoxymetho
xy-ethylene 141 217
*102 13*
Poly-p-xylenediamine
sebacate 204 Tri 5.74 4.87 20.6 76, 55, 65 1 1.169 Z
D. POLYAMIDES
Nylon 4.10 153 254
Nylon 4.12 153 245
Nylon 5.9 2 19.5
Nylon 6.6
! 25 Tri

!
C
1

4.9 5.4 17.2 48, 77, 63 1 1.24 1.09
52
265
2
11.10
82
Z
54 1.220 1.069 9.7
155

8.79
216

" 25 Tri

!
C
i
1

4.9 8.0 17.2 90, 77, 67 2 1.248
f

Nylon 6.10
! 25 Tri

!
C
i
1

4.95 5.4 22.4 49, 76, 63 1 1.16
f
228
51
7.12
160
Z
*282.43* 153 1.17 216
54 1.152 1.041
" 25 Tri

!
C
i
1

4.9 8.0 22.4 90, 77, 67 2 1196
f

Nylon 7.7 63
Pseudo-
hex

!
C
s
1

4.82 19.9* 4.82 " = 60 1 1.108
# 65 18.95 205
2
Z
Nylon 8,10 153 207

(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Nylon 9.9 110 24.0 175
# 65
Pseudo-
hex
1
Nylon 10.6 110 20.0 230
Nylon 10.9 137 214
8.76
159


# 65
Pseudo-
hex
2
*324.49*
Nylon 10.10 110 25.6 196
8.29
159


*338.52* 65 Tri
137 216
7.82
160


Nylon 6 3 Mono

!
C
2
2
9.56 17.2* 8.01 " = 67.5 8 1.23 215 4.96
155
Z
26 Mono

!
C
2
2
4.81 17.10 7.61 " = 79,5
4
f
1.21 223
253
4.32
216

135 9.65 17.2 8.11 " = 66.3
65 2
212 Mono

!
C
2
2
9.45 8.02 17.08 " = 68
213 1.23 1.10
Nylon 7 61 Tri 4.9 5.4 9.85 49, 77, 63
1
f
1.211
f


225
146


65

!
C
1
1
-

!
C
i
1
1 1.20
153
217
153


233
215


Nylon 8 61 Hex 4.9 4.9 21.7 2
1.038
f

185
146


65
Pseudo-
hex
!
C
2
2

1. 18
153


202
153


121 Mono
Nylon 9 65 1
194
146


177 209
Nylon 10 61 Hex 4.9 4.9 26.5
1.019
f

177
146


65
Pseudo-
hex
!
C
2
2
2
192
177


Nylon 11 59 Tri 9.6 4.2 15.0 72, 90, 64 2
1.192
f


194
101


61 Tri 4.9 5.4 14.0 49, 77, 63
1.228
f


182
146


65

!
C
1
1
-

!
C
i
1
I
Nylon 12 177 179
Nylon 13 177 183
Nylon 22 177 145

(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
E. POLYETHERS


Polyvinylmethyl ether 176 Rho

!
D
3d
6
16.20 16.20 6.50 18 3-1
*58.07* 67
144
114


Polyvinylethyl ether 114
*72.10 86
Polyvinyl-n-propyl ether 114
*86 12* 76
Polyvinylisopropyl ether 114
*86.12* 161 Tet 17.2 17.2 35.5 190 17-5
Polyvioyl-n-butyl ether 114
*100.14* 64
Polyvinylisobutyl ether 8 Ortho 16.8 9.70 6.50 H
*114.17* 114
6
f
0.940
115
46

3-1
Polyvinyl-t-butyl ether 114 165
*100.14* 1.10 260
Polyvinylneopentyl ether 114
*100.14* 161 Ortho 18.2 10.5 6.50 216 3-1
Polyvinylbenzyl ether 114
Polyvinyl-2-chloroethyl
ether
114 162
Polyvinyl-2-methoxyethyl
ether
114 150
Polyvinyl-2,2,2-
trifluoroethyl ether
114 73
Polymethylpropenyl ether 113 128
Polyethylpropenyl ether 113 287
Poly- n-propylpropenyl
ether
113 230
Polytetrahydrofuran 180 168
Polyoxacyclobutane
(polytrimethylene oxide)
147 37
*58. 08* 33
Poly-3,3-bisdimethyl
oxacyclohutane
147
*86.13* 47

(continued)

Crystallographic Data for Various Polymers (continued)



Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Poly-3,3-bisethoxymethyl-
oxacyclobutane
151 83
*174.23*
Poly-3,3-bishydroxy-
methyloxacyclobutane
151 280
*118.13*
Poly-3,3-bisfluoromethyl-
oxacyclobutane -
149 135
*122.11*
Poly-3,3-bischloromethyl-
oxacyclobutane

! 148 4.8 180
*155.03*
190
173


" 172 Mono

!
C
s
1
-

!
C
d
2
6.85 11.42 4.75 " = 109.8 2 1.47
Poly-3,3-bisbromomethyl-
oxacyclobutane
150 220
*243.95*
Poly-3,3-bisiodomethyl-
oxacyclobutane *337.98*
150 290
F. CELLULOSICS
Cellulose I 22 Mono 8.35 10.3 7.9 " = 84 2 1.592 Z
28 10.34*
20

!
C
2

98 Mono 8.20 10.3* 7.90 " = 83.3 1.625
Cellulose II 22 Mono 8.14 9.14 " = 62 2 1.583 Z
28 10.34*
98 Mono 8.02 10.3* 9.03 " = 62.8 1.62
Cellulose III 28 1.62
Cellulose IV 98 Mono 8.12 10.3* 7.99 " = 90 1.61
Cellulose X 98 Mono 8.10 30.3* 8.16 " = 78.3 1.615
Cellulose trinitrate 24 Ortho 12.25 25.4* 9.0
4
f
2.07
f


697
77
0.9-1.5
77

Z

700
81


Cellulose 2,4,4-nitrate 81 617 1.35
Cellulose triacetate 4
Pseudo-
ortho
!
C
2
2
24.5 11.6* 10.43 4 1.30
306
144

Z
Cellulose tripropionate 144 145

(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Cellulose tributyrate 118 207 3.0
Cellulose tricaprylate 117 116 3.1
Cellulose trivalerate 144 122
Cellulose tricaproate 141 94
Cellulose triheptylate 144 88
Cellulose tricaprate 144 88
Cellulose trilaurate 144 91
Cellulose trimyristate 144 106
Cellulose tripalmitate 144 10,5
G. OTHER POLYMERS
Polyoxymethylene 42 Hex

!
C
3
3
-

!
C
3
4
4.46 4.46 17.30 9 1.506 1.21 181 0.890
91

134
1.59
186
9-5
Polyethylene oxide 109 9.5 19.5* 12.0 " = 101 36
1.205
f


66
81
198
81

188 Mono 7.95 13.11 19.39 " = 124.6 28 1.23 7-2
194 Mono 8.03 13.09 19.52 " = 125.1
1.47
182


Polypropylene oxide 13 Ortho

!
C
2v
9
-

!
D
2
4
10.52 4.67 7.16 4 1.096 75
18
Z
41 Ortho 10.52 4.68 7.10
1.102
f

78 Ortho

!
D
2
4
10.40 4.64 6.92 1. 154
f

139 0.998
Polytrimethylene oxide 181 34
Polyhexamethylene oxide 181 58
Polydecamethylene oxide 181 79
Poly-2-vinvlpyridine 185 6.7 212
Polystyrene oxide 164 149
Polybutadiene oxide 164 74
Polyacetone 214 Tet

!
S
4
14.65 14.65 10.22 28 60 7-2
Polyketone alternating
Et/CO
193 Ortho

!
D
2h
16
7.97 4.76 7.57 4 1.296 Z
*55 06*
Poly-t-butylvinylketone 198 150
Polyepibromohydrin
(bromomethyl ethylene
164 112
oxide)

(continued)
Crystallographic Data for Various Polymers (continued)


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Polyepichlorohydrin
chloromethyl ethylene 119 7.05 117
194 Ortho

!
D
2
40r
-

!
C
2v
9

12.14 4.90 7.07 121
Polyepifluorohydrin
(fluoromethyl ethylene 119 68
oxide)
Poly-trans-2-butene oxide 165 1 114
Poly-cis-2-butene oxide 165 162
Polyacetaldehyde 92 Tet

!
C
4h
6

14.60 14.60 4.79 16 1.14 4-1
97 14.63 14.63 4.79 1.14
Polypropionaldehyde 92 Tet

!
C
4h
6

17.52 17.52 4.78 16 1.05 4-1
Poly-n-butyraldehyde 92 Tet

!
C
4h
6

20.01 20.01 4.78 16 1.00 4-1
96 0.997
Polyisobutyraldehyde 96 Tet 5.2 4-1
Polyisovaleraldehyde 96 Tet 20.6 20.6 5.2 16 1. 037
f

Poly-bisphenol A 5 Ortho

!
D
2
2
-

!
D
2
3

11.9 10.1 21.5 8 1.30 267 Z
Polydimethylene oxide 180 62
*60 05
Polydecamethylene oxide 180 72
*172.26*
Polymethylisobutoxyethvl
ene 67 13.77 7-2
Polydiketene 190 115
Poly-"-propiolactone 190 122
Polytrioxane 190 Hex 9.26 9.26 8.60 198
Polydimethylsiloxane 197 Mono 13.0 8.3* 7.75 " = 60 6 1.07 0.98
Polyhexamethylene
sulfone 39 Mono 9.88 9.26 18.24 " = 121.7 8 1.39
f
Z
Polyhexamethylene
pentamethylene sulfone 39 Mono 9.88 9.26 34.00 " = 121.7 8 1.42
f
Z
Polyhexamethylene
tetramethylene sulfone 39 Mono 9.88 9.2(5 15.68 " = 121.7 4 1 46
f
Z



a
Tri = triclinic, mono = monoclinic, ortho = orthorhombic, tet = tetragonal, rho = rhomboliedral, and hex = hexagonal.
b
See International Tables for X-Ray Crystallography, Kynoch Press, Birmingham, England, 1952.
c
Unless otherwise noted (by *) c is the fiber axis (chain direction).
d
Unless otherwise noted, all angles are 90.
e
H = helix, Z = zigzag, figures indicate helix pitch.
f
Calculated from tabulated data.
g
Molecular weight of monomer unit.
* See footnote c.

Crystallographic Data for Various Polymers


Unit cell parameters Density, g./cc.
Polymer Ref.
Crystal
system
a
Space
group
b
a b c
c
Angles
d
!, ", #
Monomer
Units in
cell Cryst. Amorph.
M. p.,
C.
Heat of
fusion,
kcal./
monomer
unit
Chain
confor-
mation
e

Column No.: 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Polypentamethylene
sulfone
39 Mono 9.88 9.26 7.76 " = 121.7 4
1.48
f
Z
Polypentamethylene
tetramethylene sulfone
39 Mono 9.88 9.26 28.33 " = 121.7 8
1.53
f
Z
Polydimethyl ketene
I 179 8.8 4 230
130 255
II 179 170
Polymethylene sulfide 181 241
Polydimethylene sulfide 181 190
Polytrimethylene sulfide 181 100
Polytetramethylene sulfide 181 67
Polyhexamethylene sulfide 181 79
Polydeeamethylene sulfide 181 91
Polyethylene disulfide 134 8.8 8-2
Polyethylene tetrasulfide 134 4.32 4-1
530 POLYMER SINGLE CRYSTALS


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Hall, London (1955).
25. C. W. Bunn and E. V. Garner, Proc. Roy. Soc. (London), A189, 39 (1947).
26. A. Okada, Chem. High Polymers (Japan), 7, 122 (1950).
27. R. De P. Daubeny, C. W. Bunn, and C. J. Brown, Proc. Roy. Soc. (London), A226, 531 (1954).
28. H. J. Wellard, J. Polymer Sci., 13, 471 (1954).
29. C. W. Bunn, Nature, 161, 929 (1948).
30. J. D. Stroupe and R. E. Hughes, J. Am. Chem. Soc., 80, 1768 (1958).
31. T. G. Fox, B. S. Garrett, W. E. Goode, S. Gratch, J. F. Kincaid, A. Spell, and J. D. Stroupe, J. Am. Chem. Soc.,
80, 1768 (1958).
32. R. C. Reinhardt, Ind. Eng. Chem., 35, 422 (1943).
33. S. Narita and K. Okuda, J. Polymer Sci., 38, 270 (1959).
34. C. S. Fuller, S, J. Frosch, and N. R. Pape, J. Am. Chem. Soc., 62, 1905 (1940).
35. G. Natta, P. Corradini, and I. W. Bassi, Makromol. Chem., 21, 240 (1956).
36. G. Natta and P. Corradini, Angew. Chem., 68, 615 (1956).
37. G. Natta, P. Corradini, and L. Porri, Atti, 20, 728 (1956).
38. J. D. McCullough, R. S. Bauer, and T. L. Jacobs, Chem. & Ind. (London), 1957, 706.
39. H. D. Noether, J. Polymer Sci., 25, 217 (1957).
40. C. W. Bunn, Proc. Roy. Soc. (London), A180, 40 (1942).
41. C. Shambelan, Ph.D. Thesis, U. of Penna., 1959, Dissertation Abstr., 20, 120 (1959).
42. C. F. Hammer, T. A. Koch, and J. F. Whitney, J. Appl. Polymer Sci., 1, 169 (1959).
43. W. Goggin and R. Lowry, Ind. Eng. Chem., 34, 327 (1942).
44. G. Natta, Chem. & Ind. (London), 1957, 1520.
45. G. Natta, P. Pino, P. Corradini, F. Danusso, E. Mantica, G. Mazzanti, and G. Moraglio, J. Am. Chem. Soc., 77,
1708 (1955).
46. R. Boyer, Compt. Rend. de la 2E Reunion de Chimie Physique, (June 2-7, 1952, Paris), p. 383.
47. D. E. Roberts and L. Mandelkerrn, J. Am. Chem. Soc., 80, 1289 (1958).
48. F. P. Reding, J. Polymer Sci., 21, 547 (1956).
49. J. D. Hoffman and J. J. Weeks, J. Research Natl. Bur. Standards, 60, 465 (1958).
50. L. Wood, N. Bekkedahl, and R. E. Gibson, J. Chem. Phys., 13, 475 (1945).
51. R. Beaman and F. Cramer, J. Polymer Sci., 21, 223 (1956).
52. H. Starkweather, Jr., G. Moore, J. Hansen, T. Roder, and R. Brooks, J. Polymer Sci., 21, 189 (1956).
53. R. Wiley, Ind. Eng. Chem., 38, 959 (1946).
54. H. W. Starkweather, Jr., and R. E. Moynihan, J. Polymer Sci., 22, 363 (1956).
55. F. C. Frank, A. Keller, and A. O'Connor, Phil. Mag., 4, 200 (1959).
56. G. Natta, P. Corradini, and 1. W. Bassi, Atti, 23, 363 (1958).
57. L. E. Nielsen, unpublished results.
58. P. W. Teare and D. R. Holmes, J. Polymer Sci., 24, 496 (1957).

APPENDIX I 531


59. K. Little, Br. J. Appl. Phys., 10, 225 (1959).
60. G. Natta, P. Corradini and 1. W. Bassi, Makromol. Chem., 33, 247 (1959).
61. W. P. Slichter, J. Polymer Sci., 36, 259 (1959).
62. R. C. Golike, J. Polymer Sci., 42, 583 (1960).
63. Y. Kinoshita, Makromol. Chem., 33, 21 (1959).
64. P. H. Burleigh, J. Am. Chem. Soc., 82, 749 (1960).
65. Y. Kinoshita, Makromol. Chem., 33, 1 (1959).
66. R. E. Moynihan, J. Am. Chem. Soc., 81, 1045 (1959).
67. G. Natta, Makromol. Chem., 35, 94 (1960).
68. J. Bateman, R. E. Richards, G. Farrow, and I. M. Ward, Polymer, 1, 63 (1960).
69. P. Corradini, Atti, 25, 517 (1958).
70. G. Natta, P. Corradini, and I. W. Bassi, Gazz. Chim. Ital., 89, 784 (1959).
71. G. Natta, G. Mazzanti, P. Longi, and F. Bernardini, Chim. e Ind. (Milan), 40, 813 (1958).
72. W. D. Niegisch and P. R. Swan, J. Appl. Phys., 31, 1906 (1960).
73. P. Corradini, G. Natta, and 1. W. Bassi, Angew. Chem., 70, 598 (1958).
74. D. Sianesi, G. Natta, and P. Corradini, Gazz. Chim. Ital., 89, 775 (1959).
75. G. Natta, F. Danusso, and D. Sianesi, Makromol. Chem., 28, 253 (1958); and D. Sianesi, M. Rampichini, and F.
Danusso, Chim. e Ind. (Milan), 41, 287 (1959).
76. G. Natta, G. Mazzanti, and P. Corradini, Atti, 25, 3 (1958).
77. W. R. Krigbaum and N. Tokita, J. Polymer Sci., 43, 467 (1960).
78. E. Stanley and M. Litt, J. Polymer Sci., 43, 453 (1960).
79. D. 1. Sapper, J. Polymer Sci., 43, 383 (1960).
80. P. Corradini and P. Ganis, J. Polymer Sci., 43, 311 (1960).
81. L. Mandelkern, Chem. Rev., 56, 903 (1956).
82. J. R. Schaefgen, J. Polymer Sci., 38, 549 (1959).
83. F. Danusso, G. Moraglio, and E. Flores, Atti, 25, 520 (1958).
84. R. C. Wilhoit and M. Dole, J. Phys. Chem., 57, 14 (1953).
85. F. A. Quinn, Jr., and L. Mandelkern, J. Am. Chem. Soc., 80, 3178 (1958).
86. F. W. Billmeyer, Jr., J. Appl. Phys., 28, 1114 (1957).
87. M. Dole, J. Polymer Sci., 19, 347 (1956).
88. A. M. Bueche, J. Am. Chem. Soc., 74, 65 (1952).
89. F. Danusso and G. Moraglio, Atti, 27, 381 (1959).
90. T. W. Campbell and A. C. Haven, Jr., J. Appl. Polymer Sci., 1, 73 (1959).
91. H. W. Starkweather, Jr., and R. H. Boyd, J. Phys. Chem., 64, 410 (1960).
92. G. Natta, G. Mazzanti, P. Corradini, and 1. W. Bassi, Makromol. Chem., 37, 156 (1960).
93. D. V. Badami, Polymer, 1, 273 (1960).
94. J. H. Griffith and B. G. Ranby, J. Polymer Sci., 44, 369 (1960).
95. C. G. Overberger, A. E. Borchert, and A. Katchman, J. Polymer Sci., 44, 491 (1960).
96. G. Natta, G. Mazzanti, P. Corradini, A. Valvassori, and 1. W. Bassi, Atti, 28, 18 (1960).
97. G. Natta, G. Mazzanti, P. Corradini, P. Chini, and 1. W. Bassi, Atti, 28, 8 (1960).
98. . Ellefsen, Norelco Reporter, 7, 104 (1960).
99. G. Farrow, J. McIntosh, and I. M. Ward, Makromol. Chem., 38, 147 (1960).
100. N. G. Esipova, L. Pan-Tun, N. S. Andreeva, and P. V. Kozlov, Vysokomol. Soed., 2, 1109 (1960).
532 POLYMER SINGLE CRYSTALS


101. A. G. M. Last, J. Polymer Sci., 39, 543 (1959).
102. D. J. Shields and H. W. Coover, Jr., J. Polymer Sci., 39, 532 (1959).
103. S. Murahashi, S. Nozakura, and H. Tadokoro, Bull. Chem. Soc. Japan, 32, 534 (1959).
104. T. F. Yen, J. Polymer Sci., 38, 272 (1959).
105. C. S. Fu11er and C. L. Erickson, J. Am. Chem. Soc., 59, 344 (1937).
106. C. S. Fu11er and C. J. Frosch, J. Am. Chem. Soc., 61,2575 (1939).
107. C. S. Fu11er, C. J. Frosch, and N. R. Pape, J. Am. Chem. Soc., 64, 154 (1942).
108. C. S. Fu11er and C. S. Frosch, J. Phys. Chem., 43, 323 (1939).
109. C. S. Fuller, Chem. Rev., 26, 143 (1940).
110. W. O. Baker and C. S. Fu11er, J. Am. Chem. Soc., 64, 2399 (1942).
111. A. Conix and R. Van Kerpel, J. Polymer Sci., 40, 521 (1959).
112. R. F. Heck and D. S. Breslow, J. Polymer Sci., 41, 521 (1960).
113. R. F. Heck and D. S. Breslow, J. Polymer Sci., 41,520 (1960).
114. E. J. Vandenberg, R. F. Heck, and D. S. Breslow, J. Polymer Sci., 41, 519 (1960).
115. A. M. Liquori, Acta Cryst., 8, 345 (1955).
116. S. Furuya and M. Honda, J. Polymer Sci., 28, 232 (1958).
117. P. Goodman, J. Polymer Sci., 24, 307 (1960).
118. L. Mandelkern and P. J. Flory, J. Am. Chem. Soc., 73, 3206 (1951).
119. S. Ishida and S. Murahashi, J. Polymer Sci., 40, 571 (1959).
120. B. S. Garrett, W. E. Goode, S. Gratch, J. F. Kincaid, C. L. Levesque, A. Spell, J. D. Stroupe, and W. H.
Watanabe, J. Am. Chem. Soc., 81, 1007 (1959).
121. D. C. Vogelsong and E. M. Pearce, J. Polymer Sci., 45, 546 (1960).
122. P. Cortadini and P. Ganis, Nuovo Cimento, 15, Suppl. I, 104 (1960).
123. G. Natta, P. Corradini, and 1. W. Bassi, Nuovo Cimento, 15, Suppl. 1, 83 (1960).
124. G. Natta and P. Corradini, Nuovo Cimento, 15, Suppl. 1, 111 (1960).
125. P. Corradini and P. Ganis, Nuovo Cimento, 15, Suppl. 1, 93 (1960).
126. G. Natta, P. Corradini, and 1. W. Bassi, Nuovo Cimento, 15, Suppl. 1, 52 (1960).
127. G. Natta and P. Corradini, Nuovo Cimento, 15, Suppl. 1,40 (1960).
128. G. Natta, P. Corradini, and 1. W. Bassi, Nuovo Cimento, 15, Suppl. 1, 68 (1960).
129. P. Pino and G. P. Lorenzi, J. Am. Chem. Soc., 82, 4745 (1960).
130. G. Natta, G. Mazzanti, G. Pregaglia, M. Binaghi, and M. Peraldo, J. Am. Chem. Soc., 82, 4742 (1960).
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