Documentos de Académico
Documentos de Profesional
Documentos de Cultura
][
]
m=1, n=2
for 20
o
C:
k = 0.062 s
-1
mol
-2
dm
9
Temperature
0
C
Average time
taken for
sodium
thiosulphate to
disappear
completely /s
(0.05)
Rate of
reaction s
-1
k (s
-1
mol
-2
dm
9
)
ln k (s
-1
mol
-
2
dm
9
)
1/T
20 27.00 0.0370 0.062 -2.786 0.050
30 16.57 0.0604 0.101 -2.296 0.033
40 10.73 0.0932 0.155 -1.862 0.025
50 5.60 0.1786 0.298 -1.212 0.020
60 4.97 0.2012 0.335 -1.093 0.017
Figure 2: processed data
Figure 3: showing graph of temperature against rate of reaction
0
0.05
0.1
0.15
0.2
0.25
0 10 20 30 40 50 60 70
r
a
t
e
o
f
r
e
a
c
t
i
o
n
s
-
1
Temperature
o
C
Graph of temperature against rate of reaction
Figure 4: showing graph of ln k against 1/T
y = -51.888x - 0.345
-3.5
-3
-2.5
-2
-1.5
-1
-0.5
0
-0.01 0 0.01 0.02 0.03 0.04 0.05 0.06
l
n
K
(
s
-
1
m
o
l
-
2
d
m
9
)
1/T (
o
C
-1
)
Graph of ln K against 1/T
) (
)
Ea=504.2508 Js
-1
mol
-1
dm
9
Conclusion
By observing figure 3, we can see an exponentially increase trend. This mean the temperature
play a significance role in chemical reaction. The higher the temperature, the faster the rate of
reaction. However, if you notice the graph is exponential. This is because when temperature too
high, the excessive kinetic energy could not be used. Therefore, the rate of reaction would not
increase anymore.
Moving to the figure 4, the graph of ln K against 1/T is actually to find the ln A or also
identify as Y-intersect. Using the data collected, the graph constructed and extrapolated to get the
value of -0.345 s
-1
mol
-2
dm
9
. From ln A, we can calculate the activation energy (Ea).
Evaluation
The random error is less in this experiment because we are using apparatus with low
uncertainties such as pipette and measuring cylinder. However, there may be some systematic
error due involving human.
Weaknesses
Improvements
The temperature would have changed from its
initial temperature as all experiments were
run in room temperature. Hence the sodium
thiosulphate solution would have either
cooled down or heated up while running the
experiment leading to a high uncertainty.
Could have run each experiments in different
atmosphere (with different temperatures) so
that the change of initial temperature is
altered in a great amount.
Human error of the stop watch Since the
time of the sulfur formation was recorded by
a stopwatch where a human stops the
stopwatch relying on his sight; it would lead
to a big uncertainty.
Use a reliable mechanic method where the
time is measured by a machine rather than
humans, so that it would reduce the human
error and allow more accurate data.
The drawing of the X. Each drawing of the X
had different thickness and darkness. Hence
when stopping the time for the complete
sulfur formation (when the X mark was no
longer visible) it would have ass been
different as the dissimilar darkness would
have caused me to have different standard of
darkness of the sodium thiosulphate solution
and hence lead to great uncertainty.
Should have used a printed X Mark where all
the darkness would have been the same as the
computer would have drawn it. It would have
reduced the human error.