WILSON

Smith y Van Ness

Pagina 512.

Para el sistema 2-propanol(l)/agua(2), los valores siguientes de parmetros son recomendados para la ecuaci
a12=437.98 cal/mol, a21=1238 cal/mol
V, = 76.92
cm3/mol
V2 = 18.07 cm3/mol
Adems, se tienen las siguientes ecuaciones de Antoine:

ln P1sat 16.6780

3640.20
T 53.54

ln P2sat 16.28870

3816.44
T 46.13

en donde T est en kelvins y la presin de vapor est en kPa. R=1.987cal/molK

a) P y {yi} para T = 353.15 K y xl= 0.25.
b) P y {xi}, para T = 353.15 K y y1 = 0.60.
c) T y {yi}, para P = 101.33 kPa y xl = 0.85.
d) T y {xi}, para P = 101.33 kPa y y1 = 0.40.

A12
A21

ln 1 ln x1 x 2 A12 x 2

x1 x 2 A12 x 2 x1 A21
A12
A21

ln 2 ln x 2 x1 A21 x1

x1 x 2 A12 x 2 x1 A21

WILSON

etros son recomendados para la ecuacin de Wilson:

V2
a12
A12 exp
V1
RT
V1
a 21
A21 exp
V2
RT
x1 1 P1*
y1
P

A21

x 2 x1 A21
A21

x 2 x1 A21

P x1 * 1 P1* x2 * 2 P

Ti sat

Bi
Ci
Ai ln P

T xi Ti sat

Presin de Burbuja

V2
V1
T
x1
P1 sat
P2 sat
R
a12
a21
A12
A21
gama1
gama2
P
y1

cm3/mol
cm3/mol
K
x2
1
kPa
*
P

x
*

P
x2 * 2 P
1
1
1
kPa
cal/molK
cal/mol
cal/mol
x1 1 P1*
y1
P

kPa
y2
Las cantidades en verde tienen frmula
Las cantidades en rosa son datos

Sacar P1 sat
Sacar P2 sat
Ecuacin Antonie

Sacar A12

x2 * 2 P

Sacar A21
Sacar 1
Sacar 2

Sacar P

Sacar y1
y2=1-y1

A12

V2
a
exp 12
V1
RT

A21

V1
a
exp 21
V2
RT

A1
ln 1 ln x1 x 2 A12 x 2
x1 x
A1
ln 2 ln x 2 x1 A21 x1
x1 x

 A12
A21

x 2 A12 x 2

x1 x 2 A12 x 2 x1 A21
A12
A21

x1 A21 x1

x1 x 2 A12 x 2 x1 A21

Presin de Roco
b) P y {xi}, para T = 353.15 K y y1 = 0.60.

R
V1
V2
T
y1
P1 sat
P2 sat
a12
a21
P
67.01262
96.7214
96.71598
96.71358
96.71252
96.71206
96.71186
96.71178
96.71174
96.71172
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171

1.987
76.92
18.07
353.2
0.6
92.59
47.38
438
1238

cal/molK
cm3/mol
cm3/mol
K
y2
kPa
kPa
cal/mol
cal/mol

x1
0.434254
0.439235
0.442562
0.444773
0.446237
0.447205
0.447843
0.448264
0.448541
0.448724
0.448844
0.448923
0.448975
0.449009
0.449032
0.449047
0.449056
0.449063
0.449067
0.449070
0.449072

x2
0.565746
0.560765
0.557438
0.555227
0.553763
0.552795
0.552157
0.551736
0.551459
0.551276
0.551156
0.551077
0.551025
0.550991
0.550968
0.550953
0.550944
0.550937
0.550933
0.550930
0.550928

Los resultados estn en amarillo

0.4

A12
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856

A21
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423

gama1
1.426964
1.416157
1.409083
1.404444
1.401398
1.399398
1.398082
1.397218
1.396649
1.396275
1.396029
1.395867
1.395761
1.395691
1.395645
1.395614
1.395594
1.395581
1.395573
1.395567
1.395563

Sacar P1sat y P2sat

1
y1
P1

y2

sat

P 2sat

y1P
P1 sat

x1

x 2 1 x1

gama2
1.456151
1.46476
1.470556
1.474428
1.477002
1.478707
1.479834
1.480577
1.481067
1.48139
1.481602
1.481742
1.481834
1.481895
1.481935
1.481961
1.481978
1.48199
1.481997
1.482002
1.482005

A 12

V2
a 12
exp
V1
RT

A 21

V1
a 21
exp
V2
RT

ln 1 ln x1 x2 A12 x2
x
1

ln 2 ln x2 x1 A21 x1
x
1

El cambio de P es muy
pequeo

A12
A21

x2 A12
x2 x1 A21

A12
A21

x2 A12
x2 x1 A21

1
y1

1 P1

x1

sat

y2

2 P2sat

y1 P
1 P1 sat

A12

A12

A21

x2 x1 A21

A21

x2 x1 A21

Temperatura de Burbuja

V2
V1
P
x1
R
B
A
C
Ti
T
P1 sat
a12
a21
A12
A21
l

ln gama1
ln gama 2

P1 sat
ITERACIONES

18.07
76.92
101.33
0.85
1.987
3640.2
16.678
53.54
355.39
358.05

cm3/mol
cm3/mol
kPa
x2

0.15

3816.4
16.289 Datos de Antoine
46.13
373.15 K
K

112.61 57.602 P2 sat

437.98 cal/mol
1238 cal/mol
0.1269
0.7471
0.0195 1.0197 gama1
0.9268 2.5265 gama2
95.539 kPa
P1 sat
95.538685
95.247734
95.242343
95.242243
95.242241
95.242241
95.242241

T
353.924485
353.848902
353.8475
353.847474
353.847474
353.847474
353.847474

A12
0.126021
0.126004
0.126004
0.126004
0.126004
0.126004
0.126004

A21
0.732062
0.731786
0.731781
0.731781
0.731781
0.731781
0.731781

gama 1
1.020288
1.020299
1.020299
1.020299
1.020299
1.020299
1.020299

95.242241 353.847474
95.242241 353.847474
95.242241 353.847474

0.126004
0.126004
0.126004

0.731781
0.731781
0.731781

Como el cambio de T es pequeo ya se puede sacar y

1.020299
1.020299
1.020299

Ti

sat

T
ln P1sat 16.6780

Bi

Ai ln P

xT
i

sat

3640.20
T 53.54

V2

A12
exp
V1
R

V1

A21
exp
V2
R

ln 1 ln x1 x 2 A12 x 2
x1

ln 2 ln x 2 x1 A21 x1
x1
gama 2
2.562357232
2.563023943
2.563036316
2.563036546
2.56303655
2.56303655
2.56303655

y1

y1
sat
1

x1 1 x2 2 P

Bi
T
Ai ln P1sa

2.56303655
2.56303655
2.56303655 0.81515098 0.18484902

Bi
T
Ai ln P1sa

Ti

sat

3640.20
53.54

Bi

Ci
Ai ln P

xT
i

sat

ln P2sat 16.28870

V2
a12
A12
exp
V1
RT
V1
a 21
A21
exp
V2
RT

A12
A21

ln x1 x 2 A12 x 2

x1 x 2 A12 x 2 x1 A21
A12
A21

ln x 2 x1 A21 x1

x1 x 2 A12 x 2 x1 A21
sat
1

P2sat

x1 1 x2 2
sat
P
1

Bi
T
Ci
sat
Ai ln P1

3816.44
T 46.13

Bi
T
Ci
sat
Ai ln P1
DT son pequeas

y1

x P
P

*
1 1 1

T de Roco
d) T y {xi}, para P = 101.33 kPa y y1 = 0.40.

R
V2
V1
P
y1
B
A
C
Ti
T

1.987
18.07
76.92
101.33
0.4
3640.2
16.678
53.54
248.31
267.86

cal/molK
a12
cm3/mol
a21
cm3/mol
kPa
y2
0.6
3816
16.29 Datos de Antoine
46.13
280.9 K
K

ln P1 sat

P1 sat

ln P2 sat

0.7357

kPa
K
P1 sat
T
0.735667

437.98
1238

267.8588

0.397 P2 sat kPa

kPa
P2 sat
0.397128

A12
0.103166

Se itera hasta que DT sea pequea.

A21
0.415811

x1

Ti sat

cal/mol
cal/mol

ln P1sat 16.6780

Bi
Ci
Ai ln P

xT
i

sat

3640.20
T 53.54

ln P2sat 16.28870

Pi sat P
i

yii Pj
i Pi sat
sat

Bi
Ci
sat
Ai ln P1

ln P2sat 16.28870

x2

3816.44
T 46.13

3816.44
T 46.13

A12

V2
a
exp 12
V1
RT

A21

V1
a 21
exp
V2
RT

x1

y1 P
1 P1 sat

A12
A21

ln 1 ln x1 x2 A12 x2

x
A
x

x
A
2 12
2
1 21
1

A12
A21

ln 2 ln x2 x1 A21 x1

x
A
x

x
A
2 12
2
1 21
1

ln P2sat 16.28870

3816.44
T 46.13

3816.44
T 46.13

A12
A21

x2 A12 x2 x1 A21

A12
A21

x2 A12 x2 x1 A21