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SIMULACION DEL REACTOR DE LECHO FIJO POR EL

MODELO DE DOS DIMENSIONES

ndice
Presentacin
CASO I: REACTOR HOMOGENEO
CASO II: CONSIDERANDO DIFUSION RADIAL
CASO III: CON DIFUSION AXIAL Y RADIAL
COMPARACION DEL CASO I, II YIII
PUNTOS CALIENTES
Conclusiones

PRESENTACION
Los reactores de lecho fijo consisten en uno o ms tubos empacados con partculas
de catalizador, que operan en posicin vertical. Las partculas catalticas pueden
variar de tamao y forma: granulares, cilndricas, esfricas, etc. En algunos casos,
especialmente con catalizadores metlicos como el platino, no se emplean partculas
de metal, sino que ste se presenta en forma de mallas de alambre. El lecho
catalizador est constitudo por un conjunto de capas de este material. Estas mallas
catalticas se emplean enprocesos comerciales para la oxidacin de amoniaco y para
la oxidacin del acetaldehdico a cido actico.

Debido a la necesidad de eliminar o aadir calor, no es posible usar un solo tubo


de gra dimetro empacado con el catalizador. En su lugar, el reactor deber
construirse con cierto nmero de tubos engarzados en un solo cuerpo. El intercambio
energtico con los alrededores se obtiene circulando, algunas veces hirviendo un
fluido en el espacio que hay entre los tubos. Si el efecto calorfico es considerable, los
tubos de catalizador deben de ser pequeos (de hasta 1 plg de dimetro) para evitar
temperaturas excesivas en la mezcla reaccionante. El problema de la decisin del
dimetro del tubo y, por tanto, cuntos tubos son necesarios para una produccin
dada, constituye un obstculo importante en el diseo de estos reactores.

ECUACIN GENERAL DE BALANCE DE MATERIA Y ENERGA

Conservacin de materia

Conservacin de energa
(

Donde:
: Porosidad del lecho
Ker: Conductividad efectiva radial
Der: Difusividad efectiva radial
CA: Concentracin en cada r, z
T: Temperatura en cada r, z
S:

Velocidad superficial

b:

Densidad del catalizador

A: Coeficiente estequiometrico
g:

Densidad del fluido

Cpg: Calor especifico del fluido

CASO I
REACTOR HOMOGENEO

CASO I: REACTOR HOMOGENEO

No se considera difusin radial ni axial:


Esto quiere decir que tanto la concentracin como
constantes en el eje r (eje radial)

la

temperatura se mantienen

De la figura se cumple lo siguiente:

En el eje radial:

Sabemos que la derivada se define coma la pendiente de la funcin:

De la misma manera se tiene lo siguiente:

()

()

Reemplazando la condicin () en la ecuacin (1) y la condicin () ecuacin 2 se tiene


lo siguiente:

Despejando el trmino diferencial

(5)

La ecuacin (5) lo ponemos en funcin de la conversin

Se sabe que:

Derivando

Reemplazando en la ecuacin (5) y que

se tiene:

. (7)

La ecuacin de velocidad para la oxidacin del anhdrido sulfuroso:

Donde:

Datos del Reactor y de la operacin:

Oxidacin del Anhdrido Sulfuroso

Composicin del
alimento

6,5% mol de SO2


93,5% mol de aire seco

Catalizador del
lecho

Pt/Al2O3(esferas)
dp= 0,3175cm
b=
1025Kg cat/m3 L = 0,5

Propiedades del
Flujo y fase fluida

Temperatura de
alimentacin, To

= 0,5864

400C

Temperatura de la
pared, Tw

197C

Dimetro del tubo,


Dt

5,23cm

Longitud del tubo

9,14cm

Numero de Peclet de
transferencia de
calor radial, PeHr

4,4

Numero de Peclet de
transferencia de
masa radial, PeHr

9,6

Numero de Biot en la
pared Biw

6,67

SOLUCION EN POLYMATH

LENGUAJE EN POLYMATH
# Distancia de reactor
z(0) = 0
z(f) = 0.1524
# Balance de Materia y Energia
d(X)/d(z) = db * Rx / (Cao * Us)
d(T)/d(z) = db * (-dH) * Rx / (Us * df * Cpf) # Temperatura obtenida en C
# Condiciones Iniciales
X(0) = 0 # Conversion a la entrada del reactor
T(0) = 400 # Temperatura a la entrada del reactor
# Velocidad de la reaccion en funcion de la Conversion y Presion R = funcion(x,T), donde T debe
ser usada en Kelvin
Rx = (K1 * Po2 * Pso2 * (1 - Pso3 / (Pso2 * Kp * (Po2) ^ 0.5))) / (22.414 * (1 + K2 * Pso2 + K3 *
Pso3) ^ 2)
Trx = T + 273.15
K1 = exp(12.160 - 5473 / (Trx))
K2 = exp(-9.953 + 8619 / (Trx))
K3 = exp(-71.745 + 52596 / (Trx))
Kp = exp(11300 / (Trx) - 10.68)

# Calculo de las Presiones


Pso2 = Pao * (1 - X)
Po2 = Pbo - 0.5 * Pao * X
Pso3 = Pao * X

# Propiedades del Fluido


P = 1.6 # Presion del sistema
R = 0.082 # Constante universal de los gases
db = 1025 # Densidad del Lecho catalitico
Cpf = 1.09 # Capacidad Calorifica del Fluido
Us = 2914.393 # Velocidad del Fluido G/df
G = 1709 # Flujo masico
df = 0.5864 # Densidad del Fluido
dH = -94886 # Entalpia de la Reaccion

# Calculo de la Concetracion Inicial


Cao = Pao / (R * Tin)
Tin = (400 + 273.15)
# Calculo de la Presion inicial
ya = 0.065
Pao = ya * P
Pbo = (1 - ya) * P * 0.21

Con las tablas obtenidas por polymath, procedemos a graficar

0.000

0.0000

400.00

0.015

0.0245257

406.8598

0.030

0.0505842

414.1483

0.046

0.0886139

424.7851

0.061

0.1599124

444.7272

0.076

0.3207904

489.7244

0.091

0.624388

574.6401

0.107

0.7754533

616.8927

0.122

0.7878356

620.356

0.137

0.788415

620.5181

0.152

0.788441

620.5253

CONVERSION vs. LONGITUD DEL REACTOR

X vs Z
0.8
0.7

Conversion

0.6
0.5
0.4
P=1.6

0.3
0.2
0.1
0.0
0.000 0.015

0.030

0.046 0.061

0.076

0.091 0.107

0.122 0.137

0.152

Z en metros

TEMPERATURA vs. LONGITUD DEL REACTOR

Temperatura

T vs Z
640
620
600
580
560
540
520
500
480
460
440
420
400
0.000 0.015 0.030 0.046 0.061 0.076 0.091 0.107 0.122 0.137 0.152
Z en metros

P= 1.6 atm

CASO II
CON DIFUSION RADIAL

CASO II: CON DIFUSION RADIAL


Balance de materia:

2C 1 C
C
Der 2
b A ( X ,T ) 0
Us
r r
z
r

(1)

Se sabe que: C = CA0 - CAoX


Derivando tenemos:

C C Ao X

Lo reemplazamos en la ecuacin (1):

C Ao 2 X 1 (C Ao )X
(C Ao )X

b A ( X ,T ) 0
Us
2
r
r
z
r

Der

Dividiendo entre (-CAo)


2 X 1 X
X b A ( X ,T )

0
Us
2
r r
z
C Ao
r

Der

Despejando tenemos:

X .d P 2 X 1 X

z
PEMr . r 2 r r

Luego: A 1 ;

b
C AoUs

b . A .rA ( X , T )

C A0 .U S

C1 ;

Der
Us

C2

Reemplazando:
2 X 1 X
X
C 2 2
C1 ( X ,T ) 0
z
r r
r

Balance de energa:

2T 1 T
T
Ker 2
b (Hr ) ( X ,T ) 0
Us f C pf
r r
z
r

Despejando:

T
Ker

z Us f C pf

2T 1 T b . Hr .rA( X ,T )
2

r r
U S . f .CPf
r

b ( r )
Ker
C3 ;
C4
f C pf Us
Us f C pf

Haciendo:

Finalmente tenemos:

2 X 1 X
X
C 2 2
z
r r
r

C1.rA ( X ,T )

2T 1 T
T
C 3.rA ( X ,T )
C 4 2
z
r r
r
Condiciones inciales:
X(o) = 0
T(o) = 400oC
El radio del reactor se divide en cinco partes iguales:
Radio del reactor:

ri r i ; i 0,1,2,3,4,5
r es la fraccion del radio

Los puntos mximos y mnimos:


Xo
To
0;
0
z
z

Para r = 0
2
1 X X

lim
r 2
r 0 r r

2
1 T T

2
lim
r 0 r r
r

Reemplazando en estas ecuaciones:

2 X 1 X
X
C 2 2
z
r r
r

C1.rA ( X ,T )

2T 1 T
T
C 3.rA ( X ,T )
C 4 2
z
r

Tenemos:

2 X
X
2C 2 2
z
r

C1.rA ( X ,T )

2T
T
2C 4 2 C 3.rA ( X ,T )
z
r
X i
X 2 X i X i 1
2C 2. i 1
C1.rA X i ,Ti
z
r 2

Ti
T 2Ti Ti 1
2C 4. i 1
C 3.rA X i ,Ti
z
r 2

i=0

X 0
X 2 X 0 X 1
2C 2. 1
C1.rA X i ,Ti
z
r 2

T0
T 2T0 T1
2C 4. 1
C 3.rA X i ,Ti
z
r 2

Estos puntos no existen: X-1; T-1

Por discretizacion regresiva:


X i X i X i 1

r
r

Cuando i = 0; reemplazando: Xo = X-1, To = T-1


Para r 0
X 2 X i X i 1
X i
1 X i X i 1
C 2. i 1

C1.rA X i ,Ti
2
z
ir
r
r

T 2Ti Ti 1
Ti
1 Ti Ti 1
C 4. i 1

C 3.rA X i , Ti
2
z
ir r
r

Cuando i = 1

X 2X1 X 0
X 1
1 X1 X 0
C 2. 2

C1.rA X1 ,T1
2
z
1r r
r

T 2T1 T0
T1
1 T1 T0
C 4. 2

C 3.rA X1 ,T1
2
z
1r r
r

Cuando i = 2

X 2X 2 X1
X 2
1 X 2 X1
C 2. 3

C1.rA X 2 ,T2
2
z
2r r
r

T 2T2 T1
T2
1 T2 T1
C 4. 3

C 3.rA X 2 ,T2
2
z
2r r
r

Cuando i = 3

X 2X 3 X 2
X 3
1 X 3 X 2
C 2. 4

C1.rA X 3 ,T3
2
z
3

T 2T3 T2
T3
1 T3 T2
C 4. 4

C 3.rA X 3 ,T3
2
z
3r r
r

Cuando i = 4

X 2X 4 X 3
X 4
1 X 4 X 3
C 2. 5

C1.rA X 4 ,T4
2
z
4r r
r

T 2T4 T3
T4
1 T4 T3
C 4. 5

C 3.rA X 4 ,T4
2
z
4r r
r

Cuando i = 5

X 2X 5 X 4
X 5
1 X5 X4
C 2. 6

2
z
5r r
r

C1.rA X 5 ,T5

T 2T5 T4
T5
1 T5 T4
C 4. 6

C 3.rA X 5 ,T5
2
z
5r r
r

Condiciones de Frontera:

Para el balance de materia:


Para r = R = ri ir
C A
0
r

X i1 X i 0 ;
r R;

X
0
r

i 5 X6 X5

C A
0
r

x
0
r

Reemplazando:

X 2X 5 X 4
X 5
1 X 5 X 4
C 2. 5

C1.rA X 5 ,T5
2
z
5r r
r

Para el Balance de Energa:


Para: r = R;

Transferencia de calor:
k

T
T
h
hTi Tw
Ti Tw
r
r
k

Ti 1 Ti
h
h
Ti Tw
r
k
k

Entonces:
Para i = 5
T6 T5

hr
hr
T5
Tw
k
k

hr
hr
T6 1
Tw
T5
k
k

Adems se sabe que:

ri ir
rh
K
irh
Biw
K
Biw

Reemplazando:

X5 X4
X 5
1 X 5 X 4
C 2.

C1.rA X 5 ,T5
2
z
5r r
r
Biw

Bi
1

T5 w Tw 2T5 T4
T5
1 T5 T4
5
5

C 4.

C 3.rA X 5 ,T5

z
5r r
r 2

Condiciones inciales:
Cuando Z = 0

conversin temperatura
Xo(0) = 0

T0(0) = 0

X1 (0) = 0

T1(0) = 0

X2 (0) = 0

T2(0) = 0

X3 (0) = 0

T3(0) = 0

X4 (0) = 0

T4(0) = 0

X5 (0) = 0

T5(0) = 0

SOLUCION EN POLYMATH

LENGUAJE EN POLYMATH
# Distancia del Reactor
z(0) = 0
z(f) = 0.1524
# Propiedades del Fluido
P = 1.60 # Presion del sistema
R = 0.082 # Constante Universl de los gases
df = 0.5864 # Densidad del fluido
Tw = 197 # Temperatura de la pared
Phr = 4.4 # Peclet Calor Radial
Pmr = 9.6 # Peclet Masa Radial
Bi = 6.67 # Numero de Biot de la pared
dp = 0.003175 # Densidad del Catalizador
E = 0.5 # Porosidad del Lecho catalitico
db = 1025 # Densidad del lecho
G = 1709 # Flujo masico
Us = 2914.393 # Velocidad
dH = -94886 # Entalpia
Cpf = 1.09 # Capacidad Calorifica del Fluido
dr = (0.02615) / 5 # Espaciamiento Radial 5*dr=Radio
# Calculo de la Concetracion Inicial
Cao = Pao / (R * (Tin))
Tin = 400 + 273.15
# Calculo de la Presion inicial
ya = 0.065

Pao = P * ya
Pbo = (1 - ya) * P * 0.21
# Definicion de Parametros de las Ecuaciones Diferenciales de Materia y Energia
# Para EDB Materia
pi1 = E * Us * dp / (Us * Pmr)
pi2 = db / (Us * Cao)
# Para EDB Energia
pi3 = dp / Phr
pi4 = -dH * db / (Us * df * Cpf)

# Balance de Materia para 5 divisiones del Radio


d(x0)/d(z) = 2 * pi1 * (x1 - 2 * x0 + x0) / dr ^ 2 + pi2 * R0
d(x1)/d(z) = pi1 * ((x2 - 2 * x1 + x0) + (x1 - x0) / 1) / dr ^ 2 + pi2 * R1
d(x2)/d(z) = pi1 * ((x3 - 2 * x2 + x1) + (x2 - x1) / 2) / dr ^ 2 + pi2 * R2
d(x3)/d(z) = pi1 * ((x4 - 2 * x3 + x2) + (x3 - x2) / 3) / dr ^ 2 + pi2 * R3
d(x4)/d(z) = pi1 * ((x5 - 2 * x4 + x3) + (x4 - x3) / 4) / dr ^ 2 + pi2 * R4
d(x5)/d(z) = pi1 * ((x6 - 2 * x5 + x4) + (x5 - x4) / 5) / dr ^ 2 + pi2 * R5
# Valores iniciales de conversion y Temperatura
x0(0) = 0
x1(0) = 0
x2(0) = 0
x3(0) = 0
x4(0) = 0
x5(0) = 0
# Balance de Energia para 5 divisiones del Radio
d(T0)/d(z) = 2 * pi3 * (T1 - 2 * T0 + T0) / dr ^ 2 + pi4 * R0
d(T1)/d(z) = pi3 * ((T2 - 2 * T1 + T0) + (T1 - T0) / 1) / dr ^ 2 + pi4 * R1
d(T2)/d(z) = pi3 * ((T3 - 2 * T2 + T1) + (T2 - T1) / 2) / dr ^ 2 + pi4 * R2
d(T3)/d(z) = pi3 * ((T4 - 2 * T3 + T2) + (T3 - T2) / 3) / dr ^ 2 + pi4 * R3
d(T4)/d(z) = pi3 * ((T5 - 2 * T4 + T3) + (T4 - T3) / 4) / dr ^ 2 + pi4 * R4
d(T5)/d(z) = pi3 * ((T6 - 2 * T5 + T4) + (T5 - T4) / 5) / dr ^ 2 + pi4 * R5
# Valores iniciales de conversion y Temperatura
T0(0) = 400
T1(0) = 400
T2(0) = 400
T3(0) = 400
T4(0) = 400
T5(0) = 400

# Para i = 0
K10 = exp(12.160 - 5473 / (T0 + 273.15))
K20 = exp(-9.953 + 8619 / (T0 + 273.15))
K30 = exp(-71.745 + 52596 / (T0 + 273.15))
Kp0 = exp(11300 / (T0 + 273.15) - 10.68)
Pa0 = Pao * (1 - x0)
Pb0 = Pbo - 0.5 * Pao * x0
Pc0 = Pao * x0
R0 = (K10 * Pb0 * Pa0 * (1 - Pc0 / (Pa0 * Kp0 * (Pb0) ^ 0.5))) / (22.414 * (1 + K20 * Pa0 + K30 *
Pc0) ^ 2)

# Para i = 1
K11 = exp(12.160 - 5473 / (T1 + 273.15))
K21 = exp(-9.953 + 8619 / (T1 + 273.15))
K31 = exp(-71.745 + 52596 / (T1 + 273.15))
Kp1 = exp(11300 / (T1 + 273.15) - 10.68)
Pa1 = Pao * (1 - x1)
Pb1 = Pbo - 0.5 * Pao * x1
Pc1 = Pao * x1
R1 = (K11 * Pb1 * Pa1 * (1 - Pc1 / (Pa1 * Kp1 * (Pb1) ^ 0.5))) / (22.414 * (1 + K21 * Pa1 + K31 *
Pc1) ^ 2)
# Para i = 2
K12 = exp(12.160 - 5473 / (T2 + 273.15))
K22 = exp(-9.953 + 8619 / (T2 + 273.15))
K32 = exp(-71.745 + 52596 / (T2 + 273.15))
Kp2 = exp(11300 / (T2 + 273.15) - 10.68)
Pa2 = Pao * (1 - x2)
Pb2 = Pbo - 0.5 * Pao * x2
Pc2 = Pao * x2
R2 = (K12 * Pb2 * Pa2 * (1 - Pc2 / (Pa2 * Kp2 * (Pb2) ^ 0.5))) / (22.414 * (1 + K22 * Pa2 + K32 *
Pc2) ^ 2)
# Para i = 3
K13 = exp(12.160 - 5473 / (T3 + 273.15))
K23 = exp(-9.953 + 8619 / (T3 + 273.15))
K33 = exp(-71.745 + 52596 / (T3 + 273.15))
Kp3 = exp(11300 / (T3 + 273.15) - 10.68)
Pa3 = Pao * (1 - x3)
Pb3 = Pbo - 0.5 * Pao * x3
Pc3 = Pao * x3
R3 = (K13 * Pb3 * Pa3 * (1 - Pc3 / (Pa3 * Kp3 * (Pb3) ^ 0.5))) / (22.414 * (1 + K23 * Pa3 + K33 *
Pc3) ^ 2)
# Para i = 4
K14 = exp(12.160 - 5473 / (T4 + 273.15))
K24 = exp(-9.953 + 8619 / (T4 + 273.15))
K34 = exp(-71.745 + 52596 / (T4 + 273.15))
Kp4 = exp(11300 / (T4 + 273.15) - 10.68)
Pa4 = Pao * (1 - x4)
Pb4 = Pbo - 0.5 * Pao * x4
Pc4 = Pao * x4
R4 = (K14 * Pb4 * Pa4 * (1 - Pc4 / (Pa4 * Kp4 * (Pb4) ^ 0.5))) / (22.414 * (1 + K24 * Pa4 + K34 *
Pc4) ^ 2)
# Para i = 5
K15 = exp(12.160 - 5473 / (T5 + 273.15))
K25 = exp(-9.953 + 8619 / (T5 + 273.15))
K35 = exp(-71.745 + 52596 / (T5 + 273.15))
Kp5 = exp(11300 / (T5 + 273.15) - 10.68)
Pa5 = Pao * (1 - x5)
Pb5 = Pbo - 0.5 * Pao * x5
Pc5 = Pao * x5
R5 = (K15 * Pb5 * Pa5 * (1 - Pc5 / (Pa5 * Kp5 * (Pb5) ^ 0.5))) / (22.414 * (1 + K25 * Pa5 + K35 *
Pc5) ^ 2)
# en i= 5 hay intercambio de calor con el exterior

T6 = T5 - Bi * (T5 - Tw) / 5
# para x valor minimo dx/dr = 0 en i =5
x6 = x5

Con las tablas obtenidas por polymath, procedemos a graficar


DATOS OBTENIDOS EN POLYMATH
ro

r1

Radio

r2

r3

r4

r5

0.00523

0.01046

0.01569

0.02092

0.02615

x0

x1

x2

x3

x4

x5

0.0000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.0152

0.025

0.023

0.017

0.004

0.020

0.0245188

0.0244299

xprom

0.0305

0.0504852

0.0501527

0.0478677

0.0377272

0.0177939

0.0051528

0.035

0.0457

0.0868168

0.0835159

0.0701128

0.0420615

0.0182194

0.0060648

0.051

0.0610

0.1446385

0.1283229

0.0864383

0.0428475

0.0187751

0.0069482

0.071

0.0762

0.2391598

0.1861042

0.0951262

0.0436372

0.0193669

0.0078096

0.099

0.0914

0.3793842

0.2557484

0.0996847

0.0446674

0.0200022

0.0086534

0.135

0.1067

0.5419311

0.3333168

0.1044463

0.0458546

0.020685

0.0094841

0.176

0.1219

0.6736494

0.4116675

0.1113297

0.0472624

0.0214188

0.0103061

0.213

0.1372

0.7541042

0.4808613

0.1204608

0.0489946

0.022213

0.0111239

0.240

0.1524

0.7980479

0.5299375

0.1310985

0.0511199

0.0230818

0.0119426

0.258

ro

r1

Radio
z
0.0000

r2

r3

r4

r5

0.00523

0.01046

0.01569

0.02092

0.02615

T0

T1

T2

T3

T4

T5

400.000

400.000

400.000

400.000

400.000

400.000

Tprom
400.000

0.0152

406.8572

406.8403

406.6297

404.6377

390.7559

326.7332

390.409

0.0305

414.0097

413.615

411.223

400.9677

368.9261

291.1729

383.319

0.0457

423.3305

421.0735

412.5478

391.4339

348.9197

271.5301

378.139

0.0610

436.3372

428.8973

410.0592

380.2471

332.3455

259.3035

374.532

0.0762

454.6058

436.5931

404.7496

369.2411

318.8762

250.9334

372.500

0.0914

477.6067

443.7096

398.4598

358.8974

307.8717

244.791

371.889

0.1067

498.1099

449.692

392.4978

349.4955

298.764

240.0527

371.435

0.1219

505.9351

453.4905

387.151

341.1703

291.1446

236.2663

369.193

0.1372

501.659

453.5445

382.1258

333.8768

284.7215

233.1675

364.849

0.1524

491.3662

448.2249

376.8912

327.4304

279.2634

230.5893

358.961

X vs Z
0.8
0.7

Conversion

0.6
T0

0.5

T1

0.4

T2

0.3

T3

0.2

T4
T5

0.1
0.0
0.0000 0.0152 0.0305 0.0457 0.0610 0.0762 0.0914 0.1067 0.1219 0.1372 0.1524
Z en metros

T vs Z
520.0

Temperatura

470.0
420.0

T0
T1

370.0

T2
T3

320.0

T4
T5

270.0
220.0
0.0000 0.0152 0.0305 0.0457 0.0610 0.0762 0.0914 0.1067 0.1219 0.1372 0.1524
Z en metros

Perfil de conversion
0.8
0.0000

0.7

0.0152

Conversion

0.6

0.0305

0.5

0.0457

0.4

0.0610

0.3

0.0762
0.0914

0.2

0.1067
0.1

0.1219

0.0
0

0.00523

0.01046

0.01569

0.02092

0.02615

Radio en Metros

0.1372
0.1524

Perfil de Temperatura
510.0
470.0

0.0000
0.0152

Temperatura

430.0

0.0305
0.0457

390.0

0.0610
350.0

0.0762
0.0914

310.0

0.1067
0.1219

270.0

0.1372
230.0
0

0.00523

0.01046

0.01569

Radio en Metros

0.02092

0.02615

0.1524

X promedio
0.300

Conversion Promedio

0.250
0.200
0.150
0.100
0.050
0.000
0.0000

0.0200

0.0400

0.0600

0.0800

0.1000

0.1200

0.1400

0.1600

0.1800

0.1400

0.1600

0.1800

Z en metros

T promedio
405.000
400.000

Tmeperatura Promedio

395.000
390.000
385.000
380.000
375.000
370.000
365.000
360.000
355.000
0.0000

0.0200

0.0400

0.0600

0.0800

0.1000

Z en metros

0.1200

CASO III
CON DIFUSION AXIAL Y
RADIAL

CASO III: CON DIFUSION AXIAL Y RADIAL

1. BALANCE DE MATERIA:

Ecuacin de conservacin de cantidad de materia

2 C A 1 C A
2C A
C A b . A .rA ( X , T )

EDer

EDeZ
US

0 .(1)
2
2

r r
z
z
r

Donde:
CA= CA0- CA0X ,dCA = CAo.dx

U S . dp
Der
U dp
Pehz S .
Dez
Pemr

Reemplazand
o en (1) se
2 X 1 X PeMr 2 X PeMr X b . A PeMr .rA ( X , T )

0............(2)
2
2
r r Pemz z
.d P z
.C A0 .U S .d P
r
obtiene:

Donde:

PeMr
Pemz

PeMr
.d P

b . A PeMr
.C A0 .U S .d P

Se obtiene:
2 X 1 X
2 X
X

1 2 2
3 rA ( X , T ) 0.......... ...( 3)
2
r r
z
r
z

Luego discretizando
Si: i = 0
(

2 X 1 2 X 2 X 3

rA ( X , T ) 0
2 z 2
2 z
2
r 2

X i 1, j 2 X i , j X i 1, j
r

1 ( X i , j 1 2 X i , j X i , j 1 )
2

2 ( X i , j X i , j 1 )
2

3
2

rA ( X i , j 1 , Ti , j 1 ) 0......( 4)

Si : i0

X i 1, j 2 X i , j X i 1,, j
r 2

( X i , j X i , j 1 )
1 X i , j X i 1, j ( X i , j 1 2 X i , j X i , j 1 )
1
2
3rA ( X i , j 1,Ti , j 1 ) 0.......... ..( 5)
2
ir
r
z
z

Entonces:

Para los valores:


i=0, j=1,,6

se aplicara la frmula (4)

Para los valores:


i=1,,5 y j=1,,6;

se aplicara la frmula (5)

Para los valores:


i=0,.,5 y j=0

son valores iniciales de x = 0

Para los valores:


i= 5 y j=0,.,6

por ser valor mnimo : dx/dr = 0

Para los valores:


j = 6 , i = 0,..,5

por ser valor mximo:

dx/dz = 0

2. BALANCE ENERGIA:

Ecuacin de conservacin de Energa

2
2 T 1 T
K ez T U S b C P T b .( Hr )rA ( X , T ) 0 ..( 6 )
K er 2
r
r r
z
z 2

Donde:

Ker

GdpCPg

Kez

GdpCPg

PeHr
PeHZ

Reemplazando en (5) se obtiene:

2T 1 T PEHr 2T U s PEHr . g T b .PEHr HR.rA ( X , T )

0.............(7)
G.d P
z
d P .G.C Pg
r 2 r r PEHa z 2

Donde:

Pe Hr
Pe HZ

U s PEHr . g

G.d P

b .PEHr (Hr )
d P .G.C Pg

Se obtiene:
2T 1 T
2T
T

5
6 rA ( X , T ) 0.
4
2
2
r
r r
z
z

Luego discretizando

Si: i = 0

1 T
2T
lim r 0 ( . ) 2
r r
r
2T 4 2T 5 T 6

rA ( X , T ) 0
r 2 2 z 2 2 z 2
Ti 1, j 1 2Ti , j 1 Ti 1, j 1
r

Si : i1
Ti 1, j 2Ti , j Ti 1,, j
r 2

4 (Ti , j 1 2Ti , j Ti , j 1 ) 5 (Ti , j 1 Ti , j ) 6


2

z 2

Para los valores:


i=0 j=1,,6

rA ( X i , j 1 , Ti , j 1 ) 0....( 8)

(Ti , j 1 2Ti , j Ti , j 1 )
(Ti , j Ti , j 1 )
1 Ti , j Ti 1, j
4

6 rA ( X i , j 1 , Ti , j 1 ) 0....( 9)
5
ir
r
z
z 2

Entonces:

Para los valores:

se aplicara la frmula (8)

i=1,,5 y j=1,,6;

se aplicara la frmula (9)

Para los valores:


i=0,.,5 y j=0

su temperatura inicial es: 400C

Para los valores:


i= 5 y j=0,.,6

existe intercambio de calor en sector externo

Se utiliza:

Para los valores:


j = 6 , i = 0,..,5

por ser valor mximo:

dT/dz = 0

Para la Ecuacin de velocidad:

Para valores de i=0,..,5 y j=0,..,6

SOLUCION EN POLYMATH

LENGUAJE EN POLYMATH

# Constantes de las Ecuaciones de Balance Materia


pi1 = ( Us * dp / Pmz) / (Us * dp / Pmr)
pi2 = -Us/(E * (Us * dp / Pmr))
pi3 = db / (Cao * E * (Us * dp / Pmr))
# Constantes de las Ecuaciones de Balance de Energia
pi4 = (dp * G * Cpf / Phz) / (dp * G * Cpf / Phr)
pi5 = -Us * df * Cpf / (dp * G * Cpf / Phr)
pi6 = db * (-dH) / (dp * G * Cpf / Phr)

# Datos del problema


db = 1025 # Densidad del lecho
G = 1709 # Flujo masico
Us = 2914.393 # Velocidad
dH = -94886 # Entalpia
Cpf = 1.09 # Capacidad Calorifica del Fluido
df = 0.5864 # Densidad del Fluido
Tw = 197 # Temperatura de la pared
Phr = 4.4 # Peclet de calor en direccion radial
Pmr = 9.6 # Peclet de masa en direccion radial
Phz = 4.4 # Peclet de Calor en Direccion Axial
Pmz = 9.6 # Peclet de Masa en Direccion Axial
Bi = 6.67 # Numero de Biot
dp = 0.003175
E = 0.5 # Porosidad del lecho
dz = (0.1524)/6
dr = 0.02615 / 5
# Calculo de la Concetracion inicial
Tin = 400 +273
Cao = Pao / (R * Tin )
R = 0.082
# Calculo de la Presiones iniciales
P = 1.6
ya = 0.065
Pao = 1.7 * 0.065
Pbo = (1 - ya) * P * 0.21

K101 = exp(12.16 - 5473 / (T01 + 273))


K102 = exp(12.16 - 5473 / (T02 + 273))
K103 = exp(12.16 - 5473 / (T03 + 273))
K104 = exp(12.16 - 5473 / (T04 + 273))
K105 = exp(12.16 - 5473 / (T05 + 273))
K106 = exp(12.16 - 5473 / (T06 + 273))
K111 = exp(12.16 - 5473 / (T11 + 273))
K112 = exp(12.16 - 5473 / (T12 + 273))
K113 = exp(12.16 - 5473 / (T13 + 273))
K114 = exp(12.16 - 5473 / (T14 + 273))
K115 = exp(12.16 - 5473 / (T15 + 273))
K116 = exp(12.16 - 5473 / (T16 + 273))
K121 = exp(12.16 - 5473 / (T21 + 273))
K122 = exp(12.16 - 5473 / (T22 + 273))
K123 = exp(12.16 - 5473 / (T23 + 273))
K124 = exp(12.16 - 5473 / (T24 + 273))
K125 = exp(12.16 - 5473 / (T25 + 273))
K126 = exp(12.16 - 5473 / (T26 + 273))
K131 = exp(12.16 - 5473 / (T31 + 273))

K132 = exp(12.16 - 5473 / (T32 + 273))


K133 = exp(12.16 - 5473 / (T33 + 273))
K134 = exp(12.16 - 5473 / (T34 + 273))
K135 = exp(12.16 - 5473 / (T35 + 273))
K136 = exp(12.16 - 5473 / (T36 + 273))

K141 = exp(12.16 - 5473 / (T41 + 273))


K142 = exp(12.16 - 5473 / (T42 + 273))
K143 = exp(12.16 - 5473 / (T43 + 273))
K144 = exp(12.16 - 5473 / (T44 + 273))
K145 = exp(12.16 - 5473 / (T45 + 273))
K146 = exp(12.16 - 5473 / (T46 + 273))

K151 = exp(12.16 - 5473 / (T51 + 273))


K152 = exp(12.16 - 5473 / (T52 + 273))
K153 = exp(12.16 - 5473 / (T53 + 273))
K154 = exp(12.16 - 5473 / (T54 + 273))
K155 = exp(12.16 - 5473 / (T55 + 273))
K156 = exp(12.16 - 5473 / (T56 + 273))
K201 = exp(-9.953 + 8619 / (T01 + 273))
K202 = exp(-9.953 + 8619 / (T02 + 273))
K203 = exp(-9.953 + 8619 / (T03 + 273))
K204 = exp(-9.953 + 8619 / (T04 + 273))
K205 = exp(-9.953 + 8619 / (T05 + 273))
K206 = exp(-9.953 + 8619 / (T06 + 273))

K211 = exp(-9.953 + 8619 / (T11 + 273))


K212 = exp(-9.953 + 8619 / (T12 + 273))
K213 = exp(-9.953 + 8619 / (T13 + 273))
K214 = exp(-9.953 + 8619 / (T14 + 273))
K215 = exp(-9.953 + 8619 / (T15 + 273))
K216 = exp(-9.953 + 8619 / (T16 + 273))
K221 = exp(-9.953 + 8619 / (T21 + 273))
K222 = exp(-9.953 + 8619 / (T22 + 273))
K223 = exp(-9.953 + 8619 / (T23 + 273))
K224 = exp(-9.953 + 8619 / (T24 + 273))
K225 = exp(-9.953 + 8619 / (T25 + 273))
K226 = exp(-9.953 + 8619 / (T26 + 273))
K231 = exp(-9.953 + 8619 / (T31 + 273))
K232 = exp(-9.953 + 8619 / (T32 + 273))
K233 = exp(-9.953 + 8619 / (T33 + 273))
K234 = exp(-9.953 + 8619 / (T34 + 273))
K235 = exp(-9.953 + 8619 / (T35 + 273))
K236 = exp(-9.953 + 8619 / (T36 + 273))
K241 = exp(-9.953 + 8619 / (T41 + 273))
K242 = exp(-9.953 + 8619 / (T42 + 273))
K243 = exp(-9.953 + 8619 / (T43 + 273))
K244 = exp(-9.953 + 8619 / (T44 + 273))
K245 = exp(-9.953 + 8619 / (T45 + 273))
K246 = exp(-9.953 + 8619 / (T46 + 273))

K251 = exp(-9.953 + 8619 / (T51 + 273))


K252 = exp(-9.953 + 8619 / (T52 + 273))
K253 = exp(-9.953 + 8619 / (T53 + 273))
K254 = exp(-9.953 + 8619 / (T54 + 273))
K255 = exp(-9.953 + 8619 / (T55 + 273))
K256 = exp(-9.953 + 8619 / (T56 + 273))
K301 = exp(-71.745 + 52596 / (T01 + 273))
K302 = exp(-71.745 + 52596 / (T02 + 273))
K303 = exp(-71.745 + 52596 / (T03 + 273))
K304 = exp(-71.745 + 52596 / (T04 + 273))
K305 = exp(-71.745 + 52596 / (T05 + 273))
K306 = exp(-71.745 + 52596 / (T06 + 273))
K311 = exp(-71.745 + 52596 / (T11 + 273))
K312 = exp(-71.745 + 52596 / (T12 + 273))
K313 = exp(-71.745 + 52596 / (T13 + 273))
K314 = exp(-71.745 + 52596 / (T14 + 273))
K315 = exp(-71.745 + 52596 / (T15 + 273))
K316 = exp(-71.745 + 52596 / (T16 + 273))
K321 = exp(-71.745 + 52596 / (T21 + 273))
K322 = exp(-71.745 + 52596 / (T22 + 273))
K323 = exp(-71.745 + 52596 / (T23 + 273))
K324 = exp(-71.745 + 52596 / (T24 + 273))
K325 = exp(-71.745 + 52596 / (T25 + 273))
K326 = exp(-71.745 + 52596 / (T26 + 273))
K331 = exp(-71.745 + 52596 / (T31 + 273))
K332 = exp(-71.745 + 52596 / (T32 + 273))
K333 = exp(-71.745 + 52596 / (T33 + 273))
K334 = exp(-71.745 + 52596 / (T34 + 273))
K335 = exp(-71.745 + 52596 / (T35 + 273))
K336 = exp(-71.745 + 52596 / (T36 + 273))
K341 = exp(-71.745 + 52596 / (T41 + 273))
K342 = exp(-71.745 + 52596 / (T42 + 273))
K343 = exp(-71.745 + 52596 / (T43 + 273))
K344 = exp(-71.745 + 52596 / (T44 + 273))
K345 = exp(-71.745 + 52596 / (T45 + 273))
K346 = exp(-71.745 + 52596 / (T46 + 273))
K351 = exp(-71.745 + 52596 / (T51 + 273))
K352 = exp(-71.745 + 52596 / (T52 + 273))
K353 = exp(-71.745 + 52596 / (T53 + 273))
K354 = exp(-71.745 + 52596 / (T54 + 273))
K355 = exp(-71.745 + 52596 / (T55 + 273))
K356 = exp(-71.745 + 52596 / (T56 + 273))
Kp01 = exp(11300 / (T01 + 273) - 10.68)
Kp02 = exp(11300 / (T02 + 273) - 10.68)
Kp03 = exp(11300 / (T03 + 273) - 10.68)
Kp04 = exp(11300 / (T04 + 273) - 10.68)
Kp05 = exp(11300 / (T05 + 273) - 10.68)
Kp06 = exp(11300 / (T06 + 273) - 10.68)

Kp11 = exp(11300 / (T11 + 273) - 10.68)


Kp12 = exp(11300 / (T12 + 273) - 10.68)
Kp13 = exp(11300 / (T13 + 273) - 10.68)
Kp14 = exp(11300 / (T14 + 273) - 10.68)
Kp15 = exp(11300 / (T15 + 273) - 10.68)
Kp16 = exp(11300 / (T16 + 273) - 10.68)
Kp21 = exp(11300 / (T21 + 273) - 10.68)
Kp22 = exp(11300 / (T22 + 273) - 10.68)
Kp23 = exp(11300 / (T23 + 273) - 10.68)
Kp24 = exp(11300 / (T24 + 273) - 10.68)
Kp25 = exp(11300 / (T25 + 273) - 10.68)
Kp26 = exp(11300 / (T26 + 273) - 10.68)
Kp31 = exp(11300 / (T31 + 273) - 10.68)
Kp32 = exp(11300 / (T32 + 273) - 10.68)
Kp33 = exp(11300 / (T33 + 273) - 10.68)
Kp34 = exp(11300 / (T34 + 273) - 10.68)
Kp35 = exp(11300 / (T35 + 273) - 10.68)
Kp36 = exp(11300 / (T36 + 273) - 10.68)
Kp41 = exp(11300 / (T41 + 273) - 10.68)
Kp42 = exp(11300 / (T42 + 273) - 10.68)
Kp43 = exp(11300 / (T43 + 273) - 10.68)
Kp44 = exp(11300 / (T44 + 273) - 10.68)
Kp45 = exp(11300 / (T45 + 273) - 10.68)
Kp46 = exp(11300 / (T46 + 273) - 10.68)
Kp51 = exp(11300 / (T51 + 273) - 10.68)
Kp52 = exp(11300 / (T52 + 273) - 10.68)
Kp53 = exp(11300 / (T53 + 273) - 10.68)
Kp54 = exp(11300 / (T54 + 273) - 10.68)
Kp55 = exp(11300 / (T55 + 273) - 10.68)
Kp56 = exp(11300 / (T56 + 273) - 10.68)
Pa01 = Pao * (1 - x01)
Pa02 = Pao * (1 - x02)
Pa03 = Pao * (1 - x03)
Pa04 = Pao * (1 - x04)
Pa05 = Pao * (1 - x05)
Pa06 = Pao * (1 - x06)
Pa11 = Pao * (1 - x11)
Pa12 = Pao * (1 - x12)
Pa13 = Pao * (1 - x13)
Pa14 = Pao * (1 - x14)
Pa15 = Pao * (1 - x15)
Pa16 = Pao * (1 - x16)
Pa21 = Pao * (1 - x21)
Pa22 = Pao * (1 - x22)
Pa23 = Pao * (1 - x23)
Pa24 = Pao * (1 - x24)
Pa25 = Pao * (1 - x25)
Pa26 = Pao * (1 - x26)
Pa31 = Pao * (1 - x31)

Pa32 = Pao * (1 - x32)


Pa33 = Pao * (1 - x33)
Pa34 = Pao * (1 - x34)
Pa35 = Pao * (1 - x35)
Pa36 = Pao * (1 - x36)
Pa41 = Pao * (1 - x41)
Pa42 = Pao * (1 - x42)
Pa43 = Pao * (1 - x43)
Pa44 = Pao * (1 - x44)
Pa45 = Pao * (1 - x45)
Pa46 = Pao * (1 - x46)
Pa51 = Pao * (1 - x51)
Pa52 = Pao * (1 - x52)
Pa53 = Pao * (1 - x53)
Pa54 = Pao * (1 - x54)
Pa55 = Pao * (1 - x55)
Pa56 = Pao * (1 - x56)
Pb01 = Pbo - 0.5 * Pao * x01
Pb02 = Pbo - 0.5 * Pao * x02
Pb03 = Pbo - 0.5 * Pao * x03
Pb04 = Pbo - 0.5 * Pao * x04
Pb05 = Pbo - 0.5 * Pao * x05
Pb06 = Pbo - 0.5 * Pao * x06
Pb11 = Pbo - 0.5 * Pao * x11
Pb12 = Pbo - 0.5 * Pao * x12
Pb13 = Pbo - 0.5 * Pao * x13
Pb14 = Pbo - 0.5 * Pao * x14
Pb15 = Pbo - 0.5 * Pao * x15
Pb16 = Pbo - 0.5 * Pao * x16
Pb21 = Pbo - 0.5 * Pao * x21
Pb22 = Pbo - 0.5 * Pao * x22
Pb23 = Pbo - 0.5 * Pao * x23
Pb24 = Pbo - 0.5 * Pao * x24
Pb25 = Pbo - 0.5 * Pao * x25
Pb26 = Pbo - 0.5 * Pao * x26
Pb31 = Pbo - 0.5 * Pao * x31
Pb32 = Pbo - 0.5 * Pao * x32
Pb33 = Pbo - 0.5 * Pao * x33
Pb34 = Pbo - 0.5 * Pao * x34
Pb35 = Pbo - 0.5 * Pao * x35
Pb36 = Pbo - 0.5 * Pao * x36

Pb41 = Pbo - 0.5 * Pao * x41


Pb42 = Pbo - 0.5 * Pao * x42
Pb43 = Pbo - 0.5 * Pao * x43
Pb44 = Pbo - 0.5 * Pao * x44
Pb45 = Pbo - 0.5 * Pao * x45
Pb46 = Pbo - 0.5 * Pao * x46
Pb51 = Pbo - 0.5 * Pao * x51

Pb52 = Pbo - 0.5 * Pao * x52


Pb53 = Pbo - 0.5 * Pao * x53
Pb54 = Pbo - 0.5 * Pao * x54
Pb55 = Pbo - 0.5 * Pao * x55
Pb56 = Pbo - 0.5 * Pao * x56

Pr01 = Pao * x01


Pr02 = Pao * x02
Pr03 = Pao * x03
Pr04 = Pao * x04
Pr05 = Pao * x05
Pr06 = Pao * x06
Pr11 = Pao * x11
Pr12 = Pao * x12
Pr13 = Pao * x13
Pr14 = Pao * x14
Pr15 = Pao * x15
Pr16 = Pao * x16

Pr21 = Pao * x21


Pr22 = Pao * x22
Pr23 = Pao * x23
Pr24 = Pao * x24
Pr25 = Pao * x25
Pr26 = Pao * x26
Pr31 = Pao * x31
Pr32 = Pao * x32
Pr33 = Pao * x33
Pr34 = Pao * x34
Pr35 = Pao * x35
Pr36 = Pao * x36
Pr41 = Pao * x41
Pr42 = Pao * x42
Pr43 = Pao * x43
Pr44 = Pao * x44
Pr45 = Pao * x45
Pr46 = Pao * x46
Pr51 = Pao * x51
Pr52 = Pao * x52
Pr53 = Pao * x53
Pr54 = Pao * x54
Pr55 = Pao * x55
Pr56 = Pao * x56

f(x01) = 2 * (x11 - 2 * x01 + x01) / dr ^ 2 + pi1 * (x02 - 2 * x01 + x00) / dz ^ 2 + pi2 * (x01 - x00) / dz
+ pi3 * (K101 * Pb01 * Pa01 * (1 - Pr01 / (Pa01 * (Pb01 ^ 0.5) * Kp01))) / (22.414 * (1 + K201 * Pa01
+ K301 * Pr01) ^ 2)

f(x02) = 2 * (x12 - 2 * x02 + x02) / dr ^ 2 + pi1 * (x03 - 2 * x02 + x01) / dz ^ 2 + pi2 * (x02 - x01) / dz
+ pi3 * (K102 * Pb02 * Pa02 * (1 - Pr02 / (Pa02 * (Pb02 ^ 0.5) * Kp02))) / (22.414 * (1 + K202 * Pa02
+ K302 * Pr02) ^ 2)
f(x03) = 2 * (x13 - 2 * x03 + x03) / dr ^ 2 + pi1 * (x04 - 2 * x03 + x02) / dz ^ 2 + pi2 * (x03 - x02) / dz
+ pi3 * (K103 * Pb03 * Pa03 * (1 - Pr03 / (Pa03 * (Pb03 ^ 0.5) * Kp03))) / (22.414 * (1 + K203 * Pa03
+ K303 * Pr03) ^ 2)
f(x04) = 2 * (x14 - 2 * x04 + x04) / dr ^ 2 + pi1 * (x05 - 2 * x04 + x03) / dz ^ 2 + pi2 * (x04 - x03) / dz
+ pi3 * (K104 * Pb04 * Pa04 * (1 - Pr04 / (Pa04 * (Pb04 ^ 0.5) * Kp04))) / (22.414 * (1 + K204 * Pa04
+ K304 * Pr04) ^ 2)
f(x05) = 2 * (x15 - 2 * x05 + x05) / dr ^ 2 + pi1 * (x06 - 2 * x05 + x04) / dz ^ 2 + pi2 * (x05 - x04) / dz
+ pi3 * (K105 * Pb05 * Pa05 * (1 - Pr05 / (Pa05 * (Pb05 ^ 0.5) * Kp05))) / (22.414 * (1 + K205 * Pa05
+ K305 * Pr05) ^ 2)
f(x06) = 2 * (x16 - 2 * x06 + x06) / dr ^ 2 + pi1 * (x06 - 2 * x06 + x05) / dz ^ 2 + pi2 * (x06 - x05) / dz
+ pi3 * (K106 * Pb06 * Pa06 * (1 - Pr06 / (Pa06 * (Pb06 ^ 0.5) * Kp06))) / (22.414 * (1 + K206 * Pa06
+ K306 * Pr06) ^ 2)
f(T01) = 2 * (T11 - 2 * T01 + T01) / dr ^ 2 + pi4 * (T02 - 2 * T01 + T00) / dz ^ 2 + pi5 * (T01 - T00) /
dz + pi6 * (K101 * Pb01 * Pa01 * (1 - Pr01 / (Pa01 * (Pb01 ^ 0.5) * Kp01))) / (22.414 * (1 + K201 *
Pa01 + K301 * Pr01) ^ 2)
f(T02) = 2 * (T12 - 2 * T02 + T02) / dr ^ 2 + pi4 * (T03 - 2 * T02 + T01) / dz ^ 2 + pi5 * (T02 - T01) /
dz + pi6 * (K102 * Pb02 * Pa02 * (1 - Pr02 / (Pa02 * (Pb02 ^ 0.5) * Kp02))) / (22.414 * (1 + K202 *
Pa02 + K302 * Pr02) ^ 2)
f(T03) = 2 * (T13 - 2 * T03 + T03) / dr ^ 2 + pi4 * (T04 - 2 * T03 + T02) / dz ^ 2 + pi5 * (T03 - T02) /
dz + pi6 * (K103 * Pb03 * Pa03 * (1 - Pr03 / (Pa03 * (Pb03 ^ 0.5) * Kp03))) / (22.414 * (1 + K203 *
Pa03 + K303 * Pr03) ^ 2)
f(T04) = 2 * (T14 - 2 * T04 + T04) / dr ^ 2 + pi4 * (T05 - 2 * T04 + T03) / dz ^ 2 + pi5 * (T04 - T03) /
dz + pi6 * (K104 * Pb04 * Pa04 * (1 - Pr04 / (Pa04 * (Pb04 ^ 0.5) * Kp04))) / (22.414 * (1 + K204 *
Pa04 + K304 * Pr04) ^ 2)
f(T05) = 2 * (T15 - 2 * T05 + T05) / dr ^ 2 + pi4 * (T06 - 2 * T05 + T04) / dz ^ 2 + pi5 * (T05 - T04) /
dz + pi6 * (K105 * Pb05 * Pa05 * (1 - Pr05 / (Pa05 * (Pb05 ^ 0.5) * Kp05))) / (22.414 * (1 + K205 *
Pa05 + K305 * Pr05) ^ 2)
f(T06) = 2 * (T16 - 2 * T06 + T06) / dr ^ 2 + pi4 * (T06 - 2 * T06 + T05) / dz ^ 2 + pi5 * (T06 - T05) /
dz + pi6 * (K106 * Pb06 * Pa06 * (1 - Pr06 / (Pa06 * (Pb06 ^ 0.5) * Kp06))) / (22.414 * (1 + K206 *
Pa06 + K306 * Pr06) ^ 2)

f(x11) = (x21 - 2 * x11 + x01) / dr ^ 2 + (x11 - x01) / (1 * dr ^ 2) + pi1 * (x12 - 2 * x11 + x10) / dz ^ 2
+ pi2 * (x11 - x10) / dz + pi3 * (K111 * Pb11 * Pa11 * (1 - Pr11 / (Pa11 * (Pb11 ^ 0.5) * Kp11))) /
(22.414 * (1 + K211 * Pa11 + K311 * Pr11) ^ 2)
f(x12) = (x22 - 2 * x12 + x02) / dr ^ 2 + (x12 - x02) / (1 * dr ^ 2) + pi1 * (x13 - 2 * x12 + x11) / dz ^ 2
+ pi2 * (x12 - x11) / dz + pi3 * (K112 * Pb12 * Pa12 * (1 - Pr12 / (Pa12 * (Pb12 ^ 0.5) * Kp12))) /
(22.414 * (1 + K212 * Pa12 + K312 * Pr12) ^ 2)
f(x13) = (x23 - 2 * x13 + x03) / dr ^ 2 + (x13 - x03) / (1 * dr ^ 2) + pi1 * (x14 - 2 * x13 + x12) / dz ^ 2
+ pi2 * (x13 - x12) / dz + pi3 * (K113 * Pb13 * Pa13 * (1 - Pr13 / (Pa13 * (Pb13 ^ 0.5) * Kp13))) /
(22.414 * (1 + K213 * Pa13 + K313 * Pr13) ^ 2)
f(x14) = (x24 - 2 * x14 + x04) / dr ^ 2 + (x14 - x04) / (1 * dr ^ 2) + pi1 * (x15 - 2 * x14 + x13) / dz ^ 2
+ pi2 * (x14 - x13) / dz + pi3 * (K114 * Pb14 * Pa14 * (1 - Pr14 / (Pa14 * (Pb14 ^ 0.5) * Kp14))) /
(22.414 * (1 + K214 * Pa14 + K314 * Pr14) ^ 2)
f(x15) = (x25 - 2 * x15 + x05) / dr ^ 2 + (x15 - x05) / (1 * dr ^ 2) + pi1 * (x16 - 2 * x15 + x14) / dz ^ 2
+ pi2 * (x15 - x14) / dz + pi3 * (K115 * Pb15 * Pa15 * (1 - Pr15 / (Pa15 * (Pb15 ^ 0.5) * Kp15))) /
(22.414 * (1 + K215 * Pa15 + K315 * Pr15) ^ 2)
f(x16) = (x26 - 2 * x16 + x06) / dr ^ 2 + (x16 - x06) / (1 * dr ^ 2) + pi1 * (x16 - 2 * x16 + x15) / dz ^ 2
+ pi2 * (x16 - x15) / dz + pi3 * (K116 * Pb16 * Pa16 * (1 - Pr16 / (Pa16 * (Pb16 ^ 0.5) * Kp16))) /
(22.414 * (1 + K216 * Pa16 + K316 * Pr16) ^ 2)
f(T11) = (T21 - 2 * T11 + T01) / dr ^ 2 + (T11 - T01) / (1 * dr ^ 2) + pi4 * (T12 - 2 * T11 + T10) / dz ^
2 + pi5 * (T11 - T10) / dz + pi6 * (K111 * Pb11 * Pa11 * (1 - Pr11 / (Pa11 * (Pb11 ^ 0.5) * Kp11))) /
(22.414 * (1 + K211 * Pa11 + K311 * Pr11) ^ 2)

f(T12) = (T22 - 2 * T12 + T02) / dr ^ 2 + (T12 - T02) / (1 * dr ^ 2) + pi4 * (T13 - 2 * T12 + T11) / dz ^
2 + pi5 * (T12 - T11) / dz + pi6 * (K112 * Pb12 * Pa12 * (1 - Pr12 / (Pa12 * (Pb12 ^ 0.5) * Kp12))) /
(22.414 * (1 + K212 * Pa12 + K312 * Pr12) ^ 2)
f(T13) = (T23 - 2 * T13 + T03) / dr ^ 2 + (T13 - T03) / (1 * dr ^ 2) + pi4 * (T14 - 2 * T13 + T12) / dz ^
2 + pi5 * (T13 - T12) / dz + pi6 * (K113 * Pb13 * Pa13 * (1 - Pr13 / (Pa13 * (Pb13 ^ 0.5) * Kp13))) /
(22.414 * (1 + K213 * Pa13 + K313 * Pr13) ^ 2)
f(T14) = (T24 - 2 * T14 + T04) / dr ^ 2 + (T14 - T04) / (1 * dr ^ 2) + pi4 * (T15 - 2 * T14 + T13) / dz ^
2 + pi5 * (T14 - T13) / dz + pi6 * (K114 * Pb14 * Pa14 * (1 - Pr14 / (Pa14 * (Pb14 ^ 0.5) * Kp14))) /
(22.414 * (1 + K214 * Pa14 + K314 * Pr14) ^ 2)
f(T15) = (T25 - 2 * T15 + T05) / dr ^ 2 + (T15 - T05) / (1 * dr ^ 2) + pi4 * (T16 - 2 * T15 + T14) / dz ^
2 + pi5 * (T15 - T14) / dz + pi6 * (K115 * Pb15 * Pa15 * (1 - Pr15 / (Pa15 * (Pb15 ^ 0.5) * Kp15))) /
(22.414 * (1 + K215 * Pa15 + K315 * Pr15) ^ 2)
f(T16) = (T26 - 2 * T16 + T06) / dr ^ 2 + (T16 - T06) / (1 * dr ^ 2) + pi4 * (T16 - 2 * T16 + T15) / dz ^
2 + pi5 * (T16 - T15) / dz + pi6 * (K116 * Pb16 * Pa16 * (1 - Pr16 / (Pa16 * (Pb16 ^ 0.5) * Kp16))) /
(22.414 * (1 + K216 * Pa16 + K316 * Pr16) ^ 2)

f(x21) = (x31 - 2 * x21 + x11) / dr ^ 2 + (x21 - x11) / (2 * dr ^ 2) + pi1 * (x22 - 2 * x21 + x20) / dz ^ 2
+ pi2 * (x21 - x20) / dz + pi3 * (K121 * Pb21 * Pa21 * (1 - Pr21 / (Pa21 * (Pb21 ^ 0.5) * Kp21))) /
(22.414 * (1 + K221 * Pa21 + K321 * Pr21) ^ 2)
f(x22) = (x32 - 2 * x22 + x12) / dr ^ 2 + (x22 - x12) / (2 * dr ^ 2) + pi1 * (x23 - 2 * x22 + x21) / dz ^ 2
+ pi2 * (x22 - x21) / dz + pi3 * (K122 * Pb22 * Pa22 * (1 - Pr22 / (Pa22 * (Pb22 ^ 0.5) * Kp22))) /
(22.414 * (1 + K222 * Pa22 + K322 * Pr22) ^ 2)
f(x23) = (x33 - 2 * x23 + x13) / dr ^ 2 + (x23 - x13) / (2 * dr ^ 2) + pi1 * (x24 - 2 * x23 + x22) / dz ^ 2
+ pi2 * (x23 - x22) / dz + pi3 * (K123 * Pb23 * Pa23 * (1 - Pr23 / (Pa23 * (Pb23 ^ 0.5) * Kp23))) /
(22.414 * (1 + K223 * Pa23 + K323 * Pr23) ^ 2)
f(x24) = (x34 - 2 * x24 + x14) / dr ^ 2 + (x24 - x14) / (2 * dr ^ 2) + pi1 * (x25 - 2 * x24 + x23) / dz ^ 2
+ pi2 * (x24 - x23) / dz + pi3 * (K124 * Pb24 * Pa24 * (1 - Pr24 / (Pa24 * (Pb24 ^ 0.5) * Kp24))) /
(22.414 * (1 + K224 * Pa24 + K324 * Pr24) ^ 2)
f(x25) = (x35 - 2 * x25 + x15) / dr ^ 2 + (x25 - x15) / (2 * dr ^ 2) + pi1 * (x26 - 2 * x25 + x24) / dz ^ 2
+ pi2 * (x25 - x24) / dz + pi3 * (K125 * Pb25 * Pa25 * (1 - Pr25 / (Pa25 * (Pb25 ^ 0.5) * Kp25))) /
(22.414 * (1 + K225 * Pa25 + K325 * Pr25) ^ 2)
f(x26) = (x36 - 2 * x26 + x16) / dr ^ 2 + (x26 - x16) / (2 * dr ^ 2) + pi1 * (x26 - 2 * x26 + x25) / dz ^ 2
+ pi2 * (x26 - x25) / dz + pi3 * (K126 * Pb26 * Pa26 * (1 - Pr26 / (Pa26 * (Pb26 ^ 0.5) * Kp26))) /
(22.414 * (1 + K226 * Pa26 + K326 * Pr26) ^ 2)
f(T21) = (T31 - 2 * T21 + T11) / dr ^ 2 + (T21 - T11) / (2 * dr ^ 2) + pi4 * (T22 - 2 * T21 + T20) / dz ^
2 + pi5 * (T21 - T20) / dz + pi6 * (K121 * Pb21 * Pa21 * (1 - Pr21 / (Pa21 * (Pb21 ^ 0.5) * Kp21))) /
(22.414 * (1 + K221 * Pa21 + K321 * Pr21) ^ 2)
f(T22) = (T32 - 2 * T22 + T12) / dr ^ 2 + (T22 - T12) / (2 * dr ^ 2) + pi4 * (T23 - 2 * T22 + T21) / dz ^
2 + pi5 * (T22 - T21) / dz + pi6 * (K122 * Pb22 * Pa22 * (1 - Pr22 / (Pa22 * (Pb22 ^ 0.5) * Kp22))) /
(22.414 * (1 + K222 * Pa22 + K322 * Pr22) ^ 2)
f(T23) = (T33 - 2 * T23 + T13) / dr ^ 2 + (T23 - T13) / (2 * dr ^ 2) + pi4 * (T24 - 2 * T23 + T22) / dz ^
2 + pi5 * (T23 - T22) / dz + pi6 * (K123 * Pb23 * Pa23 * (1 - Pr23 / (Pa23 * (Pb23 ^ 0.5) * Kp23))) /
(22.414 * (1 + K223 * Pa23 + K323 * Pr23) ^ 2)
f(T24) = (T34 - 2 * T24 + T14) / dr ^ 2 + (T24 - T14) / (2 * dr ^ 2) + pi4 * (T25 - 2 * T24 + T23) / dz ^
2 + pi5 * (T24 - T23) / dz + pi6 * (K124 * Pb24 * Pa24 * (1 - Pr24 / (Pa24 * (Pb24 ^ 0.5) * Kp24))) /
(22.414 * (1 + K224 * Pa24 + K324 * Pr24) ^ 2)
f(T25) = (T35 - 2 * T25 + T15) / dr ^ 2 + (T25 - T15) / (2 * dr ^ 2) + pi4 * (T26 - 2 * T25 + T24) / dz ^
2 + pi5 * (T25 - T24) / dz + pi6 * (K125 * Pb25 * Pa25 * (1 - Pr25 / (Pa25 * (Pb25 ^ 0.5) * Kp25))) /
(22.414 * (1 + K225 * Pa25 + K325 * Pr25) ^ 2)
f(T26) = (T36 - 2 * T26 + T16) / dr ^ 2 + (T26 - T16) / (2 * dr ^ 2) + pi4 * (T26 - 2 * T26 + T25) / dz ^
2 + pi5 * (T26 - T25) / dz + pi6 * (K126 * Pb26 * Pa26 * (1 - Pr26 / (Pa26 * (Pb26 ^ 0.5) * Kp26))) /
(22.414 * (1 + K226 * Pa26 + K326 * Pr26) ^ 2)

f(x31) = (x41 - 2 * x31 + x21) / dr ^ 2 + (x31 - x21) / (3 * dr ^ 2) + pi1 * (x32 - 2 * x31 + x30) / dz ^ 2
+ pi2 * (x31 - x30) / dz + pi3 * (K131 * Pb31 * Pa31 * (1 - Pr31 / (Pa31 * (Pb31 ^ 0.5) * Kp31))) /
(22.414 * (1 + K231 * Pa31 + K331 * Pr31) ^ 2)
f(x32) = (x42 - 2 * x32 + x22) / dr ^ 2 + (x32 - x22) / (3 * dr ^ 2) + pi1 * (x33 - 2 * x32 + x31) / dz ^ 2
+ pi2 * (x32 - x31) / dz + pi3 * (K132 * Pb32 * Pa32 * (1 - Pr32 / (Pa32 * (Pb32 ^ 0.5) * Kp32))) /
(22.414 * (1 + K232 * Pa32 + K332 * Pr32) ^ 2)
f(x33) = (x43 - 2 * x33 + x23) / dr ^ 2 + (x33 - x23) / (3 * dr ^ 2) + pi1 * (x34 - 2 * x33 + x32) / dz ^ 2
+ pi2 * (x33 - x32) / dz + pi3 * (K133 * Pb33 * Pa33 * (1 - Pr33 / (Pa33 * (Pb33 ^ 0.5) * Kp33))) /
(22.414 * (1 + K233 * Pa33 + K333 * Pr33) ^ 2)
f(x34) = (x44 - 2 * x34 + x24) / dr ^ 2 + (x34 - x24) / (3 * dr ^ 2) + pi1 * (x35 - 2 * x34 + x33) / dz ^ 2
+ pi2 * (x34 - x33) / dz + pi3 * (K134 * Pb34 * Pa34 * (1 - Pr34 / (Pa34 * (Pb34 ^ 0.5) * Kp34))) /
(22.414 * (1 + K234 * Pa34 + K334 * Pr34) ^ 2)
f(x35) = (x45 - 2 * x35 + x25) / dr ^ 2 + (x35 - x25) / (3 * dr ^ 2) + pi1 * (x36 - 2 * x35 + x34) / dz ^ 2
+ pi2 * (x35 - x34) / dz + pi3 * (K135 * Pb35 * Pa35 * (1 - Pr35 / (Pa35 * (Pb35 ^ 0.5) * Kp35))) /
(22.414 * (1 + K235 * Pa35 + K335 * Pr35) ^ 2)
f(x36) = (x46 - 2 * x36 + x26) / dr ^ 2 + (x36 - x26) / (3 * dr ^ 2) + pi1 * (x36 - 2 * x36 + x35) / dz ^ 2
+ pi2 * (x36 - x35) / dz + pi3 * (K136 * Pb36 * Pa36 * (1 - Pr36 / (Pa36 * (Pb36 ^ 0.5) * Kp36))) /
(22.414 * (1 + K236 * Pa36 + K336 * Pr36) ^ 2)
f(T31) = (T41 - 2 * T31 + T21) / dr ^ 2 + (T31 - T21) / (3 * dr ^ 2) + pi4 * (T32 - 2 * T31 + T30) / dz ^
2 + pi5 * (T31 - T30) / dz + pi6 * (K131 * Pb31 * Pa31 * (1 - Pr31 / (Pa31 * (Pb31 ^ 0.5) * Kp31))) /
(22.414 * (1 + K231 * Pa31 + K331 * Pr31) ^ 2)
f(T32) = (T42 - 2 * T32 + T22) / dr ^ 2 + (T32 - T22) / (3 * dr ^ 2) + pi4 * (T33 - 2 * T32 + T31) / dz ^
2 + pi5 * (T32 - T31) / dz + pi6 * (K132 * Pb32 * Pa32 * (1 - Pr32 / (Pa32 * (Pb32 ^ 0.5) * Kp32))) /
(22.414 * (1 + K232 * Pa32 + K332 * Pr32) ^ 2)
f(T33) = (T43 - 2 * T33 + T23) / dr ^ 2 + (T33 - T23) / (3 * dr ^ 2) + pi4 * (T34 - 2 * T33 + T32) / dz ^
2 + pi5 * (T33 - T32) / dz + pi6 * (K133 * Pb33 * Pa33 * (1 - Pr33 / (Pa33 * (Pb33 ^ 0.5) * Kp33))) /
(22.414 * (1 + K233 * Pa33 + K333 * Pr33) ^ 2)
f(T34) = (T44 - 2 * T34 + T24) / dr ^ 2 + (T34 - T24) / (3 * dr ^ 2) + pi4 * (T35 - 2 * T34 + T33) / dz ^
2 + pi5 * (T34 - T33) / dz + pi6 * (K134 * Pb34 * Pa34 * (1 - Pr34 / (Pa34 * (Pb34 ^ 0.5) * Kp34))) /
(22.414 * (1 + K234 * Pa34 + K334 * Pr34) ^ 2)
f(T35) = (T45 - 2 * T35 + T25) / dr ^ 2 + (T35 - T25) / (3 * dr ^ 2) + pi4 * (T36 - 2 * T35 + T34) / dz ^
2 + pi5 * (T35 - T34) / dz + pi6 * (K135 * Pb35 * Pa35 * (1 - Pr35 / (Pa35 * (Pb35 ^ 0.5) * Kp35))) /
(22.414 * (1 + K235 * Pa35 + K335 * Pr35) ^ 2)
f(T36) = (T46 - 2 * T36 + T26) / dr ^ 2 + (T36 - T26) / (3 * dr ^ 2) + pi4 * (T36 - 2 * T36 + T35) / dz ^
2 + pi5 * (T36 - T35) / dz + pi6 * (K136 * Pb36 * Pa36 * (1 - Pr36 / (Pa36 * (Pb36 ^ 0.5) * Kp36))) /
(22.414 * (1 + K236 * Pa36 + K336 * Pr36) ^ 2)

f(x41) = (x51 - 2 * x41 + x31) / dr ^ 2 + (x41 - x31) / (4 * dr ^ 2) + pi1 * (x42 - 2 * x41 + x40) / dz ^ 2
+ pi2 * (x41 - x40) / dz + pi3 * (K141 * Pb41 * Pa41 * (1 - Pr41 / (Pa41 * (Pb41 ^ 0.5) * Kp41))) /
(22.414 * (1 + K241 * Pa41 + K341 * Pr41) ^ 2)
f(x42) = (x52 - 2 * x42 + x32) / dr ^ 2 + (x42 - x32) / (4 * dr ^ 2) + pi1 * (x43 - 2 * x42 + x41) / dz ^ 2
+ pi2 * (x42 - x41) / dz + pi3 * (K142 * Pb42 * Pa42 * (1 - Pr42 / (Pa42 * (Pb42 ^ 0.5) * Kp42))) /
(22.414 * (1 + K242 * Pa42 + K342 * Pr42) ^ 2)
f(x43) = (x53 - 2 * x43 + x33) / dr ^ 2 + (x43 - x33) / (4 * dr ^ 2) + pi1 * (x44 - 2 * x43 + x42) / dz ^ 2
+ pi2 * (x43 - x42) / dz + pi3 * (K143 * Pb43 * Pa43 * (1 - Pr43 / (Pa43 * (Pb43 ^ 0.5) * Kp43))) /
(22.414 * (1 + K243 * Pa43 + K343 * Pr43) ^ 2)
f(x44) = (x54 - 2 * x44 + x34) / dr ^ 2 + (x44 - x34) / (4 * dr ^ 2) + pi1 * (x45 - 2 * x44 + x43) / dz ^ 2
+ pi2 * (x44 - x43) / dz + pi3 * (K144 * Pb44 * Pa44 * (1 - Pr44 / (Pa44 * (Pb44 ^ 0.5) * Kp44))) /
(22.414 * (1 + K244 * Pa44 + K344 * Pr44) ^ 2)
f(x45) = (x55 - 2 * x45 + x35) / dr ^ 2 + (x45 - x35) / (4 * dr ^ 2) + pi1 * (x46 - 2 * x45 + x44) / dz ^ 2
+ pi2 * (x45 - x44) / dz + pi3 * (K145 * Pb45 * Pa45 * (1 - Pr45 / (Pa45 * (Pb45 ^ 0.5) * Kp45))) /
(22.414 * (1 + K245 * Pa45 + K345 * Pr45) ^ 2)
f(x46) = (x56 - 2 * x46 + x36) / dr ^ 2 + (x46 - x36) / (4 * dr ^ 2) + pi1 * (x46 - 2 * x46 + x45) / dz ^ 2
+ pi2 * (x46 - x45) / dz + pi3 * (K146 * Pb46 * Pa46 * (1 - Pr46 / (Pa46 * (Pb46 ^ 0.5) * Kp46))) /
(22.414 * (1 + K246 * Pa46 + K346 * Pr46) ^ 2)

f(T41) = (T51 - 2 * T41 + T31) / dr ^ 2 + (T41 - T31) / (4 * dr ^ 2) + pi4 * (T42 - 2 * T41 + T40) / dz ^
2 + pi5 * (T41 - T40) / dz + pi6 * (K141 * Pb41 * Pa41 * (1 - Pr41 / (Pa41 * (Pb41 ^ 0.5) * Kp41))) /
(22.414 * (1 + K241 * Pa41 + K341 * Pr41) ^ 2)
f(T42) = (T52 - 2 * T42 + T32) / dr ^ 2 + (T42 - T32) / (4 * dr ^ 2) + pi4 * (T43 - 2 * T42 + T41) / dz ^
2 + pi5 * (T42 - T41) / dz + pi6 * (K142 * Pb42 * Pa42 * (1 - Pr42 / (Pa42 * (Pb42 ^ 0.5) * Kp42))) /
(22.414 * (1 + K242 * Pa42 + K342 * Pr42) ^ 2)
f(T43) = (T53 - 2 * T43 + T33) / dr ^ 2 + (T43 - T33) / (4 * dr ^ 2) + pi4 * (T44 - 2 * T43 + T42) / dz ^
2 + pi5 * (T43 - T42) / dz + pi6 * (K143 * Pb43 * Pa43 * (1 - Pr43 / (Pa43 * (Pb43 ^ 0.5) * Kp43))) /
(22.414 * (1 + K243 * Pa43 + K343 * Pr43) ^ 2)
f(T44) = (T54 - 2 * T44 + T34) / dr ^ 2 + (T44 - T34) / (4 * dr ^ 2) + pi4 * (T45 - 2 * T44 + T43) / dz ^
2 + pi5 * (T44 - T43) / dz + pi6 * (K144 * Pb44 * Pa44 * (1 - Pr44 / (Pa44 * (Pb44 ^ 0.5) * Kp44))) /
(22.414 * (1 + K244 * Pa44 + K344 * Pr44) ^ 2)
f(T45) = (T55 - 2 * T45 + T35) / dr ^ 2 + (T45 - T35) / (4 * dr ^ 2) + pi4 * (T46 - 2 * T45 + T44) / dz ^
2 + pi5 * (T45 - T44) / dz + pi6 * (K145 * Pb45 * Pa45 * (1 - Pr45 / (Pa45 * (Pb45 ^ 0.5) * Kp45))) /
(22.414 * (1 + K245 * Pa45 + K345 * Pr45) ^ 2)
f(T46) = (T56 - 2 * T46 + T36) / dr ^ 2 + (T46 - T36) / (4 * dr ^ 2) + pi4 * (T46 - 2 * T46 + T45) / dz ^
2 + pi5 * (T46 - T45) / dz + pi6 * (K146 * Pb46 * Pa46 * (1 - Pr46 / (Pa46 * (Pb46 ^ 0.5) * Kp46))) /
(22.414 * (1 + K246 * Pa46 + K346 * Pr46) ^ 2)

f(x51) = (x51 - 2 * x51 + x41) / dr ^ 2 + (x51 - x41) / (5 * dr ^ 2) + pi1 * (x52 - 2 * x51 + x50) / dz ^ 2
+ pi2 * (x51 - x50) / dz + pi3 * (K151 * Pb51 * Pa51 * (1 - Pr51 / (Pa51 * (Pb51 ^ 0.5) * Kp51))) /
(22.414 * (1 + K251 * Pa51 + K351 * Pr51) ^ 2)
f(x52) = (x52 - 2 * x52 + x42) / dr ^ 2 + (x52 - x42) / (5 * dr ^ 2) + pi1 * (x53 - 2 * x52 + x51) / dz ^ 2
+ pi2 * (x52 - x51) / dz + pi3 * (K152 * Pb52 * Pa52 * (1 - Pr52 / (Pa52 * (Pb52 ^ 0.5) * Kp52))) /
(22.414 * (1 + K252 * Pa52 + K352 * Pr52) ^ 2)
f(x53) = (x53 - 2 * x53 + x43) / dr ^ 2 + (x53 - x43) / (5 * dr ^ 2) + pi1 * (x54 - 2 * x53 + x52) / dz ^ 2
+ pi2 * (x53 - x52) / dz + pi3 * (K153 * Pb53 * Pa53 * (1 - Pr53 / (Pa53 * (Pb53 ^ 0.5) * Kp53))) /
(22.414 * (1 + K253 * Pa53 + K353 * Pr53) ^ 2)
f(x54) = (x54 - 2 * x54 + x44) / dr ^ 2 + (x54 - x44) / (5 * dr ^ 2) + pi1 * (x55 - 2 * x54 + x53) / dz ^ 2
+ pi2 * (x54 - x53) / dz + pi3 * (K154 * Pb54 * Pa54 * (1 - Pr54 / (Pa54 * (Pb54 ^ 0.5) * Kp54))) /
(22.414 * (1 + K254 * Pa54 + K354 * Pr54) ^ 2)
f(x55) = (x55 - 2 * x55 + x45) / dr ^ 2 + (x55 - x45) / (5 * dr ^ 2) + pi1 * (x56 - 2 * x55 + x54) / dz ^ 2
+ pi2 * (x55 - x54) / dz + pi3 * (K155 * Pb55 * Pa55 * (1 - Pr55 / (Pa55 * (Pb55 ^ 0.5) * Kp55))) /
(22.414 * (1 + K255 * Pa55 + K355 * Pr55) ^ 2)
f(x56) = (x56 - 2 * x56 + x46) / dr ^ 2 + (x56 - x46) / (5 * dr ^ 2) + pi1 * (x56 - 2 * x56 + x55) / dz ^ 2
+ pi2 * (x56 - x55) / dz + pi3 * (K156 * Pb56 * Pa56 * (1 - Pr56 / (Pa56 * (Pb56 ^ 0.5) * Kp56))) /
(22.414 * (1 + K256 * Pa56 + K356 * Pr56) ^ 2)
f(T51) = (T61 - 2 * T51 + T41) / dr ^ 2 + (T51 - T41) / (5 * dr ^ 2) + pi4 * (T52 - 2 * T51 + T50) / dz ^
2 + pi5 * (T51 - T50) / dz + pi6 * (K151 * Pb51 * Pa51 * (1 - Pr51 / (Pa51 * (Pb51 ^ 0.5) * Kp51))) /
(22.414 * (1 + K251 * Pa51 + K351 * Pr51) ^ 2)
f(T52) = (T62 - 2 * T52 + T42) / dr ^ 2 + (T52 - T42) / (5 * dr ^ 2) + pi4 * (T53 - 2 * T52 + T51) / dz ^
2 + pi5 * (T52 - T51) / dz + pi6 * (K152 * Pb52 * Pa52 * (1 - Pr52 / (Pa52 * (Pb52 ^ 0.5) * Kp52))) /
(22.414 * (1 + K252 * Pa52 + K352 * Pr52) ^ 2)
f(T53) = (T63 - 2 * T53 + T43) / dr ^ 2 + (T53 - T43) / (5 * dr ^ 2) + pi4 * (T54 - 2 * T53 + T52) / dz ^
2 + pi5 * (T53 - T52) / dz + pi6 * (K153 * Pb53 * Pa53 * (1 - Pr53 / (Pa53 * (Pb53 ^ 0.5) * Kp53))) /
(22.414 * (1 + K253 * Pa53 + K353 * Pr53) ^ 2)
f(T54) = (T64 - 2 * T54 + T44) / dr ^ 2 + (T54 - T44) / (5 * dr ^ 2) + pi4 * (T55 - 2 * T54 + T53) / dz ^
2 + pi5 * (T54 - T53) / dz + pi6 * (K154 * Pb54 * Pa54 * (1 - Pr54 / (Pa54 * (Pb54 ^ 0.5) * Kp54))) /
(22.414 * (1 + K254 * Pa54 + K354 * Pr54) ^ 2)
f(T55) = (T65 - 2 * T55 + T45) / dr ^ 2 + (T55 - T45) / (5 * dr ^ 2) + pi4 * (T56 - 2 * T55 + T54) / dz ^
2 + pi5 * (T55 - T54) / dz + pi6 * (K155 * Pb55 * Pa55 * (1 - Pr55 / (Pa55 * (Pb55 ^ 0.5) * Kp55))) /
(22.414 * (1 + K255 * Pa55 + K355 * Pr55) ^ 2)
f(T56) = (T66 - 2 * T56 + T46) / dr ^ 2 + (T56 - T46) / (5 * dr ^ 2) + pi4 * (T56 - 2 * T56 + T55) / dz ^
2 + pi5 * (T56 - T55) / dz + pi6 * (K156 * Pb56 * Pa56 * (1 - Pr56 / (Pa56 * (Pb56 ^ 0.5) * Kp56))) /
(22.414 * (1 + K256 * Pa56 + K356 * Pr56) ^ 2)

T61 =
T62 =
T63 =
T64 =
T65 =
T66 =

T51 - Bi*(T51 - Tw)/5


T52 - Bi*(T52 - Tw)/5
T53 - Bi*(T53 - Tw)/5
T54 - Bi*(T54 - Tw)/5
T55 - Bi*(T55 - Tw)/5
T56 - Bi*(T56 - Tw)/5

x00 = 0
x10 = 0
x20 = 0
x30 = 0
x40 = 0
x50 = 0
x01(0) = 0
x02(0) = 0
x03(0) = 0
x04(0) = 0
x05(0) = 0
x06(0) = 0
x11(0) = 0
x12(0) = 0
x13(0) = 0
x14(0) = 0
x15(0) = 0
x16(0) = 0
x21(0) = 0
x22(0) = 0
x23(0) = 0
x24(0) = 0
x25(0) = 0
x26(0) = 0
x31(0) = 0
x32(0) = 0
x33(0) = 0
x34(0) = 0
x35(0) = 0
x36(0) = 0
x41(0) = 0
x42(0) = 0
x43(0) = 0
x44(0) = 0
x45(0) = 0
x46(0) = 0
x51(0) = 0
x52(0) = 0
x53(0) = 0
x54(0) = 0
x55(0) = 0
x56(0) = 0
T00 = 400
T10 = 400
T20 = 400

T30 = 400
T40 = 400
T50 = 400
T01(0) = 400
T02(0) = 400
T03(0) = 400
T04(0) = 400
T05(0) = 400
T06(0) = 400
T11(0) = 400
T12(0) = 400
T13(0) = 400
T14(0) = 400
T15(0) = 400
T16(0) = 400
T21(0) = 400
T22(0) = 400
T23(0) = 400
T24(0) = 400
T25(0) = 400
T26(0) = 400
T31(0) = 400
T32(0) = 400
T33(0) = 400
T34(0) = 400
T35(0) = 400
T36(0) = 400
T41(0) = 400
T42(0) = 400
T43(0) = 400
T44(0) = 400
T45(0) = 400
T46(0) = 400
T51(0) = 400
T52(0) = 400
T53(0) = 400
T54(0) = 400
T55(0) = 400
T56(0) = 400

Con las tablas obtenidas por polymath, procedemos a graficar


DATOS OBTENIDOS EN POLYMATH

ro
Radio

r1
0

x0

r2
0.00523

x1

r3
0.01046

x2

r4
0.01569

x3

r5
0.02092

x4

0.02615
x5

xprom

0.0254

0.033205

0.0304528

0.0241723

0.0141693

0.0037283

0.0004082

0.01768932

0.0508

0.0621238

0.0510427

0.0331441

0.0156018

0.0044601

0.0008516

0.02787068

0.0762

0.0743783

0.0565632

0.0337676

0.0158213

0.0051107

0.0013177

0.0311598

0.1016

0.0730974

0.0547159

0.0329347

0.0159783

0.0056959

0.0017967

0.03070315

0.127

0.0684806

0.0517973

0.0320125

0.0160927

0.0062261

0.0022813

0.02948175

0.1524

0.0639686

0.0490635

0.031104

0.0161683

0.006707

0.0027627

0.02829568

ro
Radio

r1
0

T0

r2
0.00523

T1

r3
0.01046

T2

r4
0.01569

T3

r5
0.02092

T4

0.02615
T5

Tprom

400

400

400

400

400

400

400

0.0254

408.0895

406.6659

402.9154

394.5097

374.5033

320.175

384.476467

0.0508

411.5191

407.0443

397.5037

380.2837

347.0625

281.0043

370.736267

0.0762

407.4392

400.5537

387.003

363.9168

324.0797

259.7039

357.11605

0.1016

398.1714

390.3222

374.4462

347.7533

305.7875

246.8546

343.8892

0.127

387.0574

378.6604

361.2166

332.7341

291.2583

238.3402

331.5445

0.1524

375.5467

366.7055

348.3545

319.4386

279.7556

232.3394

320.356717

X vs Z
0.08
0.07

Conversion

0.06
T0

0.05

T1

0.04

T2

0.03

T3

0.02

T4
T5

0.01
0.00
0

0.015240.030480.045720.06096 0.0762 0.091440.106680.121920.13716 0.1524


Z en metros

T vs Z
420.0
400.0
380.0
Temperatura

360.0

T0

340.0

T1

320.0

T2

300.0

T3

280.0

T4

260.0

T5

240.0
220.0
0

0.015240.030480.045720.060960.07620.091440.106680.121920.137160.1524
Z en metros

Perfil de conversion
0.08
0.07
0.06
Conversion

0
0.05

0.0254
0.0508

0.04

0.0762

0.03

0.1016
0.02

0.127
0.1524

0.01
0.00
0

0.00523

0.01046

0.01569

0.02092

0.02615

Radio en Metros

Perfil de Temperatura
430.0
410.0

Temperatura

390.0
370.0

350.0

0.0254

330.0

0.0508

310.0

0.0762

290.0

0.1016

270.0

0.127
0.1524

250.0
230.0
0

0.00523

0.01046

0.01569

Radio en Metros

0.02092

0.02615

X promedio
0.035

Conversion Promedio

0.03
0.025
0.02
0.015
0.01
0.005
0
0

0.02

0.04

0.06

0.08

0.1

0.12

0.14

0.16

0.18

0.12

0.14

0.16

0.18

Z en metros

T promedio
400

Tmeperatura Promedio

390
380
370
360
350
340
330
320
310
300
0

0.02

0.04

0.06

0.08

0.1

Z en metros

COMPARACION DEL
CASO I, II YIII

COMPARACION DEL CASO I, II YIII


Se obtuvo las siguientes tablas
CASO I
Z

CASO II
Xprom

CASO III
xprom

xprom

0.000
0.015
0.030
0.046
0.061
0.076
0.091
0.107
0.122
0.137
0.152

0.0000

0.0245257
0.0505842
0.0886139
0.1599124
0.3207904
0.624388
0.7754533
0.7878356
0.788415
0.788441

0.0000
0.0152
0.0305
0.0457
0.0610
0.0762

0.000
0.000
0.000
0.000
0.000
0.000

0
0.0254
0.0508
0.0762
0.1016
0.127

0
0
0
0
0
0

0.0914

0.000

0.1524

0.1067
0.1219
0.1372

0.000
0.000
0.000

0.1524

0.000

X vs Z
0.8
0.7
0.6

Conversion

0.5
Caso 1

0.4

Caso 2
0.3

Caso 3

0.2
0.1
0.0
-0.015 0.000 0.015 0.030 0.046 0.061 0.076 0.091 0.107 0.122 0.137 0.152
Longitud del reactor metros

Se obtuvo las siguientes tablas


CASO I
Z
0.000
0.015
0.030
0.046
0.061
0.076

CASO II
Tprom
400.00

406.8598
414.1483
424.7851
444.7272
489.7244

z
0.0000
0.0152
0.0305
0.0457
0.0610
0.0762

CASO III
Tprom
0
0
0
0
0
0

z
0
0.0254
0.0508
0.0762
0.1016
0.127

Tprom
0
0
0
0
0
0

0.091
0.107
0.122
0.137
0.152

574.6401
616.8927
620.356
620.5181
620.5253

0.0914

0.1067
0.1219
0.1372

0
0
0

0.1524

0.1524

X vs Z
0.8
0.7
0.6

Conversion

0.5
Caso 1

0.4

Caso 2
0.3

Caso 3

0.2
0.1
0.0
-0.015 0.000 0.015 0.030 0.046 0.061 0.076 0.091 0.107 0.122 0.137 0.152
Longitud del reactor metros

PUNTOS CALIENTES

PUNTOS CALIENTES
TABLAS OBTENIDAS EN POLYMATH
390C
r

400C
r

z
10
9
8
7
6
5
4
3
2

0.002
0.008
0.02
0.035
0.055
0.08
0.12
0.135
0.151

410C
r

z
0
1
2
3
4
5
6
7
8

0
0
0
0
0
0
0
0
0

z
0
1
2
3
4
4
3
2
1

0.023
0.023
0.023
0.023
0.025
0.05
0.088
0.116
0.129

420C
r

z
0
1
2
2
1
0

430C
r

0.041
0.042
0.045
0.101
0.12
0.126

z
0
1
1
0

0.056
0.058
0.11
0.119

GRAFICA DE PUNTOS CALIENTES

9
10
10
9
8
7
6
5
4

0
0
0
0
0.005
0.015
0.029
0.047
0.074

3
2
1
0

0.105
0.126
0.138
0.143

440C
r

0.134

z
0
1
1
0

0.068
0.079
0.096
0.11

CONCLUSIONES

La presin que utilizamos para el trabajo fue de 1.6 atm. Estuvimos probando con
varias presiones, y esta fue la que mejor se adecuo a las graficas dadas por el
profesor.
Comparando los tres casos, concluimos que el caso que mejor se ajusta al trabajo es
el caso II. Del cual se obtiene una conversin de 0.798 a la presin de 1.6 atm.
En el caso III se observo una conversin mnima (muy baja) esto se deba al igualar
el peclet axial con el peclet radial, (no tenamos datos del peclet radial de masa y
calor).
Los valores mas altos en el caso III son los valores centrales, tal como se observa en
la grafica.

FIN

CASO III
MODIFICADO
CON DIFUSION AXIAL Y
RADIAL

SOLUCION EN POLYMATH
LENGUAJE EN POLYMATH

Calculated values of NLE variables


Variable Value

f(x)

Initial Guess

x01

0.0736259 6.149E-07 0

x02

0.1577011 6.391E-07 0

x03

0.2533425 -3.403E-08 0

x04

0.3513065 -5.805E-08 0

x05

0.4294447 -3.635E-06 0

x06

0.4663684 -4.697E-06 0

T01

408.209

4.188E-05 400.

T02

419.8046

4.35E-05

T03

441.2436

-2.367E-06 400.

10 T04

475.2143

-4.003E-06 400.

11 T05

506.0725

-0.0002476 400.

12 T06

499.5153

-0.0003198 400.

13 x11

0.0362447 1.555E-08 0

14 x12

0.0727259 8.195E-09 0

15 x13

0.1066693 3.7E-09

16 x14

0.1333403 1.401E-09 0

17 x15

0.1471837 3.765E-09 0

18 x16

0.1474863 -2.762E-08 0

19 T11

409.9081

1.057E-06 400.

20 T12

419.9525

5.617E-07 400.

21 T13

429.1264

2.454E-07 400.

22 T14

436.5353

1.001E-07 400.

23 T15

435.7941

2.489E-07 400.

24 T16

413.4572

-1.906E-06 400.

25 x21

0.0150895 9.863E-09 0

26 x22

0.0253191 1.312E-08 0

27 x23

0.0306477 2.094E-08 0

28 x24

0.0331322 1.616E-08 0

29 x25

0.0344738 3.405E-09 0

30 x26

0.0351303 1.471E-10 0

31 T21

407.8283

6.716E-07 400.

32 T22

408.5118

8.976E-07 400.

33 T23

402.4555

1.428E-06 400.

34 T24

393.5392

1.103E-06 400.

35 T25

383.775

2.274E-07 400.

36 T26

371.0321

1.168E-08 400.

37 x31

0.0060563 3.242E-08 0

38 x32

0.0079257 7.98E-08

39 x33

0.0086074 1.466E-08 0

40 x34

0.0091252 4.258E-10 0

41 x35

0.0095016 9.255E-12 0

400.

42 x36

0.0097058 2.187E-13 0

43 T31

398.5568

2.209E-06 400.

44 T32

386.2546

5.432E-06 400.

45 T33

370.9801

9.97E-07

46 T34

356.2591

2.592E-08 400.

47 T35

342.8984

4.634E-09 400.

48 T36

330.5216

-1.519E-09 400.

49 x41

0.0014707 2.232E-06 0

50 x42

0.0017463 6.058E-08 0

51 x43

0.0019836 6.279E-11 0

52 x44

0.0021775 -1.435E-13 0

53 x45

0.0023179 1.022E-12 0

54 x46

0.0023939 -6.128E-13 0

55 T41

376.2505

0.0001521 400.

56 T42

349.3648

4.13E-06

57 T43

326.983

8.268E-09 400.

58 T44

309.4037

1.234E-09 400.

59 T45

295.6876

-9.838E-10 400.

60 T46

284.7872

1.332E-09 400.

61 x51

0.000118

4.238E-08 0

62 x52

0.0002281 -4.72E-14

63 x53

0.000326

64 x54

0.0004069 -1.167E-13 0

65 x55

0.0004659 4.008E-14 0

66 x56

0.0004981 3.054E-14 0

67 T51

320.3186

2.889E-06 400.

68 T52

281.4645

-5.52E-09

400.

69 T53

260.4833

-4.2E-09

400.

70 T54

247.9473

2.224E-09 400.

71 T55

239.7515

5.852E-11 400.

72 T56

233.993

1.339E-09 400.

Variable Value
1

Pmz

0.01

0.5

0.082

Phz

9.

Phr

4.4

dp

0.003175

400.

400.

9.864E-14 0

db

1025.

1709.

Us

2914.393

10

dH

-9.489E+04

11

Cpf

1.09

12

df

0.5864

13

Tw

197.

14

pi5

-1385.827

15

Pmr

9.6

16

pi4

0.4888889

17

pi1

960.

18

Bi

6.67

19

pi6

7.235E+07

20

pi2

-6047.244

21

dz

0.0254

22

dr

0.00523

23

Tin

673.

24

Pao

0.1105

25

Cao

0.0020023

26

1.6

27

ya

0.065

28

pi3

1.062E+06

29

Pbo

0.31416

30

K101

61.91454

31

K102

70.826

32

K103

89.77875

33

K104

127.1352

34

K105

169.8609

35

K106

160.0284

36

K111

63.16464

37

K112

70.94545

38

K113

78.65786

39

K114

85.32788

40

K115

84.64238

41

K116

65.8368

42

K121

61.63703

43

K122

62.13592

44

K123

57.81914

45

K124

51.87981

46

K125

45.91801

47

K126

38.9382

48

K131

55.16234

49

K132

47.37996

50

K133

38.91154

51

K134

31.89568

52

K135

26.41136

53

K136

22.01137

54

K141

41.69075

55

K142

28.966

56

K143

20.86502

57

K144

15.84317

58

K145

12.63015

59

K146

10.46477

60

K151

18.83306

61

K152

9.867191

62

K153

6.692647

63

K154

5.228571

64

K155

4.420328

65

K156

3.915641

66

K201

14.87236

67

K202

12.03401

68

K203

8.283879

69

K204

4.789504

70

K205

3.034829

71

K206

3.333624

72

K211

14.41147

73

K212

12.00211

74

K213

10.20183

75

K214

8.974493

76

K215

9.089221

77

K216

13.50112

78

K221

14.97795

79

K222

14.789

80

K223

16.56477

81

K224

19.64795

82

K225

23.81261

83

K226

30.87275

84

K231

17.83845

85

K232

22.6658

86

K233

30.90608

87

K234

42.26924

88

K235

56.89405

89

K236

75.80611

90

K241

27.72428

91

K242

49.1949

92

K243

82.4678

93

K244

127.232

94

K245

181.8075

95

K246

244.4789

96

K251

96.90825

97

K252

268.1985

98

K253

494.2702

99

K254

729.1366

100 K255

949.8571

101 K256

1149.675

102 K301

236.225

103 K302

64.87775

104 K303

6.644177

105 K304

0.2346565

106 K305

0.014495

107 K306

0.025709

108 K311

194.9381

109 K312

63.83557

110 K313

23.67893

111 K314

10.83071

112 K315

11.70366

113 K316

130.9079

114 K321

246.6463

115 K322

228.2596

116 K323

455.9817

117 K324

1292.186

118 K325

4176.448

119 K326

2.037E+04

120 K331

716.5909

121 K332

3090.28

122 K333

2.05E+04

123 K334

1.386E+05

124 K335

8.493E+05

125 K336

4.894E+06

126 K341

1.057E+04

127 K342

3.497E+05

128 K343

8.182E+06

129 K344

1.154E+08

130 K345

1.019E+09

131 K346

6.207E+09

132 K351

2.19E+07

133 K352

1.092E+10

134 K353

4.556E+11

135 K354

4.885E+12

136 K355

2.453E+13

137 K356

7.865E+13

138 Kp01

368.0263

139 Kp02

278.8054

140 Kp03

170.8751

141 Kp04

83.31468

142 Kp05

45.80652

143 Kp06

51.80783

144 Kp11

353.1462

145 Kp12

277.8371

146 Kp13

224.5206

147 Kp14

189.7895

148 Kp15

192.9767

149 Kp16

324.1911

150 Kp21

371.4556

151 Kp22

365.3241

152 Kp23

423.8803

153 Kp24

530.1936

154 Kp25

682.1725

155 Kp26

958.8266

156 Kp31

467.1136

157 Kp32

639.4263

158 Kp33

960.1839

159 Kp34

1447.547

160 Kp35

2137.049

161 Kp36

3113.302

162 Kp41

832.7102

163 Kp42

1766.141

164 Kp43

3476.802

165 Kp44

6138.577

166 Kp45

9801.704

167 Kp46

1.445E+04

168 Kp51

4295.899

169 Kp52

1.632E+04

170 Kp53

3.637E+04

171 Kp54

6.055E+04

172 Kp55

8.564E+04

173 Kp56

1.1E+05

174 Pa01

0.1023643

175 Pa02

0.093074

176 Pa03

0.0825057

177 Pa04

0.0716806

178 Pa05

0.0630464

179 Pa06

0.0589663

180 Pa11

0.106495

181 Pa12

0.1024638

182 Pa13

0.098713

183 Pa14

0.0957659

184 Pa15

0.0942362

185 Pa16

0.0942028

186 Pa21

0.1088326

187 Pa22

0.1077022

188 Pa23

0.1071134

189 Pa24

0.1068389

190 Pa25

0.1066906

191 Pa26

0.1066181

192 Pa31

0.1098308

193 Pa32

0.1096242

194 Pa33

0.1095489

195 Pa34

0.1094917

196 Pa35

0.1094501

197 Pa36

0.1094275

198 Pa41

0.1103375

199 Pa42

0.110307

200 Pa43

0.1102808

201 Pa44

0.1102594

202 Pa45

0.1102439

203 Pa46

0.1102355

204 Pa51

0.110487

205 Pa52

0.1104748

206 Pa53

0.110464

207 Pa54

0.110455

208 Pa55

0.1104485

209 Pa56

0.110445

210 Pb01

0.3100922

211 Pb02

0.305447

212 Pb03

0.3001628

213 Pb04

0.2947503

214 Pb05

0.2904332

215 Pb06

0.2883931

216 Pb11

0.3121575

217 Pb12

0.3101419

218 Pb13

0.3082665

219 Pb14

0.306793

220 Pb15

0.3060281

221 Pb16

0.3060114

222 Pb21

0.3133263

223 Pb22

0.3127611

224 Pb23

0.3124667

225 Pb24

0.3123294

226 Pb25

0.3122553

227 Pb26

0.3122191

228 Pb31

0.3138254

229 Pb32

0.3137221

230 Pb33

0.3136844

231 Pb34

0.3136558

232 Pb35

0.313635

233 Pb36

0.3136238

234 Pb41

0.3140787

235 Pb42

0.3140635

236 Pb43

0.3140504

237 Pb44

0.3140397

238 Pb45

0.3140319

239 Pb46

0.3140277

240 Pb51

0.3141535

241 Pb52

0.3141474

242 Pb53

0.314142

243 Pb54

0.3141375

244 Pb55

0.3141343

245 Pb56

0.3141325

246 Pr01

0.0081357

247 Pr02

0.017426

248 Pr03

0.0279943

249 Pr04

0.0388194

250 Pr05

0.0474536

251 Pr06

0.0515337

252 Pr11

0.004005

253 Pr12

0.0080362

254 Pr13

0.011787

255 Pr14

0.0147341

256 Pr15

0.0162638

257 Pr16

0.0162972

258 Pr21

0.0016674

259 Pr22

0.0027978

260 Pr23

0.0033866

261 Pr24

0.0036611

262 Pr25

0.0038094

263 Pr26

0.0038819

264 Pr31

0.0006692

265 Pr32

0.0008758

266 Pr33

0.0009511

267 Pr34

0.0010083

268 Pr35

0.0010499

269 Pr36

0.0010725

270 Pr41

0.0001625

271 Pr42

0.000193

272 Pr43

0.0002192

273 Pr44

0.0002406

274 Pr45

0.0002561

275 Pr46

0.0002645

276 Pr51

1.304E-05

277 Pr52

2.52E-05

278 Pr53

3.602E-05

279 Pr54

4.496E-05

280 Pr55

5.149E-05

281 Pr56

5.504E-05

282 T61

155.8116

283 T62

168.7888

284 T63

175.7966

285 T64

179.9836

286 T65

182.721

287 T66

184.6443

288 x00

289 x10

290 x20

291 x30

292 x40

293 x50

294 T00

400.

295 T10

400.

296 T20

400.

297 T30

400.

298 T40

400.

299 T50

400.

Nonlinear equations
1

f(x01) = 2 * (x11 - 2 * x01 + x01) / dr ^ 2 + pi1 * (x02 - 2 * x01 + x00) / dz ^ 2 + pi2 * (x01
- x00) / dz + pi3 * (K101 * Pb01 * Pa01 * (1 - Pr01 / (Pa01 * (Pb01 ^ 0.5) * Kp01))) / (22.414
* (1 + K201 * Pa01 + K301 * Pr01) ^ 2) = 0

f(x02) = 2 * (x12 - 2 * x02 + x02) / dr ^ 2 + pi1 * (x03 - 2 * x02 + x01) / dz ^ 2 + pi2 * (x02
- x01) / dz + pi3 * (K102 * Pb02 * Pa02 * (1 - Pr02 / (Pa02 * (Pb02 ^ 0.5) * Kp02))) / (22.414
* (1 + K202 * Pa02 + K302 * Pr02) ^ 2) = 0

f(x03) = 2 * (x13 - 2 * x03 + x03) / dr ^ 2 + pi1 * (x04 - 2 * x03 + x02) / dz ^ 2 + pi2 * (x03
- x02) / dz + pi3 * (K103 * Pb03 * Pa03 * (1 - Pr03 / (Pa03 * (Pb03 ^ 0.5) * Kp03))) / (22.414
* (1 + K203 * Pa03 + K303 * Pr03) ^ 2) = 0

f(x04) = 2 * (x14 - 2 * x04 + x04) / dr ^ 2 + pi1 * (x05 - 2 * x04 + x03) / dz ^ 2 + pi2 * (x04
- x03) / dz + pi3 * (K104 * Pb04 * Pa04 * (1 - Pr04 / (Pa04 * (Pb04 ^ 0.5) * Kp04))) / (22.414
* (1 + K204 * Pa04 + K304 * Pr04) ^ 2) = 0

f(x05) = 2 * (x15 - 2 * x05 + x05) / dr ^ 2 + pi1 * (x06 - 2 * x05 + x04) / dz ^ 2 + pi2 * (x05
- x04) / dz + pi3 * (K105 * Pb05 * Pa05 * (1 - Pr05 / (Pa05 * (Pb05 ^ 0.5) * Kp05))) / (22.414
* (1 + K205 * Pa05 + K305 * Pr05) ^ 2) = 0

f(x06) = 2 * (x16 - 2 * x06 + x06) / dr ^ 2 + pi1 * (x06 - 2 * x06 + x05) / dz ^ 2 + pi2 * (x06
- x05) / dz + pi3 * (K106 * Pb06 * Pa06 * (1 - Pr06 / (Pa06 * (Pb06 ^ 0.5) * Kp06))) / (22.414
* (1 + K206 * Pa06 + K306 * Pr06) ^ 2) = 0

f(T01) = 2 * (T11 - 2 * T01 + T01) / dr ^ 2 + pi4 * (T02 - 2 * T01 + T00) / dz ^ 2 + pi5 *


(T01 - T00) / dz + pi6 * (K101 * Pb01 * Pa01 * (1 - Pr01 / (Pa01 * (Pb01 ^ 0.5) * Kp01))) /
(22.414 * (1 + K201 * Pa01 + K301 * Pr01) ^ 2) = 0

f(T02) = 2 * (T12 - 2 * T02 + T02) / dr ^ 2 + pi4 * (T03 - 2 * T02 + T01) / dz ^ 2 + pi5 *


(T02 - T01) / dz + pi6 * (K102 * Pb02 * Pa02 * (1 - Pr02 / (Pa02 * (Pb02 ^ 0.5) * Kp02))) /
(22.414 * (1 + K202 * Pa02 + K302 * Pr02) ^ 2) = 0

f(T03) = 2 * (T13 - 2 * T03 + T03) / dr ^ 2 + pi4 * (T04 - 2 * T03 + T02) / dz ^ 2 + pi5 *


(T03 - T02) / dz + pi6 * (K103 * Pb03 * Pa03 * (1 - Pr03 / (Pa03 * (Pb03 ^ 0.5) * Kp03))) /
(22.414 * (1 + K203 * Pa03 + K303 * Pr03) ^ 2) = 0

f(T04) = 2 * (T14 - 2 * T04 + T04) / dr ^ 2 + pi4 * (T05 - 2 * T04 + T03) / dz ^ 2 + pi5 *


10 (T04 - T03) / dz + pi6 * (K104 * Pb04 * Pa04 * (1 - Pr04 / (Pa04 * (Pb04 ^ 0.5) * Kp04))) /
(22.414 * (1 + K204 * Pa04 + K304 * Pr04) ^ 2) = 0
f(T05) = 2 * (T15 - 2 * T05 + T05) / dr ^ 2 + pi4 * (T06 - 2 * T05 + T04) / dz ^ 2 + pi5 *
11 (T05 - T04) / dz + pi6 * (K105 * Pb05 * Pa05 * (1 - Pr05 / (Pa05 * (Pb05 ^ 0.5) * Kp05))) /
(22.414 * (1 + K205 * Pa05 + K305 * Pr05) ^ 2) = 0
f(T06) = 2 * (T16 - 2 * T06 + T06) / dr ^ 2 + pi4 * (T06 - 2 * T06 + T05) / dz ^ 2 + pi5 *
12 (T06 - T05) / dz + pi6 * (K106 * Pb06 * Pa06 * (1 - Pr06 / (Pa06 * (Pb06 ^ 0.5) * Kp06))) /
(22.414 * (1 + K206 * Pa06 + K306 * Pr06) ^ 2) = 0
f(x11) = (x21 - 2 * x11 + x01) / dr ^ 2 + (x11 - x01) / (1 * dr ^ 2) + pi1 * (x12 - 2 * x11 +
13 x10) / dz ^ 2 + pi2 * (x11 - x10) / dz + pi3 * (K111 * Pb11 * Pa11 * (1 - Pr11 / (Pa11 * (Pb11
^ 0.5) * Kp11))) / (22.414 * (1 + K211 * Pa11 + K311 * Pr11) ^ 2) = 0
f(x12) = (x22 - 2 * x12 + x02) / dr ^ 2 + (x12 - x02) / (1 * dr ^ 2) + pi1 * (x13 - 2 * x12 +
14 x11) / dz ^ 2 + pi2 * (x12 - x11) / dz + pi3 * (K112 * Pb12 * Pa12 * (1 - Pr12 / (Pa12 * (Pb12
^ 0.5) * Kp12))) / (22.414 * (1 + K212 * Pa12 + K312 * Pr12) ^ 2) = 0
f(x13) = (x23 - 2 * x13 + x03) / dr ^ 2 + (x13 - x03) / (1 * dr ^ 2) + pi1 * (x14 - 2 * x13 +
15 x12) / dz ^ 2 + pi2 * (x13 - x12) / dz + pi3 * (K113 * Pb13 * Pa13 * (1 - Pr13 / (Pa13 * (Pb13
^ 0.5) * Kp13))) / (22.414 * (1 + K213 * Pa13 + K313 * Pr13) ^ 2) = 0
f(x14) = (x24 - 2 * x14 + x04) / dr ^ 2 + (x14 - x04) / (1 * dr ^ 2) + pi1 * (x15 - 2 * x14 +
16 x13) / dz ^ 2 + pi2 * (x14 - x13) / dz + pi3 * (K114 * Pb14 * Pa14 * (1 - Pr14 / (Pa14 * (Pb14
^ 0.5) * Kp14))) / (22.414 * (1 + K214 * Pa14 + K314 * Pr14) ^ 2) = 0
f(x15) = (x25 - 2 * x15 + x05) / dr ^ 2 + (x15 - x05) / (1 * dr ^ 2) + pi1 * (x16 - 2 * x15 +
17 x14) / dz ^ 2 + pi2 * (x15 - x14) / dz + pi3 * (K115 * Pb15 * Pa15 * (1 - Pr15 / (Pa15 * (Pb15
^ 0.5) * Kp15))) / (22.414 * (1 + K215 * Pa15 + K315 * Pr15) ^ 2) = 0
f(x16) = (x26 - 2 * x16 + x06) / dr ^ 2 + (x16 - x06) / (1 * dr ^ 2) + pi1 * (x16 - 2 * x16 +
18 x15) / dz ^ 2 + pi2 * (x16 - x15) / dz + pi3 * (K116 * Pb16 * Pa16 * (1 - Pr16 / (Pa16 * (Pb16
^ 0.5) * Kp16))) / (22.414 * (1 + K216 * Pa16 + K316 * Pr16) ^ 2) = 0
f(T11) = (T21 - 2 * T11 + T01) / dr ^ 2 + (T11 - T01) / (1 * dr ^ 2) + pi4 * (T12 - 2 * T11 +
19 T10) / dz ^ 2 + pi5 * (T11 - T10) / dz + pi6 * (K111 * Pb11 * Pa11 * (1 - Pr11 / (Pa11 * (Pb11
^ 0.5) * Kp11))) / (22.414 * (1 + K211 * Pa11 + K311 * Pr11) ^ 2) = 0
f(T12) = (T22 - 2 * T12 + T02) / dr ^ 2 + (T12 - T02) / (1 * dr ^ 2) + pi4 * (T13 - 2 * T12 +
20 T11) / dz ^ 2 + pi5 * (T12 - T11) / dz + pi6 * (K112 * Pb12 * Pa12 * (1 - Pr12 / (Pa12 * (Pb12
^ 0.5) * Kp12))) / (22.414 * (1 + K212 * Pa12 + K312 * Pr12) ^ 2) = 0
f(T13) = (T23 - 2 * T13 + T03) / dr ^ 2 + (T13 - T03) / (1 * dr ^ 2) + pi4 * (T14 - 2 * T13 +
21 T12) / dz ^ 2 + pi5 * (T13 - T12) / dz + pi6 * (K113 * Pb13 * Pa13 * (1 - Pr13 / (Pa13 * (Pb13
^ 0.5) * Kp13))) / (22.414 * (1 + K213 * Pa13 + K313 * Pr13) ^ 2) = 0
f(T14) = (T24 - 2 * T14 + T04) / dr ^ 2 + (T14 - T04) / (1 * dr ^ 2) + pi4 * (T15 - 2 * T14 +
22 T13) / dz ^ 2 + pi5 * (T14 - T13) / dz + pi6 * (K114 * Pb14 * Pa14 * (1 - Pr14 / (Pa14 * (Pb14
^ 0.5) * Kp14))) / (22.414 * (1 + K214 * Pa14 + K314 * Pr14) ^ 2) = 0
f(T15) = (T25 - 2 * T15 + T05) / dr ^ 2 + (T15 - T05) / (1 * dr ^ 2) + pi4 * (T16 - 2 * T15 +
23 T14) / dz ^ 2 + pi5 * (T15 - T14) / dz + pi6 * (K115 * Pb15 * Pa15 * (1 - Pr15 / (Pa15 * (Pb15
^ 0.5) * Kp15))) / (22.414 * (1 + K215 * Pa15 + K315 * Pr15) ^ 2) = 0

f(T16) = (T26 - 2 * T16 + T06) / dr ^ 2 + (T16 - T06) / (1 * dr ^ 2) + pi4 * (T16 - 2 * T16 +


24 T15) / dz ^ 2 + pi5 * (T16 - T15) / dz + pi6 * (K116 * Pb16 * Pa16 * (1 - Pr16 / (Pa16 * (Pb16
^ 0.5) * Kp16))) / (22.414 * (1 + K216 * Pa16 + K316 * Pr16) ^ 2) = 0
f(x21) = (x31 - 2 * x21 + x11) / dr ^ 2 + (x21 - x11) / (2 * dr ^ 2) + pi1 * (x22 - 2 * x21 +
25 x20) / dz ^ 2 + pi2 * (x21 - x20) / dz + pi3 * (K121 * Pb21 * Pa21 * (1 - Pr21 / (Pa21 * (Pb21
^ 0.5) * Kp21))) / (22.414 * (1 + K221 * Pa21 + K321 * Pr21) ^ 2) = 0
f(x22) = (x32 - 2 * x22 + x12) / dr ^ 2 + (x22 - x12) / (2 * dr ^ 2) + pi1 * (x23 - 2 * x22 +
26 x21) / dz ^ 2 + pi2 * (x22 - x21) / dz + pi3 * (K122 * Pb22 * Pa22 * (1 - Pr22 / (Pa22 * (Pb22
^ 0.5) * Kp22))) / (22.414 * (1 + K222 * Pa22 + K322 * Pr22) ^ 2) = 0
f(x23) = (x33 - 2 * x23 + x13) / dr ^ 2 + (x23 - x13) / (2 * dr ^ 2) + pi1 * (x24 - 2 * x23 +
27 x22) / dz ^ 2 + pi2 * (x23 - x22) / dz + pi3 * (K123 * Pb23 * Pa23 * (1 - Pr23 / (Pa23 * (Pb23
^ 0.5) * Kp23))) / (22.414 * (1 + K223 * Pa23 + K323 * Pr23) ^ 2) = 0
f(x24) = (x34 - 2 * x24 + x14) / dr ^ 2 + (x24 - x14) / (2 * dr ^ 2) + pi1 * (x25 - 2 * x24 +
28 x23) / dz ^ 2 + pi2 * (x24 - x23) / dz + pi3 * (K124 * Pb24 * Pa24 * (1 - Pr24 / (Pa24 * (Pb24
^ 0.5) * Kp24))) / (22.414 * (1 + K224 * Pa24 + K324 * Pr24) ^ 2) = 0
f(x25) = (x35 - 2 * x25 + x15) / dr ^ 2 + (x25 - x15) / (2 * dr ^ 2) + pi1 * (x26 - 2 * x25 +
29 x24) / dz ^ 2 + pi2 * (x25 - x24) / dz + pi3 * (K125 * Pb25 * Pa25 * (1 - Pr25 / (Pa25 * (Pb25
^ 0.5) * Kp25))) / (22.414 * (1 + K225 * Pa25 + K325 * Pr25) ^ 2) = 0
f(x26) = (x36 - 2 * x26 + x16) / dr ^ 2 + (x26 - x16) / (2 * dr ^ 2) + pi1 * (x26 - 2 * x26 +
30 x25) / dz ^ 2 + pi2 * (x26 - x25) / dz + pi3 * (K126 * Pb26 * Pa26 * (1 - Pr26 / (Pa26 * (Pb26
^ 0.5) * Kp26))) / (22.414 * (1 + K226 * Pa26 + K326 * Pr26) ^ 2) = 0
f(T21) = (T31 - 2 * T21 + T11) / dr ^ 2 + (T21 - T11) / (2 * dr ^ 2) + pi4 * (T22 - 2 * T21 +
31 T20) / dz ^ 2 + pi5 * (T21 - T20) / dz + pi6 * (K121 * Pb21 * Pa21 * (1 - Pr21 / (Pa21 * (Pb21
^ 0.5) * Kp21))) / (22.414 * (1 + K221 * Pa21 + K321 * Pr21) ^ 2) = 0
f(T22) = (T32 - 2 * T22 + T12) / dr ^ 2 + (T22 - T12) / (2 * dr ^ 2) + pi4 * (T23 - 2 * T22 +
32 T21) / dz ^ 2 + pi5 * (T22 - T21) / dz + pi6 * (K122 * Pb22 * Pa22 * (1 - Pr22 / (Pa22 * (Pb22
^ 0.5) * Kp22))) / (22.414 * (1 + K222 * Pa22 + K322 * Pr22) ^ 2) = 0
f(T23) = (T33 - 2 * T23 + T13) / dr ^ 2 + (T23 - T13) / (2 * dr ^ 2) + pi4 * (T24 - 2 * T23 +
33 T22) / dz ^ 2 + pi5 * (T23 - T22) / dz + pi6 * (K123 * Pb23 * Pa23 * (1 - Pr23 / (Pa23 * (Pb23
^ 0.5) * Kp23))) / (22.414 * (1 + K223 * Pa23 + K323 * Pr23) ^ 2) = 0
f(T24) = (T34 - 2 * T24 + T14) / dr ^ 2 + (T24 - T14) / (2 * dr ^ 2) + pi4 * (T25 - 2 * T24 +
34 T23) / dz ^ 2 + pi5 * (T24 - T23) / dz + pi6 * (K124 * Pb24 * Pa24 * (1 - Pr24 / (Pa24 * (Pb24
^ 0.5) * Kp24))) / (22.414 * (1 + K224 * Pa24 + K324 * Pr24) ^ 2) = 0
f(T25) = (T35 - 2 * T25 + T15) / dr ^ 2 + (T25 - T15) / (2 * dr ^ 2) + pi4 * (T26 - 2 * T25 +
35 T24) / dz ^ 2 + pi5 * (T25 - T24) / dz + pi6 * (K125 * Pb25 * Pa25 * (1 - Pr25 / (Pa25 * (Pb25
^ 0.5) * Kp25))) / (22.414 * (1 + K225 * Pa25 + K325 * Pr25) ^ 2) = 0
f(T26) = (T36 - 2 * T26 + T16) / dr ^ 2 + (T26 - T16) / (2 * dr ^ 2) + pi4 * (T26 - 2 * T26 +
36 T25) / dz ^ 2 + pi5 * (T26 - T25) / dz + pi6 * (K126 * Pb26 * Pa26 * (1 - Pr26 / (Pa26 * (Pb26
^ 0.5) * Kp26))) / (22.414 * (1 + K226 * Pa26 + K326 * Pr26) ^ 2) = 0
f(x31) = (x41 - 2 * x31 + x21) / dr ^ 2 + (x31 - x21) / (3 * dr ^ 2) + pi1 * (x32 - 2 * x31 +
37 x30) / dz ^ 2 + pi2 * (x31 - x30) / dz + pi3 * (K131 * Pb31 * Pa31 * (1 - Pr31 / (Pa31 * (Pb31
^ 0.5) * Kp31))) / (22.414 * (1 + K231 * Pa31 + K331 * Pr31) ^ 2) = 0
f(x32) = (x42 - 2 * x32 + x22) / dr ^ 2 + (x32 - x22) / (3 * dr ^ 2) + pi1 * (x33 - 2 * x32 +
38 x31) / dz ^ 2 + pi2 * (x32 - x31) / dz + pi3 * (K132 * Pb32 * Pa32 * (1 - Pr32 / (Pa32 * (Pb32
^ 0.5) * Kp32))) / (22.414 * (1 + K232 * Pa32 + K332 * Pr32) ^ 2) = 0
f(x33) = (x43 - 2 * x33 + x23) / dr ^ 2 + (x33 - x23) / (3 * dr ^ 2) + pi1 * (x34 - 2 * x33 +
39 x32) / dz ^ 2 + pi2 * (x33 - x32) / dz + pi3 * (K133 * Pb33 * Pa33 * (1 - Pr33 / (Pa33 * (Pb33
^ 0.5) * Kp33))) / (22.414 * (1 + K233 * Pa33 + K333 * Pr33) ^ 2) = 0

f(x34) = (x44 - 2 * x34 + x24) / dr ^ 2 + (x34 - x24) / (3 * dr ^ 2) + pi1 * (x35 - 2 * x34 +


40 x33) / dz ^ 2 + pi2 * (x34 - x33) / dz + pi3 * (K134 * Pb34 * Pa34 * (1 - Pr34 / (Pa34 * (Pb34
^ 0.5) * Kp34))) / (22.414 * (1 + K234 * Pa34 + K334 * Pr34) ^ 2) = 0
f(x35) = (x45 - 2 * x35 + x25) / dr ^ 2 + (x35 - x25) / (3 * dr ^ 2) + pi1 * (x36 - 2 * x35 +
41 x34) / dz ^ 2 + pi2 * (x35 - x34) / dz + pi3 * (K135 * Pb35 * Pa35 * (1 - Pr35 / (Pa35 * (Pb35
^ 0.5) * Kp35))) / (22.414 * (1 + K235 * Pa35 + K335 * Pr35) ^ 2) = 0
f(x36) = (x46 - 2 * x36 + x26) / dr ^ 2 + (x36 - x26) / (3 * dr ^ 2) + pi1 * (x36 - 2 * x36 +
42 x35) / dz ^ 2 + pi2 * (x36 - x35) / dz + pi3 * (K136 * Pb36 * Pa36 * (1 - Pr36 / (Pa36 * (Pb36
^ 0.5) * Kp36))) / (22.414 * (1 + K236 * Pa36 + K336 * Pr36) ^ 2) = 0
f(T31) = (T41 - 2 * T31 + T21) / dr ^ 2 + (T31 - T21) / (3 * dr ^ 2) + pi4 * (T32 - 2 * T31 +
43 T30) / dz ^ 2 + pi5 * (T31 - T30) / dz + pi6 * (K131 * Pb31 * Pa31 * (1 - Pr31 / (Pa31 * (Pb31
^ 0.5) * Kp31))) / (22.414 * (1 + K231 * Pa31 + K331 * Pr31) ^ 2) = 0
f(T32) = (T42 - 2 * T32 + T22) / dr ^ 2 + (T32 - T22) / (3 * dr ^ 2) + pi4 * (T33 - 2 * T32 +
44 T31) / dz ^ 2 + pi5 * (T32 - T31) / dz + pi6 * (K132 * Pb32 * Pa32 * (1 - Pr32 / (Pa32 * (Pb32
^ 0.5) * Kp32))) / (22.414 * (1 + K232 * Pa32 + K332 * Pr32) ^ 2) = 0
f(T33) = (T43 - 2 * T33 + T23) / dr ^ 2 + (T33 - T23) / (3 * dr ^ 2) + pi4 * (T34 - 2 * T33 +
45 T32) / dz ^ 2 + pi5 * (T33 - T32) / dz + pi6 * (K133 * Pb33 * Pa33 * (1 - Pr33 / (Pa33 * (Pb33
^ 0.5) * Kp33))) / (22.414 * (1 + K233 * Pa33 + K333 * Pr33) ^ 2) = 0
f(T34) = (T44 - 2 * T34 + T24) / dr ^ 2 + (T34 - T24) / (3 * dr ^ 2) + pi4 * (T35 - 2 * T34 +
46 T33) / dz ^ 2 + pi5 * (T34 - T33) / dz + pi6 * (K134 * Pb34 * Pa34 * (1 - Pr34 / (Pa34 * (Pb34
^ 0.5) * Kp34))) / (22.414 * (1 + K234 * Pa34 + K334 * Pr34) ^ 2) = 0
f(T35) = (T45 - 2 * T35 + T25) / dr ^ 2 + (T35 - T25) / (3 * dr ^ 2) + pi4 * (T36 - 2 * T35 +
47 T34) / dz ^ 2 + pi5 * (T35 - T34) / dz + pi6 * (K135 * Pb35 * Pa35 * (1 - Pr35 / (Pa35 * (Pb35
^ 0.5) * Kp35))) / (22.414 * (1 + K235 * Pa35 + K335 * Pr35) ^ 2) = 0
f(T36) = (T46 - 2 * T36 + T26) / dr ^ 2 + (T36 - T26) / (3 * dr ^ 2) + pi4 * (T36 - 2 * T36 +
48 T35) / dz ^ 2 + pi5 * (T36 - T35) / dz + pi6 * (K136 * Pb36 * Pa36 * (1 - Pr36 / (Pa36 * (Pb36
^ 0.5) * Kp36))) / (22.414 * (1 + K236 * Pa36 + K336 * Pr36) ^ 2) = 0
f(x41) = (x51 - 2 * x41 + x31) / dr ^ 2 + (x41 - x31) / (4 * dr ^ 2) + pi1 * (x42 - 2 * x41 +
49 x40) / dz ^ 2 + pi2 * (x41 - x40) / dz + pi3 * (K141 * Pb41 * Pa41 * (1 - Pr41 / (Pa41 * (Pb41
^ 0.5) * Kp41))) / (22.414 * (1 + K241 * Pa41 + K341 * Pr41) ^ 2) = 0
f(x42) = (x52 - 2 * x42 + x32) / dr ^ 2 + (x42 - x32) / (4 * dr ^ 2) + pi1 * (x43 - 2 * x42 +
50 x41) / dz ^ 2 + pi2 * (x42 - x41) / dz + pi3 * (K142 * Pb42 * Pa42 * (1 - Pr42 / (Pa42 * (Pb42
^ 0.5) * Kp42))) / (22.414 * (1 + K242 * Pa42 + K342 * Pr42) ^ 2) = 0
f(x43) = (x53 - 2 * x43 + x33) / dr ^ 2 + (x43 - x33) / (4 * dr ^ 2) + pi1 * (x44 - 2 * x43 +
51 x42) / dz ^ 2 + pi2 * (x43 - x42) / dz + pi3 * (K143 * Pb43 * Pa43 * (1 - Pr43 / (Pa43 * (Pb43
^ 0.5) * Kp43))) / (22.414 * (1 + K243 * Pa43 + K343 * Pr43) ^ 2) = 0
f(x44) = (x54 - 2 * x44 + x34) / dr ^ 2 + (x44 - x34) / (4 * dr ^ 2) + pi1 * (x45 - 2 * x44 +
52 x43) / dz ^ 2 + pi2 * (x44 - x43) / dz + pi3 * (K144 * Pb44 * Pa44 * (1 - Pr44 / (Pa44 * (Pb44
^ 0.5) * Kp44))) / (22.414 * (1 + K244 * Pa44 + K344 * Pr44) ^ 2) = 0
f(x45) = (x55 - 2 * x45 + x35) / dr ^ 2 + (x45 - x35) / (4 * dr ^ 2) + pi1 * (x46 - 2 * x45 +
53 x44) / dz ^ 2 + pi2 * (x45 - x44) / dz + pi3 * (K145 * Pb45 * Pa45 * (1 - Pr45 / (Pa45 * (Pb45
^ 0.5) * Kp45))) / (22.414 * (1 + K245 * Pa45 + K345 * Pr45) ^ 2) = 0
f(x46) = (x56 - 2 * x46 + x36) / dr ^ 2 + (x46 - x36) / (4 * dr ^ 2) + pi1 * (x46 - 2 * x46 +
54 x45) / dz ^ 2 + pi2 * (x46 - x45) / dz + pi3 * (K146 * Pb46 * Pa46 * (1 - Pr46 / (Pa46 * (Pb46
^ 0.5) * Kp46))) / (22.414 * (1 + K246 * Pa46 + K346 * Pr46) ^ 2) = 0
f(T41) = (T51 - 2 * T41 + T31) / dr ^ 2 + (T41 - T31) / (4 * dr ^ 2) + pi4 * (T42 - 2 * T41 +
55 T40) / dz ^ 2 + pi5 * (T41 - T40) / dz + pi6 * (K141 * Pb41 * Pa41 * (1 - Pr41 / (Pa41 * (Pb41
^ 0.5) * Kp41))) / (22.414 * (1 + K241 * Pa41 + K341 * Pr41) ^ 2) = 0

f(T42) = (T52 - 2 * T42 + T32) / dr ^ 2 + (T42 - T32) / (4 * dr ^ 2) + pi4 * (T43 - 2 * T42 +


56 T41) / dz ^ 2 + pi5 * (T42 - T41) / dz + pi6 * (K142 * Pb42 * Pa42 * (1 - Pr42 / (Pa42 * (Pb42
^ 0.5) * Kp42))) / (22.414 * (1 + K242 * Pa42 + K342 * Pr42) ^ 2) = 0
f(T43) = (T53 - 2 * T43 + T33) / dr ^ 2 + (T43 - T33) / (4 * dr ^ 2) + pi4 * (T44 - 2 * T43 +
57 T42) / dz ^ 2 + pi5 * (T43 - T42) / dz + pi6 * (K143 * Pb43 * Pa43 * (1 - Pr43 / (Pa43 * (Pb43
^ 0.5) * Kp43))) / (22.414 * (1 + K243 * Pa43 + K343 * Pr43) ^ 2) = 0
f(T44) = (T54 - 2 * T44 + T34) / dr ^ 2 + (T44 - T34) / (4 * dr ^ 2) + pi4 * (T45 - 2 * T44 +
58 T43) / dz ^ 2 + pi5 * (T44 - T43) / dz + pi6 * (K144 * Pb44 * Pa44 * (1 - Pr44 / (Pa44 * (Pb44
^ 0.5) * Kp44))) / (22.414 * (1 + K244 * Pa44 + K344 * Pr44) ^ 2) = 0
f(T45) = (T55 - 2 * T45 + T35) / dr ^ 2 + (T45 - T35) / (4 * dr ^ 2) + pi4 * (T46 - 2 * T45 +
59 T44) / dz ^ 2 + pi5 * (T45 - T44) / dz + pi6 * (K145 * Pb45 * Pa45 * (1 - Pr45 / (Pa45 * (Pb45
^ 0.5) * Kp45))) / (22.414 * (1 + K245 * Pa45 + K345 * Pr45) ^ 2) = 0
f(T46) = (T56 - 2 * T46 + T36) / dr ^ 2 + (T46 - T36) / (4 * dr ^ 2) + pi4 * (T46 - 2 * T46 +
60 T45) / dz ^ 2 + pi5 * (T46 - T45) / dz + pi6 * (K146 * Pb46 * Pa46 * (1 - Pr46 / (Pa46 * (Pb46
^ 0.5) * Kp46))) / (22.414 * (1 + K246 * Pa46 + K346 * Pr46) ^ 2) = 0
f(x51) = (x51 - 2 * x51 + x41) / dr ^ 2 + (x51 - x41) / (5 * dr ^ 2) + pi1 * (x52 - 2 * x51 +
61 x50) / dz ^ 2 + pi2 * (x51 - x50) / dz + pi3 * (K151 * Pb51 * Pa51 * (1 - Pr51 / (Pa51 * (Pb51
^ 0.5) * Kp51))) / (22.414 * (1 + K251 * Pa51 + K351 * Pr51) ^ 2) = 0
f(x52) = (x52 - 2 * x52 + x42) / dr ^ 2 + (x52 - x42) / (5 * dr ^ 2) + pi1 * (x53 - 2 * x52 +
62 x51) / dz ^ 2 + pi2 * (x52 - x51) / dz + pi3 * (K152 * Pb52 * Pa52 * (1 - Pr52 / (Pa52 * (Pb52
^ 0.5) * Kp52))) / (22.414 * (1 + K252 * Pa52 + K352 * Pr52) ^ 2) = 0
f(x53) = (x53 - 2 * x53 + x43) / dr ^ 2 + (x53 - x43) / (5 * dr ^ 2) + pi1 * (x54 - 2 * x53 +
63 x52) / dz ^ 2 + pi2 * (x53 - x52) / dz + pi3 * (K153 * Pb53 * Pa53 * (1 - Pr53 / (Pa53 * (Pb53
^ 0.5) * Kp53))) / (22.414 * (1 + K253 * Pa53 + K353 * Pr53) ^ 2) = 0
f(x54) = (x54 - 2 * x54 + x44) / dr ^ 2 + (x54 - x44) / (5 * dr ^ 2) + pi1 * (x55 - 2 * x54 +
64 x53) / dz ^ 2 + pi2 * (x54 - x53) / dz + pi3 * (K154 * Pb54 * Pa54 * (1 - Pr54 / (Pa54 * (Pb54
^ 0.5) * Kp54))) / (22.414 * (1 + K254 * Pa54 + K354 * Pr54) ^ 2) = 0
f(x55) = (x55 - 2 * x55 + x45) / dr ^ 2 + (x55 - x45) / (5 * dr ^ 2) + pi1 * (x56 - 2 * x55 +
65 x54) / dz ^ 2 + pi2 * (x55 - x54) / dz + pi3 * (K155 * Pb55 * Pa55 * (1 - Pr55 / (Pa55 * (Pb55
^ 0.5) * Kp55))) / (22.414 * (1 + K255 * Pa55 + K355 * Pr55) ^ 2) = 0
f(x56) = (x56 - 2 * x56 + x46) / dr ^ 2 + (x56 - x46) / (5 * dr ^ 2) + pi1 * (x56 - 2 * x56 +
66 x55) / dz ^ 2 + pi2 * (x56 - x55) / dz + pi3 * (K156 * Pb56 * Pa56 * (1 - Pr56 / (Pa56 * (Pb56
^ 0.5) * Kp56))) / (22.414 * (1 + K256 * Pa56 + K356 * Pr56) ^ 2) = 0
f(T51) = (T61 - 2 * T51 + T41) / dr ^ 2 + (T51 - T41) / (5 * dr ^ 2) + pi4 * (T52 - 2 * T51 +
67 T50) / dz ^ 2 + pi5 * (T51 - T50) / dz + pi6 * (K151 * Pb51 * Pa51 * (1 - Pr51 / (Pa51 * (Pb51
^ 0.5) * Kp51))) / (22.414 * (1 + K251 * Pa51 + K351 * Pr51) ^ 2) = 0
f(T52) = (T62 - 2 * T52 + T42) / dr ^ 2 + (T52 - T42) / (5 * dr ^ 2) + pi4 * (T53 - 2 * T52 +
68 T51) / dz ^ 2 + pi5 * (T52 - T51) / dz + pi6 * (K152 * Pb52 * Pa52 * (1 - Pr52 / (Pa52 * (Pb52
^ 0.5) * Kp52))) / (22.414 * (1 + K252 * Pa52 + K352 * Pr52) ^ 2) = 0
f(T53) = (T63 - 2 * T53 + T43) / dr ^ 2 + (T53 - T43) / (5 * dr ^ 2) + pi4 * (T54 - 2 * T53 +
69 T52) / dz ^ 2 + pi5 * (T53 - T52) / dz + pi6 * (K153 * Pb53 * Pa53 * (1 - Pr53 / (Pa53 * (Pb53
^ 0.5) * Kp53))) / (22.414 * (1 + K253 * Pa53 + K353 * Pr53) ^ 2) = 0
f(T54) = (T64 - 2 * T54 + T44) / dr ^ 2 + (T54 - T44) / (5 * dr ^ 2) + pi4 * (T55 - 2 * T54 +
70 T53) / dz ^ 2 + pi5 * (T54 - T53) / dz + pi6 * (K154 * Pb54 * Pa54 * (1 - Pr54 / (Pa54 * (Pb54
^ 0.5) * Kp54))) / (22.414 * (1 + K254 * Pa54 + K354 * Pr54) ^ 2) = 0
f(T55) = (T65 - 2 * T55 + T45) / dr ^ 2 + (T55 - T45) / (5 * dr ^ 2) + pi4 * (T56 - 2 * T55 +
71 T54) / dz ^ 2 + pi5 * (T55 - T54) / dz + pi6 * (K155 * Pb55 * Pa55 * (1 - Pr55 / (Pa55 * (Pb55
^ 0.5) * Kp55))) / (22.414 * (1 + K255 * Pa55 + K355 * Pr55) ^ 2) = 0

f(T56) = (T66 - 2 * T56 + T46) / dr ^ 2 + (T56 - T46) / (5 * dr ^ 2) + pi4 * (T56 - 2 * T56 +


72 T55) / dz ^ 2 + pi5 * (T56 - T55) / dz + pi6 * (K156 * Pb56 * Pa56 * (1 - Pr56 / (Pa56 * (Pb56
^ 0.5) * Kp56))) / (22.414 * (1 + K256 * Pa56 + K356 * Pr56) ^ 2) = 0
Explicit equations
1

Pmz = 0.01
Peclet de Masa en Direccion Axial

E = 0.5
Porosidad del lecho

R = 0.082

Phz = 9
Peclet de Calor en Direccion Axial

Phr = 4.4
Peclet de calor en direccion radial

dp = 0.003175

db = 1025
Densidad del lecho

G = 1709
Flujo masico

Us = 2914.393
Velocidad

10

dH = -94886
Entalpia

11

Cpf = 1.09
Capacidad Calorifica del Fluido

12

df = 0.5864
Densidad del Fluido

13

Tw = 197
Temperatura de la pared

14

pi5 = -Us * df * Cpf / (dp * G * Cpf / Phr)

15

Pmr = 9.6
Peclet de masa en direccion radial

16

pi4 = (dp * G * Cpf / Phz) / (dp * G * Cpf / Phr)

17

pi1 = ( Us * dp / Pmz) / (Us * dp / Pmr)

18

Bi = 6.67
Numero de Biot

19

pi6 = db * (-dH) / (dp * G * Cpf / Phr)

20

pi2 = -Us/(E * (Us * dp / Pmr))

21

dz = (0.1524)/6

22

dr = 0.02615 / 5

23

Tin = 400 +273

24

Pao = 1.7 * 0.065

25

Cao = Pao / (R * Tin )

26

P = 1.6

27

ya = 0.065

28

pi3 = db / (Cao * E * (Us * dp / Pmr))

29

Pbo = (1 - ya) * P * 0.21

30

K101 = exp(12.16 - 5473 / (T01 + 273))

31

K102 = exp(12.16 - 5473 / (T02 + 273))

32

K103 = exp(12.16 - 5473 / (T03 + 273))

33

K104 = exp(12.16 - 5473 / (T04 + 273))

34

K105 = exp(12.16 - 5473 / (T05 + 273))

35

K106 = exp(12.16 - 5473 / (T06 + 273))

36

K111 = exp(12.16 - 5473 / (T11 + 273))

37

K112 = exp(12.16 - 5473 / (T12 + 273))

38

K113 = exp(12.16 - 5473 / (T13 + 273))

39

K114 = exp(12.16 - 5473 / (T14 + 273))

40

K115 = exp(12.16 - 5473 / (T15 + 273))

41

K116 = exp(12.16 - 5473 / (T16 + 273))

42

K121 = exp(12.16 - 5473 / (T21 + 273))

43

K122 = exp(12.16 - 5473 / (T22 + 273))

44

K123 = exp(12.16 - 5473 / (T23 + 273))

45

K124 = exp(12.16 - 5473 / (T24 + 273))

46

K125 = exp(12.16 - 5473 / (T25 + 273))

47

K126 = exp(12.16 - 5473 / (T26 + 273))

48

K131 = exp(12.16 - 5473 / (T31 + 273))

49

K132 = exp(12.16 - 5473 / (T32 + 273))

50

K133 = exp(12.16 - 5473 / (T33 + 273))

51

K134 = exp(12.16 - 5473 / (T34 + 273))

52

K135 = exp(12.16 - 5473 / (T35 + 273))

53

K136 = exp(12.16 - 5473 / (T36 + 273))

54

K141 = exp(12.16 - 5473 / (T41 + 273))

55

K142 = exp(12.16 - 5473 / (T42 + 273))

56

K143 = exp(12.16 - 5473 / (T43 + 273))

57

K144 = exp(12.16 - 5473 / (T44 + 273))

58

K145 = exp(12.16 - 5473 / (T45 + 273))

59

K146 = exp(12.16 - 5473 / (T46 + 273))

60

K151 = exp(12.16 - 5473 / (T51 + 273))

61

K152 = exp(12.16 - 5473 / (T52 + 273))

62

K153 = exp(12.16 - 5473 / (T53 + 273))

63

K154 = exp(12.16 - 5473 / (T54 + 273))

64

K155 = exp(12.16 - 5473 / (T55 + 273))

65

K156 = exp(12.16 - 5473 / (T56 + 273))

66

K201 = exp(-9.953 + 8619 / (T01 + 273))

67

K202 = exp(-9.953 + 8619 / (T02 + 273))

68

K203 = exp(-9.953 + 8619 / (T03 + 273))

69

K204 = exp(-9.953 + 8619 / (T04 + 273))

70

K205 = exp(-9.953 + 8619 / (T05 + 273))

71

K206 = exp(-9.953 + 8619 / (T06 + 273))

72

K211 = exp(-9.953 + 8619 / (T11 + 273))

73

K212 = exp(-9.953 + 8619 / (T12 + 273))

74

K213 = exp(-9.953 + 8619 / (T13 + 273))

75

K214 = exp(-9.953 + 8619 / (T14 + 273))

76

K215 = exp(-9.953 + 8619 / (T15 + 273))

77

K216 = exp(-9.953 + 8619 / (T16 + 273))

78

K221 = exp(-9.953 + 8619 / (T21 + 273))

79

K222 = exp(-9.953 + 8619 / (T22 + 273))

80

K223 = exp(-9.953 + 8619 / (T23 + 273))

81

K224 = exp(-9.953 + 8619 / (T24 + 273))

82

K225 = exp(-9.953 + 8619 / (T25 + 273))

83

K226 = exp(-9.953 + 8619 / (T26 + 273))

84

K231 = exp(-9.953 + 8619 / (T31 + 273))

85

K232 = exp(-9.953 + 8619 / (T32 + 273))

86

K233 = exp(-9.953 + 8619 / (T33 + 273))

87

K234 = exp(-9.953 + 8619 / (T34 + 273))

88

K235 = exp(-9.953 + 8619 / (T35 + 273))

89

K236 = exp(-9.953 + 8619 / (T36 + 273))

90

K241 = exp(-9.953 + 8619 / (T41 + 273))

91

K242 = exp(-9.953 + 8619 / (T42 + 273))

92

K243 = exp(-9.953 + 8619 / (T43 + 273))

93

K244 = exp(-9.953 + 8619 / (T44 + 273))

94

K245 = exp(-9.953 + 8619 / (T45 + 273))

95

K246 = exp(-9.953 + 8619 / (T46 + 273))

96

K251 = exp(-9.953 + 8619 / (T51 + 273))

97

K252 = exp(-9.953 + 8619 / (T52 + 273))

98

K253 = exp(-9.953 + 8619 / (T53 + 273))

99

K254 = exp(-9.953 + 8619 / (T54 + 273))

100 K255 = exp(-9.953 + 8619 / (T55 + 273))

101 K256 = exp(-9.953 + 8619 / (T56 + 273))


102 K301 = exp(-71.745 + 52596 / (T01 + 273))
103 K302 = exp(-71.745 + 52596 / (T02 + 273))
104 K303 = exp(-71.745 + 52596 / (T03 + 273))
105 K304 = exp(-71.745 + 52596 / (T04 + 273))
106 K305 = exp(-71.745 + 52596 / (T05 + 273))
107 K306 = exp(-71.745 + 52596 / (T06 + 273))
108 K311 = exp(-71.745 + 52596 / (T11 + 273))
109 K312 = exp(-71.745 + 52596 / (T12 + 273))
110 K313 = exp(-71.745 + 52596 / (T13 + 273))
111 K314 = exp(-71.745 + 52596 / (T14 + 273))
112 K315 = exp(-71.745 + 52596 / (T15 + 273))
113 K316 = exp(-71.745 + 52596 / (T16 + 273))
114 K321 = exp(-71.745 + 52596 / (T21 + 273))
115 K322 = exp(-71.745 + 52596 / (T22 + 273))
116 K323 = exp(-71.745 + 52596 / (T23 + 273))
117 K324 = exp(-71.745 + 52596 / (T24 + 273))
118 K325 = exp(-71.745 + 52596 / (T25 + 273))
119 K326 = exp(-71.745 + 52596 / (T26 + 273))
120 K331 = exp(-71.745 + 52596 / (T31 + 273))
121 K332 = exp(-71.745 + 52596 / (T32 + 273))
122 K333 = exp(-71.745 + 52596 / (T33 + 273))
123 K334 = exp(-71.745 + 52596 / (T34 + 273))
124 K335 = exp(-71.745 + 52596 / (T35 + 273))
125 K336 = exp(-71.745 + 52596 / (T36 + 273))
126 K341 = exp(-71.745 + 52596 / (T41 + 273))
127 K342 = exp(-71.745 + 52596 / (T42 + 273))
128 K343 = exp(-71.745 + 52596 / (T43 + 273))
129 K344 = exp(-71.745 + 52596 / (T44 + 273))
130 K345 = exp(-71.745 + 52596 / (T45 + 273))
131 K346 = exp(-71.745 + 52596 / (T46 + 273))
132 K351 = exp(-71.745 + 52596 / (T51 + 273))
133 K352 = exp(-71.745 + 52596 / (T52 + 273))
134 K353 = exp(-71.745 + 52596 / (T53 + 273))
135 K354 = exp(-71.745 + 52596 / (T54 + 273))
136 K355 = exp(-71.745 + 52596 / (T55 + 273))
137 K356 = exp(-71.745 + 52596 / (T56 + 273))
138 Kp01 = exp(11300 / (T01 + 273) - 10.68)
139 Kp02 = exp(11300 / (T02 + 273) - 10.68)

140 Kp03 = exp(11300 / (T03 + 273) - 10.68)


141 Kp04 = exp(11300 / (T04 + 273) - 10.68)
142 Kp05 = exp(11300 / (T05 + 273) - 10.68)
143 Kp06 = exp(11300 / (T06 + 273) - 10.68)
144 Kp11 = exp(11300 / (T11 + 273) - 10.68)
145 Kp12 = exp(11300 / (T12 + 273) - 10.68)
146 Kp13 = exp(11300 / (T13 + 273) - 10.68)
147 Kp14 = exp(11300 / (T14 + 273) - 10.68)
148 Kp15 = exp(11300 / (T15 + 273) - 10.68)
149 Kp16 = exp(11300 / (T16 + 273) - 10.68)
150 Kp21 = exp(11300 / (T21 + 273) - 10.68)
151 Kp22 = exp(11300 / (T22 + 273) - 10.68)
152 Kp23 = exp(11300 / (T23 + 273) - 10.68)
153 Kp24 = exp(11300 / (T24 + 273) - 10.68)
154 Kp25 = exp(11300 / (T25 + 273) - 10.68)
155 Kp26 = exp(11300 / (T26 + 273) - 10.68)
156 Kp31 = exp(11300 / (T31 + 273) - 10.68)
157 Kp32 = exp(11300 / (T32 + 273) - 10.68)
158 Kp33 = exp(11300 / (T33 + 273) - 10.68)
159 Kp34 = exp(11300 / (T34 + 273) - 10.68)
160 Kp35 = exp(11300 / (T35 + 273) - 10.68)
161 Kp36 = exp(11300 / (T36 + 273) - 10.68)
162 Kp41 = exp(11300 / (T41 + 273) - 10.68)
163 Kp42 = exp(11300 / (T42 + 273) - 10.68)
164 Kp43 = exp(11300 / (T43 + 273) - 10.68)
165 Kp44 = exp(11300 / (T44 + 273) - 10.68)
166 Kp45 = exp(11300 / (T45 + 273) - 10.68)
167 Kp46 = exp(11300 / (T46 + 273) - 10.68)
168 Kp51 = exp(11300 / (T51 + 273) - 10.68)
169 Kp52 = exp(11300 / (T52 + 273) - 10.68)
170 Kp53 = exp(11300 / (T53 + 273) - 10.68)
171 Kp54 = exp(11300 / (T54 + 273) - 10.68)
172 Kp55 = exp(11300 / (T55 + 273) - 10.68)
173 Kp56 = exp(11300 / (T56 + 273) - 10.68)
174 Pa01 = Pao * (1 - x01)
175 Pa02 = Pao * (1 - x02)
176 Pa03 = Pao * (1 - x03)
177 Pa04 = Pao * (1 - x04)
178 Pa05 = Pao * (1 - x05)

179 Pa06 = Pao * (1 - x06)


180 Pa11 = Pao * (1 - x11)
181 Pa12 = Pao * (1 - x12)
182 Pa13 = Pao * (1 - x13)
183 Pa14 = Pao * (1 - x14)
184 Pa15 = Pao * (1 - x15)
185 Pa16 = Pao * (1 - x16)
186 Pa21 = Pao * (1 - x21)
187 Pa22 = Pao * (1 - x22)
188 Pa23 = Pao * (1 - x23)
189 Pa24 = Pao * (1 - x24)
190 Pa25 = Pao * (1 - x25)
191 Pa26 = Pao * (1 - x26)
192 Pa31 = Pao * (1 - x31)
193 Pa32 = Pao * (1 - x32)
194 Pa33 = Pao * (1 - x33)
195 Pa34 = Pao * (1 - x34)
196 Pa35 = Pao * (1 - x35)
197 Pa36 = Pao * (1 - x36)
198 Pa41 = Pao * (1 - x41)
199 Pa42 = Pao * (1 - x42)
200 Pa43 = Pao * (1 - x43)
201 Pa44 = Pao * (1 - x44)
202 Pa45 = Pao * (1 - x45)
203 Pa46 = Pao * (1 - x46)
204 Pa51 = Pao * (1 - x51)
205 Pa52 = Pao * (1 - x52)
206 Pa53 = Pao * (1 - x53)
207 Pa54 = Pao * (1 - x54)
208 Pa55 = Pao * (1 - x55)
209 Pa56 = Pao * (1 - x56)
210 Pb01 = Pbo - 0.5 * Pao * x01
211 Pb02 = Pbo - 0.5 * Pao * x02
212 Pb03 = Pbo - 0.5 * Pao * x03
213 Pb04 = Pbo - 0.5 * Pao * x04
214 Pb05 = Pbo - 0.5 * Pao * x05
215 Pb06 = Pbo - 0.5 * Pao * x06
216 Pb11 = Pbo - 0.5 * Pao * x11
217 Pb12 = Pbo - 0.5 * Pao * x12

218 Pb13 = Pbo - 0.5 * Pao * x13


219 Pb14 = Pbo - 0.5 * Pao * x14
220 Pb15 = Pbo - 0.5 * Pao * x15
221 Pb16 = Pbo - 0.5 * Pao * x16
222 Pb21 = Pbo - 0.5 * Pao * x21
223 Pb22 = Pbo - 0.5 * Pao * x22
224 Pb23 = Pbo - 0.5 * Pao * x23
225 Pb24 = Pbo - 0.5 * Pao * x24
226 Pb25 = Pbo - 0.5 * Pao * x25
227 Pb26 = Pbo - 0.5 * Pao * x26
228 Pb31 = Pbo - 0.5 * Pao * x31
229 Pb32 = Pbo - 0.5 * Pao * x32
230 Pb33 = Pbo - 0.5 * Pao * x33
231 Pb34 = Pbo - 0.5 * Pao * x34
232 Pb35 = Pbo - 0.5 * Pao * x35
233 Pb36 = Pbo - 0.5 * Pao * x36
234 Pb41 = Pbo - 0.5 * Pao * x41
235 Pb42 = Pbo - 0.5 * Pao * x42
236 Pb43 = Pbo - 0.5 * Pao * x43
237 Pb44 = Pbo - 0.5 * Pao * x44
238 Pb45 = Pbo - 0.5 * Pao * x45
239 Pb46 = Pbo - 0.5 * Pao * x46
240 Pb51 = Pbo - 0.5 * Pao * x51
241 Pb52 = Pbo - 0.5 * Pao * x52
242 Pb53 = Pbo - 0.5 * Pao * x53
243 Pb54 = Pbo - 0.5 * Pao * x54
244 Pb55 = Pbo - 0.5 * Pao * x55
245 Pb56 = Pbo - 0.5 * Pao * x56
246 Pr01 = Pao * x01
247 Pr02 = Pao * x02
248 Pr03 = Pao * x03
249 Pr04 = Pao * x04
250 Pr05 = Pao * x05
251 Pr06 = Pao * x06
252 Pr11 = Pao * x11
253 Pr12 = Pao * x12
254 Pr13 = Pao * x13
255 Pr14 = Pao * x14
256 Pr15 = Pao * x15

257 Pr16 = Pao * x16


258 Pr21 = Pao * x21
259 Pr22 = Pao * x22
260 Pr23 = Pao * x23
261 Pr24 = Pao * x24
262 Pr25 = Pao * x25
263 Pr26 = Pao * x26
264 Pr31 = Pao * x31
265 Pr32 = Pao * x32
266 Pr33 = Pao * x33
267 Pr34 = Pao * x34
268 Pr35 = Pao * x35
269 Pr36 = Pao * x36
270 Pr41 = Pao * x41
271 Pr42 = Pao * x42
272 Pr43 = Pao * x43
273 Pr44 = Pao * x44
274 Pr45 = Pao * x45
275 Pr46 = Pao * x46
276 Pr51 = Pao * x51
277 Pr52 = Pao * x52
278 Pr53 = Pao * x53
279 Pr54 = Pao * x54
280 Pr55 = Pao * x55
281 Pr56 = Pao * x56
282 T61 = T51 - Bi*(T51 - Tw)/5
283 T62 = T52 - Bi*(T52 - Tw)/5
284 T63 = T53 - Bi*(T53 - Tw)/5
285 T64 = T54 - Bi*(T54 - Tw)/5
286 T65 = T55 - Bi*(T55 - Tw)/5
287 T66 = T56 - Bi*(T56 - Tw)/5
288 x00 = 0
289 x10 = 0
290 x20 = 0
291 x30 = 0
292 x40 = 0
293 x50 = 0
294 T00 = 400
295 T10 = 400

296 T20 = 400


297 T30 = 400
298 T40 = 400
299 T50 = 400

Con las tablas obtenidas por polymath procedemos a graficar


DATOS OBTENIDOS EN POLYMATH

ro
Radio

r1
0

x0

r2
0.00523

x1

r3
0.01046

x2

r4
0.01569

x3

r5
0.02092

x4

0.02615
x5

xprom

0.0254

0.0736259

0.0362447

0.0150895

0.0060563

0.0014707

0.000118

0.02210085

0.0508

0.1577011

0.0727259

0.0253191

0.0079257

0.0017463

0.0002281

0.04427437

0.0762

0.2533425

0.1066693

0.0306477

0.0086074

0.0019836

0.000326

0.06692942

0.1016

0.3513065

0.1333403

0.0331322

0.0091252

0.0021775

0.0004069

0.0882481

0.127

0.4294447

0.1471837

0.0344738

0.0095016

0.0023179

0.0004659

0.10389793

0.1524

0.4663684

0.1474863

0.0351303

0.0097058

0.0023939

0.0004981

0.1102638

ro
Radio

r1
0

T0

r2
0.00523

T1

r3
0.01046

T2

r4
0.01569

T3

r5
0.02092

T4

0.02615
T5

Tprom

400

400

400

400

400

400

400

0.0254

408.209

409.9081

407.8283

398.5568

376.2505

320.3186

386.845217

0.0508

419.8046

419.9525

408.5118

386.2546

349.3648

281.4645

377.5588

0.0762

441.2436

429.1264

402.4555

370.9801

326.983

260.4833

371.87865

0.1016

475.2143

436.5353

393.5392

356.2591

309.4037

247.9473

369.816483

0.127

506.0725

435.7941

383.775

342.8984

295.6876

239.7515

367.32985

0.1524

499.5153

413.4572

371.0321

330.5216

284.7872

233.993

355.551067

X vs Z

0.50
0.45
0.40
Conversion

0.35

T0

0.30

T1

0.25

T2

0.20

T3

0.15
0.10

T4

0.05

T5

0.00
0

0.015240.030480.045720.060960.07620.091440.106680.121920.137160.1524
Z en metros

T vs Z
570.0
520.0

Temperatura

470.0
T0
420.0

T1
T2

370.0

T3
320.0

T4
T5

270.0
220.0
0

0.015240.030480.045720.06096 0.0762 0.091440.106680.121920.13716 0.1524


Z en metros

Perfil de conversion
0.50
0.45

Conversion

0.40
0.35

0.30

0.0254

0.25

0.0508

0.20

0.0762

0.15

0.1016

0.10

0.127

0.05

0.1524

0.00
0

0.00523

0.01046

0.01569

0.02092

0.02615

Radio en Metros

Temperatura

Perfil de Temperatura
530.0
510.0
490.0
470.0
450.0
430.0
410.0
390.0
370.0
350.0
330.0
310.0
290.0
270.0
250.0
230.0

0
0.0254
0.0508
0.0762
0.1016
0.127
0.1524

0.00523

0.01046

0.01569

Radio en Metros

0.02092

0.02615

X promedio
0.12

Conversion Promedio

0.1
0.08
0.06
0.04
0.02
0
0

0.02

0.04

0.06

0.08

0.1

0.12

0.14

0.16

0.18

0.12

0.14

0.16

0.18

Z en metros

T promedio
400
390

Tmeperatura Promedio

380
370
360
350
340
330
320
310
300
0

0.02

0.04

0.06

0.08

0.1

Z en metros

HALLANDO EL PESO DEL CATALIZADOR


W V D..........(1)

Z d2

Donde:

= 0.5 (porosidad)

D = 800Kg/m3 (densidad del catalizador)


Z= 0.1524m (longitud del catalizador)
d = 0.0523m (dimetro del catalizador)
Reemplazando datos en (1)
W

0.1524 0.05232 * 0.5 * 800

W 0.1309Kg