Ambedkar Nagar

Prime Classes for IIT-JEE/PMT, Ambedkar nagar

1. For an adiabatic process which of the following is correct?
(a) q = 0 (b) DE = q (c) q = +w (d) pDv = 0
2. In an isothermal process
(a) Temperature is kept constant (b) no heat exchanges (c) no work is done (d) None of these
3. In case of an isothermal reversible process involving an ideal gas, work done is given by
(a) q = w (b) q = DE + w (c) q = E (d) q = DE w
4. What is the work done when an ideal gas expands from 10
3
m
3
to 10
2
m
3
at 300 K, against a constant pressure of
10
5
Nm
2
?
5. Calculate the values of q, w and DE when one mole of a gas absorbs 500 J of heat at constant volume and
temperature rises from 25 C to 35 C.
6. Work done by the gas when the gas expands isothermally and reversibly is
(a) zero (b) minimum (c) maximum (d) cannot be determined
7. A gaseous system changes from state P(P
1
, V
1
, T
1
) to Q(P
2
, V
2
, T
2
), Q to R(P
3
, V
3
, T
3
) and finally from R to P.
The whole process is called
(a) reversible process (b) cyclic process (c) spontaneous process (d) isobaric process
8. If a balloon is inflated from 0.100 L to 1.85 L against an external pressure of 1.00 atm, how much work is done?
9. A gas present in a cylinder fitted with a frictionless piston expands against a constant pressure of 1 atmosphere
from a volume of 2L to a volume of 12 L. In doing so, it absorbs 800 J heat from surroundings. Determine the
increase in internal energy of the process.
10. A certain process results in a gas system releasing 68.3 kJ of energy. During the process, 15.8 kcal of heat is
released by the system. If the external pressure is kept constant at 1.00 atm and the initial volume of the gas is
10.0 L, what is the final volume of the gas? (1 cal = 4.18 J, 101.3 J = 1.00 atmL)
11. What work is to be done on 2 mol of a perfect gas at 27C if it is compressed reversibly and isothermally from a
pressure of 1.01 10
5
Nm
2
to 5.05 10
6
Nm
2
(R = 8.314 J mol
1
K
1
).
12. When 1.010 g of sugar is burned in a bomb calorimeter, the temperature rises from 24.92 C to 28.33 C. If C
cal
=
4.90 kJ/C, find DE for burning 1 mole.
13. What is DH
rxn/mol Mg
for the reaction Mg(s) + 2 HCl(aq) MgCl
2
(aq) + H
2
(g) if 0.158 g Mg reacts in
100.0 mL of solution and changes the temperature from 25.6 C to 32.8 C?
14. Determine the heat of transformation of rhombic sulphur into monoclinic sulphur.
15. Given the following information:
2 NO(g) + O
2
(g) 2 NO
2
(g) DH = 116 kJ
2 N
2
(g) + 5 O
2
(g) + 2 H
2
O(l) 4 HNO
3
(aq) DH = 256 kJ
N
2
(g) + O
2
(g) 2 NO(g) DH = +183 kJ
Calculate the DH for the reaction below: 3 NO
2
(g) + H
2
O(l) 2 HNO
3
(aq) + NO(g) DH = ?
16. Calculate resonance energy of benzene from the following data:
(i) benzene = 358.5 kJ mol
1
(ii) Heat of atomization of carbon is 716.8 kJ mol
-1

(iii) Bond energies of CH, CC, C = C and HH bonds are 490, 340, 620 and 436.9 kJ mol
1
respectively.
17. For the reaction
H=-780.9kcal, E for the reaction will be
(a) 781.80 Kcal (b) 780.009 Kcal (c) 780.75 Kcal (d) 780.05 Kcal
18. When 1 gram of methane (CH
4
) burns in O
2
the heat evolved (measured under standard conditions) is 13.3 kcal.
What is the heat of combustion?
(a) 13.3 k cals (b) +213 k cals (c) 213 k cals (d) 416 k cals
19. When 4.184 J of heat is transferred to 1 g of water at 20 C, its temperature rises to 21 C. The molar heat capacity
at this temperature is (in J/k)
(a) 18 (b)18/4.184 (c) 75.4 (d) 4.184
20. When 0.532 g of benzene (B.P 80 C) is burnt in a constant volume system with an excess of oxygen, 22.3 kJ of
heat is given out. for the combustion process is given by
(a) 21 kJ (b) 1234.98 kJ (c) 221 kJ (d) 3273.26 kJ
Prime Classes for IIT-JEE/PMT, Ambedkar nagar
Ambedkar Nagar
Prime Classes for IIT-JEE/PMT, Ambedkar nagar
21. Consider the reaction

H= 98.3 kJ. If the enthalpy of formation

of SO
3
(g) is 395.4 kJ, then the enthalpy of formation of SO
2
(g) is
(a) 297.1 kJ (b) 493.7 Kj (c) 493.7 kJ (d) 297.1 kJ
22. Calculate the heat change for the following reaction:

H
f
for CH4 , H2O and CO2 are
17.89, 68.3 and94.05 kcal/mole.
23. Calculate the heat of combustion of benzene from the following data:



24. Calculate E for the following reaction at 27
o
C.

Given H = 337 kcal

R= 1.987 cal deg
1
mole
1
25. Calculate the heat of combustion of acetic acid at 25
o
C if the heat of formation of CH
3
COOH(l),CO
2
(g) and H
2
O(l)
are 116.4, 94.0 and 68.3 kcal mole
1
respectively.
26. Reacting 50 mL of H
2
(g) with 50 mL of C
2
H
4
(g) produces 50 mL of C
2
H
6
(g) at 1.5 atm. If the reaction produces 3.1 x
10
2
J of heat and the decrease in volume requires the surroundings do 7.6 J of work on the gases, what is the
change in internal energy of the gases?
27. A gas mixture of 3.67 litres of ethylene and methane on complete combustion produces 6.11 litres of CO
2
at 25
o
C.
Find the amount of heat evolved on burning one litre of the gas mixture. The heat of combustion of ethylene and
methane are -1423 and -891 kJ mole
-1
at 25
o
C.
28. Calculate the enthalpy of vaporization per mole for ethanal if change in entropy is 109.8 JK
1
mol
1
and its
boiling point is 78.5
0
C.
29. Calculate the temperature at which liquid water will be in equilibrium with Water vapour.
30. Standard free energies of formation for NH
3
(g), NO(g) and H
2
O(l) are 16.8, 86.7 and 237.2 kJ mol
1
. From the
above data calculate the standard free energy change for the following reaction.
31. What is the minimum potential difference required to reduce Alumina (Al
2
O
3
) at 500
o
C. Given that F = 96500 C and
DG
o
for the following reaction is 960000 J/mol.
32. Standard Gibbs free energy of ammonia is 33.294 x 10
3
J/mol at 25 C. Calculate the value of equilibrium
constant.
33. Enthalpy change for the transition of liquid water to steam at 100C is 40.8 kJ mol
-1
. Calculate the entropy
change for vapourization of water.
34. If a refrigerator door is kept open, then the
(a) room cools down (b) room gets heated up (c) no effect on room temperature (d) None of these
35. When enthalpy and entropy changes for a chemical reaction are 25 10
2
Cals and 7.4 Cals deg
1
respectively. The
reaction at 298 K is (a) spontaneous (b) reversible (c) irreversible (d) non spontaneous
36. Entropy depends on (a) volume (b) temperature (c) pressure (d) All of these
37. Consider the following reaction occurring in a automobile engine The signs of for THE reaction would be
(a) +, , + (b) , +, (c) , +, + (d) +, +,
38. According to third law of thermodynamics the entropy is minimum at 0 K for
(a) liquids (b) elements in their atomic form (c) perfectly crystalline solids (d) All of these
H = 11720 cal
H = -68320 cal
2 2
C(s) + O (g) CO (g)
H =-93050 cal
vap
vap
H 40.73 kJ / mol.
S 0.109 kJ / mol. /K


3 2 2
4NH (g) 5O (g) 4NO(g) 6H O(l)
1
2 3 2
2 4
Al O 4e Al O
3 3

8 18 2 2 2
2C H g 25O g 16CO g 18H O g