Documentos de Académico
Documentos de Profesional
Documentos de Cultura
Darren Darren A. A. Lytle, Lytle, Jeremy Jeremy Payne Payne and and Michael Michael Schock Schock U.S. U.S. Environmental Environmental Protection Protection Agency Agency ORD, ORD, NRMRL, NRMRL, WSWRD, WSWRD, TTEB, TTEB, Cincinnati, Cincinnati, Ohio Ohio 45268 45268
Lytle.darren@epa.gov Lytle.darren@epa.gov
AWWA ACE, Orlando, June 2004
Acknowledgements
Christy Frietch, Cheryl James, Tim Hodapp, and Tori Blackschlager-U.S. EPA Abraham Chen, Bruce Sass, Lili WangBattelle Memorial Institute
Project Objective
Determine the composition of solids collected from DW DS where measurable amounts of arsenic in the finished water -pipe sections (corrosion products, deposits, etc.,) -fire hydrant flush (loose particles, corrosion products, etc.)
Pipe Material
Took what we could get when we could get it. Any material was acceptable (PVC, AC, cast iron, copper, etc..) Scrape (layering if possible), grind
Sample Preparation
Solids Analysis
Acid digestion/ICP-MS (Battelle) ! Ca, Mn, Fe, Mg, P, Si, As ! Units XRF (Univ. of Cincinnati Geology Dept.) ! Cl, S, Ba, Ca, Mn, Mg XRD ! Mineral phases Electron mircoprobe-WDS (Battelle) ! Quantitative elemental mapping SEM-Wavelength dispersive spectrometerimaging and elemental mapping
Analysis Techniques
Identification of crystalline minerals Crystal size approximation
X-ray Diffraction
Analysis Techniques
X-ray Photaelectron Spectrometry
Determines oxidation state, bonding energy, bond type, and chemical composition
Electron Microprobe
Determines the chemical composition of very small samples, and produce high resolution elemental maps
Analysis Techniques
Provides quantitative elemental composition of solid samples This technique is destructive
X-Ray Florescence
Steel
Arsenic distribution
Cumulative effect of corrosion, hydraulic scouring and dissolution of corrosion scales. Usually measured as concentration of iron in bulk water
Tubercle Structure
Soft Inner Layer
Tubercle Structure
When oxidants are not present at the surface, ferrous iron can diffuse into solution and is oxidized there- particles
Copper Pitting
Insert Cu pipe photo here
Hole
4 mm
CopperPitting
4 mm
Lead Aging
Lead Aging
Goethite