Van der Waals:

( )
2
a
P v b RT
v
| |
+ =
|
\
Van der Waals:
( )
2
a
P v b RT
v
| |
+ =
|
\
9
8
3
c c
c
a RT v
v
b
=
=
Berthelot:
( )
2
a
P v b RT
Tv
| |
+ =
|
\
Clausius:
( )
2
( )
a
P v b RT
T v c
| |
+ =
|
+
\
Virial:
2
= + + + +
B C
Pv A
v v
Redlich - Kwong (RK)
( )
RT a
P
v b
Tv v b
=

+
2 2.5
0.42748
0.08664
c
c
c
c
R T
a
P
RT
b
P
=
=
Soave - Redlich - Kwong (SRK)
( )
RT a
P
v b v v b

=
+
( )( )
2 2
2
2 0.5
0.42747
0.08664
1 0.48508 1.55171 0.15613 1
=
=
(
= + +

c
c
c
c
r
R T
a
P
RT
b
P
T
Peng - Robinson (PR):
2 2
2
RT a
P
v b v bv b

=
+
( )( )
2 2
2
2 0.5
0.45724
0.07780
1 0.37464 1.54226 0.26992 1
=
=
(
= + +

c
c
c
c
r
R T
a
P
RT
b
P
T
Beattie - Bridgeman
2
0 0
3
1 1 1
b C a
Pv RT v B A
v vT v
(
| | | | | |
= +
| | | (
\ \ \

Benedict-Webb-Rubin (BWR)
2
0
0 0
2
2 3 6 3 2 2
1
v
C
RTB A
RT RTb a a C
T
P e
v v v v v T v

| |

|
\

| |
= + + + + +
|
\