Batch - XII - old Q:1.

Stoichiometry

DPP - 1

A glass vessel weighed 20.2376 gm when empty and 20.3102 gm when filled to an etched mark with water at 40C. The same vessel was then dried and filled to the same mark with a solution 40C. The vessel was now found to weight 20.3300 gm. What is density of the solution. Two flasks A and B of 500 ml each are filled respectively with O2 & SO2 at 300K and 1 atmp. The flask contain. Number of molecules in 100 ml each of O2 , NH 3 , CO2 at NTP are in order

Q:2.

Q:3.

ACO2 O2 NH 3 B NH 2 O2 CO2 C NH 3 CO2 O2

Q:4. Q:5.

(D) same

A piece of Cu weighs 0.635 g. How many atoms of Cu does it contains ? Calculate the number of molecules in 11.2 litres of SO2 gas at NTP. .

*Q:6. From 200 mg of CO2 ,1021 molecules are removed. How many moles of CO2 are left ? Q:7. Q:8. Calculate volume of 20 g of hydrogen gas at NTP. What volume shall be occupied by 6.022 10 23 molecules of any gas at NTP ?

*Q:9. In 4g atoms(mol) of Ag, calculate (a) weight of Ag (b) weight of one atom of Ag; at wt of Ag = 108 Q:10. How many mole and molecules of O2 are there in 64 g O2 ? What is the mass of one molecules of O2 ? Q:11. How many year it would take to spend Avogadros number of rupees at the rate of 10 lac rupees per second ? Q:12. From 200 mg of CO2 ,1021 molecules are removed. How many g and miole of CO2 are left ? Q:13. Number of sulphate ions in 39.2 g of chromium sulphate are ____________________.

Batch - XII - Old

*Q:1.

Stoichiometry

DPP - 2

A clay was dried partially dried and then contained 50% silica and 7% water. The originalclay contained 12% water. What is the % of silica in the original sample ? A granulated sample of aircraft alloy (Al, Mg, Cu) weighing 8.72 g was first treated with alkali to dissolved Al, then with very dilute HCl to dissolve Mg, leaving a residue of Cu. The residue after alkali boiling weighe 2.10 g, and the acid insoluble residue from this weighed 0.69 gm. What is the composition of the alloy ? The atomic weight of two elements A and B are 20 and 40 respectively. If x gm of A contains atoms, how many atoms are present in 2x gm of B. How nuch calcium is in the amount of calcium nitrate that contains 20 gm of nitrogen. Two element P and Q form P2 O3 and PQ2 . If 0.15 mole of P2 Q3 weight 15.9 gm and 0.15 mole of PQ2 weigh 9.3 gm. Find at . wt. of P and Q. Which of the following sample contains the smallest number of atoms (a) 1 g O2 (b) 1 g C8 H 18 (c) 1 g LiF (d) 1 g B4 H10

Q:2.

Q:3.

*Q:4. Q:5.

Q:6.

Q:7. Q:8.

How many atoms are there in 100 amu of He ? Calculate the following : (a) number of atoms in 2.3 kg
23 11

Na

(Na = 23) (Br = 80) (N = 14, H = 1) ((Pb = 206, Cr = 52) (O = 16, S = 32)

(b) niumber of atims in 32.0 g Br2 (c) number of molecules in 51.0 g of NH 3 (d) number of formula units in 159 g PbCrO4 (e) number of SO4 2 ions in 14.3 g of Cr2 SO4 3 Q:9. Q:10. Q:11. Q:12.

The mass of 1 x 1022 molecules of CuSO4 .H 2O is ______________. Calculate the number of each atom present in 122.5 g of KClO3 . Find the number of atoms in 48 g of ozone at NTP. Calculate the number of oxygen atoms in 0.2 mole of Na2 CO3 .10 H 2 O.

Q:13. Find the ratio of number of molecules contained in 1 g of NH 3 and 1 g of N 2 . Q:14. Calculate the total number of atoms in 0.5 moles of K 2Cr2O7 .

Batch - XII - old

Q:1. Q:2.

Stoichiometry

DPP - 3

Density of ethanol is 0.7893 g/mL. If 1.2 mol of it are needed for a particular expt, what volume of it should be measured. In an expt., it is found that at STP, 1 gm Ra, produced 1.07 x 10-4 mL, He per day. In another series of expt. 1 gm Ra was found to emit 3.4 x 1010 a particle per second. Compute value of Avogadros number. . A drug marijuna owes its activity to tetrahydrocarbinol, which contains 70% as many C atoms as H atoms and 15 times as many hydrogen atoms. The number of mole in a gm of it is 0.003118. Determine the molecular formula. Copper forms two oxides. For the same amount of copper, twice as much oxygen was used to form the first oxide than to form the second one. What is the ratio of the valencies of copper in the first and second oxides ? 105 ml of pure water (40C) is saturated with NH 3 gas, producing a solution of density 0.9 g/ml. If this solution contain contains 30% of NH 3 by weight, calculate its volume.

*Q:3.

*Q:4.

*Q:5.

Q:6.

A sample of KClO3 on decomposition yielded 448 ml of oxygen gas at NTP. Calculate (a) wt. of oxygen produced, (c) wt. of KCl produced. (b) wt. of KClO3 originally taken and (K = 39, Cl = 35.5, O = 16)

Q:7.

Titanium, which is used to make airplane enguines and frames, can be obtained from titanium tetrachloride, which in turns is obtained from titanium oxide by the following process :

3TiO2 s 4C s 6Cl2 g 3TiCl4 g 2CO2 g 2CO g

A vessel contains 4.15 g

TiO2 , 5.67 g C and 6.78 g Cl2 supose the reaction goes to completion as written, how many gram

of TiCl4 can be produced ? (Ti = 48) Q:8. Q:9. *Q:10. What amount of CaO will be produced by 1 of calcium ? What weight of oxygen will react with 1 of calcium ? (Ca = 40) A sample of KClO3 on decomposition yielded 448 ml of oxygen gas at NTP. . (i) wt. of oxygen produced (ii) wt. of KClO3 originally taken and Q:11. (iii) wt. of KCl produced

What is the number of moles of Fe OH 3 (s) that can be produced by allowing 1 mole of Fe2 S3 ,2 moles of mole of

H 2O and 3

O2 react ?

(( 2 Fe2 S3 s 6 H 2 O1 3O2 g 4 FeOH 3 s 6 S s Q:12. In a process for producing acetic acid, oxygen gas is bubbled into acetaldehyde containing maganese (II) acetate (catalyst) under pressure at 600C.

2CH 3CHO O2 2CH 3COOH

In a laboratory test of the reaction, 20 g of CH 3COOH and 10 g of (a) How many grams of CH 3COOH can be produced ?

O2 were put into a reaction vessel.

(b) How many grams of the excess reactent remain after the reaction is complete ?

Batch - XII - old

Stoichiometry

DPP - 4

*Q:1. An compound which contains one atom X and two atoms of Y for each three atoms of Z is made by mixing 5 gm of X, 1.15 x 1023 atoms of Y and 0.03 mole of Z atoms. Given that only 4.40 gm of compound results. Calculate at. wt. of Y if at. wt. of X and Z are 60 and 80 amu respectively. Q:3. Q:4. How many moles of AgCl will be formed by equal masses ten gm each of KCl and NaCl. A trivalent metal forms a chloride. When 2.395 gm of salt is dissolved in water and treated with excess AgNO3 . The mass of AgCl formed is 5.168 gm. Find atomic mass of metal. Q:5. When 2.16 g HgO is heated, the volume of oxygen produced at STP is ___________ dm3 .

*Q:6. A polystyrene, having formula Br2C6 H 3 C3 H 8 n , was prepared by heating with tribromobenzoyl peroxide in the absence of air. If it was found to contain 10.46% bromine by weight, find the value of n. Q:7. Q:8. Calculate the number of oxygen atoms in 0.2 mole of Na2CO3 .10 H 2O. Calculate the weight of lime (CaO) that can be prepared by heating 200 kG of limestone CaCO3 which is 95% pure. Equal weight of Zn metal and iodine are mixed together and the iodine completely converted to Znl2 . What fraction by weight of the original zinc remains unreacted ?

Q:9.

Q:10. Three atoms of magnesium combine with 2 atoms of nitrogen. What will be the weighth of magnesium which combines with 1.86 g of nitrogen ? Q:11. How many litres of liquid CCl4 (d = 1.5 g.cc) must be measured out contain 1 x 1025 CCl4 molecules ? Q:12. How many gm of Nitrogen gas can maximum obtained from 720 kg of urea.