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Upper Dharamsala
Chemistry –XII
General Instructions
7. The rate constant of a reaction is 2X10-2 L mol-1 S-1 . What is the order of reaction?
9. Cesium chloride crystallizes as a body-centered cubic lattice and has a density of 4.0 gcm-3.
Calculate the length of the edge of the unit cell of cesium chloride crystal. Molar mass of
CsCl = 168.5 g mol -1, NA =6.02X1023 mol-1.
10. Calculate the packing efficiency of packing in the case of simple cubic structure.
17. Out line the principle of refining of metals by the following method:-
i) Zone refining ii) Electrolytic refining
18. The choice of a reducing agent in a particular case depends upon thermodynamic factor.
How far do you agree with this statement? Support your answer with example.
19. 2.82 g of glucose (molar mass 180 g mol-1) are dissolved in 30 g of water calculate molality
of solution and mole fraction of the water.
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20. What is vont Hoff factor? What type of values can it have if in solution, the solute
molecules undergo i) association ii) dissociation?
21. Show that ethyl alcohol and dimethyl ether are isomer. Explain why the boiling point of
ethyl alcohol is higher than that of dimethyl ether.
22. i) Explain Reimer-Tiemann reaction with the help of mechanism of the reaction.
ii) Arrange the following in increasing order of acidic strength
phenol, m-cresol, o-cresol, p-cresol
23. i)Arrange the given compounds according to increasing acidic strength, Benzoic acid,
4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid.
ii) How will you distinguish between Propanol and Propanone? Write chemical reaction.
24. While preparing monobromoaniline why is aniline acetylated before reacting it with
bromine? Explain.
26. The value of molar conductivity at infinite dilution for HCl,NaCl and CH3COONa are
426.1 ,126.5 and 91.0 Ωcm2 mol -1 respectively. Calculate the value of molar conductivity at
infinite dilution for Acitic acid.
27. What do you mean by Popoff’s rule? Explain with suitable example.
OR
i) Define the term activation energy. What is the unit of activation energy?
ii) Sketch a labeled potential energy diagram for exothermic reaction and endothermic reaction
in presence and absence of catalyst.
iii) What do you mean by Pseudo first order reaction give one example?
29. i) How will you differentiate between physical adsorption and chemical adsorption?
ii) define the term Gold number
OR
30. An organic compound C2H4O gives red colour precipitate when warmed with Fehling
solution. It also undergoes aldol condensation in presence of NaOH.
i) Write the IUPAC name of the compound ii) write the balanced chemical equation for reaction
iii) What is the state of hybridization of carbon and oxygen in the compound.
OR
Conversions:-
i) Acetaldehyde to iso-propyl alcohol ii) Propanoic acid to Propanol
iii) Acetic acid to methylamine iv) Propanone to Propene
v) benzene to methyl benzoate
===========================GOOD LUCK==========================
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