Documentos de Académico
Documentos de Profesional
Documentos de Cultura
2001 8
32 8
MIP
( , 100083)
, ,
, , :
, ,
12. 4 , 6 , RON MON
1. 3 , ( ) 15% ,
:
20 ,
, ;
,
(
, , ,
, (
0. 08%
) ,
80% ,
( ) 40% ~ 65% ,
,
,
( )
( )
40% , ( )
2. 5% ,
35% ,
,
MIP[ 1] ( Maximizing Iso-Paraffins)
,
, ,
[ 2]
1,
: 2000-12-04; : 2001-01-11
: , 1987
,
2001
32
, ;
( 1 ) ,
, ,
, ,
; ,
, ,
1 1
, ,
, ,
,
;
2 ( 2 )
n-C 10H 22
n-C 7H 16 + C3H 6
i- C 8H 16
lgK E( )
4C 6H 12
510
2. 04
2. 46
2i-C 4H 8
1. 68
2. 10
3C6 H14 + C 6H 6
12. 44
11. 09
11. 22
10. 35
0. 32
0. 25
C 6H 12 + 3i-C5- H 10
3C 5H 12 + C 6H 6
1-C 4H 8
1-C 4H 8+ i- C 4H 10
i-2-C 4H 8
1-C 4H 8
454
i- C 4H 8
( 510
527
)/
kJ mol- 1
33 812
2. 23
35 514
- 115 713
- 77 278
0. 09
- 5 142
0. 236
i-C8 H18
- 3. 3
2 , 2 ,
, ,
,
,
,
,
,
, ,
,
,
, ;
,
RAG- 1
,
, ,
2 ,
, ,
3
,
2 ,
,
37% ,
. MIP
3. 54% 5. 88% ,
,
500
530
/ h- 1
10
78
3. 58
2. 95
22. 59
28. 08
47. 82
40. 63
3 ,
1. 95% , 98% ,
11. 99
11. 69
87. 43% ,
6. 02
8. 58
8. 00
7. 64
)/%
0. 43
8. 08
8. 21
9. 08
6. 44
4. 69
1. 53
4. 18
RON
90. 2
93. 7
MON
79. 3
81. 2
30. 04
25. 99
25. 55
49. 20
37. 67
18. 71
5. 88
3. 54
31. 79
15. 17
6. 74
6. 10
)/%
450
24. 25 ,
, , 2
,
,
[ 3] :
2 ( 3 ) ,
,
0. 45
, ,
, ,
6. 36
87. 43
3. 82
0. 21
1. 50
0. 23
)/%
) /%
5. 59( 4. 99)
8. 10( 7. 53)
2001
32
4, MIP
[ 4]
4 , MIP FCC
, ,
,
; ,
, 3. 08%
2. 97% 6. 47% 6. 17% ;
, ,
43. 70% , ;
,
5 MIP FCC
MIP
, FCC
4
MIP
4 , MIP
( + + ) 84. 01%
80. 72% , ,
FCC
, 27. 2% , FCC
39. 6% 12. 4 , (
)/%
3. 08
2. 97
16. 92
15. 33
) 6. 4 , 6
; 24. 5% , FCC
45. 07
43. 70
32. 78% 8. 28
22. 02
21. 69
15. 0% , , MON
6. 44
10. 14
6. 47
6. 17
1. 3, RON , MIP
/ %
71. 54
68. 17
( + ) / %
67. 09
65. 39
( + + ) / %
84. 01
80. 72
,
,
0. 761 4
0. 759 7
1 129
1 329
; ; FCC
42
16
( ) / %
86. 96
86. 52
MIP ; MIP
( ) / %
12. 92
12. 95
1. 1
1. 8
> 1 000
572
( 20
) / g cm - 3
- 1
( ) / g g
( ) / g g- 1
/ gI ( 100g) - 1
/ min
FCC
MIP
,
6
,
,
MON
79. 8
78. 5
RON
91. 7
91. 7
28. 94
25. 43
8. 42
9. 5
24. 5
32. 78
37. 56
31. 52
41. 6
35. 2
27. 2
39. 6
31. 2
25. 2
) /%
, ,
,
MIP,
, ,
,
( ) / %
LV-23;
1 .
. MIP
. , CN 1232069A. 1999
1237477A. 1999
. . , CN
and Technical A spects. Cat al Rev- Sci Eng, 1989, 31( 3) : 215~ 354
4 .
. , CN 1245202A. 1999
Abstract
A concept of two different reaction zones was proposed based on the FCC react ion mechanism
and verified by the experimental results of a fixed- fluidized bed reactor. The concept was used to design a novel reactor
with corresponded operation measures. Further experiments were conducted on the newly designed pilot plant riser reactor. In comparison with the conventional FCC at similar condit ions, the pilot plant results showed that the olefin content in the cracked naphtha dropped by 12% and both of iso- paraffin and aromatics increased by about 6v% , and its
MON increased by 1. 3 unit with RON unchanged. The cracked naphtha had a longer induct ion period and its sulfur
content decreased by 15% .
Key Words: catalytic cracking; riser reactor; react ion mechanism; gasoline stock; olefin
, ,
( 3) : 12 5
4 ,
, ,
, 3
, ,
270kt/ a
2000 12 ,2000 12 31
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MTBE
1997 70kt/ a ,
BF3
BF3 ,
270kt/ a:
( 1) : ADV
69 ,
, ,
59
69 , 75 ,
( 2) :
,
,
Triconex TS3000
, 5 000t
, ,
, , ,
500t ,
,