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Water and effluent treatment Heating and cooling utilities Heat recovery system Separation and recycle system
Reactor
Environmental issues
When designing and operating process plant, consideration must be given to:
All emissions to land, air, water, Waste management, Smells, Noise, Visual impact, Other Environmental friendliness of product
Continuous
Production > 5x106 kg/h Single product No severe fouling Good catalyst life Proven process design Established market
Batch
Production < 5x106 kg/h Range of products Severe fouling Short catalyst life Uncertain design New product
Thickener Design
Water
Solids
Most widely used method of removing fine solids from dilute slurries is by sedimentation using a THICKENER Two Processes Occurring...
Thickening To increase the solids concentration of a slurry Clarification To produce a recycle water stream that is free of solids (i.e. clarified)
With the development of polymeric flocculants, the two processes occur simultaneously in one vessel
Introduction
Clarifying
Sometimes the prime objective is to get the cleanest possible overflow
In some cases the underflow density may be compromised as this is of secondary importance. The clarifier generally looks like a thickener but may have features to enhance particle capture.
Thickening
The basic purpose of thickening is to remove as much water from a slurry as to give us a thick underflow, and a clean/clear overflow
A thickener is used to accelerate the process of settling and dewatering of solids in a slurry using flocculants The desired end product will determine how the thickener is designed and operated.
Thickening - calculations
Thickener Design
If more solids are fed to the thickener, they will not leave the thickener through the underflow!
t=0
UP UTotal
UP
Settling: SPS = UP * CV Flow: SFS = VFlow/A * CV = UFlow * CV TOTAL FLUX below: STOTAL = UP * CV + UUnderFlow * CV
UOFlow
UUFlow
VUFlow
= UT (1-Cv)4.65 * CV - VOverflow/A * CV
Scrit
SFS a CV SPS = UP CV
CVFeed
CVcrit
Thickener Design
Height
Feeding zone Clarifying zone Swarm settling Transient zone Compression zone Rake
Concentration
Conventional Thickener
Traditionally no flocculants and hence large diameters. Low unit area throughput t/m2.hr. Slow to react automated (feedback) control more difficult. Control based on constant solids inventory difficult. Suitable for highly variable flow and solids loading. UF density can be variable High capital cost.
16 | |
Paste Thickener
Also makes use of flocculation. Unit area throughput t/m2.hr maximised but secondary to UF density. Consistent high yield stress underflow (+150 Pa) Small footprint but relatively tall. Control based on underflow properties (and torque). Automation important for stable operation. Best suited to relatively consistent process. High underflow solids concentration > than 50%
High side walls (usually in excess of 6m) Increased floor slope (generally between 30-45)
17 | |
Lamella thickeners
u u
Tanks, filled with a number of closely spaced inclined plates Short settling distance to the upper surface of each plate and then slide down the inclined plate)
Main parts: Vessel, Feed well, drive, rake, discharge Types: Conventional thickeners: 30 - 200 m diameter High rate thickeners High compression thickeners (high) Deep cone thickeners, Rakeless thickeners Lamella, Flocculation is important (feed well design)
GL&V
Thickener Design
FLOCCULATION
Solids flux loading Volumetric flux Feed concentration Particle size distribution Particle density Particle charge
UNDERFLOW
Dosage Temperature and pH Concentration of stock solution Number of addition points Mixing conditions at addition points Flocculant type
Rate of underflow removal OVERFLOW Underflow concentration Volumetric flux Viscosity of underflow Clarity of overflow liquid material
Bed height characteristics Concentration profile Bed rise velocity Compression effects
Residence time
Feed entry position (high rate thickening)
All solid minerals in suspension have a charged surface Number of charges and sign of charge depend on... pH Other ions Coal tailings generally negative in charge (except at very low pH)
Plane of Shear
Flocculation
Long chain polymer (hydrocarbon) with charged groups attached. Very large molecules with Molecular Weights in the millions.
The chains uncoil due to charged site repulsion and hydration effects around the charge sites. The large molecules can reach out a long way and can interact with multiple particles simultaneously holding them , drawing them together.
Flocculation If the amount of flocculant is increased, the underflow density will increase to a peak. Above this flocc dose the underflow density decreases due to over flocculation and inclusion of excess water within the floccs. What types of flocculants are there? Anionic, Neutral, Cationic, Different charge species on chain determine category. Anionic and less so neutrals most common in mining. Cationic use rare for minerals. 23 | |
Coagulants
Uses
PROBLEM Suggested Action SETTLING RATE TOO SLOW Increase polymer dilution Reduce slurry agitation
RESULT
Multi-point addition ...................... More effective conditioning to build larger flocs Change pH .................................. Optimised performance of polymer Dilute feed solids ......................... Reduced hindered settling SETTLING RATE TOO FAST Reduced effective polymer dosage Decrease dosage ........................ Formation of large flocs prevented Increase slurry agitation .............. (flocculant capture maintained) Multi-point addition ...................... More flocculant available for particle capture where shear is high Less for floc building where flocculant is low
Multi-point addition ...................... More flocculant available for particle capture where shear is high Less for floc building where flocculant is low
Increase molecular weight of flocculant Higher settling rate ..................................... Better compaction Recycle underflow to feed (least favoured Increased feed solids density option) ........................... Increased floc density
Raise rakes
40.5 m
Test work has shown that the clarifier should be sized based on a rise rate of 3.5 m/h : Note : A 3.5 m/h Rise Rate is equivalent to a Volumetric Loading of 3.5 m 3 / m 2 h For say 500 m 3 /h of feed ' slurry' (at low %w/w solids), we have 500 m 3 slurry h
2 mT 2 hickener Area h x 142.9 m T hickener Area 3.5 m 3 slurry
13.5 m
31 | |
Outcome / Expectation
Fundamental understanding
Compact, simple and relative (Fluid flow) low capital cost Absence of moving parts => low Fluid flow: minimum maintenance fluidisation & bubbling Relatively high thermal efficiency velocity Gentle powder handling
Good gas-solids contact Fluidised bed designs and shapes Good heat transfer due to good Mostly circular. Why? mixing Near isothermal conditions Freeboard, wider diameter at possible due to good heat top exchange (good control)
Design examples
Overview of Filtration Processes Separation: No cake formed Cake formation Deep granular beds Pressure Cartridge filter Vacuum Gravity Centrifugal batch and continuous
Deep Bed Filtration Applications: Liquor clarification (polishing) after leaching Wastewater treatment Solids removal (valuable solids) Nutrient removal (chem. precip. phosphorous) Operation: Filtration Phase (collecting solids inside the bed) Cleaning Phase or back-washing (removing trapped solids from the bed)
Solid-Liquid Separation Driving Forces Gravity (drainage) e.g. on stockpile, bunker Vacuum (sucking water + air through the filter cake) Mechanical pressure (squeezing) Slurry pressure (pumping through filter) Air pressure (blowing water, air through the filter cake) Centrifugal force (spinning packed bed in a perforated bowl)
Laboratory Filter for determining filtration rate Filtration rate (mass of filtrate versus time and filter area) Cake formation time / drying Gas flow rate to design vacuum pump Final cake moisture (wt%) Specific filter cake resistance rc Filter media resistance Rm in (1/m) Effect of Filtration Parameters Operating Parameters Pressure drop across the cake Filter speed (interrelated with cake thickness and filtration time) Trough slurry level for rotary filter Material Properties Feed size distribution, Feed solids concentration, Feed composition (ash, mineralogy, shape, hydrophobicity) Flocculation, Viscosity and Temperature Design Parameters Maximal filter speed Filter cloth permeability
Mineral Processing
Introduction and Overview Comminution Crushing and Grinding Sizing Screening and Classification Beneficiation Density Separation, Magnetic Separation Flotation, Sorting Solid / Liquid - Separation Thickening, Clarification Filtration, Centrifugation Tailings Handling and disposal Storage and Transport
Schematic of mining-processing
Water Mining Tailings/Waste Solid/Liquid Separation Tailings Chemicals
Crushing Grinding
Beneficiation Solid/Liquid Separation Product Recovery
Roasting
Leaching
Purification
Solid/Liquid Separation
COMMUNITION - Crushing
Crushing reduces ROM ore to -10mm to -15mm Usual ly involves several stages - primary, secondary, tertiary if needed, reduction ratio about 3:1 to 4:1 each stage Screening between stages to bypass fines and recycle oversize Typical crushers: jaw (primary), gyratory (secondary)
COMMINUTION - Grinding
Reducing particles to micron size Grind to liberation size (P80 < 75 microns) Multi stages, SAG mills, rod mills, ball mills, etc Classification by hydrocyclones to recycle oversized materials Grinding also liberates unwanted impurities
Crushing Practice
Jaw crusher primary Gyratory crushers primary Cone crushers secondary Roll crushers soft e. g. coal Impact crusher Hammer mills High pressure grinding rolls Shredders recycling
Crushers
(d)
Grinding Practice
Ball mill Rod mill Autogenous mill Semi-autogenous mill (SAG) High pressure grinding roll
N>Nc
Nc
42.3 D
Grinding Practice
Ball mill - using steel or other balls as media Rod mill - using steel rods as media Autogenous mill (+ no Contamination) using coarse product as media (sandstone lumps used to grind sand) Semi-autogenous mill (SAG) N>Nc using coarse product and steel balls as medium size is not grind autogeneous
For Example
1m sample to 200m
1. 2. 3. 4. 5. Primary Crushing (RR 5:1), Secondary crushing (RR 5:1) Tertiary crushing (RR 5:1), Primary grinding (RR 20:1) Final grinding (RR 20:1)
1m0.2m0.04m0.008m0.0004m0.00002m
Volume occupied by the broken particles is significantly larger than the uncrushed rock.
O/F
O/F
U/F
U/F
Comminution PSD
Q3(d) 100% Product B Feed Product A
0% d
Comminution PSD
Q3(d) 100%
0% d
coarse
Vibrating Screens: Vibrating screen coarse/medium DMS sieve bend Banana screens Classification (Particles in a fluid) Hydrocyclones: fines Elutriators and others: accurate fines
15-20
Screen
Zone 1
Zone 2
Zone 3
Screen length
1 - 2 m/s
Zone 1 Zone 2 0.5 - 0.8 m/s
Zone 3
Screen length
30 25 20
Banana Screen
15
0% d
Tailings
Gravity Separation
Principle: Float/sink method rely on differences in specific density of minerals Practice: similar devices used for size classification Jigs (coarse size) pulsing bed on a screen Flowing film separators Drums, cones, cyclones
1) Jigging
Oscilating jig up and down under water in the denser and larger particles forming the low layers, with the finer lighter particles on top. Two stage strokes:
1. pulsion stroke - particle bed elevated above jig plate 2. Suction stroke - particles settle back on the plate
http://www.youtube.com/watch?v=9gqzvTMnhVQ
Hindered settling
Consolidated trickling
Start
2) Shaking tables
Flowing film type separator - heavy minerals The separation is controlled by 1.operating variables-wash water, feed pulp
3) Spiral
Heavy mineral deposits such as ilmenite, rutile,
zircon, monazite
5) Knelson Concentrator
Gravitational force + centrifugal force
Ferrosilica FeSi SD = 6700 kg/m3 (with ca 15 % Si) Practice: TESKA and Daniels Bath Cyclones, LarCoDem
(gravity) (centrifugal)
Sorting - Principles
Using different physical properties to sort materials: Sorter functions: singulation - detection ejection
optical characteristics (colour, shape) Practice: magnetic susceptibilities Hand and machine sorting of x-ray fluorescence diamonds, glass, coal, radioactive radioactivity material electrical and thermal (PET bottles, plastics, recycling of conductivity waste) electrical charging
Paramagnetic materials: e.g. hematite, ilmenite ... attracted by a magnetic field Practice Ferromagnetic materials: Wet drum low intensity iron, magnetite magnetic separator very strongly paramagnetic Wet high intensity magn materials separators (WHIMS) Diamagnetic materials quartz and feldspar repelled by a magnetic field
Electrostatic Separation
Principles Electrostatic charges result in separation Particle charging (induction, ion bombardment, contact) Separation at a grounded surface Separation by trajectory of particles
Electrostatic Separation
Dry or wet low intensity, or wet high intensity mag. sepn,(WHIMS) - relies on different magnetic susceptibilities Electric separation ( High tension separation) relies on forces acting on charged or polarised particles for separation
FLOTATION
Relies on air bubbles to float mineral particles for collection as concentrates Add reagents to enhance collection (collectors) and to stabilise froth bubbles (frothers) Types: Conventional, column, Jamieson cells Produces sulphide concentrates - Cu 20% to 30% (from <2% in ores), Pb 60% to 70% (from 5%), Zn 48% to 60% (from 5%), Ni 10% to 20% (from <2%)
Selectively removes target metal from pregnant leach liquor via an organic extractant Extensively used for copper and nickel recovery, e.g. using oxime chemicals to extract Cu from 2g/L leach liquor and concentrate to 50g/L, or D2EHPA to upgrade Ni from 3g/L to 100g/L
for processing PGMs and rare earths
May involve use of pressure vessels (most expensive), stirred reactors, or heaps or dumps (cheapest)
ELECTROWINNING (EW
Recovers high purity metals by DC electrolysis of high purity liquors (Cu, Zn, Ni, etc.) Products: 99.99+%Cu, 99.9% Zn Acid is produced during EW of Cu, Zn, etc. for recycling to leaching Energy consumptions: 2.5 kWh/kg Cu, 3.5 kWh/kg Zn, 12 kWh/kg Al (high temp melts)
Used for refining smelter products upgrading cast smelter anodes (95% Cu) to 99.99+%Cu cathode Cells dissolve copper anodes and plate copper cathodes, simultaneously By-products: Au, Ag and other PGMs Energy consumption: 0.25 kWh/kg Cu as cells require lower voltage.
ELECTROREFINING
PRECIPITATION
Achieved by adding chemicals (sulphide, hydroxide, hydrogen) to solution, precipitating the target metal as a solid (metal hydroxide, sulphide or pure metals) Used for liquor purification (as in water treatment) or for recovering products (production of alumina, Al2O3).
Achieved by adding a less valuable metal (A) to the solution (higher reduction potential) The target metal (B) electrochemically cements onto the remainder of A Used for liquor purification (cementation of Ni, Co, etc. from zinc sulphate liquors using zinc powder) or for product recovery (gold recovery using zinc or copper powder)
CEMENTATION
PYROMETALLURGICAL PROCESSING
Roasting - apply high temperatures (9000C) to convert sulphides to oxides,etc. Smelting - to melt and separate metals from slag (e.g. to produce blister copper) Calcining - heating to drive off water or carbon dioxide Sintering - heating with binder to convert fines to lumps
CYANIDE MANAGEMENT
acid dissociable) for tailing disposal Currently relies on cyanide
produces acid and liberates base NSW-EPA sets 20-30 ppm CN (weak
New technologies:
RESIN TECHNOLOGY
Recovers gold and other base metals as products -Recovers cyanide as HCN for recycling -Discharges to tailings contain less than 5 ppm CNwad (May Day Mines) -Yet to be accepted by industry