Documentos de Académico
Documentos de Profesional
Documentos de Cultura
Temperatura (K)
304
Volumen de O2 leido
0.006
4492.2
2.64E-03
Tiempo (t)
1.5
1.7
2
2.2
2.5
2.7
3
3.2
3.5
3.7
4
4.2
4.5
4.7
5
5.2
5.5
5.7
6
6.2
6.5
6.7
7
7.2
7.5
7.7
8
8.2
8.5
8.7
Volumen O2 (ml)
0
1.15
1.47
2.11
2.45
3.11
3.46
4.1
4.46
5.13
5.51
6.2
7
7.3
8.1
8.42
9.25
9.56
10.43
11.16
12.05
12.51
13.41
14.19
15.12
15.53
16.49
17.3
18.26
19.09
0
0.2
0.5
0.7
1
1.2
1.5
1.7
2
2.2
2.5
2.7
3
3.2
3.5
3.7
4
4.2
4.5
4.7
5
5.2
5.5
5.7
6
6.2
6.5
6.7
7
7.2
9
9.2
20.07
20.51
7.5
7.7
MTODO DIFERENCI
Ln (-dCa/dt) = Ln (Ca)
Se graficara Ca vs t, para luego ajustarla a una ecuacion cuadratica y derivarla. Con la inform
para obtener mediante la pendiente y la interseccion el orden de reaccin y la constante de
CA VS t
0.5
Series1
Linear (Series1)
y = 9E-05x2 - 0.0066x + 0.4438
Poly. (Series1)
R = 0.9994
Ca (mol/L)
0.4
0.3
0.2
0.1
0
0
10
20
t (min)
30
0.0051972
0.0050766
0.0050082
0.004884
0.00474
0.004686
0.004542
0.0044844
0.004335
0.0042792
0.0041226
0.0039912
0.003831
0.0037482
0.0035862
0.0034458
0.0032784
0.0032046
0.0030318
0.002886
0.0027132
0.0025638
0.0023874
0.0023082
MTODO INTEGR
ORDEN CERO
Ca=Ca,0 - Kt
CA VS t
Axis Title
CA VS t
y = -0.0047x + 0.4372
R = 0.9907
0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
Series1
Linear (Series1)
Linear (Series1)
10
15
20
25
Axis Title
ORDEN 2
1/Ca - 1/Ca,o = Kt
1/Ca - 1/Ca,o
0
0.012872532
0.7
0.6
0.5
Axis Title
0.032467603
0.04572581
0.065912389
0.079573844
0.10037909
0.114462449
0.135915208
0.150440297
0.172571237
0.187559144
0.2104009
0.225874076
0.249461413
0.265443785
0.289813771
0.306330866
0.331523068
0.34860215
0.374658848
0.392329063
0.419295487
0.437588035
0.465512624
0.484460939
0.513395636
0.533035589
0.56303616
0.583406289
0.61453268
0.63567444
0.4
0.3
0.2
0.1
0
comparacion
La que presenta mayor linealidad es la de orden dos. Asi pues:
Orden
K/1/min)
2
0.007
PREIN
hidrogeno
PO 2 Patm h Pvap
Altura (cm)
Presion O2 (Pa)
48.5
48.3
48
47.8
47.5
47.3
47
46.8
46.5
46.3
46
45.8
45.5
45.3
45
44.8
44.5
44.3
44
43.8
43.5
43.3
43
42.8
42.5
42.3
42
41.8
41.5
41.3
02
PO 2V O
RT amb
Moles de O2
92074.95
92094.57
92124
92143.62
92173.05
92192.67
92222.1
92241.72
92271.15
92290.77
92320.2
92339.82
92369.25
92388.87
92418.3
92437.92
92467.35
92486.97
92516.4
92536.02
92565.45
92585.07
92614.5
92634.12
92663.55
92683.17
92712.6
92732.22
92761.65
92781.27
0
7.43426E-06
1.85916E-05
2.60338E-05
3.7203E-05
4.46531E-05
5.58342E-05
6.32922E-05
7.44851E-05
8.19511E-05
9.31559E-05
0.00010063
0.000111846
0.000119328
0.000130557
0.000138047
0.000149287
0.000156785
0.000168037
0.000175543
0.000186807
0.00019432
0.000205596
0.000213118
0.000224406
0.000231935
0.000243235
0.000250772
0.000262084
0.000269629
Moles H2O2
0
1.48685E-05
3.71832E-05
5.20675E-05
7.4406E-05
8.93061E-05
0.000111668
0.000126584
0.00014897
0.000163902
0.000186312
0.00020126
0.000223693
0.000238657
0.000261114
0.000276093
0.000298574
0.000313569
0.000336074
0.000351085
0.000373614
0.00038864
0.000411193
0.000426235
0.000448811
0.00046387
0.00048647
0.000501544
0.000524168
0.000539258
41
40.8
92810.7
92830.32
0.000280953
0.000288506
0.000561905
0.000577011
DO DIFERENCIAL
dt) = Ln (Ca) - Ln K
0.006
0.005793
0.0057354
0.0056202
0.005559
0.0054402
0.0053772
0.005262
0.0051972
0.0050766
0.0050082
0.004884
0.00474
0.004686
0.004542
0.0044844
ln(-dCA/dt)
-5.11599581
-5.151104987
-5.161097784
-5.181388029
-5.192337043
-5.213939454
-5.225587486
-5.247244096
-5.25963526
-5.283113533
-5.29667871
-5.321790723
-5.351718143
-5.363175939
-5.394387835
-5.407150572
ln(CA)
-0.820980552
-0.826628487
-0.835165217
-0.840900189
-0.849569419
-0.855394048
-0.864199799
-0.870116826
-0.879063303
-0.885075597
-0.894167205
-0.900277773
-0.909519125
-0.915731115
-0.925127051
-0.931443766
LN(
-1.5
Ln (-dCa/dt)
(-dCA/dt)|t
0.004335
0.0042792
0.0041226
0.0039912
0.003831
0.0037482
0.0035862
0.0034458
0.0032784
0.0032046
0.0030318
0.002886
0.0027132
0.0025638
0.0023874
0.0023082
-5.441033669
-5.453989203
-5.491271247
-5.523663341
-5.564629413
-5.586479554
-5.630662133
-5.670599181
-5.72039978
-5.743168001
-5.798598776
-5.847883819
-5.909626529
-5.966264746
-6.037550371
-6.071287279
-0.940999361
-0.94742427
-0.957144857
-0.963681602
-0.973572784
-0.980225197
-0.990292866
-0.997064978
-1.007315341
-1.014211396
-1.024650991
-1.031675467
-1.042311189
-1.049468809
-1.060307939
-1.067603691
DO INTEGRAL
Ca,o
0.44
ORDEN UNO
Ln(Ca,o / Ca) = Kt
Ln(ca0/ca)
Orden 2
0.3
0.25
Axis Title
0
0.005647935
0.014184665
0.019919636
0.028588867
0.034413496
0.043219246
0.049136273
0.058082751
0.064095045
0.073186653
0.079297221
0.088538573
0.094750563
0.104146499
0.110463213
0.120018809
0.126443718
0.136164305
0.14270105
0.152592232
0.159244645
0.169312314
0.176084426
0.186334789
0.193230844
0.203670439
0.210694915
0.221330637
0.228488257
0.239327387
0.246623139
0.2
0.15
0.1
0.05
0
0
10
Axis Title
y = 0.0316x - 0.0097
Orden 2
y = 0.0316x - 0.0097
R = 0.9987
0.7
0.6
0.5
0.4
Series1
0.3
Linear (Series1)
0.2
0.1
0
0
10
15
Axis Title
20
25
PREINFORME PRACTICA 5
CH O
2 2
H O , inici
H O , rxn
2 2
2 2
V s ln
Conc. H2O2
0.44
0.437521913
0.433802804
0.431322077
0.427599008
0.425115642
0.421388614
0.418902608
0.41517162
0.412682974
0.408948027
0.406456742
0.402717834
0.40022391
0.396481043
0.393984478
0.390237652
0.387738448
0.383987662
0.381485818
0.377731073
0.37522659
0.371467885
0.368960762
0.365198097
0.362688334
0.35892171
0.356409308
0.352638725
0.350123682
96567.15
96586.77
7.79689E-06
1.55938E-05
0.437401037
2.7
2.8
3
3.1
3.2
3.4
3.5
3.7
3.8
4
4.3
4.5
4.75
5
5.3
5.5
5.7
6
6.2
6.5
6.7
7
7.2
7.5
7.7
8
8.2
8.5
8.7
9
6.31
7.02
7.3
8
8.3
9.3
9.37
10.07
10.38
11.43
12.3
13.37
14.3
15.38
16.3
17.23
18.33
19.26
20.4
21.35
22.5
23.5
25.1
26.09
27.3
28.35
29.58
30.56
32.21
0.346349139
0.343831458
9.2
9.5
9.7
10
10.2
10.5
10.5
33.22
34.46
35.51
37.2
38.27
39.59
y = 3.7087x - 2.0032
R = 0.9666
LN(-DCA/DT) VS LN(CA)
-0.5
0
-5.2
-5.4
-5.6
-5.8
-6
Ln (Ca)
-6.2
Series1
concentracin H2O2
-5
-1
0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
0
Orden Rxn
Ln K
K(1/min)
3.708
-2.003
0.134929886
orden 1
y = 0.0122x + 0.0016
R = 0.9957
Series2
Linear (Series2)
10
15
Axis Title
20
25
ACTICA 5
Temperatura (K)
298
Tiempo (t)
0.006
4492.2
2.64E-03
Volumen (ml)
0
0.27
0.98
1.26
1.96
2.26
3.26
3.33
4.03
4.34
5.39
6.26
7.33
8.26
9.34
10.26
11.19
12.29
13.22
14.36
15.31
16.46
17.46
19.06
20.05
21.26
22.31
23.54
24.52
26.17
uyuyuiyiu hjjjjjjjj
0
0.2
0.4
0.5
0.6
0.8
0.9
1.1
1.2
1.4
1.7
1.9
2.15
2.4
2.7
2.9
3.1
3.4
3.6
3.9
4.1
4.4
4.6
4.9
5.1
5.4
5.6
5.9
6.1
6.4
27.18
28.42
29.47
31.16
32.23
33.55
6.6
6.9
7.1
7.4
7.6
7.9
40.8
40.5
40.3
40
39.8
39.5
92830.32
92859.75
92879.37
92908.8
92928.42
92957.85
0.000247291
0.000258613
0.000266165
0.0002775
0.00028506
0.000296406
0.000494581
0.000517226
0.00053233
0.000554999
0.000570119
0.000592812
MTODO DIFERENCIAL
Ln (-dCa/dt) = Ln (Ca) - Ln K
Se graficara Ca vs t, para luego ajustarla a una ecuacion cuadratica y derivarla. Con la informacion obtenida se graficara
para obtener mediante la pendiente y la interseccion el orden de reaccin y la constante de velocidad respectivamente
Ca vs t
(-dCA/dt)|t
y = 2E-05x2 - 0.0035x + 0.4385
Series1
Linear (Series1)
Poly. (Series1)
10
20
Tiempo
30
40
0.003
0.0029892
0.0029608
0.0029496
0.0029216
0.0029096
0.0028696
0.0028668
0.0028388
0.0028264
0.0027844
0.0027496
0.0027068
0.0026696
ln(-dCA/dt)
-5.80914299
-5.812749486
-5.822295777
-5.826085711
-5.835623868
-5.839739664
-5.853582632
-5.854558854
-5.864373851
-5.868751462
-5.883722869
-5.896299832
-5.911988154
-5.925826631
0.0026264
0.0025896
0.0025524
0.0025084
0.0024712
0.0024256
0.0023876
0.0023416
0.0023016
0.0022376
0.002198
0.0021496
0.0021076
0.0020584
0.0020192
0.0019532
0.0019128
0.0018632
0.0018212
0.0017536
0.0017108
0.001658
-5.942141192
-5.956251855
-5.970721186
-5.988110179
-6.003051416
-6.021676363
-6.037466602
-6.056920823
-6.074150746
-6.102351416
-6.120207423
-6.142473501
-6.16220542
-6.185826297
-6.205053886
-6.238286226
-6.259187142
-6.285459839
-6.308259655
-6.346084461
-6.370794182
-6.402143222
MTODO INTEGRAL
En este metodo se graficaran las expresiones obtenidas en la suposicion de cada orden, y se comparara la linea
una. Quien tenga mayor linealidad entonces sera la orden de la reaccin y se calculara la constante de velocidad co
obtenidos de la grafica.
Conc. H2O2
0.44
0.43751901
0.435036964
0.433795545
0.432553862
0.430069704
0.428827229
0.426341487
0.42509822
0.422610895
0.418877927
0.416387962
0.41327402
0.410158429
0.406417542
0.403922298
0.401425997
0.397679567
0.395180627
0.391430237
0.388928657
0.385174308
0.382670088
0.378911779
0.37640492
0.372642652
0.370133153
0.366366925
0.363854786
0.360084599
0.357569821
0.353795674
0.351278256
0.347500149
0.344980092
0.341198026
ln(-dCA/dt) vs ln(Ca)
y = 2.2941x
R = 0.9891
-5.7
-1.2
-1
-0.8
-0.6
-0.4
-0.2 -5.8 0
-5.9
ln(-dCA/dt)
ln(CA)
-0.820980552
-0.826635123
-0.832324278
-0.835181951
-0.838048425
-0.843807982
-0.846701171
-0.852514641
-0.85543503
-0.861303394
-0.870175746
-0.876137853
-0.883644418
-0.891211781
-6
-6.1
Series1
-6.2
Linear (Series1)
-6.3
-6.4
lnCa
-6.5
-0.900374219
-0.906532752
-0.912732078
-0.922108706
-0.928412335
-0.937947974
-0.944359353
-0.9540593
-0.960582049
-0.970451873
-0.9770898
-0.987135357
-0.993892465
-1.004119921
-1.011000429
-1.021416278
-1.028424633
-1.039035725
-1.046176618
-1.056990184
-1.064268569
-1.07529225
Orden Rxn
Ln K
K(1/min)
2.297
-3.889
0.0204658
y = 2.2941x - 3.8932
R = 0.9891
Series1
Linear (Series1)