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1.01
1+,1
2.2
H
3
CH3COO
ammonium
NH4
benzoate
C6H5COO
BO3
borate
hydrogen
6.94
1+
9.01
2+
acetate (ethanoate)
C2
carbonate
CO3
hydrogen sulfate
HSO4
sulfite
SO3
hydrogen sulfite
HSO3
hydrogen sulfide
HS
thiocyanate
SCN
thiosulfate
S2O3
HOOCCOO
permanganate
MnO4
peroxide
O2
persulfide
S2
CIO3
12
chlorite
CIO2
hypochlorite
OCl or CIO
phosphate
PO4
hydrogen phosphate
HPO4
dihydrogen phosphate
H2PO4
magnesium
sodium
19
hydrogen oxalate
chlorate
Mg
SO4
beryllium
Na
sulfate
OOCCOO
CIO4
1.3
SiO3
oxalate
perchlorate
0.9
silicate
Be
2+
OH
NO2
Li
1+
nitrite
HCO3
24.31
CN
NO3
hydrogen carbonate
22.99
cyanide
nitrate
1.6
11
Cr2O7
IO3
1.0
lithium
dichromate
iodate
CrO4
hydroxide
carbide
chromate
39.10
1+
20
40.08
2+
21
44.96
3+
22
47.87
4+, 3+
23
50.94
5+, 4+
24
52.00
3+, 2+
25
54.94
2+, 4+
26
55.85
3+, 2+
27
58.93
2+, 3+
0.8
1.0
1.4
1.5
1.6
1.7
1.6
1.8
1.9
Ca
Sc
Ti
Cr
Mn
Fe
Co
potassium
37
85.47
1+
calcium
38
scandium
87.62
2+
39
titanium
88.91
3+
40
vanadium
91.22
4+
41
chromium
92.91
5+, 3+
42
manganese
95.94
6+
43
(98)
7+
iron
44
cobalt
101.07
3+
45
102.91
3+
0.8
1.0
1.2
1.3
1.6
2.2
2.1
2.2
2.3
Rb
Sr
Zr
Nb
Mo
Tc
Ru
Rh
rubidium
55
strontium
132.91
1+
56
yttrium
137.33
2+
57
zirconium
138.91
3+
72
niobium
178.49
4+
73
molybdenum
180.95
5+
74
183.84
6+
technetium
75
186.21
7+
ruthenium
76
rhodium
190.23
4+
77
0.8
0.9
1.1
1.3
1.5
1.7
1.9
2.2
2.2
Cs
Ba
La
Hf
Ta
Re
Os
Ir
cesium
87
barium
(223)
1+
88
lanthanum
(226)
2+
89
0.7
0.9
1.1
Fr
Ra
Ac
francium
radium
(227)
3+
actinium
hafnium
104
Rf
tantalum
(261)
4+
rutherfordium
105
tungsten
(262)
Db
106
rhenium
(266)
Sg
dubnium
seaborgium
107
osmium
(264)
Bh
108
4+
iridium
(277)
Hs
bohrium
192.22
109
(268)
Mt
hassium
meitnerium
58
References
Lide, D.R. 2005. CRC Handbook of Chemistry
and Physics. 86th ed. Boca Raton: CRC Press.
Speight, James G. 2005. Langes Handbook of
Chemistry. 16th ed. New York: McGraw-Hill, Inc.
IUPAC commission on atomic weights and
isotopic abundances. 2002. http://www.chem.
qmw.ac.uk/iupac/AtWt/index.html.
140.12
3+
59
140.91
3+
60
144.24
3+
1.1
1.1
1.1
Ce
Pr
Nd
cerium
90
4+
91
231.04
5+, 4+
92
(145)
3+
238.03
6+, 4+
Pm
promethium
93
62
(237)
5+
samarium
94
1.5
1.7
1.3
1.3
Th
Pa
Np
Pu
protactinium uranium
3+, 2+
Sm
1.3
thorium
150.36
1.2
praseodymium neodymium
232.04
61
neptunium
(244)
4+, 6+
plutonium
11
10
12
13
14
15
16
17
18
Key
26
Atomic number
Most stable
ion charges
3+, 2+
1.8
Electronegativity
Fe
Symbol
iron
Name
10.81
2+, 3+
29
63.55
2+, 1+
65.41
2+
12.01
26.98
3+
31
14
2+
69.72
3+
49
114.82
3+
15
32
72.64
4+
33
2+, 1+
81
1+, 3+
82
207.2*
2+, 4+
34
121.76
3+, 5+
52
84
2.0
Pt
Au
Hg
Tl
Pb
Bi
Po
(271)
111
(272)
Ds
54
Xe
83
bismuth
126.90
antimony
3+, 5+
53
iodine
(209)
2+, 4+
902
254
polonium
85
83.80
krypton
Te
1.9
110
tellurium
208.98
bromine
127.60
36
2.6
1.8
lead
2.7
1.8
thallium
79.90
2.1
1.9
mercury
35
Kr
2.4
gold
selenium
2.2
platinum
78.96
39.95
argon
Br
51
4+, 2+
chlorine
Se
50
118.71
sulfur
As
arsenic
tin
204.38
74.92
germanium
Sb
200.59
18
Sn
80
3.0
In
3+, 1+
35.45
2.6
Cd
196.97
17
2.2
Ag
79
Ar
Pd
4+, 2+
32.07
Cl
2.1
195.08
16
phosphorus
2.0
indium
1.8
78
20.18
neon
Si
1.7
cadmium
30.97
fluorine
1.9
silver
oxygen
3.2
2.2
palladium
10
2.6
Ge
112.41
2.2
silicon
gallium
48
19.00
1.9
Ga
1+
nitrogen
28.09
Zn
107.87
Ne
Cu
47
Ni
2+, 3+
16.00
2.0
106.42
carbon
1.8
46
1.7
zinc
14.01
helium
1.9
copper
He
1.9
nickel
4.0
1.6
30
4.00
3.4
aluminium
58.69
3.0
Al
28
Liquids
2.6
13
Non-metallic solids
2.0
boron
* Based on 126 C
Gases
Atomic molar
mass (g/mol)
55.85
Metallic solids
131.29
xenon
(210)
86
(222)
2.2
At
Rn
astatine
radon
* The isotopic mix of naturally occurring lead is more variable than other
elements, preventing precision to greater than tenths of a gram per mole.
Rg
darmstadtium roentgenium
63
151.96
3+, 2+
64
157.25
3+
65
158.93
3+
66
162.50
3+
67
164.93
3+
68
167.26
3+
69
168.93
1.2
1.2
1.2
1.2
1.3
Eu
Gd
Tb
Dy
Ho
Er
Tm
europium
95
(243)
3+, 4+
gadolinium
96
(247)
3+
terbium
97
(247)
3+, 4+
dysprosium
98
(251)
3+
holmium
99
erbium
(252)
3+
100
(257)
3+
101
Am
Cm
Bk
Cf
Es
Fm
Md
curium
berkelium
californium
einsteinium
fermium
70
173.04
3+, 2+
ytterbium
(258)
2+, 3+
102
(259)
2+, 3+
No
71
174.97
3+
1.0
Yb
thulium
americium
3+
mendelevium nobelium
Lu
lutetium
103
(262)
3+
Lr
lawrencium
Chemistry Notation
Symbol
c
Term
Unit(s)
J/(g.C) or J/(g.K)
Ek
kinetic energy
kJ
Ep
potential energy
kJ
enthalpy (heat)
kJ
f H
V or J/C
kJ/mol
current
Kc
equilibrium constant
Ka
Kb
molar mass
mass
amount of substance
mol
pressure
kPa
charge
temperature (absolute)
temperature (Celsius)
time
volume
amount concentration
A or C/s
g/mol
g
mol/L
Symbol
Term
standard
[]
amount concentration
Miscellaneous
25.00 C is equivalent to 298.15 K
Specific Heat Capacities at 298.15 K and 100.000 kPa
cair = 1.01 J/(g.C)
cpolystyrene foam cup = 1.01 J/(g.C)
ccopper = 0.385 J/(g.C)
caluminium = 0.897 J/(g.C)
ciron = 0.449 J/(g.C)
ctin = 0.227 J/(g.C)
cwater = 4.19 J/(g.C)
Water Autoionization Constant (Dissociation Constant)
Kw = 1.0 10 14 at 298.15 K (for ion concentrations in mol/L)
Faraday Constant
F = 9.65 104 C/mol e
Quadratic Formula
2
x = -b ! b - 4ac
2a
Selected SI Prefixes
Exponential
Symbol
Value
tera
1012
giga
109
mega
106
kilo
103
milli
10 3
micro
10 6
nano
10 9
pico
10 12
Prefix
Formula
Al2O3(s)
NH3(g)
NH4Cl(s)
NH4NO3(s)
BaCO3(s)
BaCl2(s)
Ba(OH)2(s)
BaO(s)
BaSO4(s)
C6H6(l)
C4H10(g)
CaCO3(s)
CaCl2(s)
Ca(OH)2(s)
CaO(s)
CaSO4(s)
CO2(g)
CO(g)
Cr2O3(s)
Cu2O(s)
CuO(s)
CuSO4(s)
Cu2S(s)
CuS(s)
N2O4(g)
C2H6(g)
CH3COOH(l)
C2H5OH(l)
C2H4(g)
C2H2(g)
C6H12O6(s)
HBr(g)
HCl(g)
HF(g)
HI(g)
HClO4(l)
H2O2(l)
H2S(g)
FeO(s)
Fe2O3(s)
Fe3O4(s)
PbBr2(s)
PbCl2(s)
PbO(s)
PbO2(s)
MgCO3(s)
MgCl2(s)
4
f H (kJ/mol)
1 675.7
45.9
314.4
365.6
1 213.0
855.0
944.7
548.0
1 473.2
+49.1
125.7
1 207.6
795.4
985.2
634.9
1 434.5
393.5
110.5
1 139.7
168.6
157.3
771.4
79.5
53.1
+11.1
84.0
484.3
277.6
+52.4
+227.4
1 273.3
36.3
92.3
273.3
+26.5
40.6
187.8
20.6
272.0
824.2
1 118.4
278.7
359.4
219.0
277.4
1 095.8
641.3
Formula
Mg(OH)2(s)
MgO(s)
MgSO4(s)
MnO(s)
MnO2(s)
HgO(s)
HgS(s)
CH2O(g)
CH4(g)
HCOOH(l)
CH3OH(l)
NiO(s)
HNO3(l)
NO2(g)
NO(g)
C8H18(l)
C5H12(l)
PCl5(s)
PCl3(l)
PCl3(g)
KBr(s)
KClO3(s)
KCl(s)
KOH(s)
C3H8(g)
SiO2(s)
AgBr(s)
AgCl(s)
AgI(s)
NaBr(s)
NaCl(s)
NaOH(s)
NaI(s)
C12H22O11(s)
SO2(g)
H2SO4(l)
SO3(l)
SO3(g)
SnCl2(s)
SnCl4(l)
SnO(s)
SnO2(s)
H2O(l)
H2O(g)
ZnO(s)
ZnS(s)
5
f H (kJ/mol)
924.5
601.6
1 284.9
385.2
520.0
90.8
58.2
108.6
74.6
425.0
239.2
240.6
174.1
+ 33.2
+ 91.3
250.1
173.5
443.5
319.7
287.0
393.8
397.7
436.5
424.6
103.8
910.7
100.4
127.0
61.8
361.1
411.2
425.8
287.8
2 226.1
296.8
814.0
441.0
395.7
325.1
511.3
280.7
577.6
285.8
241.8
350.5
206.0
Ion
Solubility
greater than
or equal to
0.1mol/L
(very soluble)
NH4+
NO3
ClO3
ClO4
CH3COO
most
most
Cl
Br
I
most
most
IO3
OOCCOO2
OH
Group 1 ions
Group 1 ions
Group 1 ions
NH4+
NH4+
Co(IO3)2
NH4+
Fe2(OOCCOO)3
Li+
Mg2+
Solubility
less than
0.1mol/L
(slightly
soluble)
SO42
CO32
PO43
SO32
RbClO4
Ca2+
CsClO4
Sr2+
AgCH3COO
Ba
Hg2(CH3COO)2
2+
Fe2+
Hg22+
Pb2+
Ca2+
Cu+
Sr2+
Ag+
Ba2+
Hg22+
Ag+
2+
Pb
Tl+
most
most
most
Hg22+
2+
Pb
Ra2+
Note: This solubility table is only a guideline that is established using the Ksp values. A concentration of 0.1mol/L
corresponds to approximately 10g/L to 30g/L depending on molar mass. Hg22+ is a polyatomic ion of mercury.
Symbol
Colour
lithium
Li
red
sodium
Na
yellow
potassium
violet
rubidium
Rb
violet
cesium
Cs
violet
calcium
Ca
yellowish red
strontium
Sr
scarlet red
barium
Ba
yellowish green
copper
Cu
blue to green
boron
yellowish green
lead
Pb
blue-white
Note: The flame test can be used to determine the identity of a metal or a metal ion. Blue to green indicates arange of
colours that might appear.
6
Reduction Half-Reaction
F2(g) + 2 e
PbO2(s) + SO42 (aq) + 4 H+(aq) + 2 e
MnO4 (aq) + 8 H+(aq) + 5 e
Au3+(aq) + 3 e
ClO4 (aq) + 8 H+(aq) + 8 e
Cl2(g) + 2 e
2 HNO2(aq) + 4 H+(aq) + 4 e
Cr2O72(aq) + 14 H+(aq) + 6 e
O2(g) + 4 H+(aq) + 4 e
MnO2(s) + 4 H+(aq) + 2 e
Br2(l) + 2 e
2+
Hg (aq) + 2 e
OCl (aq) + H2O(l) + 2 e
2 NO3 (aq) + 4 H+(aq) + 2 e
Ag+(aq) + e
Fe3+(aq) + e
O2(g) + 2 H+(aq) + 2 e
I2(s) + 2 e
O2(g) + 2 H2O(l) + 4 e
Cu2+(aq) + 2 e
SO42 (aq) + 4 H+(aq) + 2 e
Sn4+(aq) + 2 e
S(s) + 2 H+(aq) + 2 e
AgBr(s) + e
2 H+(aq) + 2 e
Pb2+(aq) + 2 e
Sn2+(aq) + 2 e
AgI(s) + e
Ni2+(aq) + 2 e
Co2+(aq) + 2 e
PbSO4(s) + 2 e
Se(s) + 2 H+(aq) + 2 e
Cd2+(aq) + 2 e
Cr3+(aq) + e
Fe2+(aq) + 2 e
2 F (aq)...................................................... +2.87
PbSO4(s) + 2 H2O(l) . ............................... +1.69
Mn2+(aq) + 4 H2O(l) ................................ +1.51
Au(s) ........................................................... +1.50
Cl (aq) + 4 H2O(l) . .................................. +1.39
2 Cl (aq) ..................................................... +1.36
N2O(g) + 3 H2O(l) . .................................. +1.30
2 Cr3+(aq) + 7 H2O(l) ............................... +1.23
2 H2O(l) . .................................................... +1.23
Mn2+(aq) + 2 H2O(l) ................................ +1.22
2 Br (aq) ..................................................... +1.07
Hg(l) ........................................................... + 0.85
Cl (aq) + 2 OH (aq) ................................. + 0.84
N2O4(g) + 2 H2O(l) .................................. + 0.80
Ag(s) ........................................................... + 0.80
Fe2+(aq) ...................................................... + 0.77
H2O2(l) ....................................................... + 0.70
2 I (aq) ....................................................... + 0.54
4 OH (aq) ................................................... + 0.40
Cu(s) ........................................................... + 0.34
H2SO3(aq) + H2O(l) ................................. + 0.17
Sn2+(aq) . .................................................... + 0.15
H2S(aq) . ..................................................... + 0.14
Ag(s) + Br (aq) ......................................... + 0.07
H2(g) .......................................................... 0.00
Pb(s) ........................................................... 0.13
Sn(s) . .......................................................... 0.14
Ag(s) + I (aq) ........................................... 0.15
Ni(s) . .......................................................... 0.26
Co(s) ........................................................... 0.28
Pb(s) + SO42 (aq) ..................................... 0.36
H2Se(aq) . ................................................... 0.40
Cd(s) .......................................................... 0.40
Cr2+(aq) ...................................................... 0.41
Fe(s) . .......................................................... 0.45
NO(g) + 2 OH (aq) .................................. 0.46
2 Ag(s) + S2(aq) ...................................... 0.69
Zn(s) ........................................................... 0.76
H2(g) + 2OH (aq) .................................... 0.83
Cr(s) . .......................................................... 0.91
Se2(aq) ...................................................... 0.92
SO32(aq) + 2OH (aq) ............................. 0.93
Al(s) . .......................................................... 1.66
Mg(s) .......................................................... 2.37
Na(s) ........................................................... 2.71
Ca(s) ........................................................... 2.87
Ba(s) ........................................................... 2.91
K(s) ............................................................. 2.93
Li(s)............................................................. 3.04
*For 1.0 mol/L solutions at 298.15 K (25.00 C) and a pressure of 101.325 kPa
very large
very large
HSO4 (aq)
NO3(aq)
H2O(l)
HSO3(aq)
SO42(aq)
H2SO4(aq)
HNO3(aq)
H3O+(aq)
HOOCCOOH(aq)
H2SO3(aq)
HSO4 (aq)
hydronium ion
oxalic acid
sulfurous acid
aqueous hydrogen sulfite
7.4 10 4
6.3 10 4
5.6 10 4
1.8 10 4
C3H5O(COOH)2COO (aq)
F(aq)
NO2(aq)
HCOO (aq)
OOCCOO2(aq)
C3H5O(COOH)3(aq)
HF(aq)
HNO2(aq)
HCOOH(aq)
HOOCCOO (aq)
1.4 10 4
9.1 10 5
C2H5OCOO (aq)
HC6H6O6 (aq)
1.5 10 4
6.9 10 3
H2PO4 (aq)
1.0 10 2
1.4 10 2
5.6 10 2
H3PO4(aq)
lactic acid
C2H5OCOOH(aq)
2-hydroxypropanoic acid
ascorbic acid
H C H O (aq)
2(1,2-dihydroxyethyl)-4,5-dihydroxy-furan-3-one 2 6 6 6
phosphoric acid
aqueous hydrogen phosphate
citric acid
2-hydroxy-1,2,3-propanetricarboxylic acid
hydrofluoric acid
aqueous hydrogen fluoride
nitrous acid
aqueous hydrogen nitrite
formic acid
methanoic acid
very large
Cl(aq)
HCl(aq)
HOOCCOO (aq)
very large
Br(aq)
HBr(aq)
very large
I (aq)
HI(aq)
Ka
very large
Acid Formula
HClO4(aq)
perchloric acid
aqueous hydrogen perchlorate
hydroiodic acid
aqueous hydrogen iodide
hydrobromic acid
aqueous hydrogen bromide
hydrochloric acid
aqueous hydrogen chloride
sulfuric acid
aqueous hydrogen sulfate
nitric acid
aqueous hydrogen nitrate
Common Name
IUPAC / Systematic Name
1.7 10 5
1.5 10 5
1.3 10 5
C3H5OCOOH(COO)22(aq)
C3H7COO (aq)
C2H5COO (aq)
HCO3(aq)
C3H5O(COO)33(aq)
HS(aq)
SO32(aq)
HPO42(aq)
C3H5O(COOH)2COO (aq)
C3H7COOH(aq)
C2H5COOH(aq)
H2CO3(aq)
C3H5OCOOH(COO)22(aq)
H2S(aq)
HSO3(aq)
H2PO4 (aq)
butanoic acid
propanoic acid
hydrosulfuric acid
aqueous hydrogen sulfide
6.2 10 10
4.8 10 13
1.0 10 14
CN(aq)
NH3(aq)
CO32(aq)
C6H6O62(aq)
PO43(aq)
OH (aq)
HCN(aq)
NH4+(aq)
HCO3(aq)
HC6H6O6 (aq)
HPO42(aq)
H2O(l)
ammonium ion
water
Note: An approximation may be used instead of the quadratic formula when the concentration of H3O+ produced is less than 5% of the original acid
concentration (or the concentration of the acid is 1000 times greater than the Ka). An approximation can also be used for weak bases. The formulas
of the carboxylic acids have been written so that the COOH group can be easily recognized. Either the common or IUPAC name is acceptable.
2.0 10 12
4.7 10 11
5.6 10 10
4.0 10 8
OCl(aq)
6.2 10 8
6.3 10 8
8.9 10 8
4.0 10 7
HOCl(aq)
hypochlorous acid
aqueous hydrogen hypochlorite
hydrocyanic acid
aqueous hydrogen cyanide
1.8 10 5
CH3COO (aq)
CH3COOH(aq)
4.5 10 7
6.3 10 5
C6H5COO (aq)
C6H5COOH(aq)
benzoic acid
benzenecarboxylic acid
acetic acid
ethanoic acid
Colour Change as
pH Increases
Ka
HMv(aq) / Mv(aq)
0.0 1.6
yellow to blue
~2 10 1
H2Cr(aq) / HCr(aq)
0.0 1.0
7.0 8.8
red to yellow
yellow to red
~3 10 1
3.5 10 9
1.2 2.8
8.0 9.6
red to yellow
yellow to blue
2.2 10 2
6.3 10 10
orange IV
HOr(aq) / Or(aq)
1.4 2.8
red to yellow
~1 10 2
methyl orange
HMo(aq) / Mo (aq)
3.2 4.4
red to yellow
3.5 10 4
bromocresol green
HBg(aq) / Bg(aq)
3.8 5.4
yellow to blue
1.3 10 5
methyl red
HMr(aq) / Mr(aq)
4.8 6.0
red to yellow
1.0 10 5
chlorophenol red
HCh(aq) / Ch(aq)
5.2 6.8
yellow to red
5.6 10 7
bromothymol blue
HBb(aq) / Bb (aq)
6.0 7.6
yellow to blue
5.0 10 8
phenol red
HPr(aq) / Pr(aq)
6.6 8.0
yellow to red
1.0 10 8
phenolphthalein
HPh(aq) / Ph(aq)
8.2 10.0
colourless to pink
3.2 10 10
thymolphthalein
HTh(aq) / Th(aq)
9.4 10.6
colourless to blue
1.0 10 10
alizarin yellow R
HAy(aq) / Ay(aq)
10.1 12.0
yellow to red
6.9 10 12
indigo carmine
HIc(aq) / Ic(aq)
11.4 13.0
blue to yellow
~6 10 12
1,3,5trinitrobenzene
HNb(aq) / Nb (aq)
12.0 14.0
colourless
to orange
~1 10 13
Indicator
methyl violet
cresol red
thymol blue
Suggested
Abbreviations
HCr(aq) / Cr2(aq)
H2Tb(aq) / HTb (aq)
10
1.0 mol/L
0.010 mol/L
chromate
yellow
pale yellow
chromium(III)
blue-green
green
chromium(II)
dark blue
pale blue
cobalt(II)
red
pink
copper(I)
blue-green
pale blue-green
copper(II)
blue
pale blue
dichromate
orange
pale orange
iron(II)
lime green
colourless
iron(III)
orange-yellow
pale yellow
manganese(II)
pale pink
colourless
nickel(II)
blue-green
pale blue-green
permanganate
deep purple
purple-pink
11
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