AP Chemistry Chapter 4 Test: Aqueous Reactions and solution Stoichiometry Multiple Choice: select the best possible answer

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1) O f the compounds below, only _________ is not an electrolyte. a. HCl b. Rb2SO4 c. Ar d. KOH e. NaCl 2) All weak electrolytes are____. a. salts b. acids c. bases d. molecular e. ionic 3) What are the spectator ions in the reaction between KOH(aq) and HNO3 (aq)? a. K+ and H+ b. H+ and OH+ c. K+ and NO3d. H+ and NO3e. OH- only 4) Ca(OH)2 is a a. strong base b. weak base c. strong acid d. weak acid e. binary compound 5) The net ionic equation for formation of an aqueous solution of Al(NO3)3 via mixing solid Al(OH)3 and aqueous nitric acid is_________. a. Al(OH)3(s) + 3HNO3 (aq) 3H2O (l) + Al(NO3)3(aq) b. Al(OH)3(s) + 3NO3- (aq) 3OH-(aq) + Al(NO3)3(aq) c. Al(OH)3(s) + 3NO3- (aq) 3OH-(aq) + Al(NO3)3(s) d. Al(OH)3(s) + 3H+(aq) 3H2O (l) + Al3+ (aq) e. Al(OH)3(s) + 3HNO3 (aq) 3H2O (l) + Al3+ (aq) + NO3-(aq) 6) One method of removal of metal ions from a solution is to convert the metal to its elemental form so it can be filtered out as a solid. Which metal can be used to remove aluminum ions from solution? a. zinc b. cobalt c. lead

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d. copper e. nickel f. none of these Of the following elements, ____________ is the most easily oxidized. a. oxygen b. fluorine c. nitrogen d. aluminum e. gold Which of the following is the correct expression for molarity? a. mol solute/L solvent b. mol solute/mL solvent c. mmol solute/mL solution d. mol solute/kg solvent e. mol solute/L solution How many grams of CH3OH must be added to water to prepare a50 mL of a solution that is 2.0 MCH3OH ? a. 9.6 X 103 b. 4.3 X 102 c. 2.4 d. 9.6 e. 4.3 What volume (mL) of 7.48 X 10-2 M phosphoric acid can be neutralized with 115 mL of 0.244 M sodium hydroxide? a. 125 b. 375 c. 750 d. 188 e. 75.0 Oxalic acid is a diprotic acid. Calculate the percent of oxalic acid (H2C2O4) in a solid given that a 0.7984 g sample of that solid required 37.98 mL of 0.2283 M NaOH for neutralization. a. 48.89 b. 97.78 c. 28.59 d. 1.086 e. 22.83

Part 2: Show all work for the following questions on separate paper. 1) Classify each of the following aqueous solutions as a nonelectrolyte, weak electrolyte, or a strong electrolyte in water: (a) HBrO (b) HNO3 (c) KOH (d) CoSO4 (e) sucrose, C6H12O6 (f) O2 2) Write a balanced molecular equation and a net ionic equation for the reaction that occurs when solid iron(II) sulfide reacts with an aqueous solution of hydrobromic acid. 3) Determine the oxidation number for the indicated element in each of the following compounds: (a) Co in CoCl2 (b) Ga in Ga(OH)3; (c) P in HPO42-; (d) C in C2O424) How many moles of KMnO4 are present in 75.0 mL of a 0.0850 M solution? 5) Glycerol, C3H8O3, is a substance used extensively in the manufacture of cosmetics, foodstuffs, antifreeze, and plastics. Glycerol is a water-soluble liquid with a density of 1.2656 g/mL at 15C. Calculate the molarity of a solution of glycerol made by dissolving 40.000 mL glycerol at 15C in enough water to make 250.00 mL of solution. 6) Tartaric acid, H2C4H4O6, has two acidic hydrogens. The acid is often present in wines and precipitates from solutions as the wine ages. A solution containing an unknown concentration of the acid is titrated with NaOH. It requires 22.62 mL of 0.2000 M NaOH solution to titrate both acidic protons in 40.00 mL of the tartaric acid solution. Write a balanced net ionic equation for the neutralization reaction, and calculate the molarity of the tartaric acid solution.