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Cálculos calorimetria

Cálculos calorimetria

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Publicado porJose Mendoza Ciacks

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Published by: Jose Mendoza Ciacks on Mar 23, 2012
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05/03/2013

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Cálculos

Capacidad calorífica del calorímetro
Calculando m
1

Ρ= m/v m
1
= Ρv v= 250 ml Ρ=.9958 g/ml T= 298 K
m
1
= (250 ml) (.9958 g/ml)= 248.95 g

Calculando m
2

Ρ= m/v m
2
= Ρv v= 100 ml Ρ=.9906 g/ml T= 318 K
m
1
= (100 ml) (.9906 g/ml)= 99.96 g

Fórmula para calcular la capacidad calorífica del calorímetro
Cp
H2O
= 4.174 J/g K m
1
= 99.96 g m
2
= 248.95 g T
1
= 297 K T
2
= 318 K T
3
= 304 K
Cp
H2O
m
2
(T
2
-T
3
) = (C + Cp
H2O
m
1
) (T
3
-T
1
)
C = [Cp
H2O
m
2
(T
2
-T
3
) - Cp
H2O
m
1
(T
3
-T
1
)] / (T
3
-T
1
)
C = [4.174 J/g K * 248.95 g (318 K - 304 K] - 4.174 J/g K * 99.96 g (304 K - 297 K)] / (304 K - 297 K)
C = -770.9 J/K










Calculando Cp para la solución problema
Calculando m
1

Ρ= m/v m
1
= Ρv v= 250 ml Ρ=.9958 g/ml T= 298 K
m
1
= (250 ml) (.9958 g/ml)= 248.95 g

Calculando m
3

Ρ= m/v m
3
= Ρv v= 125 ml Ρ=1.013 g/ml T= 327 K
m
1
= (125 ml) (1.013 g/ml)= 126.625 g

Fórmula para calcular la capacidad calorífica del calorímetro
Cp
H2O
= 4.174 J/g K m
1
= 248.95 g m
3
= 126.625 g T
1
= 297 K T
4
= 327 K T
5
= 307 K
C = -770.9 J/K
Calculando Cp de solución problema
Cp = [(C + Cp
H2O
m
1
) (T
5
-T
1
)]/ m
3
(T
4
-T
5
)
Cp = -770.9 J/K + 4.174 J/g K * 248.95 g (307 K – 297 K) / 126.625 g (327 K – 297 K)
Cp = 2.118 J / g K


9 J/K + 4.625 g T1= 297 K T4 = 327 K T5 = 307 K .95 g Calculando m3 Ρ= m/v m3= Ρv v= 125 ml Ρ=1.9958 g/ml)= 248.625 g Fórmula para calcular la capacidad calorífica del calorímetro CpH2O = 4.118 J / g K m1 = 248.013 g/ml)= 126.9958 g/ml T= 298 K m1 = (250 ml) (.9 J/K Calculando Cp de solución problema Cp = [(C + CpH2O m1) (T5-T1)]/ m3 (T4-T5) Cp = -770.625 g (327 K – 297 K) Cp = 2.95 g (307 K – 297 K) / 126.174 J/g K * 248.95 g m3 = 126.174 J/g K C = -770.Calculando Cp para la solución problema Calculando m1 Ρ= m/v m1= Ρv v= 250 ml Ρ=.013 g/ml T= 327 K m1 = (125 ml) (1.

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