Determinacin del Orden de la Reaccin a travs del Mtodo de Integracin

Reaccin General: A ==> productos

Ley de Velocidad de Reaccin:

time (seg) Concentration [M] Average rate (M/s)

[A] (M)
Veloc. V (M/s)
50
0.1
0.00019
100
0.0905
0.00017
150
0.082
0.00016
200
0.0741
0.00014
300
0.0671
0.000122
400
0.0549
0.000101
500
0.0448
0.00008
800
0.0368
0.000056

ln [A] = X
-2.302585
-2.402405
-2.501036
-2.60234
-2.701571
-2.902242
-3.105547
-3.302257

1.9
1.7
1.6
1.4
1.22
1.01
0.8
0.56

-4

-3

-2

-1

Ln V

10000

ln V = Y
-8.568486
-8.679712
-8.740337
-8.873868
-9.01149
-9.20039
-9.433484
-9.790159

y = 1.1832x - 5.81
R = 0.9894
Ln [A]

-8.4
-8.6
-8.8
-9
-9.2
-9.4
-9.6
-9.8
-10

Mtodo de Integracin
V = K [ A ]n

(1)

Ln V = Ln K + n Ln [ A ]
Y = a + b*X
donde: Y = Ln V
a = factor de posicin = Ln K
b = pendiente = n
X = Ln [A]

-8.4
-8.6 0
-8.8
-9
-9.2
-9.4
-9.6
-9.8
-10

Linealizando esta ecuacin se obtiene que:

(2)

DETERMINACION DE ORDEN DE REACCION POR METODO DE INTEGRACIO

ZnS(s) + O2(g) ==> ZnO(s) + SO2(g)
tiempo (seg) C (mol/L) /\ C
/\ t
195
0.0162
604
0.0147
-0.0015
1246
0.0129
-0.0018
2180
0.0110
-0.0019
4140
0.0089
-0.0021
4655
0.0080
-0.0009
6210
0.0068
-0.0012
8135
0.0057
-0.0011

409
642
934
1960
515
1555
1925

ln (C O2) = X ln (-dC/dt) = Y
-4.12274404
-4.21990779 -12.5160053
-4.35052797 -12.7845569
-4.50986001 -13.1053778
-4.721704 -13.7465177
-4.82831374 -13.2572827
-4.99083267 -14.0746645
-5.1672891 -14.3751263

-12
-6
Ln V

DATOS:

-4

-2

-12.5 0
-13

y = 1.8922x - 4.5454
R = 0.9061

-13.5
-14
-14.5

Ln [C O2]

METODO DE INTEGRACION
V = K [ A ]n

(1)

Ln V = Ln K + n Ln [ A ]
pero V = -d[C O2]/dt

(2)

donde V = velocidad de reaccin

Ln [-d( C O2/dt)] = Ln K + n Ln [ A ]

(3)

DETERMINACION DE ORDEN DE REACCION POR METODO DE INTEGRACIO

ZnS(s) + O2(g) ==> ZnO(s) + SO2(g)

R=

T (K)
k (1/seg)
338 4.87E-03
328 1.50E-03
318 4.98E-04
308 1.35E-04
298 3.46E-05
273 7.87E-07

1/T = X

Ln k = Y

0.00295858 -5.32466134
0.00304878
0.003144654
0.003246753
0.003355705
0.003663004

-6.50229017
-7.60491048
-8.91023578
-10.2716569
-14.0550376

1.99 cal/(K -1 mol-1)

8,314 J/(K-1 mol -1)

Ln k

DATOS:

0
-2 0
-4
-6
-8
-10
-12
-14
-16

y=

OR METODO DE INTEGRACION
k = Ae[-Eact/(R*T)]

Ecuacin de Arrhenius

ln k = ln A - (Eact/R) * (1/T)

Ecuacin de Arrhenius linealizada

Y = a + b*X

Pendiente =
-12376 (- Eact/R)
entonces => Energa de activacin =
24628.24 cal/mol

0.002

y = -12376x + 31.273
R = 0.9999

1/T

0.004