Documentos de Académico
Documentos de Profesional
Documentos de Cultura
Classification - I
b) Chocolate (same)
c) Non - Chocolate Confectionary product
i) hard candy
ii) chewy candy (including granola bar)
iii)soft candy
iv) iced/coated candy
v) Panned
vi)licorice type
d) gum based
Chewing gum, bubble gum
i) containing sugar
ii) not containing sugar
Sugar Confectionary
Traditionally in India confectionary has meant barfi, chikki and the like which are available
in the un ordanized sector but in market, confectionary means Western Confectionary
which was introduced in India through Traders from the west through the Silk Route and
through invaders from west including the British. Sugar confectionary fundamentally is a
solution of sugar and liquid flucose cooked with desired consistency followed by addition
of colors, flavors and optional ingredient based on desired product type. it can be a hard
boiled confectionary or may be toffee or it could be an eclair or lozenges and so on. It
might be interesting to note that conady word used to refers to confectionary product
derived from Arabic word ʻQandeʼ which means sugar confectionary.
Confectionary Composition
Essential ingredients are like water, sugar, liquid glucose and optional ingredients provide
value addition to confectionary product rendering them a richer, a premium status in terms
of appearance, taste, mouth feel.
Sensory Analysis
Color, flavor, after taste, use of optional ingredients are all governed by the Indian Food
Law. The PFA Act 1954. Hence one needs to thoroughly verify legal compliance before
choosing ingredients. Needless to mention all the ingredients used in our products have
total legal compliance.
There are variety of optional ingredients that could be used in confectionary product
dependency on the product type.
The following are some of the key optional ingredients used -
i) Milk and Milk Products - Butter, Cream
ii) Fats & Oils - Milk fat, Vanaspati, and other kinds of vegetable oil depending on product
category, richness required of the product
iii)Flavor - Probably most important from the point of view of product quality and oral
gratification. The flavor could be natural or nature identical or synthetic
iv)Color - From an aesthetic component of product, the colors are added to associate a
product to a particular flavor. eg in an orange flavored candy we add orange color and
so on.
v) Acidulants - Food acids like citric acid, malic acid etc which are used to give tangy or
sourness to the product. These are mainly used for fruit flavored candies like orange,
lemon flavor etc.
vi)Emulsifiers - Special fats used in fat based formulation to facilitate uniform mixing of fat
with water base. Thereby insuring where a uniform distribution in final product.
vii)Buffer agents - Used in acid base formulations to guard against sugar acid level which
would cause inversion or break down of sugar which cause stickiness of sugar.
Raw Materials
Sugar is one of the essential ingredients in any type of confectionary product. Functionally
sugar acts as sweetening or bulking agent. In India, the sugar generally comes from sugar
cane. Crushing the ripe sugar cane and extracting itʼs juice to manufacture the sugar. The
juice is then bleached used SO2, concentrated into a viscous liquid and finally the sugar
crystallization is by centrifugation. The most important parameter in the level of bleaching
which determines the whiteness of sugar and thereby product quality. The commercial
sources of sweet beverage or confectionary depends greatly on uniformity texture and
distinctive taste and then depends greatly on the sweetening agent. The presence of
certain non-sugar solids in trace amounts can completely make certain beverage or
confectionary. For this reason the beverage flavors and confectionary industry demands a
truly natural sweetener which is available in most perfect form as highly standardized liquid
sugar.
1. Dry sugar
2. Invert Sugar
3. Liquid Sugar
4. Sucrose / Fructose
5. Mishri
6. Khandsari
7. Bura Sugar
8. Refined Sugar
9. Beet Sugar
Fructose - 173
Invert Sugar - 130
Glucose - 74
Sorbitol - 60
Mannitol - 50
Xylose - 40
Mallose - 32
Galactose - 32
Rafinose - 23
Lactose - 16
The most important ingredient is liquid glucose which is called the heart of confectionary
because there can be no sugar confectionary without Glucose. Functionally, liquid glucose
acts as a doctoring agent meaning it binds and holds the sugar and prevents in
transforming by recrystallization during cooking. It is commonly derived from tapioca or
maize starch. The process involves the crushing or slurring of tapioca ships with water and
extracting the milk. The starch milk is then digested (either enzymatically, or acid
digestion) bleached, desalted, concentrated to a viscous mass which is liquid glucose.
Sucrose
Made from sugar cane or sugar beat, sugar is one product that is 89.9% pure . It has no
vitamins, no minerals and no undesirable ingredients and no impurities. Pure sucrose,
carbohydrate energy. There are very fine, fine, superfine, extra fine, light brown, medium
brown and dark brown, free flowing brown and soft brown sugars. There are confectioners
sugars, hastess tablets, crystal tablets and dots and there are totally organix raw sugar. All
white granulated sugar are almost identical. it is a highly refined product with no flavors
except sweetness. it has about 180 cal/teaspoon and no nutritive quality. Sweetness of
granulated sugar due to crystal size and method of processing which means larger the
crystal, purer the sugar. The brown sugar is white sugar with molasses added. In
conventional type whether they are light, medium, dark brown, soft and moist. They have
same sweetening power as white sugar. But they have definite flavors that is desirable
with some grains. Although many people think brown sugar is more nutritious than white. It
has same nutritional value and it has undergone the same degree of refining.
Sucrose is a di sacchride sugar and is one of the most important ingredients. Probably the
least understood about itʼs many properties and reactions. Sucrose is practically never
used alone but in combination with other ingredients with which it may react. Sucrose is
inherently acidic in nature. This is enhanced at high temperatures. It is highly unbuffered.
Only trace amounts of ash is present. Presence of trace natural salts such as NaCl, Mg,
K2HPO4 tend to increase inversion. Alkaline salts such as NaHCO3, NaKCO3 minimize
inversion but increase color while nitrogen compounds (ammonia salts, amino acids,
amides) increase both inversion and color. The latter through the mallard browning
reaction. Further more the alkaline salts, sodium carbonate, NaHCO3 cause a browning
reaction, apparently through the composition of reducing sugar form and MgCl results in
increasing inversion. Sucrose is non-reducing and doesnʼt form color unless inversion
takes place. Forming the chemically reactive mono sacchrides, dextrose and fructose. The
latter being more reactive and heat sensitive. This applies to reaction in solution and
thermal decomposition on reactions to high temperature. When sucrose is dissolved in
water, several effects occur. The most important of them are :-
1. Increase in viscosity
2. elevation in boiling point
3. increased osmotic pressure
4. heat of solution
and all of these affects the products.
Browning - Fructose being a reducing sugar will develop brown pigments on heating and
it is very active in mallard reactions with milk protein. This is a factor that affects flavor
intensity in caramel.
The relative sweetness of sugar and other sweetening agent may differ according to the
method of measurement. The presence of other materials, the salt may increase or
decrease the apparent sweetness depending on the concentration and type of food and
drink tested.
Cane or beet is a compound of two simple sugars, glucose and fructose. Glucose also
called dextrose is the principle component of starch and corn syrup. It is glucose which is
abnormally metabolized by person suffering from diabetes. Fructose however requires no
insulin for itʼs metabolism and diabetics can use it in an internally normally (essentially)
normal manner. 50-80 g are tolerated by diabetic. Fructose is used in medicine as a
course of quick energy and as in metabolic stimulant for variety of diseases and for
abnormal conditions. Fructose is not an additive not a drug. It is food.
Fructose has a sparing effect on protein and it increases the rate of metabolism of alcohol
and has been used to treat severe alcoholism. Fructose has been recommended as a
rapid source of energy to athletes as means of combating fatigue. Since the principle
source of fructose is derived by fermentations, oxygen of glucose, part of invert sugar,
fructose and sodium gluconate are readily available intermediates in combination.
Fortunately, both components of this mixture increase the sweetness and decreases the
objectionable after taste of saccharin making the combination very suited to artificial
sweetened product or low calorie product. An increase of at least 35% of sweetness of
saccaharine has been reported when it i s used with fructose and gluconate mixture. A
combination of 0.01 gm of saccharine and 1.0 g fructose will produce the sweetness level
of 7 sucrose in 1/7Th bulb and has only 1/7th calorie. This assumes saccharin is 500 times
sweeter than sugar. The sweeteners ratio is variously given 300-700 times greater.
Combination of fructose and gluconate with or without saccharine should be applicable to
soft drink formulation because this can produce sweetness, buffering power and acidity
decreases and calories often at less cost.The combination is also applicable inexpensive
sweeteners with legal medical advantage also.
High fructose corn syrup (HFCS) containing 42% fructose, 51 % dextrose and having a
sweetness = to that of sucrose. Sweeter than dextrose and slightly less sweeter than
medium invert sugar. it is produced from dextrose by enzymatisation is less color stable
then most syrup and has a synthetic effect on synthetic sweeteners such as saccharine
HFCSis sweeter than a comparable solution of sucrose when both contain the same
amount of sodium saccharine. HFCS can be used in practically every food in which liquid
sucrose or medium or totally inverse sugar is highly employed HFCS is have been
commercially utilized in confectionary and carbonate beverages, fountain syrup and
caramel food. HFCS is worked to about 5-6& more in solids than in a liquid. So it has a
higher osmotic pressure.
Honey
means the food derived entirely from the work of bees operating upon the nectar of flowers
and other sweet exudation of plants. It shall not contain more than 25 % of moisture, 0.5 %
ash and 5 % sucrose except in the case of Carbia Callosa and honey dew where it shall
be 60 % Fructose to Glucose ratio shall be 10 % The minimum reducing sugar content
(expressed as invert sugar) shall be 65 % except in the case of Callosa and honey dew
where it shall be 60 % Glucose to fructose ratio shall not be less than 0.95 %
Cube Sugar
Means the sugar in the form of cube or cuboid blocks. Manufactured from refined
crystalized sugar. It shall be white in color, free from dirt and other extraneous
contamination. It shall conform to the following standards : -
Dextrose - It is a white or light cream granular powder. Odorless and having a sweet taste.
When heated with potassium Cupric Tartarate (when Fehlingʼs A and B are put in sugar,
we get this) it shall produce a precipitate of cuprous oxide. It shall conform to the following
standards : -
Golden syrup - It is the syrup obtained by the inversion of sugar. It shall be golden yellow
in color. Pleasant in taste and free from any crystallization. It shall conform to the following
standards : -
Moisture - not more than 25 % by weight
Total Ash - not more than 2.5 % by weight
Total sugar as invert sugar - not less than 72 % by weight
SO2 - shall not exceed 70ppm
Sodium bi carbonate used for clarification purpose shall be of Food Grade quality.
Sorbitol - It is a polyhydric alcohol and is widely distributed in nature. Sources - Mountain
ash berry and produced by chemical reduction of glucose. Sorbitol is a valuable substance
in the manufacture of diabetic chocolates and confectionary because unlike some intense
sweeteners it has bulk as well as sweetness. It is available commercially in crystalline and
syrup form. The crystalline is used for chocolate manufacture. The liquid form is used in
various forms including confectionary as a softener and it will help to prevent drying out. It
is used in the manufacture of sugar less confectionary and chewing gum.
Sorbitol is polymorphic and exist in three crystalline states. Only one form ie Gamma form
is stable. The other unstable forms under the influence of moisture or heat transform into
the stable form.
Equilibrium Relative Humidity - Sorbitol syrup because of itʼs viscosity has an effect in
some formulations of retarding crystallization. In such cases it would convey extra
humictant properties to the confections as well as softening the texture. Manufacturers of
sorbitol publish data on the ERH of solutions of different strength but when used in any
ingredient with humictant properties, it is necessary to examine itʼs effect in the finished
product and this apply to sorbitol. Sorbitol has a marked cooling effect when taken into
solution and also has a high solubility.
Optional Ingredient
Milk Products :-
Milk can be in the form of condensed milk, skimmed milk, whole milk powder, butter, ghee
etc they are added to impart richness, body and natural caramel flavor to the
confectionary. When milk products are added, protein and sugar in the milk solids react
with each other and leaves a smooth feeling in the mouth. You will notice that most of
confectionary products contain milk butter. These have a dwell role of providing rich
buttery taste flavor and smooth mouth feel to the product. There are other options like
hydrogenated vegetable oil, which is commonly used in confectionary. There is palm
kernel oil which is imported and used. Fats usually added to improve the body and
smoothness of the product.
Acidulant - It could be citric acid, malleic acid of fumaric acid. The main function of the
acidulants is to give tanginess to the fruit flavored product.
Flavors - Flavors are very important ingredients in confectionary products as they act as a
key differentiator of product. The prefix orange candy or mango candy is based on the
flavor used. It is very important that the flavor is stable throughout the shelf life of the
product. There are three types of flavors -
1. Natural oils like ginger oil or eucalyptus oil. These are extracted directly from the natural
raw materials.
2. Nature identical - these are flavors which are available naturally but can also obtained
from other natural sources. For example vanillin which is obtained from vanillin plant.
This can also be extracted from cellulose present in paper.
3. Synthetic flavor - These are combinations of chemicals such as esters and aldehydes
which have characteristic odor of different fruits and other flavor notes in sugar will alter
not only the flavor but color, consistency and stability of a beverage.
Advantage of using liquid sugar : -
1. Liquid sugar can be unloaded from the delivery truck or car and moved from the storage
tanks to the syrup room with minimum labour requirement.
2. Since the liquid syrup is in solution, the time required for making syrup is reduced.
3. The quality of bottle grade liquid sugar is equal to the quality of bottle grade dry sugar.
4. Due to the elimination of bags and cost of packaging, liquid sugar is usually lower in
price than dry sugar.
Ammonium Saccharin
Calcium Cyclohexyl Sulfamate
Calcium Saccharin
Magnesium Cyclohexyl Sulfamate
Potassium Cyclohexyl Sulfamate
Saccharin
Sodium Cyclohexyl Sulfamate
Sodium Saccharin
Plantation White Sugar (commonly known as sugar means the crystallized product
obtained from sugar cane or sugar beet. It should be free from dirt, filth and iron fillings
and added coloring matter. Extraneous matter if present shouldnʼt exceed 0.1 % by weight.
It should also conform to the following standards : -
a) Moisture (when heated at 105 + - 1 degree celsius) Not more than 0.5 % by
weight
b) Sucrose content Not less than 98 % by weight
c) Ash content ! Not more 0.01%!
d)(So2 shall not exceed 70 ppm)
! ! ! ! ! ! ! # # # # ! ! !
! ! ! !
Refined sugar means white crystalline sugar obtained by refining Plantation Wide Sugar
which has been free from dirt, filth and iron fillings and added coloring matter.
Extraneous matter shall not exceed 0.1% by weight. It shall also conform to the following
standards : -
a) Moisture (when heated at 105 + - 1 degree celsius for three hours) Not more than
0.5% by weight
b) Sucrose Not less than 99.5 % by weight
c) Ash content not more than 0.01 %
Khandsari Sugar (obtained from sugarcane juice by open pan process. May be of varieties
namely - Khandsari Desi and Khandsari Sugar (sulfur) also known as Sulfur Sugar. It may
be crystalline or in powder form. It shall be free from dirt, filth, iron fillings and added
coloring matter. Extraneous matter shouldnʼt exceed 0.25 % by weight. It may contain
Sodium Bi Carbonate (good grade). It shall also conform to the following standards : -
! !
Khandsari Sugar can be distinguished from Plantation White Sugar on the following
characteristics : -
# # # # # Khandsari # # # # # # PWS #
Bura Sugar means fine grained sugar made out any kind of sugar. It is free from dirt, filth,
iron fillings and added coloring matter. It shall also conform to the following standards : -
2) Modified Toffee are similar to plain toffee in terms of processing and softness. The
only differentiator is that it contains additionally certain value added ingredients than
plain toffee. They may contain certain premium ingredients like Chocolate, coffee,
cocoa, fruits and nuts. But for these additional ingredients, they are similar to the plain
toffee. e.g. Parryʼs Coffee Bite, Candyman Eclairs .
Milk Toffee are similar to modified toffee, the only difference being that they are particularly
rich in milk solids. The PFA prescribes a minimum level of milk ingredients. Milk Toffee
must contain a minimum of 4 % milk fat, 3 % protein and 3.5 % Lactose. As you probably
know, universally Lactose is found in milk. Hence a minimum level of lactose prescription
ensures a minimum level of milk solids in the product. Currently there are no products
available in this segment. THe fact is that there some products which can fall under this
category, but no one is using this nomenclature perhaps because it is very difficult to
establish whether the product does have 3.5 % lactose or not since lactose tends to
convert to lactic acid on storage.
Butter toffee are also similar modified toffee, the only additional requirement is that it
should contain a minimum of 4 % butter fat. e.g. candyman Butterscotch, orange
Cream Licks.
Other types that are commonly available int he market are bubble gums and chewing
gums. These are different from the other categories as these contain natural or synthetic
latex, commonly known as rubber, which gives the product chewy and bubbling properties.
Bubble gums usually contain synthetic latex which is both chewy and bubble forming while
the chewing gums contain natural latex which are only chewy without bubble forming
properties.
22.02.10
Class ## # # # # Color
Azo Colors
Tartazine # # # # # Yellow
Sunset Yellow FCF# # # Orange
Ponceau 4R# # # # # Red
Red 2G# # # # # Red
Azorubine# # # # # Red
Amarnanth# # # # # Red
Brilliant Black BN# # # # Purple and Black
Brown FK# # # # # Yellow Brown
Brown HT# # # # # Brown
Allura Red AC # # # # Red and Yellow
Fast Red E# # # # # Red
Natural Colors Classification
Apart from chemical action the intensity of a color is affected by the physical condition of
the confectionary. A color that appears quite bright in a straight fondant (a type of
confectionary product) will lose a lot of itʼs brilliance when whipped up to occlude air. The
presence of solids such as fine sugars, starches or titanium dioxide also has a deadening
effect on an added color. Jellies or Turkish delight present a completely altered
appearance when a chocolate covered unit is carved or beaten exposing the color center.
With the uncovered piece the color is viewed through a semi-transparent medium which
gives a different effect.
Example of fading of color in different media
Color# EEC # SO2 (soln)! Invert Sugar# Invert Sugar# Hard Candies
# (index no.)# # # in Fondant# + light# # & Sugar/Glucose
# # # # # # # # # # Fondants
Red#
Ponceau 4R E 124! ! 2! ! 2! ! 1! All colors are reasonably stable
! ! ! ! ! ! ! ! ! ! if SO2 content is reduced by
! ! ! ! ! ! ! ! ! ! boiling
Amaranth E 125! ! 1! ! 1! ! 1! !
Erythrosine E 127! ! 1! ! 1! ! 1!
Yellow
Tartazine E 102! ! 3! ! 3! ! 2
Sunset Yellow E 103! ! 2! ! 1! ! 1
FCF! E 105! ! 1! ! 1! ! 1
Blue
Indigo carmine E132! ! 1! ! 2! ! 2
1 = Rapid Fading
2 = light or slow fading
3 = Negligible or no fading
Flavoring Materials
Classification
Flavoring materials constitute a very important group of substances in confectionary
manufacture and the character of many lines depends entirely on added flavoring. All
flavorings, whatever their physical character are composed of highly aromatic constituents
that exist naturally or are specifically selected to contribute a particular profile or subtle
differences in the overall flavor of any product in which they are used. Flavoring materials
include :-
1. Naturally Occurring plant material (herbs, spices, vanilla, fruits, nuts, aromatic
vegetables)
2. Products derived directly from such natural materials by physical process only
(extracts, essences, essential oils, oleo resins, fruit juices and concentrates)
3. Isolates or Pure Chemicals prepared from natural products (eugenol from clove, leaf oil
or citral from lemon grass oil)
4. Synthetics chemically prepared from natural isolates or other natural products (vanillin
from wood lignin)
5. Nature Identical synthetic chemicals
6. Artificial Aromatic Chemicals
7. Flavor Enhancers (maltol)
8. Taste Modifier (salts, sugar and sweeteners, organic acid or bittering agents)
9. Solvent or carrier
24.02.10
Natural Flavors
These are obtained from suitable plant sources and are generally subjected to some form
of concentration before being used in confectionary products.
Fruit Flavor -
The flavors of natural fruits are delicate, refreshing and pleasing to most people.
Unfortunately the majority are weak and when included in confectionary contribute little of
their original character to the product.
The soft fruits, strawberry, raspberry and currents contain 85-90% water and must be
concentrated considerably if used as a flavor in a fondant. Concentration under vacuum is
essential and even so appreciable, loss of flavor results. The modern method of freeze
drying deserves the original flavor true to type but the process is costly. Concentrated fruit
pulps if used in confectionary, usually require fortification with some synthetic flavor,
particularly if combined with chocolate.
Essential Oils
The essential oils constitute an enormous range of aromatic materials available for use as
flavoring or fragrance material. The nature and value of these are widely known but a
definition is appropriate here. An essential oil is a volatile mixture of organic compounds
derived by some physical process ie distillation, expression or solvent extraction from
odorous plant materials. A specific oil is derived from one botanical source with which it
agrees in both name and odor. Different parts of the same plant may yield essential oil of a
different composition and aromatic quality. The same plant grown in different location may
yield essential oil of different quality. Early investigators established that essential oils are
complex mixtures of several substances, although in certain instances one main
constituent may predominate (eg clove bud oil contains 85 to 90 % eugenol) The
constituents of essential oils may be classified in the following groups : -
Production :
Essential oils are all volatile in steam which means that they have a vapor pressure low
enough to enable them to be distilled in the presence of water without decomposition.
Being insoluble in water they can readily be separated from the aqueous distillate.
Distillation in air at ordinary pressure involves, higher temperatures and in the presence of
oxygen, results in decomposition of the heat sensitive components. However, many
essential oils can be distilled under reduced pressure and this technique is used to
prepare isolates and deterpentized oils which are valuable flavoring agents. The plant
used for distillation follow the steam distillation process. The principle steam distilled oil
used in confectionary include pepper mint, cassia, cinnamon, nutmeg, clove, pimento
(allspice) (because it has flavors of all spices), anise, rose. The essential oils obtained
from the peels of various citrus fruits (orange, sweet and bitter lemon, grapefruit,
tangerine) are not recovered by distillation, which causes serious decomposition but by
hand or machine expression. Only lime oil is recovered as a by-product of lime juice
production which involves boiling. The old method of hand extraction has largely been
discontinued but it did yield the finest oils. The majority of citrus oils are machine
expression as part of the first citrus juice operation. Special machines have been devised
to ensure that the separated oil is exposed to minimum water treatment as this results in a
better quality product. Some oil is recovered from citrus wastes by distillation but this is of
very poor quality. The presence of excessive quantities of terpenes has a detrimental
effect on the keeping properties of many essential oils. A cleaner and better flavor is
obtained by using terpene less oils which are more concentrated than the natural citrus oil.
The following essential oils are used in chocolate, cocoa and confectionary :-
1. Oil of Almond
Origin - Kernel of bitter almonds
Main flavoring component 97 % Benzaldehyde.
Badly purified oil may contain small amounts of hydrocyanic acid and
this is shown by high specific gravity the oil is stored in stopper bottle otherwise some
oxidation to benzoic acid will occur.
Uses : The flavor and the synthetic product are frequently added to pasta and to chocolate
and nougat.
2. Oil of aniseed
Origin - Aniseed
80-90% Anethole
Currently employed, this is an attractive flavor, apart from the famous aniseed balls. It
may be blended with other flavors in milk chocolate and light coatings.
3. Oil of Bay
Origin - Bay leaves
Main constituent - 50-70% phenolic acid
Uses : Bay leaves are well known in culinary arts. Both the dry leaves and the oil used
in trace amounts seem to have a synergistic effect in cocoa and chocolate.
4. Oil of Caraway
Origin - seed of carumcarui
Available in Holland and Central and Southern europe.
Main constituent - 50-60% together with D-Limonene
uses - Very useful adjunct in the flavoring of chocolates and coating. It is also used in
liquors and liquid centers and in baked confectionary. Flavoring is objectionable if used in
strong concentrations.
5. Oil of Cardamom
Origin - Cardamom seed
Main Constituent - Mixture of cineol and terpineol
Uses - Blends well with many fruit flavor. The brown seeds enhance the flavor of brown
coffee and this can be applied to coffee creams or coffee chocolates.
6. Oil of Cassia
Origin - The oil is distilled from the bud, leaves and twigs like the Chinese Cinnamon.
The bud is marketed in bails of woody dried lengths. Which are dusty to the touch and
typically aromatic.
08.03.10
7. Oil of cinnamon
Origin - The quills, as they are called ideally the under bark of the tree cinnamon
zerlanicum (not important to remember the name). Seychelles and Sri Lankha.
Main constituent
Bark contains about 2-2.5 % of the essential oil. The Oil varies somewhat according to the
place of distillation but normally contains 60-75% of cinnamic aldehyde with 5-10% of
eugenol.
Uses - Similar to Cassia but is generally considered to have a less harsh flavor. Traces of
cinnamon are supposed to enhance fruit flavor and coffee.
8. Celery seed
Origin - used for flavoring is usually of French origin. The pulverised seed is used as a
flavoring for cocoa, chocolate and various confections such as nougats and pastes. It has
the property of leaving a slightly bitter after taste. And because of this, contributes to
neutralizing sickliness.
main constituent - The oil contains mainly dextro limonine. The substance known as
sedonolide (C12 H 18 O 2 ). The oil of celery may be distilled from all plants of the plant
but that from the seeds which contain about 3 % is considered the best.
Uses - Similar to seed, but pulverised seed is preferred for powders and the oil for
confectionary.
9. Oil of Clove
Origin - Extracted from Zanzibar clove flower buds.
Constituent - The oil contains about 90 % Eugenol with associated esters.
Uses - Clove oil is very potent flavor. And is used in confectionary in minute amounts with
other flavors, particularly vanilla. In cooking it always seems to be associated with apple
dishes and could possibly be applied to some fruit flavors in confectionary.
10. Oil of Coriander
Origin - Prepared from the fruits of the Russian Coriander. The plant is also grown in
India and Morocco.
Uses - This pleasantly aromatic flavor is very usefully added to lemon flavor and liquors.
And as a minor constituent of Chocolate. Coriander seeds may be used as the center of
dragees/comfits.
Uses - The ginger oil is mainly used for hard boiled confectionary product.
Keeping properties - Lemon oil will deteriorate as a result of auto oxidation if exposed to
light and air and develops a turpentine like flavor. This may be retarded by the addition of
an anti-oxidant.
Cocoa
It is not native to India. Main cultivators are Amazonian area, Africa, Ghana, ivory coast,
Nigeria, brazil, Malaysia, Sri Lanka and very less amount in Karnataka and Kerela.
Cocoa is theobromo cocoa linn. Four to eight years are required for the growth of the
plant. Optimum temperature for growth is 45 to 48 degree Celsius. Good rainfall is
required. Soil condition should be good with good amount of mineral content. Wind is the
greatest enemy in the production of the plant. Productivity lowers in shade. Each plant
contains 25-40 beans arranged in a row. World production is from 8million tones. Indian
production is only 5000 tones. India imports 1000 tones annually to prepare various cocoa
based products, health drinks and chocolates. Products are reexported to Pakistan and
Bangladesh.
Processing:
Flow chart from Raman.
Fermentation
Heaping the beans - covering with leaves of the same plant - so chemical, microbiological
and enzymatic changes occur (purpose to remove adhering pulp, mucus, kills germs,
modify color flavor of bean, so t will be easily breakable.
Sun drying or mechanical drying can be carried out at 45 to 50 degree celsius. Where final
moisture content should be 7%
Better flavor is obtained in sun drying. Fermentation and drying alters seed coat and
change to rough skin and dried skin which can be easily removed.
Cleaning
is done by counter current air flow and magnetic separation to remove light particle and
insect infestation of bean. Irrespective of the type of equipment chosen for roasting beans
need to be cleaned before they can be processed to remove all foreign object from cocoa
meal. Clean products are not only required for product safety but these impurities can also
cause wear and tear and damage to the machine.
Cleaning is usually carried out I'm several stages
Removal of pores and fine by sieving
Removal of ferrous metal by magnet
A Set of screens remove both very large and very small particles by seiving. Cluster
beans, pieces of wood and strings and other large debris are collected by coarse screen
which cocoa bean pass through. Smaller particles are then allowed to pass through fine
screen. Broken beans are often removed as the broken seed cotyledon (nib) will quickly
deteriorate.once exposed to air and humidity. The beans are then transported usually by
falling under gravity to the next step in the cleaning process. As the beans fall a counter
current air flow aspirates low density and dust particle. The ferrous material is then
removed by magnets in a rotary drum. The cocoa beans are then spread out over a
rotating stainless steel drum jacket and even flow and controlled depth of the bean layer is
very important in obtaining a clear product. On the side of the drum, a stationary magnet
which attracts a ferrous material so that they are retained by the drum. As the drum turns,
the particles come to the non magnetic zone where they become detached from the
Drum and fall into the metal recipient. Metal detector with inject mechanism which
interrupts the flow of beans and remove the ferrous material. Destined removes stones
and other heavy particles. They operate on the principle of fluidized bed. Air passes
through an oscillating, inclined screen and then through beans that are on the top of it. The
heavy particles rest on the screens d oscillates towards the top of screen from where they
fall to s stone collecting bag. A cushion of air transports the beans towards the lower end
of the screen where they fall to the next screen. Dust is collected and separated by suction
on the end of the process and the other particles are removed with this dust as sand
particles are extremely abrasive in fine roll, refiners as well as dust contains wide variety of
biological and chemical contaminants. The chocolate manufacturer receives 20-25 tones
of green bean in bulk amount and is discharged into the field system of the factory site.
1. Development of flavor
2. Textural changes so that it is easily breakable
3. enhances cocoa taste
4. Color development
5. Removal of water
6. Few chemical changes
carried out at 115 to 140 degree celsius for 40 minutes, 200 degree for 20 minutes or
110-115 degree for 60 minutes.
Traditionally the chocolate industry roasted whole beans. The broken D shaped cotyledons
of cocoa beans are generally referred to as nibs. However over the past few decades nib
roasting has become increasingly common. Raw liquor roasting offers an alternative to
these methods. All three systems can be used by chocolate manufacturer to obtain good
results. The definition of the word Good may however differ from manufacturer to
manufacturer. Certain trends can be identified. In UK, crumb is often the basis for milk
chocolate production in which a medium type roast is normally used. In Germany, the
consumer demand is for milk chocolate with a very mild cocoa flavor and a strong milk
flavor which requires a lightly roasted cocoa liquor. In USA, a more pronounced roast is
generally preferred.
For this type of roasting, it is the utmost importance to have equally sized beans. As
smaller beans tend to be over roasted as larger beans are under roasted. The problems
caused by abnormal bean sized distribution are particularly noticeable with whole bean
roasting. However, even with the graded beans flat and other rod shaped beans will be
roasted differently from more regularly shaped beans. During whole bean roasting a slight
loss of cocoa butter will occur, due to migration into the shell. This reduces the yield in
comparison with other roasted methods. Usually, 0.5 % loss of cocoa butter will occur. The
over all amount of energy required is also less favorable, for whole bean roasting for the
following reason :-
1. The larger specific surface of the leaves and certainly that of the liquor, enables their
shorter and lower heat treatment to be used for the same flavor.
2. The shell is no longer a heat barrier, nor does it need to be heated itself.
3. both these factors increase the over all capacity of the roasting equipment when
comparing nib vs whole bean roasting.
Nib Roasting
Removal of the shell of the bean is pre requisite for nib roasting. Some beans can be de
shelled, relatively easily as for example the well fermented and properly dried beans.
Several system of thermal treatments exist. These treatments are usually followed by a
separate heat treatment to reduce the microbial contamination of the product. Although
roasting already leads to a massive reduction in micro organism, a separate heat
treatment of leaves prior to roasting will give the lowest plate count results. Nib roaster
exist both as a continuous air roaster and as drum roaster. Drum roasters are often of the
batch type. Batch drum roaster are used to preserve the top flavor components. Whereas
continuous air roasters are commonly used for West African Cocoa Bean type.
When the bean particles have been reduced in size, the cocoa butter is set free from the
bean shells, and the product becomes a paste. This raw, un roasted liquor has a better
homogeneity of particle sizes than the product obtained using the methods described
above. In order to achieve this, the product has to de-shelled as with nib roasting and the
moisture content must also be reduced, from the initial 7-8 % to 2%. This can be achieved
by combining drying with the heat treatment used, prior to de-shelling. Alternatively, drying
of the leaves or special milling techniques can be used to make the liquor sufficiently fluid
for it to be roasted. Thin film heat exchanger, with or without scrapping devices that can be
used for this purpose. Often the same type of equipment is used to de-gas or de-acidify
the roasted liquor.
Removal of shell
Removal of shell is an important step in the process of making cocoa mass. Beans are
generally broken by impact crusher. Centrifugal force is used to break the beans against
an impact plate and then they fall out of the breaker. Before breaking, some pre treatments
are required.
1. Simple pre-drying of the leaves - For instance in a narrow channel dryer, similar to the
ones used for continuous roasting.
2. Steam puffing process - In this the beans are heated with saturated steam and
subsequently dried.
3. Surface heat Treatments - During which cocoa beans are heated on the surface by
infrared radiation.
Germ free leaves passing through mill - fat melts at that temperature so that ground nib
gets liquid consistency, about 55 % fat. Sometimes a second impact stage is built into the
design. After the first impact plate, unbroken beans fall into a second rotating wheel that
swings the beans back against the impact lid. The centrifugal force of the wheel and
throughput determine the particle size distribution for a given quality of beans. This
distribution should be as homogeneous as possible and contain a minimal number of
particles, smaller than 1.5mm or bigger than 7mm. A sieve is usually mounted before the
breaker to remove broken beans that are already small to prevent them from being broken,
further into particles that are too small. Un broken beans in the outlet product are returned
to the breakers. The particles produced are very abrasive and considerable wear of the
machinery takes place. It is important therefore that the equipment is designed in such a
way that parts such as impact plate can be easily exchanged. Shell is mainly thin and plate
like. It is easily blown upwards by a stream of air whereas a spherical nib particle of a
similar size will fall under particle. Each shifter has itʼs own optimal air flow, which depends
on the size fraction being treated. The smaller particle size the more difficult the separation
between shell and nib.
The number of sieves and air classifiers depends on both the pre treatment of the beans
and state of the operation. Several types of roasters are available : -
Alkalination
Breaking
Grinding
Sifting
Cocoa Powder
Cocoa Mass
Mixing (Merangering)
Tempering
Moulding Enrobing
VIKRAM (6.04.10)
Table Vikram
1. Buhler has developed a special steam treatments screw that can be used for nibs.
2. In drum roaster water and /or steam addition is proposed as an additional micro
organism reduction step in the process before the actual roasting. In the most recent
versions of the Barths a separate reactor is recommended just before the roaster.
3. For liquor roasters, separate pin fin columns are proposed. The un roasted liquor is
mixed with a static roaster. Theraw liquor is exposed to about 1 minute to temperature
between 130-140 at 2-3 bar pressure and reduce temperature immediately. Reduction rate
factors of 10 to the power 4 have been observed.
Refining:
3-5 roll mills are employed. It gives a fine grinding. Materials are passed through closed
clearance requiring roller and particle size of material cast is 25 micro meter or less. So
crystallization is prevented.
Effects- crushing, attrition, abrasion, shearing or cocoa and sugar, desired particle size is
reached. Mixture becomes flaky powder.
Fat bloom -
Is possible due to presence of different tri glycerided there is a chance of separation of fat
crystals. This is fat bloom.
Conching:
Mixture is conched (roller within a curve tank) kneaded in special heated mixing tank fitted
with pressure roller that grind and aerate the melting mass to develop smoothness, flavor,
color to become less viscous. For emulsification of fat. Removal of sugar crystals, removal
of moisture is required. Temperature of conching is 60 degree and time is 96-120 hours.
This step essential for high quality chocolate making.
Oxidation of sugar, caramelization, development of color and flavor.
Chocolate may contain a lot of tri glycerides of different boiling point. So there is chance of
uncontrolled crystallization of sugar and fat. (Sugar bloom and fat bloom). To get uniform
crystallization, tempering is necessary. Following conching liquid chocolate is tempered by
being stirred in a heated and cooled kettle. The objective here is to melt all the tri
glycerides of the fat and the. Initiate uniform crystallization of different try glyceride
fraction. Tempering condition may vary but usually the mass is melted at 54degree and
followed by controlled cooling at 32 degree with continuos stirring for about 1 hour to get
uniform mass. Then it is placed at a mould 16 - 18 degree and 60% RH so that you can
get good chocolate. Migration of fat in chocolate is possible so aging is necessary for 6
months. Enrobing of liquid chocolate - solid i.e. mass moulded for long term storage -10 to
-20 degree of liquid chocolate. Main characteristic of chocolate is that it melts at mouth
temperature.
Sent from my iPhone
07.03.10
Flavor development
The flavor of a piece of chocolate depends on a series of processes being carried out
correctly. Conching is the final one of these processes and is the last opportunity for a
manufacturer to obtain the taste required for a particular product. it cannot however correct
previous flavor off flavors from smoke and mould arising from poor drying, nor can it make
an inferior cocoa taste like perfect. The objective of conching is essentially the removal of
undesirable flavors and in certain circumstances the development of more desirable ones
to match the final product. The former is particularly important for dark chocolate and is
largely dependent on conche (instrument for conching) ventilation and conching time. The
development of flavor in milk chocolate will also depend on the ingredients being used.
Those manufactured from milk powder maybe heated to obtain a more cooked flavor.
Whereas those starting from cocoa crumb, already contain a cooked flavor. Although this
can be strengthened during conching. This type of flavor development depends on the
conching temperature and time.
Conching can be divided into three phases or stages although not all occur for every
recipe and for all type of conching.
1. Dry Phase
2. Pasty Phase
3. Liquid Phase
Dry Phase
Chocolate mass is crumbly, Moisture is removed.
Pasty Phase
Chocolate is a thick paste, high work input required by the conching.
Liquid Phase
High speed stirring to mix in the final fat and emulsifier addition.
Graph showing the changes in conche amperage, water and chocolate mass temperature
during conching cycle.
The above figure shows the power curves of a conche that has been fitted with a servo
that changes the speed as the viscosity changes to give a uniform power input. In order to
develop a cooked flavor within a chocolate, it is necessary to reach a certain temperature
for a given time. Within limits it is possible to raise the temperature and shorten the time
and vice versa. The same is true for conching power input and if the power is increased,
shorter conching times are possible. Once the final addition of fat and emulsifier has been
made, however the Chocolate becomes very thin and it is very difficult to put a further
amount of shearing energy into the chocolate.
The chemistry of flavor development in chocolate in different stages of unique flavor. The
mix and balance of the numerous compounds that contribute to the final flavor depend on
genetics. Environmental conditions harvesting and processing. With the chocolate the
chemical complexity of flavor development is evident when one realizes the numerous
parameters that may influence it's development.
1. Fermentation
Once cocoa is harvested, biochemical mechanism that contribute precursors for
development. Even though the fermentation process facilitates the removal of the
mucilaginous pulp and prevents germination of the bean. Cocoa shells cultures only the
shells have matured could a chocolate or cocoa flavor results from further processing.
Prior to fermentation structural changes along with protein hydrolyses in cocoa seeds is
observed. Fermentation is required because unfermented beans may develop little
chocolate flavor when roasted. Excessive fermentation may also result in unwanted
flavors. In early fermentation the major sacchiride is sucrose, however it is soon
hydropower into glucose and fructose as fermentation progresses. During hydrolyses
reaction, the fructose content increases as compared to glucose after approximately two
days of fermentation. Following the fermentation the beans are dried, and this is also
instrumental in flavor precursor development. Indicator of good drying practice relating to
flavor quality of the beans are good brown color and low astringency and bitterness.
Freedom from off flavor such as excessive acidity and smoky flavor is also indicative of
proper drying. It is during the drying phase of cocoa curing that the characteristic brown
color of chocolate develops. Major oxidizing reactions occur with polyphenols catalyzed by
the enzyme polyphenol oxidase. The death of the bean, with loss of membrane integrity
allows previously restricted enzymatic reactions in brown colored formation. Excessive
heat and rapid drying may not allow for adequate loss of the volatile acids as for example
acetic acid and therefore have a detrimental effect on quality. There also may be situations
where the water activity within the bean is such that the drying process is merely a
continuation of the fermentation process and many reactions can proceed. A high level of
water activity as a result of incomplete drying or rain soaking may also recur in mould
contamination. This is particularly noticeable for beans in transit. High concentration of
strongly flavored carbonyls may result from heavy mould growth and thus alter in flavor.
Total carbonyl may double in concentration in mono carbonyls increasing by 500% and
methyl ketones exhibiting a noticeable increase.
Diagram!
Roasting:
Roasting reduces the acidity as evident by the significance decrease in the concentration
of volatile acids especially acetic acid which reduces the acidic taste. The concentration of
non volatile acids as for example oxalic, tartaric, succinic and lactic acid are not influenced
by roasting. After roasting the beans posses the typical intense aroma of cocoa. The
Roasting process normally heating the beans from 110 to 220 degree. Depending on wind
type, is needed for the reduction of moisture, release of the beans from the cell and
development of chocolate flavor. One of the most important and complex reactions
involving flavor during the roasting process is non enzymatic browning, mallard browning
or carbonyl amine reaction.
There are three stages of reaction : initiation, intermediate and final stage. One of the key
reaction is the rearrangement of the glycosylamines (reaction product of reducing sugars
and amino acids produced from additional compounds) into isomerization products.
Conching:
If the flavor change caused by conching is simply due to the coating of the particle with
cocoa butter then controlling the particle size might allow for maximum conching efficiency
because large particles require less cocoa butter per unit for coverage, the larger particle
might be easier to conche. It is important to consider the range of particle size. The mouth
determines to be gritty and also size range necessary for minimum cocoa butter used.
13.04.2010
Two major distinct forms of sweet making exists enrobing and moulding. In the first, the
chocolate is poured over the sweet centre, with any excess being removed by shaking or
blowing. In the second, it is poured into a mould where at least part of the chocolate is
allowed to set.
Components of Enrober
The above figure shows the basic component of an enrober. An enrober consists of a
driven wire grid conveyer belt (1) on which to transport the centre to be coated. This
passes over a stirred reservoir tank (2) which holds the tempered chocolate. A chocolate
pump (3) circulates the chocolate up. A riser pipe (4) and into the top flow pan (5). The flow
pan creates one or two curtains of chocolate through which the uncoated centers pass.
Positioned below the top flow pan and beneath the grid is a bottoming trough also called
surge roller trough. This trough retains chocolate falling from the curtain and feeds it
onto a flat plate. Thus forming a bed of chocolate that moves with the wire grid. The
centers entering the enrober are semi - suspended by this bed and become coated on the
under side. An air nozzle (7) is located after the chocolate curtain together with a grid
shaker frame (8). A number of grid licking roll (9) are shown located after the grid shaker.
These remove excess chocolate from the grid and product. Any chocolate drained from the
roll scrapper is returned to the reservoir tank. Higher the grid belt running along a heated
extension trough (10). The coated sweets, leaving the enrober pass over the Anti-tailing
rod which as itʼs name suggests, controls the tails or residues left by the liquid chocolate
as it separates from the wire grid and transfers into the cooler belt or plaque.
Chocolate panning
The definition of pan coating may best given as follows - Pan Coating is the built up of a
center (kernel or corpus) with a liquid or liquid and powder substance with multiple layers
or continuous phases, which are set, hardened and dried to a smooth or pearled surface
and often finished with a sealant and/or a polishing agent, utilizing rotating pans or drums,
creating a fluid bed. The machinery used is often compared visually with a cement mixer.
The drums or pans are horizontal or have their front slightly elevated and are fitted with
internal ridges which are used to aid mixing. As the product mixes, thin layers of liquid are
added to coat the center material. It is during the drying or setting of this coating that the
tumbling action causes the surface to rub against each other to form a smooth finish. Care
has to be taken before marketing the products made by panning because some countries
have standards covering pan coated goods and it is always advisable to check local laws
and regulations. Frequently panned goods are named by their centers and/or shell applied
to the confectionary. e.g. an almond center with a chocolate shell would be called as
Chocolate Almond.
Steps :-
1. Center Selection
2. Center Preparation
3. Coating Selection (largely dictated by marketing requirement)
4. Engrossing (which involves a) building the base with chocolate or other compound, b)
rapid weight gain and c) smoothing)
5. Polishing
6. Sealing
7. Packaging
Packaging Materials
a) Aluminum Foil
b) Regenerated Cellulose Film
c) Paper Board/ Wax Coated
d) Plastic Film
e) Cold seal
1. Seal Strength
2. Tensile Strength
3. Bursting Strength
4. Co-efficient of Friction
5. Moisture Vapor Resistance
6. Detection of Residual Solvent
7. Print Stability
8. Resistance to Abrasion
9. Scannability of Bar Codes
Product Definition
Milk chocolate with high milk content Min 20% dry cocoa solids
Min 20% Milk or milk products
Min 2.5% Dry, non-fat cocoa solids
Min 5% Milk fat
Min 25% Total fat
Group 1 includes hard boiled sweets (hard candy, hard and soft caramels and toffees and
most jellies) Group 2 consists of products such as fondants, fudges, grained
marshmallows and grained nougats.
It can be seen that a variety of textures are obtained as a result of various processes and
formulations and each requires a particular method of forming into pieces or bars. Different
parts of confectionary processes :-
1. Rolling and Cutting - THis is probably the oldest method of producing bars and pieces.
Mostly from plastic products like caramel, nougats and various pastes. The confection
in the right plastic condition, because of either itʼs moisture, fat content or temperature
is first fed through a roller to produce a slab of the required thickness. The slab is then
fed to knife cutter to produce wide strips that are subsequently cut into narrow bars or
small units. In a modern development of this principle the hot product is fed to iced
roller enabling the production of multiple layer slabs. The slabs are continuously cut
into strips that pass over a spreader and are then cut into Bars or small pieces.
2. Casting or Depositing :- This method is applied to hard candy, fondant, some caramel
and fudge, marshmallows and other products that can be obtained in liquid state.
a) Hard candy - Certain types may be deposited as liquid at around 150 degree celsius
into metal moulds, the surface of which are coated with a release agent (like grease,
or glossy)
b) Fondants, Jellies and Marshmallows - These are usually cast into starch moulds. The
more recent developments have been automatic depositing and release of fondant
and some other confections from metal moulds. The depositing of caramels and
toffees into silicon-rubber moulds. Silicon-Rubber has unique non stick properties as
well as being resistant to the relatively high temperature of high boiled confections.
3. Die forming :- This method is applied almost exclusively to hard candies and some
caramel and toffees. It includes normal, flavor pieces, filled pieces (bon-bon). The
principle is to cool the boiled syrup under controlled conditions until it is plastic. In this
state it is reduced to a rope which is fed to machine dies that presses the rope into
pieces that usually have some special form or pattern. This pieces are immediately fed
to a cooler and a wrapping machine. A modification of this principle is applied to
certain caramel and chewy candy. Here the rope is similarly produced but it is fed to a
cut and wrap machine which by means of high speed rotary knife cuts small pieces of
the rope. These are fed to the wrapping machines.
4. Extrusion and bar forming :- The principle of extrusion developed for many non-food
products has been applied very successfully in the confectionary industry for the
manufacture or variety of products ranging from soft materials such as marshmallows
and fondants to very plastic nougats and caramel. In the process the material to be
extruded is fed to the orifice by means of multiple rollers or screws. The cross-
sectional area of the orifice determines the shape of the final movement and many
extruders have a series of orifices producing ropes that can be cut into either bars or
small pieces. Multiple bars can be made in which two layers are extruded
simultaneously. Alternatively a bar with a center of a different confection can be made.
Extrusion allies itself to other continuous methods of cooking and enrobing. Certain
precautions must be observed in the manufacture of confectionary : -
1. Temperature
2. Fat Separation
3. Collapse after extrusion
Taru! Lakhanpal
B.E. Food Technology (Year 3)
CH-7714
University Institute of Chemical Engineering and Technology
Panjab University, Chandigarh