Ejercicios para resolver: Construir las curvas de calibracin de las siguientes tablas, obteniendo la ecuacin

que los rige, la pendiente, y R2.

b= (nxyi - x yi) / (nx2 - (x)2)
a= (yi - b x)/n
r2=(i - i)2 / (yi - )2

Dato

n=

C
(ppm) Absorbancia
0.02
0.2
0.04
0.4
0.06
0.6
0.08
0.8
0.1
1
0.15
1.5
x =

yi =

x2

xyi

i = a + bx

n=

C (ppm)

(i - )2 =

0
0.001
0.002
0.003
0.004

Absorbancia
0.09
0.195
0.295
0.396
0.498

0.005

0.599

x =

yi =

x2

xyi

xyi=

i = a + bx

n=

C (ppm)

x =

0.1
5
10
15
20

2.4
12
25
36.5
49

25

61
yi =
= yi/n=

x2

xyi

Intensidad

xyi=

(yi - )2=

(i - )2

(yi - )2

(i - )2 =

(yi - )2=

(i - )2

(yi - )2

(i - )2 =

(yi - )2=

x2 =

= yi/n=

Dato

(yi - )2

x2 =

xyi=

= yi/n=

Dato

(i - )2

i = a + bx

x2 =

Dato

n=

C (ppm)
0
0.2
0.4
0.6
0.8

0
7.5
14.8
22.6
30

37.7

x =

x2

xyi

Seal

yi =

xyi=

i = a + bx

C (ppm)
0
0.02
0.05
0.09
0.11
0.13

n=

x =

yi =

x2

xyi

Absorbancia
0.021
0.105
0.315
0.607
1.025
1.225

xyi=

i = a + bx

C (ppm)
0
1
2
3
4

n=

x =

x2

xyi

Emision

(i - )2 =

(yi - )2=

(i - )2

(yi - )2

(i - )2 =

(yi - )2=

(i - )2

(yi - )2

(i - )2 =

(yi - )2=

x2 =

= yi/n=

Dato

(yi - )2

x2 =

= yi/n=

Dato

(i - )2

i = a + bx

24
49
100
120
190
yi =

xyi=

x2 =

= yi/n=

Dato

C (ppm)
Absorbancia
0.25
0.055
0.5
0.112
0.75
0.162
1
0.216
2
0.438
2.5
0.456

n=

x =

yi =
= yi/n=

x2

xyi

xyi=

i = a + bx

(i - )2

(yi - )2

x2 =
(i - )2 =

(yi - )2=

Dato

Fraccion
mol

Abs 1

0.08
0.12
0.17
0.22
0.28
0.36
n=

x =

0.232
0.346
0.491
0.632
0.691
0.615
yi =
= yi/n=

0.23
0.35
0.49
0.59
0.69
0.72

x2

xyi

Abs 2 Abs 3

yi = a + bx

(i - )2

(yi - )2

0.233
0.345
0.492
0.599
0.689
0.725
xyi=

x2 =
(i - )2 =

(yi - )2=