Está en la página 1de 1957

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\par}{\phpg\posx3089\pvpg\posy2834\absw623\absh9272 \sl-278 \par\f10 \fs17 \cf1
4.
\par}{\phpg\posx3089\pvpg\posy2834\absw623\absh9272 \sl-282 \f10 \fs17 \cf1 4.1.

\par}{\phpg\posx3089\pvpg\posy2834\absw623\absh9272 \sl-280 \f10 \fs17 \cf1 4.2.


\par}{\phpg\posx3089\pvpg\posy2834\absw623\absh9272 \sl-279 \f10 \fs17 \cf1 4.3.
\par}{\phpg\posx3089\pvpg\posy2834\absw623\absh9272 \sl-278 \par\f10 \fs17 \cf1
5.
\par}{\phpg\posx3089\pvpg\posy2834\absw623\absh9272 \sl-282 \f10 \fs17 \cf1 5.1.
\par}{\phpg\posx3089\pvpg\posy2834\absw623\absh9272 \sl-280 \f10 \fs17 \cf1 5.2
\par
}
{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \f10 \fs17 \cf1 \f10 \fs17 \cf1
Indice
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Pre
facio
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-277 \f10 \fs17 \cf1 El
Petrleo
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-282 \f10 \fs17 \cf1 Int
roduccin
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 ori
gen del petrleo
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Com
posicin del petrleo
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Fsic
o qumica del petrleo. Sistemas multicomponentes
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Mtod
os de ensayo. Densidad
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Des
tilacin de laboratorio
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Eva
luacin de las existencias de petrleo
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Fac
tor de caracterizacin
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-278 \par\f10 \fs17 \cf1
Refinacin del petrleo
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-282 \f10 \fs17 \cf1 Tra
tamiento de impurezas oleofbicas
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Ope
raciones de refinacin, "Topping" y Vaco
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Pro
cesos de refinacin. Cintica de las reacciones
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Ele
mentos de termodinmica aplicada
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Pro
cesos pirolticos
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-279 \f10 \fs17 \cf1 Pro
cesos catalticos
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Est
ructura atmica y molecular
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Mec
anismo de la catlisis, catalizadores cidos
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-279 \f10 \fs17 \cf1 El
craqueo cataltico a lecho fluido
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Ref
ormacin cataltica, catalizadores O/R
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Iso
merizacin cataltica
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773 \sl-280 \f10 \fs17 \cf1 Hid
rogenacin e Hidrocraquo

\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
onstruccin de hidrocarburos
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
Aspectos econmicos de la refinacin.
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
uacin legal e impositiva
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
imacin de costos de refinacin
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
Adjuntos
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
las de conversin de unidades
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
relaciones propiedades fsico qumicas
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
adstica, Argentina
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
Bibliografa
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
eral
\par}{\phpg\posx4790\pvpg\posy2277\absw4771\absh9773
ecializada \par
}
{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \f10
7 \cf1 5
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
221 5
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
221 5
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
222 6
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
222 9
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
110 12
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
110 15
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
110 25
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
111 30
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
\fi113 32
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
111 33
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
111 36
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
111 42
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
111 46
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
111 55
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
110 68
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
111 69
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275
110 75
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275

\sl-280 \f10 \fs17 \cf1 Rec


\sl-278 \par\f10 \fs17 \cf1
\sl-283 \f10 \fs17 \cf1 Sit
\sl-279 \f10 \fs17 \cf1 Est
\sl-278 \par\f10 \fs17 \cf1
\sl-282 \f10 \fs17 \cf1 Tab
\sl-280 \f10 \fs17 \cf1 Cor
\sl-279 \f10 \fs17 \cf1 Est
\sl-278 \par\f10 \fs17 \cf1
\sl-282 \f10 \fs17 \cf1 Gen
\sl-280 \f10 \fs17 \cf1 Esp
\fs17 \cf1 \fi224 \f10 \fs1
\sl-282 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-278 \par\f10 \fs17 \cf1
\sl-282 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-279 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-280 \f10 \fs17 \cf1 \fi
\sl-279 \f10 \fs17 \cf1 \fi

111 80
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-280 \f10 \fs17 \cf1 \fi
111 88
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-280 \f10 \fs17 \cf1 \fi
111 98
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-280 \f10 \fs17 \cf1 100
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-280 \f10 \fs17 \cf1 103
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-278 \par\f10 \fs17 \cf1
108
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-283 \f10 \fs17 \cf1 111
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-279 \f10 \fs17 \cf1 114
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-278 \par\f10 \fs17 \cf1
120
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-282 \f10 \fs17 \cf1 120
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-280 \f10 \fs17 \cf1 123
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-279 \f10 \fs17 \cf1 124
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-278 \par\f10 \fs17 \cf1
127
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-282 \f10 \fs17 \cf1 127
\par}{\phpg\posx10431\pvpg\posy2834\absw370\absh9275 \sl-280 \f10 \fs17 \cf1 127
\par
}
\sect\sectd\pard\plain
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}}\par}{\phpg\posx495\pvpg\posy169\absw767\absh204 \b \f10 \fs21 \cf0 \b \f10 \f
s21 \cf0 home \par
}
{\phpg\posx5968\pvpg\posy368\absw1736\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 La Refinacin del Petrleo \par
}
{\phpg\posx10416\pvpg\posy332\absw729\absh178 \b \f10 \fs16 \cf8 \b \f10 \fs16 \
cf8 TOMO I \par
}
{\phpg\posx3089\pvpg\posy1437\absw1378\absh237 \b \f10 \fs21 \cf1 \b \f10 \fs21
\cf1 PREFACIO \par
}
{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \f10 \fs18 \cf1 \f10 \fs18 \cf1
El presente trabajo no pretende reemplazar los libros clsicos en la enseanza y apl
icacin de
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 la
fsico qumica del petrleo y sus productos, no obstante considerar que en los ltimos ao
s
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 no
se ha publicado suficiente bibliografa que combine adecuadamente la teora y la prct
ica,
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 sob
re los ms modernos aspectos en la materia,.
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \par\f10 \fs18 \cf1
El autor ha intentado lograr que el lector tome un concepto general
de la refinacin del
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 pet
rleo, que le permita particularizar un tema con conocimiento del espectro dentro
del cual
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 est

inmerso.
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \par\f10 \fs18 \cf1
Intentando facilitar el acceso a las partes importantes de las normas
para ensayos, se han
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 agr
egado Fichas Tcnicas de algunas de ellas, indicando la denominacin y un
resumen
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 sim
plificado de su contenido.
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \par\f10 \fs18 \cf1
El convencimiento que considerar al petrleo un sistema multicomponente permite e
xplicar la
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 may
ora de los temas, correlaciones y propiedades de los cortes, ha induci
do ha dedicar
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 esp
acio a su desarrollo.
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \par\f10 \fs18 \cf1
El uso de trminos en espaol e ingles para los mismos asuntos, as como
expresiones
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-279 \f10 \fs18 \cf1 com
unes en la industria o unidades no frecuentes en algunas magnitudes,
responde a la
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 mot
ivacin de poner al lector en los casos clsicos que se le van a presentar a diario.
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \par\f10 \fs18 \cf1
La experiencia que el autor ha hecho en YACIMIENTOS PETROLIFE
ROS FISCALES, la
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 SEC
RETARIA DE ENERGIA DE LA NACION y los cursos dictados en la Ctedra de Combustible
s
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 y L
ubricantes de la ESCUELA SUPERIOR TECNICA DE EJERCITO Gral. MANUEL M SABIO y en
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 la
UADE, UNIVERSIDAD ARGENTINA DE LA EMPRESA, juntamente con los cursos preparados
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 par
a el INSTITUTO ARGENTINO DEL PETROLEO Y DEL GAS, se ha intentado vol
car como
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-279 \f10 \fs18 \cf1 col
aboracin al conocimiento y mejor aplicacin de los productos del petrleo.
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \par\f10 \fs18 \cf1
De los defectos, errores y omisiones que se han cometido, se espera
recibir de los amables
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 lec
tores las sugerencias y proposiciones que crean convenientes, tanto en
la EST como en
\par}{\phpg\posx3089\pvpg\posy3153\absw8442\absh7757 \sl-280 \f10 \fs18 \cf1 IAP
G, en la seguridad que se tomarn en cuenta para realizar las necesarias revisione
s. \par
}
{\phpg\posx9909\pvpg\posy12673\absw722\absh198 \f10 \fs18 \cf1 \f10 \fs18 \cf1 E
l Autor \par
}
{\phpg\posx5906\pvpg\posy16270\absw88\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 3 \par
}
\sect\sectd\pard\plain
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}}\par}{\phpg\posx495\pvpg\posy169\absw767\absh204 \b \f10 \fs21 \cf0 \b \f10 \f
s21 \cf0 home \par
}
{\phpg\posx5968\pvpg\posy368\absw1736\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 La Refinacin del Petrleo \par
}
{\phpg\posx10416\pvpg\posy332\absw729\absh178 \b \f10 \fs16 \cf8 \b \f10 \fs16 \
cf8 TOMO I \par
}
{\phpg\posx3089\pvpg\posy1437\absw403\absh720 \b \f10 \fs21 \cf1 \b \f10 \fs21 \
cf1 1.
\par}{\phpg\posx3089\pvpg\posy1437\absw403\absh720 \sl-270 \par\b \f10 \fs21 \cf
1 {\b0 \f20 \fs19 1.1. }\par
}
{\phpg\posx3656\pvpg\posy1437\absw7384\absh1220 \b \f10 \fs21 \cf1 \fi153 \b \f1
0 \fs21 \cf1 EL PETROLEO
\par}{\phpg\posx3656\pvpg\posy1437\absw7384\absh1220 \sl-270 \par\b \f10 \fs21 \
cf1 \fi153 {\b0 \f20 \fs19 INTRODUCCION }
\par}{\phpg\posx3656\pvpg\posy1437\absw7384\absh1220 \sl-280 \par\b \f10 \fs21 \
cf1 {\b0 \fs18 "Lquido}{\b0 \fs18 oleoso,}{\b0 \fs18 ms}{\b0 \fs18 ligero}{\b0
\fs18 que}{\b0 \fs18 el}{\b0 \fs18 agua,}{\b0 \fs18 de}{\b0 \fs18 color}{\b
0 \fs18 oscuro}{\b0 \fs18 y}{\b0 \fs18 olor}{\b0 \fs18 fuerte,}{\b0 \fs18 q
ue}{\b0 \fs18 se}{\b0 \fs18 encuentra }\par
}
{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \f10 \fs18 \cf1 \f10 \fs18 \cf1
nativo en el interior de la tierra y a veces forma grandes manantial
es". (Dicc. Encic. Espasa
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 Cal
pe)
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 \fi
566 Desde tiempos muy remotos la humanidad conoce y de alguna manera usa el petrl
eo.
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 Se
sabe que las manifestaciones superficiales del petrleo, como los betune
s asflticos, han
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 sid
o utilizadas como fuente de luz y calor, tanto como para calafatear
embarcaciones o
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 mom
ificar cadveres. No obstante el uso intensivo es relativamente moderno,
pudiendo
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 est
ablecerse con claridad distintas pocas, perfectamente caractersticas.
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 \fi
550 Hasta 1859 la utilizacin del petrleo o del gas solo ocurri como emp
rendimientos
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 ais
lados, sobre aquellas manifestaciones superficiales de los mismos. En 1
859 se perfora en
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 Pen
nsylvania el que se considera el primer pozo de petrleo, por E. L. Drake, comenza

ndo la
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 era
conocida como del queroseno, que se extiende hasta 1900. Durante est
e perodo el
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 pri
ncipal uso fue para iluminacin.
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 \fi
566 En el principio del siglo XX irrumpe en la vida del hombre el m
otor de combustin
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 int
erna, dando comienzo a la era de la nafta, que si bien se puede co
nsiderar que perdura
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 has
ta nuestro tiempo, presenta una inflexin en el ao 1973, donde la crisis del petrleo
hizo
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-279 \f10 \fs18 \cf1 ref
lexionar sobre la necesidad de una utilizacin ms racional de este recurso. Desde e
ntonces
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 com
enz en los pases desarrollados el estudio y aplicacin de planes de ahor
ro de energa,
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-279 \f10 \fs18 \cf1 con
la mira puesta en la necesidad de incrementar la utilizacin del petrl
eo como materia
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 pri
ma petroqumica.
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 \fi
566 Si bien es de esperar varios aos de utilizacin del petrleo como fue
nte de energa,
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 pri
ncipalmente en uso automotor, no debemos descartar la realidad que est
amos en las
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 fro
nteras de utilizacin masiva de otras energas alternativas menos contamina
ntes y por lo
\par}{\phpg\posx3089\pvpg\posy2853\absw7993\absh5741 \sl-280 \f10 \fs18 \cf1 tan
to, en el inicio de una nueva era. \par
}
{\phpg\posx3089\pvpg\posy9815\absw403\absh217 \f20 \fs19 \cf1 \f20 \fs19 \cf1 1.
2. \par
}
{\phpg\posx3656\pvpg\posy9815\absw7390\absh718 \f20 \fs19 \cf1 \fi153 \f20 \fs19
\cf1 ORIGEN DEL PETROLEO
\par}{\phpg\posx3656\pvpg\posy9815\absw7390\absh718 \sl-279 \par\f20 \fs19 \cf1
{\f10 \fs18 En}{\f10 \fs18 trminos}{\f10 \fs18 legales}{\f10 \fs18 el}{\f10
\fs18 petrleo}{\f10 \fs18 ha}{\f10 \fs18 sido}{\f10 \fs18 considerado}{\
f10 \fs18 un}{\f10 \fs18 mineral}{\f10 \fs18 (aceite}{\f10 \fs18 de}{\f1
0 \fs18 piedra),}{\f10 \fs18 si }\par
}
{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \f10 \fs18 \cf1 \f10 \fs18 \cf1
bien este encasillamiento no satisface tecnolgica ni cientficamente. Evidentement
e se trata
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 de
una mezcla compleja, formada principalmente por hidrocarburos, con con
taminantes de
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 di
stinta composicin qumica que le dan caractersticas especiales.
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 \f
i566 Cuando intentamos elaborar teoras sobre su formacin, su origen, debemos armon
izar

\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 la


s mismas con hechos observables:
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \par\f10 \fs18 \cf
1 \fi558 1.- Algn mecanismo fisicoqumico llev a su formacin a partir de al
guna materia
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 \f
i861 prima.
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 \f
i558 2.- Que algn mecanismo permiti que se concentrara en un reservorio
subterrneo,
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 \f
i861 yacimiento.
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 \f
i558 3.- Que esa acumulacin ha quedado por siglos a resguardo de prdidas y destruc
cin.
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \par\f10 \fs18 \cf
1 \fi566 Por la procedencia de la materia prima han competido dos grup
os de teoras; las
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 in
orgnicas y las orgnicas.
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \par\f10 \fs18 \cf
1 \fi566 Los defensores del origen inorgnico del petrleo se basaron fundamentalmen
te en la
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 hi
ptesis de Mendleiev (1877), quin trabajando sobre algunos carburos metlicos
observ
\par}{\phpg\posx3089\pvpg\posy10673\absw7952\absh4482 \sl-280 \f10 \fs18 \cf1 la
formacin de hidrocarburos al agregarles agua. \par
}
{\phpg\posx5906\pvpg\posy16270\absw88\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 5 \par
}
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28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a

28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a
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}}\par}{\phpg\posx836\pvpg\posy332\absw729\absh178 \b \f10 \fs16 \cf8 \b \f10 \f
s16 \cf8 TOMO I \par
}
{\phpg\posx4220\pvpg\posy368\absw1736\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 La Refinacin del Petrleo \par
}
{\phpg\posx11093\pvpg\posy273\absw767\absh204 \b \f10 \fs21 \cf0 \b \f10 \fs21 \
cf0 home \par
}

{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \f10 \fs18 \cf1 \fi566 \f10 \fs18


\cf1 La principal objecin que mereci la hiptesis de Mendleiev fue que, p
or intermedio
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 de c
arburos, no pueden obtenerse una gran cantidad de hidrocarburos que sin embargo
estn
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 pres
entes en el petrleo. No obstante las objeciones que ha merecido, la c
omplejidad del
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 petrl
eo permite que algn aspecto pueda explicarse por esta hiptesis, con lo cual se pie
nsa
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 que
de todas maneras algn papel desempe.
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 \fi5
66 Las modernas teoras sobre el origen del petrleo son de carcter orgnico
, pero
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 comb
inan no solo la procedencia de la materia prima, sino las formaciones
de cuencas
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 sedi
mentarias contenedoras y las propiedades migratorias del aceite resultante.
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 \fi5
66 De acuerdo con la teora del origen orgnico la materia prima la apor
taron restos de
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 orga
nismos vegetales y animales, tanto marinos como terrestres. Algu
nos petrleos se
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 form
aron de estos materiales en el mismo lugar en que se encuentran hoy
los yacimientos,
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 otro
s han debido migrar del lugar de origen a alguna trampa.
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 \fi5
66 La conservacin del petrleo en acumulaciones comerciales siempre se pro
duce en
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 cond
iciones subterrneas, estos reservorios o trampas deben ser espacios pora
les revestidos
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 de
agua, en rocas sedimentarias. Como el petrleo y el gas son ms livianos
que el agua,
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 sube
n a la parte superior del receptculo, que deber ser cncavo e impermeable, con lo qu
e
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-279 \f10 \fs18 \cf1 qued
arn "entrampados" entre el techo y el agua.
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 \fi5
66 La forma en que se buscan y evalan las posibles disponibilidades de
petrleo se
\par}{\phpg\posx870\pvpg\posy1437\absw8099\absh4733 \sl-280 \f10 \fs18 \cf1 pued
en simplificar como sigue. \par
}
{\phpg\posx1413\pvpg\posy7317\absw7437\absh1961 \f10 \fs18 \cf1 \f10 \fs18 \cf1
1.- Estudios geolgicos de superficie en busca de zonas aptas para la formacin y
\par}{\phpg\posx1413\pvpg\posy7317\absw7437\absh1961 \sl-280 \f10 \fs18 \cf1 \fi
306 acumulacin (mapas geolgicos).
\par}{\phpg\posx1413\pvpg\posy7317\absw7437\absh1961 \sl-280 \f10 \fs18 \cf1 2.Estudios geofsicos sobre la estructura subterrnea de las zonas aptas.
En general

\par}{\phpg\posx1413\pvpg\posy7317\absw7437\absh1961 \sl-280 \f10 \fs18 \cf1 \fi


306 estos mtodos utilizan las perturbaciones que las distintas capas de
rocas pueden
\par}{\phpg\posx1413\pvpg\posy7317\absw7437\absh1961 \sl-280 \f10 \fs18 \cf1 \fi
306 causar a una seal fsica como la gravedad, el magnetismo u ondas sonoras.
\par}{\phpg\posx1413\pvpg\posy7317\absw7437\absh1961 \sl-279 \f10 \fs18 \cf1 3.Perforar un "pozo de exploracin"...
Si resulta positivo:
\par}{\phpg\posx1413\pvpg\posy7317\absw7437\absh1961 \sl-280 \f10 \fs18 \cf1 4.Perforar un "pozo de confirmacin". Si resulta positivo:
\par}{\phpg\posx1413\pvpg\posy7317\absw7437\absh1961 \sl-280 \f10 \fs18 \cf1 5.Perforar los "pozos de desarrollo". \par
}
{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \f10 \fs18 \cf1 \fi566 \f10 \fs1
8 \cf1 Al pozo exploratorio positivo se lo denomina descubridor. Los po
zos de desarrollo
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-280 \f10 \fs18 \cf1 per
miten cubicar el yacimiento, pasando a ser el petrleo contenido y no
explotado una
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-280 \f10 \fs18 \cf1 "Re
serva Comprobada".
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-279 \f10 \fs18 \cf1 \fi
566 Las reservas de petrleo deben distinguirse de los denominados "recursos petro
leros"
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-280 \f10 \fs18 \cf1 de
un pas. Como recursos se suman a las reservas comprobadas los restos
de material
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-280 \f10 \fs18 \cf1 pet
rolfero remanente en yacimientos ya explotados (en espera de tcnicas de
recuperacin
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-280 \f10 \fs18 \cf1 sec
undaria econmicas), yacimientos no cubicados (no desarrollados), yacimientos pote
nciales
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-280 \f10 \fs18 \cf1 no
perforados y depsitos de materiales alquitranosos aflorantes.
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-280 \f10 \fs18 \cf1 \fi
566 Las posibilidades de refino de cada recurso estn ligadas a la economa de la op
eracin,
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-280 \f10 \fs18 \cf1 con
siderando los precios alternativos tanto del material involucrado como
de la tecnologa
\par}{\phpg\posx870\pvpg\posy10117\absw8046\absh2717 \sl-279 \f10 \fs18 \cf1 nec
esaria para extraerlo y procesarlo segn su calidad. \par
}
{\phpg\posx870\pvpg\posy13719\absw403\absh217 \f20 \fs19 \cf1 \f20 \fs19 \cf1 1.
3. \par
}
{\phpg\posx1437\pvpg\posy13719\absw7384\absh718 \f20 \fs19 \cf1 \fi153 \f20 \fs1
9 \cf1 COMPOSICION DEL PETROLEO
\par}{\phpg\posx1437\pvpg\posy13719\absw7384\absh718 \sl-280 \par\f20 \fs19 \cf1
{\f10 \fs18 El}{\f10 \fs18
petrleo}{\f10 \fs18
crudo}{\f10 \fs18
se}{\f
10 \fs18
presenta}{\f10 \fs18
en}{\f10 \fs18
la}{\f10 \fs18
naturale
za}{\f10 \fs18
como}{\f10 \fs18
un}{\f10 \fs18
lquido}{\f10 \fs18
mvil
}{\f10 \fs18
de}{\f10 \fs18
color }\par
}
{\phpg\posx870\pvpg\posy14577\absw7961\absh1665 \f10 \fs18 \cf1 \f10 \fs18 \cf1
amarillento, pudiendo llegar hasta tener el aspecto de un material semislido de c
olor negro.
\par}{\phpg\posx870\pvpg\posy14577\absw7961\absh1665 \sl-280 \f10 \fs18 \cf1 \fi
566 En la composicin del petrleo entran fundamentalmente hidrocarburos gas
eosos,

\par}{\phpg\posx870\pvpg\posy14577\absw7961\absh1665 \sl-280 \f10 \fs18 \cf1 lqui


dos y slidos, estando estos ltimos disueltos o suspendidos en los lquido
s. Adems se
\par}{\phpg\posx870\pvpg\posy14577\absw7961\absh1665 \sl-280 \f10 \fs18 \cf1 enc
uentran otras sustancias, consideradas impurezas, tales como compuestos
de azufre,
\par}{\phpg\posx870\pvpg\posy14577\absw7961\absh1665 \sl-280 \f10 \fs18 \cf1 oxge
no, nitrgeno, trazas de metales y sales de sodio, calcio y magnesio.
\par}{\phpg\posx870\pvpg\posy14577\absw7961\absh1665 \sl-174 \par\par\f10 \fs18
\cf1 \fi5056 {\b \fs12 \cf8 6 }\par
}
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a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28

a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28

a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028af30d43e2c78774ebfbdd3e7b2d69e6b0bb
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40051451400514514005145140051451400514514005145140051451400514514005145140051451
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}}\par}{\phpg\posx495\pvpg\posy169\absw767\absh204 \b \f10 \fs21 \cf0 \b \f10 \f
s21 \cf0 home \par
}
{\phpg\posx5968\pvpg\posy368\absw1736\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 La Refinacin del Petrleo \par
}
{\phpg\posx10416\pvpg\posy332\absw729\absh178 \b \f10 \fs16 \cf8 \b \f10 \fs16 \
cf8 TOMO I \par
}
{\phpg\posx3089\pvpg\posy1437\absw7961\absh1458 \f10 \fs18 \cf1 \fi566 \f10 \fs1
8 \cf1 Como impurezas se define todo aquel material contenido en el pe
trleo que no est
\par}{\phpg\posx3089\pvpg\posy1437\absw7961\absh1458 \sl-280 \f10 \fs18 \cf1 con
stituido solo por carbono e hidrgeno. En la actualidad se consideran d
os clases de
\par}{\phpg\posx3089\pvpg\posy1437\absw7961\absh1458 \sl-280 \f10 \fs18 \cf1 imp
urezas: oleofbicas y oleoflicas. Las primeras, insolubles en el
cuerpo del petrleo
\par}{\phpg\posx3089\pvpg\posy1437\absw7961\absh1458 \sl-280 \f10 \fs18 \cf1 con
stituido por hidrocarburos, forman una fase separada y deben ser lleva
das a lmites
\par}{\phpg\posx3089\pvpg\posy1437\absw7961\absh1458 \sl-280 \f10 \fs18 \cf1 tol
erables antes de proceder al procesamiento del petrleo. Las pri
ncipales impurezas
\par}{\phpg\posx3089\pvpg\posy1437\absw7961\absh1458 \sl-280 \f10 \fs18 \cf1 ole
ofbicas son: \par
}
{\phpg\posx3656\pvpg\posy3397\absw2521\absh954 \f10 \fs18 \cf1 \f10 \fs18 \cf1 I
MPUREZAS OLEOFOBICAS
\par}{\phpg\posx3656\pvpg\posy3397\absw2521\absh954 \sl-280 \f10 \fs18 \cf1 \fi5
66 Sales
\par}{\phpg\posx3656\pvpg\posy3397\absw2521\absh954 \sl-280 \f10 \fs18 \cf1 \fi5
66 Agua

\par}{\phpg\posx3656\pvpg\posy3397\absw2521\absh954 \sl-280 \f10 \fs18 \cf1 \fi5


66 Sedimentos \par
}
{\phpg\posx7357\pvpg\posy3397\absw2198\absh954 \f10 \fs18 \cf1 \f10 \fs18 \cf1 R
ANGO DE CONTENIDO
\par}{\phpg\posx7357\pvpg\posy3397\absw2198\absh954 \sl-280 \f10 \fs18 \cf1 \fi3
28 10
- 2000 gr/m3
\par}{\phpg\posx7357\pvpg\posy3397\absw2198\absh954 \sl-280 \f10 \fs18 \cf1 \fi4
50 0,1 5 Vol. %
\par}{\phpg\posx7357\pvpg\posy3397\absw2198\absh954 \sl-280 \f10 \fs18 \cf1 \fi4
50 1
- 1000 gr/ m3 \par
}
{\phpg\posx3089\pvpg\posy4797\absw7998\absh1457 \f10 \fs18 \cf1 \fi566 \f10 \fs1
8 \cf1 La influencia de las impurezas oleofbicas en el proceso tiene que ver con
la corrosin
\par}{\phpg\posx3089\pvpg\posy4797\absw7998\absh1457 \sl-280 \f10 \fs18 \cf1 de
los equipos y el ensuciamiento de los mismos, no afectando mayormente la calidad
de los
\par}{\phpg\posx3089\pvpg\posy4797\absw7998\absh1457 \sl-280 \f10 \fs18 \cf1 pro
ductos obtenidos, salvo los no destilados.
\par}{\phpg\posx3089\pvpg\posy4797\absw7998\absh1457 \sl-280 \f10 \fs18 \cf1 \fi
566 En lo que respecta a las impurezas oleoflicas, estas estn disueltas en los hid
rocarburos
\par}{\phpg\posx3089\pvpg\posy4797\absw7998\absh1457 \sl-279 \f10 \fs18 \cf1 y g
eneralmente afectan a los procesos de elaboracin, tanto como a los productos obte
nidos.
\par}{\phpg\posx3089\pvpg\posy4797\absw7998\absh1457 \sl-280 \f10 \fs18 \cf1 Los
constituyentes tpicos de este grupo son: \par
}
{\phpg\posx3656\pvpg\posy6757\absw2727\absh1205 \f10 \fs18 \cf1 \f10 \fs18 \cf1
IMPUREZAS OLEOFILICAS
\par}{\phpg\posx3656\pvpg\posy6757\absw2727\absh1205 \sl-280 \f10 \fs18 \cf1 Com
puestos de azufre
\par}{\phpg\posx3656\pvpg\posy6757\absw2727\absh1205 \sl-279 \f10 \fs18 \cf1 Com
puestos rgano - metlicos
\par}{\phpg\posx3656\pvpg\posy6757\absw2727\absh1205 \sl-280 \f10 \fs18 \cf1 Aci
dos naftnicos
\par}{\phpg\posx3656\pvpg\posy6757\absw2727\absh1205 \sl-280 \f10 \fs18 \cf1 Com
puestos de nitrgeno \par
}
{\phpg\posx7624\pvpg\posy6757\absw2198\absh198 \f10 \fs18 \cf1 \f10 \fs18 \cf1 R
ANGO DE CONTENIDO \par
}
{\phpg\posx7624\pvpg\posy7037\absw301\absh449 \f10 \fs18 \cf1 \f10 \fs18 \cf1 0,
1
\par}{\phpg\posx7624\pvpg\posy7037\absw301\absh449 \sl-279 \f10 \fs18 \cf1 5 \pa
r
}
{\phpg\posx8191\pvpg\posy7037\absw268\absh198 \f10 \fs18 \cf1 \f10 \fs18 \cf1 5 \par
}
{\phpg\posx8491\pvpg\posy7037\absw1636\absh198 \f10 \fs18 \cf1 \f10 \fs18 \cf1 %
en peso como S \par
}
{\phpg\posx8191\pvpg\posy7317\absw2194\absh198 \f10 \fs18 \cf1 \f10 \fs18 \cf1 400 ppm como el metal \par
}
{\phpg\posx7624\pvpg\posy7597\absw666\absh450 \f10 \fs18 \cf1 \f10 \fs18 \cf1 0,
03
\par}{\phpg\posx7624\pvpg\posy7597\absw666\absh450 \sl-280 \f10 \fs18 \cf1 0,05

- \par
}
{\phpg\posx8563\pvpg\posy7597\absw1172\absh450 \f10 \fs18 \cf1 \f10 \fs18 \cf1 0
,5 % en vol.
\par}{\phpg\posx8563\pvpg\posy7597\absw1172\absh450 \sl-280 \f10 \fs18 \cf1 1,5
% en vol. \par
}
{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \f10 \fs18 \cf1 \fi566 \f10 \fs1
8 \cf1 A diferencia de las oleofbicas, que son tratadas antes d
el procesamiento, las
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-279 \f10 \fs18 \cf1 imp
urezas oleoflicas deben tratarse durante el mismo, constituyendo
un problema
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 tec
nolgico que puede resultar de alto costo.
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 \fi
550 Puede considerarse que un 95 % del petrleo esta constituido por hi
drocarburos, o
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-279 \f10 \fs18 \cf1 sea
sustancias formadas por carbono e hidrgeno. Como es conocido los hidrocarburos h
an sido
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 cla
sificados en series, denominadas homlogas. Las tres series de l
a qumica orgnica:
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 sat
urados o parafnicos, no saturados o alifticos y los aromticos o bencnicos, se encuen
tran
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 pre
sentes en el petrleo (Fig.1)
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 \fi
566 Los saturados o parafnicos, denominados as por su poca reactividad,
conforman la
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-279 \f10 \fs18 \cf1 may
or parte de los hidrocarburos del petrleo. Dentro de un rango de variacin dado por
las
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 dis
tintas procedencias, puede decirse que un 50-70 % est constitui
do por esta serie,
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 cor
respondiendo la mayor parte a los naftnicos o cicloparafinas (Fig.2).
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 \fi
566 Es de destacar que a partir del butano se presenta la
posibilidad de ismeros,
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 hid
rocarburos de igual nmero de tomos de carbono pero distinta configuracin.
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 \fi
566 A medida que aumenta el peso molecular aumenta rpidamente e
l nmero de
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 isme
ros posibles, as para el octano se tiene dieciocho hidrocarburos diferentes. Los
primeros
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 cua
tro hidrocarburos parafnicos son gaseosos en condiciones ambientes
de presin y
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 tem
peratura, los intermedios son lquidos y los ms pesados slidos. Las isoparafinas de
igual
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-279 \f10 \fs18 \cf1 nmer
o de tomos de carbono, en general, tienen punto de ebullicin ms bajo q
ue las

\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 nor


males.
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 \fi
566 Los naftenos o cicloparafinas son hidrocarburos saturados, en los cuales los
tomos de
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 car
bono estn unidos formando anillos. Entre los primeros trminos se
encuentran el
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 cclo
pentano y el ciclohexano con sus derivados isomricos.
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 \fi
566 Las fracciones de petrleo de mas alto punto de ebullicin c
ontiene un elevado
\par}{\phpg\posx3089\pvpg\posy8437\absw8066\absh6245 \sl-280 \f10 \fs18 \cf1 por
centaje de hidrocarburos naftnicos, como puede observarse en la Fig.2. \par
}
{\phpg\posx5906\pvpg\posy16270\absw88\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 7 \par
}
\sect\sectd\pard\plain
\pgwsxn11900\pghsxn16840
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s16 \cf8 TOMO I \par
}
{\phpg\posx4220\pvpg\posy368\absw1736\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 La Refinacin del Petrleo \par
}
{\phpg\posx11093\pvpg\posy273\absw767\absh204 \b \f10 \fs21 \cf0 \b \f10 \fs21 \
cf0 home \par
}
{\phpg\posx870\pvpg\posy14204\absw7952\absh1206 \f10 \fs18 \cf1 \fi566 \f10 \fs1
8 \cf1 Los hidrocarburos no saturados, por su reactividad, no suelen en
contrarse en los
\par}{\phpg\posx870\pvpg\posy14204\absw7952\absh1206 \sl-280 \f10 \fs18 \cf1 pet
rleos naturales en cantidades apreciables, pero adquieren gran importanci
a durante el
\par}{\phpg\posx870\pvpg\posy14204\absw7952\absh1206 \sl-280 \f10 \fs18 \cf1 pro
cesamiento por ser formados en los procesos de refinacin. La rotura mo
lecular de una
\par}{\phpg\posx870\pvpg\posy14204\absw7952\absh1206 \sl-280 \f10 \fs18 \cf1 par
afina por la alta temperatura (pirolisis), puede producir una molcula n
o saturada y una
\par}{\phpg\posx870\pvpg\posy14204\absw7952\absh1206 \sl-280 \f10 \fs18 \cf1 sat
urada, segn: \par
}
{\phpg\posx5927\pvpg\posy16273\absw88\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 8 \par
}
\sect\sectd\pard\plain
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}}\par}{\phpg\posx495\pvpg\posy169\absw767\absh204 \b \f10 \fs21 \cf0 \b \f10 \f
s21 \cf0 home \par
}
{\phpg\posx5968\pvpg\posy368\absw1736\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 La Refinacin del Petrleo \par
}
{\phpg\posx10416\pvpg\posy332\absw729\absh178 \b \f10 \fs16 \cf8 \b \f10 \fs16 \
cf8 TOMO I \par
}
{\phpg\posx3089\pvpg\posy3457\absw7983\absh954 \f10 \fs18 \cf1 \fi566 \f10 \fs18
\cf1 Los no saturados de una doble ligadura se llaman olefinas, de d
os, diolefinas. Es de
\par}{\phpg\posx3089\pvpg\posy3457\absw7983\absh954 \sl-280 \f10 \fs18 \cf1 dest
acar que la reactividad del doble enlace hace poco probable la existe
ncia de poliolefinas
\par}{\phpg\posx3089\pvpg\posy3457\absw7983\absh954 \sl-280 \f10 \fs18 \cf1 supe
riores en el petrleo y fracciones producto de su refinacin. Las posibilidades de i
smeros
\par}{\phpg\posx3089\pvpg\posy3457\absw7983\absh954 \sl-280 \f10 \fs18 \cf1 entr
e las olefinas aumentan por la existencia de la isomera geomtrica, segn: \par
}
{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \f10 \fs18 \cf1 \fi566 \f10 \fs1
8 \cf1 La triple ligadura, hidrocarburos acetilnicos, hace an ms improbable la pres
encia de
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-280 \f10 \fs18 \cf1 est
os en petrleos y fracciones, por su gran reactividad qumica.
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-280 \f10 \fs18 \cf1 \fi
566 La tercer serie de hidrocarburos del petrleo la forman los
aromticos, llamados
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-279 \f10 \fs18 \cf1 tam
bin bencnicos por ser derivados del benceno. Constituyen una familia muy

numerosa
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-280 \f10 \fs18 \cf1 por
la formacin de sistemas de anillos condensados, estando presentes en las fraccio
nes ms
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-279 \f10 \fs18 \cf1 pes
adas del petrleo. (Fig.2)
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-280 \f10 \fs18 \cf1 \fi
566 En la Fig.2 se ha llamado a una de las reas residuo asfltico, esta zona corres
ponde a
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-280 \f10 \fs18 \cf1 hid
rocarburos de muy alto peso molecular, grandes molculas, cuya estructura
no puede
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-280 \f10 \fs18 \cf1 enc
asillarse en una sola serie, formados mayoritariamente por aromti
cos altamente
\par}{\phpg\posx3089\pvpg\posy7097\absw8033\absh2465 \sl-280 \f10 \fs18 \cf1 con
densados. \par
}
{\phpg\posx3089\pvpg\posy10419\absw403\absh217 \f20 \fs19 \cf1 \f20 \fs19 \cf1 1
.4. \par
}
{\phpg\posx3656\pvpg\posy10419\absw7477\absh718 \f20 \fs19 \cf1 \fi153 \f20 \fs1
9 \cf1 FISICOQUIMICA DEL PETROLEO. SISTEMAS MULTICOMPONENTES
\par}{\phpg\posx3656\pvpg\posy10419\absw7477\absh718 \sl-280 \par\f20 \fs19 \cf1
{\f10 \fs18 Las}{\f10 \fs18 propiedades}{\f10 \fs18 fisicoqumicas}{\f10 \fs18
de}{\f10 \fs18 los}{\f10 \fs18 petrleos}{\f10 \fs18 varan}{\f10 \fs18 con}{\f
10 \fs18 su}{\f10 \fs18 procedencia,}{\f10 \fs18 incluso}{\f10 \fs18 si}{\f1
0 \fs18 se }\par
}
{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \f10 \fs18 \cf1 \f10 \fs18 \cf1
trata de distintos pozos de un mismo yacimiento. La bibliografa especi
alizada habla de
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 hi
drocarburos de ms de 80 tomos de carbono presentes en los petrleos que, pensando en
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 la
cantidad de ismeros posibles y las series que puede haber involucrada
s, dan mezclas
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 su
mamente complejas.
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 \f
i566 En la TABLA 1 se muestra el anlisis qumico elemental (por elemento
) de algunos
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 pe
trleos, incluida la BASE de los mismos, tema que ms adelante se ver.
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 \f
i566 Cuando se habla de petrleo se menciona "mezcla compleja" de hidroc
arburos, no
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 ob
stante, nos parece ms apropiado hablar de un "sistema multicomponente", una soluc
in
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 id
eal donde los componentes no ejercen influencias fisicoqumicas mutuas y
la presin de
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 va
por de cada componente es proporcional a su fraccin molar en el lquido. Debemos te
ner
\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 en
cuenta que la formacin natural de hidrocarburos ha seguido las leyes de la termo
dinmica

\par}{\phpg\posx3089\pvpg\posy11277\absw8024\absh2970 \sl-280 \f10 \fs18 \cf1 y,


por lo tanto, la composicin no es caprichosa. \par
}
{\phpg\posx5906\pvpg\posy16270\absw88\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 9 \par
}
\sect\sectd\pard\plain
\pgwsxn11900\pghsxn16840
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s16 \cf8 TOMO I \par
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{\phpg\posx4220\pvpg\posy368\absw1736\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 La Refinacin del Petrleo \par
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{\phpg\posx11093\pvpg\posy273\absw767\absh204 \b \f10 \fs21 \cf0 \b \f10 \fs21 \
cf0 home \par
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{\phpg\posx1040\pvpg\posy8601\absw884\absh692 \b \f10 \fs18 \cf8 \b \f10 \fs18 \
cf8 TABLA 1
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8 {\b0 \f20 \fs14 \cf1 PETROLEO }\par
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{\phpg\posx2079\pvpg\posy8601\absw4422\absh198 \f20 \fs18 \cf8 \f20 \fs18 \cf8 A
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9 H
N
0 \par
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\par
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\par
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{\phpg\posx1040\pvpg\posy10037\absw1173\absh1166 \f20 \fs14 \cf1 \f20 \fs14 \cf1
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{\phpg\posx7690\pvpg\posy11157\absw920\absh158 \f20 \fs14 \cf1 \f20 \fs14 \cf1 N
AFTENICA \par
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{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \f10 \fs18 \cf1 \fi566 \f10 \fs1
8 \cf1 Tratando al petrleo como un sistema multicomponente de hidrocarbur
os y dada la
\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 pro
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su tratamiento
\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 tec
nolgico.

\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 \fi


566 En la TABLA 2 se dan algunas constantes fsicas de hidrocarburos se
leccionados por
\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 raz
ones didcticas, con estos datos se ha construido la Fig.3(superior). Puede observ
arse en la
\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 fig
ura que las curvas Densidad - Temperatura de cada serie cumplen con
la homologa
\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 esp
erada (cambio gradual de propiedades fisicoqumicas con el peso molecular
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\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 par
afnicos, naftnicos y aromticos en forma escalonada.
\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 \fi
566 Si bien las curvas de la Fig.3 (superior) han sido construidas para hidrocar
buros puros,
\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 el
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smas constantes en
\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 sis
temas complejos como los multicomponentes. Este tipo de correlaciones p
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\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-280 \f10 \fs18 \cf1 las
mezclas como si fueran sustancias puras, utilizando anlisis de laborat
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\par}{\phpg\posx870\pvpg\posy11961\absw8051\absh3474 \sl-279 \f10 \fs18 \cf1 imp
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e,
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a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28a0028a28
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2800a28a2800a28a2800a28a2800a28a2800a28a2800a28a2803ffd9
}}\par}{\phpg\posx495\pvpg\posy169\absw767\absh204 \b \f10 \fs21 \cf0 \b \f10 \f
s21 \cf0 home \par
}
{\phpg\posx5968\pvpg\posy368\absw1736\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12 \
cf8 La Refinacin del Petrleo \par
}
{\phpg\posx10416\pvpg\posy332\absw729\absh178 \b \f10 \fs16 \cf8 \b \f10 \fs16 \
cf8 TOMO I \par
}
{\phpg\posx3089\pvpg\posy1437\absw8039\absh1458 \f10 \fs18 \cf1 \fi566 \f10 \fs1
8 \cf1 Estas correlaciones en sistemas complejos son ms importantes en l
a tcnica que las
\par}{\phpg\posx3089\pvpg\posy1437\absw8039\absh1458 \sl-280 \f10 \fs18 \cf1 det
erminaciones exactas que puedan hacerse de todos los hidrocarburos presentes, si
endo de
\par}{\phpg\posx3089\pvpg\posy1437\absw8039\absh1458 \sl-280 \f10 \fs18 \cf1 gra
n importancia que los ensayos estn normalizados para garantizar que sean reproduc
ibles
\par}{\phpg\posx3089\pvpg\posy1437\absw8039\absh1458 \sl-280 \f10 \fs18 \cf1 por
distintos tcnicos y laboratorios.
\par}{\phpg\posx3089\pvpg\posy1437\absw8039\absh1458 \sl-278 \par\f10 \fs18 \cf1
\fi173 {\f20 \cf8 TABLA}{\f20 \cf8 2}{\f20 \cf8
CONSTANTES}{\f20 \cf8
FISICAS}{\f20 \cf8 DE}{\f20 \cf8 HIDROCARBUROS }\par
}
{\phpg\posx3261\pvpg\posy3431\absw1239\absh158 \f20 \fs14 \cf1 \f20 \fs14 \cf1 H
IDROCARBURO \par
}
{\phpg\posx5926\pvpg\posy3431\absw824\absh410 \f20 \fs14 \cf1 \f20 \fs14 \cf1 DE
NSIDAD
\par}{\phpg\posx5926\pvpg\posy3431\absw824\absh410 \sl-280 \f20 \fs14 \cf1 15/15
C \par
}
{\phpg\posx7626\pvpg\posy3431\absw984\absh410 \f20 \fs14 \cf1 \f20 \fs14 \cf1 PE
SO
\par}{\phpg\posx7626\pvpg\posy3431\absw984\absh410 \sl-280 \f20 \fs14 \cf1 MOLEC
ULAR \par
}
{\phpg\posx9325\pvpg\posy3431\absw800\absh412 \f20 \fs14 \cf1 \f20 \fs14 \cf1 PU
NTO DE
\par}{\phpg\posx9325\pvpg\posy3431\absw800\absh412 \sl-282 \f20 \fs14 \cf1 EBULL
.C \par
}
{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \f20 \fs14 \cf1 \f20 \fs14 \cf1
PARAFINICOS
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi
370 Hexano
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi
370 Octano
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi
370 Decano
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi

370 Dodecano
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 CIC
LOALCANOS
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi
370 Ciclobutano
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi
370 Ciclohexano
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi
370 Ciclooctano
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 ARO
MATICOS
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi
370 Benceno
\par}{\phpg\posx3259\pvpg\posy3993\absw1276\absh2930 \sl-280 \f20 \fs14 \cf1 \fi
370 Naftaleno \par
}
{\phpg\posx6090\pvpg\posy4273\absw400\absh914 \f20 \fs14 \cf1 \f20 \fs14 \cf1 0,
664
\par}{\phpg\posx6090\pvpg\posy4273\absw400\absh914 \sl-280 \f20 \fs14 \cf1 0,703
\par}{\phpg\posx6090\pvpg\posy4273\absw400\absh914 \sl-280 \f20 \fs14 \cf1 0,730
\par}{\phpg\posx6090\pvpg\posy4273\absw400\absh914
\par
}
{\phpg\posx7694\pvpg\posy4273\absw578\absh914 \f20
cf1 86,172
\par}{\phpg\posx7694\pvpg\posy4273\absw578\absh914
24
\par}{\phpg\posx7694\pvpg\posy4273\absw578\absh914
76
\par}{\phpg\posx7694\pvpg\posy4273\absw578\absh914
28 \par
}
{\phpg\posx9508\pvpg\posy4273\absw400\absh914 \f20
cf1 68,7
\par}{\phpg\posx9508\pvpg\posy4273\absw400\absh914

\sl-280 \f20 \fs14 \cf1 0,749


\fs14 \cf1 \fi88 \f20 \fs14 \
\sl-280 \f20 \fs14 \cf1 114,2
\sl-280 \f20 \fs14 \cf1 142,2
\sl-280 \f20 \fs14 \cf1 170,3
\fs14 \cf1 \fi88 \f20 \fs14 \
\sl-280 \f20 \fs14 \cf1 125,6

\par}{\phpg\posx9508\pvpg\posy4273\absw400\absh914 \sl-280 \f20 \fs14 \cf1 174.0


\par}{\phpg\posx9508\pvpg\posy4273\absw400\absh914 \sl-280 \f20 \fs14 \cf1 216,2
\par
}
{\phpg\posx6090\pvpg\posy5673\absw400\absh662 \f20 \fs14 \cf1 \f20 \fs14 \cf1 0,
703
\par}{\phpg\posx6090\pvpg\posy5673\absw400\absh662 \sl-280 \f20 \fs14 \cf1 0,778
\par}{\phpg\posx6090\pvpg\posy5673\absw400\absh662
\par
}
{\phpg\posx7694\pvpg\posy5673\absw578\absh662 \f20
cf1 56,104
\par}{\phpg\posx7694\pvpg\posy5673\absw578\absh662
84,156
\par}{\phpg\posx7694\pvpg\posy5673\absw578\absh662
08 \par
}
{\phpg\posx9508\pvpg\posy5673\absw400\absh662 \f20
cf1 12,9
\par}{\phpg\posx9508\pvpg\posy5673\absw400\absh662

\sl-280 \f20 \fs14 \cf1 0,839


\fs14 \cf1 \fi88 \f20 \fs14 \
\sl-280 \f20 \fs14 \cf1 \fi88
\sl-280 \f20 \fs14 \cf1 112,2
\fs14 \cf1 \fi88 \f20 \fs14 \
\sl-280 \f20 \fs14 \cf1 \fi88

80,8
\par}{\phpg\posx9508\pvpg\posy5673\absw400\absh662 \sl-280 \f20 \fs14 \cf1 146,0
\par
}
{\phpg\posx6090\pvpg\posy6793\absw400\absh410 \f20 \fs14 \cf1 \f20 \fs14 \cf1 0,
879
\par}{\phpg\posx6090\pvpg\posy6793\absw400\absh410 \sl-280 \f20 \fs14 \cf1 0,962
\par
}
{\phpg\posx7694\pvpg\posy6793\absw578\absh410 \f20 \fs14 \cf1 \fi88 \f20 \fs14 \
cf1 78,108
\par}{\phpg\posx7694\pvpg\posy6793\absw578\absh410 \sl-280 \f20 \fs14 \cf1 128,1
64 \par
}
{\phpg\posx9508\pvpg\posy6793\absw400\absh410 \f20 \fs14 \cf1 \fi88 \f20 \fs14 \
cf1 80,1
\par}{\phpg\posx9508\pvpg\posy6793\absw400\absh410 \sl-280 \f20 \fs14 \cf1 218,0
\par
}
{\phpg\posx3089\pvpg\posy7597\absw7951\absh702 \f10 \fs18 \cf1 \fi566 \f10 \fs18
\cf1 La representacin de un nmero suficiente de hidrocarburos puros mejo
rara la Fig.3,
\par}{\phpg\posx3089\pvpg\posy7597\absw7951\absh702 \sl-280 \f10 \fs18 \cf1 tngas
e en cuenta que solo se han graficado unos pocos a modo de demostracin, pudiendo
\par}{\phpg\posx3089\pvpg\posy7597\absw7951\absh702 \sl-280 \f10 \fs18 \cf1 saca
rse no obstante las siguientes relaciones primarias: \par
}
{\phpg\posx3656\pvpg\posy8714\absw76\absh1208 \f10 \fs18 \cf1 {\cf1 \f0\fs23 \bu
llet }\f10 \fs18 \cf1
\par}{\phpg\posx3656\pvpg\posy8714\absw76\absh1208 \sl-281 \par\f10 \fs18 \cf1 {
\cf1 \f0\fs23 \bullet }
\par}{\phpg\posx3656\pvpg\posy8714\absw76\absh1208 \sl-280 \par\f10 \fs18 \cf1 {
\cf1 \f0\fs23 \bullet } \par
}
{\phpg\posx3967\pvpg\posy8717\absw7115\absh1710 \f10 \fs18 \cf1 \f10 \fs18 \cf1
Los puntos en el plano
"densidad - punto de ebullicin"
de las n-p
arafinas,
\par}{\phpg\posx3967\pvpg\posy8717\absw7115\absh1710 \sl-280 \f10 \fs18 \cf1 naf
tnicos y aromticos sin cadena lateral, se ubican sobre tres curvas regulares.
\par}{\phpg\posx3967\pvpg\posy8717\absw7115\absh1710 \sl-280 \f10 \fs18 \cf1 Las
parafinas ramificadas, isoparafinas, cubren una regin cercana a la curva de las
\par}{\phpg\posx3967\pvpg\posy8717\absw7115\absh1710 \sl-280 \f10 \fs18 \cf1 n-p
arafinas en el rea entre estas ltimas y los naftnicos.
\par}{\phpg\posx3967\pvpg\posy8717\absw7115\absh1710 \sl-280 \f10 \fs18 \cf1 Los
alquilbencenos, naciendo en la curva de los aromticos segn el
ncleo
\par}{\phpg\posx3967\pvpg\posy8717\absw7115\absh1710 \sl-280 \f10 \fs18 \cf1 ben
cnico que les corresponda, tendern a correrse hacia la curva de las parafinas
\par}{\phpg\posx3967\pvpg\posy8717\absw7115\absh1710 \sl-280 \f10 \fs18 \cf1 a m
edida que el grupo alquilo crezca. Lo mismo ocurrir con las alquilcicloparafinas.
\par
}
{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \f10 \fs18 \cf1 \fi566 \f10 \fs
18 \cf1 A las curvas densidad - punto de ebullicin puede superponerse,
por interpolacin
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 grf
ica, los puntos de los pesos moleculares de los mismos hidrocarburos representad
os (Fig.3,
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 in
ferior), se podr observar que se forma un haz de curvas que cortan a

las anterior, que


\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 pr
esentan una cierta regularidad. Esta regularidad permite determinar tcnic
amente el peso
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-279 \f10 \fs18 \cf1 mo
lecular, conociendo la densidad y el punto de ebullicin de un
hidrocarburo real o
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 hi
pottico desconocido.
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 \f
i566 Hemos mencionado que entre densidad, punto de ebullicin y peso mol
ecular se ha
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 es
tablecido una correlacin, que en este caso ha sido grfica. Se trata de haber deter
minado
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 un
a funcin, del tipo F(D,Te;M) = 0 que vincula a todos los hidrocarburos.
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 \f
i566 Anlogamente es posible correlacionar otras propiedades intensivas (que no de
penden
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 de
la cantidad de sustancia) como viscosidad, ndice de refraccin, etc..
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 \f
i566 Correlaciones como las estudiadas son de gran importancia e
n la tecnologa del
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 pe
trleo, como luego se ver, por el momento podemos establecer como conclusin que los
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 hi
drocarburos solo pueden estar representados por puntos entre las curvas de las p
arafinas y
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 lo
s aromticos. Un compuesto cuyas propiedades lo ubican fuera de esa rea,
no sera un
\par}{\phpg\posx3089\pvpg\posy10957\absw7989\absh3977 \sl-280 \f10 \fs18 \cf1 hi
drocarburo. \par
}
{\phpg\posx5867\pvpg\posy16270\absw168\absh138 \b \f10 \fs12 \cf8 \b \f10 \fs12
\cf8 11 \par
}
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