Sistema:

Metanol(A)

Agua(B)

DIAGRAMA T-x,y a Presin constant

8.07131
1730.63
233.426

Ingrese la Presin, mmMercurio

Constantes de A

A1

7.87863

presin en KiloP

A2
A3

1473.11
230

lnP sat A1

A2
T A3

A12
A21

xA

P B PvB
A PvA B PvB

yA

A PvA
xA
P

0.7923
0.5434

DIAGRAMA P-x,y a Temperatura constan

Ingrese la Temperatura en C =

En mmHg

GRAMA T-x,y a Presin constante

rese la Presin, mmMercurio, =

TsA=
TsB=

1200 1.5789473684 atm

76.9331658 puro
113.245748 puro

A
B
T C
PsA
PsB
xAsupuesto
113.24574772 3862.9894249
1200
1.89E-06 2.20846137
1
111.48374772 3670.9546497 1131.562491
0.010167209 2.16260194 1.00013285
109.72174772 3486.6215509 1066.3847769
0.021512377 2.11345718 1.00059225
107.95974772 3309.7660664 1004.3460406
0.034230169 2.06079951 1.00149276
106.19774772 3140.1675224 945.3284076
0.048604421 2.0042155 1.00299504
104.43574772 2977.6086698 889.21692861
0.064933663 1.94348804 1.00531735
102.67374772 2821.875718 835.89956068
0.083630404 1.87828951 1.00877008
100.91174772 2672.7583671 785.26714679
0.105626238 1.80706631 1.01390264
99.149747725 2530.0498383 737.21339417
0.130280747 1.73368424 1.02101394
97.387747725 2393.5469021 691.63485126
0.160072861 1.65323576 1.03150084
95.625747725 2263.0499042 648.43088329
0.195106331 1.56889644 1.04645933
93.863747725
2138.36279 607.50364656
0.237297714 1.48019896 1.06822036
92.101747725 2019.2931264 568.75806149
0.287475791 1.39039804 1.09942828
90.339747725 1905.6521215 532.10178427
0.347283739 1.30199499 1.14424347
88.577747725 1797.2546421 497.44517736
0.41827989 1.21853798 1.2083837
86.815747725 1693.9192295 464.70127874
0.499514839 1.14588156 1.29674251
85.053747725 1595.468112 433.78576998
0.5893538838 1.08777349 1.41368335
83.291747725 1501.7272161 404.61694314
0.687007031 1.04510173 1.56437549
81.529747725 1412.5261749 377.11566654
0.789125252 1.01792256 1.74848364
79.767747725 1327.6983341 351.20534941
0.893254629 1.00396904 1.96320452
76.93316577
1200 312.67501641
1.000056465
1 2.2086056

GRAMA P-x,y a Temperatura constante

ese la Temperatura en C =
PsA=
PsB=
P mmHg

369.16186132
418.3670107
467.57216008
516.77730946
565.98245884
615.18760822
664.3927576
713.59790698
762.80305636
812.00820574

81
1386.5703115778 puro
369.161861 puro

A
B
PsA
PsB
xAsupuesto
1386.5703116 369.16186132
1.00E-06 1.34245417
1
1386.5703116 369.16186132
0.034673937 1.31578194 1.00123182
1386.5703116 369.16186132
0.070505677 1.28973417 1.00501391
1386.5703116 369.16186132
0.107543596
1.264356 1.01148845
1386.5703116 369.16186132
0.145840209 1.23969322 1.0208152
1386.5703116 369.16186132
0.1854537 1.21579299 1.0331733
1386.5703116 369.16186132
0.226055332 1.1929183 1.04860002
1386.5703116 369.16186132
0.269632569 1.1701092 1.06816133
1386.5703116 369.16186132
0.313921862 1.14868992 1.09112264
1386.5703116 369.16186132
0.359888906 1.12825149 1.11812412

861.21335512
910.4185045
959.62365388
1008.8288033
1058.0339526
1107.239102
1156.4442514
1205.6494008
1254.8545502
1304.0596995
1386.5703116

1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132
1386.5703116 369.16186132

0.407398212
0.45724502
0.509172972
0.562571459
0.618522112
0.676805455
0.737476623
0.800495754
0.865645638
0.93237087
1.000002

1.10895884
1.0906291
1.07352577
1.05796868
1.04378886
1.03123995
1.02050388
1.01179064
1.0053302
1.00134786
1

1.14929826
1.18542141
1.2265748
1.27238669
1.32384208
1.38072582
1.4428428
1.50960257
1.57981833
1.65144753
1.72185324

Temperatura Liquido
100
96.4
93.5
91.2
89.3
87.7
84.4
81.7
78
75.3
73.1
71.2
69.3
67.5
66
65
64.5

Vapor
0
0.02
0.04
0.06
0.08
0.1
0.15
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.95
1

0
0.134
0.23
0.304
0.365
0.418
0.517
0.579
0.665
0.729
0.779
0.825
0.87
0.915
0.958
0.979
1

Temperatura
100
96.4
93.5
91.2
89.3
87.7
84.4
81.7
78
75.3
73.1
71.2
69.3
67.5
66
65
64.5

Raoult-Dalton
xA calculado yA
xA
yA
-7.56624E-013 1.34559E-005
0
0
0.0100317576 0.0672629814 0.02695035 0.0824446
0.0211024567 0.1321007906 0.0552075 0.16040638
0.0333890649 0.1945632622 0.08486695 0.23407478
0.0471133498 0.2549128694 0.11603201 0.30363329
0.0625494977 0.3131397129 0.14881455 0.36925957
0.0800457712 0.3693884948 0.18333576 0.4311256
0.1001112763 0.4251325464 0.21972704 0.48939773
0.123099558 0.4762095179 0.25813097 0.54423684
0.1500082493 0.5278532425 0.29870236 0.59579843
0.1815652377 0.577269385 0.34160945 0.6442327
0.2189970091 0.6259127408 0.38703519 0.6896847
0.2633405151 0.6726026068 0.43517868 0.73229444
0.3157332813 0.7180524009 0.48625682 0.77219695
0.3769201476 0.7633688304 0.54050601 0.80952244
0.4463444503 0.807978075 0.59818417 0.84439639
0.5228359784 0.8523569398 0.65957293 0.87693965
0.6054845935 0.898523738 0.72498005 0.90726856
0.6944714569 0.9455313674 0.79474211 0.93549503
0.793361093 0.9922332143 0.8692276 0.96172669
0.9999999978 1.0000564659
1
1

Raoult-Dalton
xA calculado
yA
xA
yA
-2.57582E-013 5.04225E-006
0
0
0.0335098665 0.1512068769 0.04836322 0.16028751
0.0681293594 0.2696606313 0.09672644 0.28683917
0.1039158776 0.3648315491 0.14508966 0.38929151
0.1409282717 0.4429252402 0.19345288 0.47392992
0.17922726 0.5081939096 0.2418161 0.54502891
0.2188618367 0.5627849352 0.29017932 0.60559666
0.2599705069 0.6130375424 0.33854254 0.65781168
0.3025384909 0.6554715488 0.38690577 0.70329037
0.3466729717 0.6933553239 0.43526899 0.74325733

0.3924439865
0.439974545
0.4893424846
0.5406089371
0.5939255297
0.6493629343
0.7069713481
0.7667192621
0.8284229894
0.8916527451
1

0.7273872529
0.7594984389
0.7898029791
0.8180407331
0.8460775638
0.874025417
0.9023605785
0.9314736049
0.9616064823
0.9927001664
1.000002

0.48363221
0.53199543
0.58035865
0.62872187
0.67708509
0.72544831
0.77381153
0.82217475
0.87053797
0.91890119
1

0.77865729
0.81023075
0.83856632
0.86413777
0.88733077
0.9084624
0.92779578
0.94555109
0.96191396
0.97704201
1

T vs X,Y

Liquido
Vapor
Liquido ideal
Vapor ideal

P vs X,Y

Liquido
Vapor
Liquido ideal
Vapor ideal

Liquido
Vapor
Liquido ideal
Vapor ideal

25

Liquido
Vapor
Liquido ideal
Vapor ideal

Liquido
Vapor
Liquido ideal
Vapor ideal

Liquido
Vapor
Liquido ideal
Vapor ideal

25