>
Dos, Dr. Associate Professor Jale Gillen
“ie Tei Unies ieee Uniesty
Kiya tchra lun
camel Engine Depart
Prot. Dr. Hanifi Sarac
‘ie Tk Onate Ya cit ue
Orme Engen Deane
irem Ozgindiz
Kiya Mohends Chemical Fairer
Bor Elementi ve Tasitlarda Kullanimi
Charasteristics of Boron and Usage in Vehicles
1. Boe
for element olarak yryazunde yaygn olarak bulunan bi
tementti Deniz sujunda 0'5 ppm 0.8 ppm, tt sularda
tee 0.01-15 pom aralgndaar.Yoksekkonsantasyonda
‘e ekonomik boptlsdah bor yatalin, borun oxnie
baglonmg bleyer olaak daha ok Turkiye ve ABD'ée
bulunmaktadt
or patyodik tablada 8 simgesi de gésteten, atom mux
tara 3, atom kites 10.8 yogunlugu 284 lem, ere
hoktae S2008C ve kayrama nokta: 3660°C aah metale
“metal ars yarimetlGzlleere sahpbirelementi.Kat-
ierumaraan 10 ve 11 olan Karat totoptan ous. Bor
testa iten sya ren set ve at Madea Amor! dura
ta ee tz halde ve sah enki Bor tbitta serbest ha:
te bulinmaz, Bor element dogada 150'den fsa minera
In yap nde yer slmasina gen, ekonomi alamda
borminesllerkasiyum, sodyum, mognezyum dementler
ie dat bese: halinde blunt. Bor mineralle a
Yeleindedegihoranarda bor obs (8,0) eren miner
{Er elup, dryads bor element apsayan yslrce mineral
‘ulunmasina rage tat Sneme ship ololan ok adit
Bor mineralleinin ten’ degere sah olanan tinea (bo
‘aks Folemanit,oleksit robert, pander, hidroborast
‘ket (1. Boe mineral nde tear clrak en faz
Is Snem tajjon botatlara Bunardan bores dogada
‘yg lak bulunasu ve kullarum alanar faci ous
eden ile geek ends, gorekse madenclixteboraks bor
‘alan yerine kllanimakiadr
2. Bor Element kel ve KimyasalSzalitier
Bor 34 grubunn tek smetal lament olup, metaller ve
‘metal oranda. Szlinlere sahil. Bor comentinin
ze! durum borun Kuck bir atom olmasindan kayak
lan, Borda sadace deQerikeektroniann ainda bulunan
Korba varken grubun otk ayelerine lave bir orbital
bulunur Bor stom grabun sige aylerinden daha ki
‘ikolupelektroniann vzakigtrmakgn dana faa ener
(ever Bor elektvonlarin gk si uttagu ign bse
{de +3 dager yon hainde bulunmaktan zvade, Kove-
lant baglar olstrur. Gununia beraer Biegler +3
‘eget oléukian fabul eli (1. Bor stomu cok kagok
‘sldugundan 8 Sonu sya Fonuldugunda, sujun elke
ronlannkenisine dogs kawelle cekerek OF baglarrin
1.Boron
‘Baron san commen element on the earth. The ange 0.5
ppm to 06 ppm ond 0.01 to 1-5 ppm nssaviater and fresh
Water, respective. The boron deposts having ecnomic
Importance, igh concentration and ongen bound ones
‘re mostly foul i Turkey and ABD.
Baron isan element which shown vith 8 symbal in the
period fable ts afomic number atomic weights 10.8
‘ens ie 284g melting points 200°, bating point
{3660 and aso i an element has semimeta reper
thes Bebweem meta and nonmetal Baron occu frm two
‘abl topes having 10 and 11 mass number. Cystine
Doran i black rd and sos but amerphous one & bron
powrder state Boron isnot found re in nature Insp of
having boron element inte stuctre af over 150 mineral
fn'natore, economical important boron minerals ving
frehyste compounds of cae, magnesium and sod
tlements. The boran minerals contans diferent Bropor
tions of boron orden ther sructare. Eventhough there
Ste hundreds of miner! that contain boron elerant i the
word only 2 few of them hove conmeral importance
‘hese are ncale bora), colemaite, ult robert, par
dlermite,bidroboracte, kere [1 The mest commeres
Important ones are borates The Goran uaed nteod of
bron sts nducry and mining ecae ofthe more
‘sage areas ad presence of widespread in nature.
2, Physica and Chemical Properties of Boron Element
The Doron which i the only nonmealic element of 24
‘groups have properties between metals and nonmetal:
‘he special cae of boven is based on smal atom. Bor
has only & orbital wich include valnce electrons but the
ther members ofthe group include an atone! ora
Boron atom i mar than othe” mombers of te Gru.
‘Due tothe more energy requ to remove electrons
boron Keep electron ery Highly. Fortis veason i fos
covalent bond instead of forming asa 3+ charge fon
‘Compounds butt ir accepted that thas 3+ charges incor
pounds Dye to small Bran atom, 8 ions i wete ead
{fo bresk the OH bonds and release Hons by pulling the
Inoter electron tonarae Rol So B(OH, and 8,0, ae
{see fons 1.$$ NGS
kopmasin, doll” iyonun serbest kalmasinasebep
lr. Yai BIOH}, ve ,0, beg asi.
2.1 Borun Fao Orel
Kat aide bor cok sere alup kinlganelr. or gig ola
fake donck bir metal paleikta op, ele 9 Het
ez. or iy etken ol seal arts fete a
tar Yan letenik su gekie agitanabili. Oda stag
‘lektronar merken cekidege aks balan olyp set
hale gegmeler guctr. iealak artic serbest Male gege
rel kstal igersinde harekete gegelr Stak yokes
‘elastal dongisinan tiuesmininortmasindan doy di
eng ars da serbest hale gecen sexton says ncn
‘madden etter artar hh
2.2 Borun KimyasalOrliker
imyasal olarak aluminyum, galyum, nyu ve taj
ddan daha cok slsyum ve karbona yn, Raton vs
"isyum gi Kovalont, motekaler bey oluyturmaya bile
biregim almski bite, degetikc orbital saysindan bit
‘kik deer elektronuna sahip ola kabon ve sis
suman fartik dsr
Boru kimyasa ki safhgina, krista yopisina ve sca
4 bag Oda seakiguda sadecs for gia reason
Verve kimyasl olarak olsen le aton, igor durum
Tanda inert bt mace.
Yoksek scalars asl galar ve H, Ge, Te harg bata
metal dogiudan reason vert Bor alt grubundle
motte har, yneyalsekeakakardaMemen heme Bo-
tun metal foaykaralayon vor.
Kista hall bor kiyasal olarak inert olup kaynamalta
olan HF ve HCIye kar dren. Sodsce ince xe
gutulddunde, tak derigh mtik ast taraindan yous
Dir sete even
Bununla irik bax ortamd br yoksligen ie tii
da, borat vermek uzee lanyasal danagume oar. Gena
ile dagids tek sina dei, bapa clemertrebilter
halide blur
Beruninorganik Kinyasiin period tablodaki herhangi
birlomentekinden cok dahe cept ve karma lug =
dis eemetedr.Gevetten de son yilaa Gok cet J3-
psa per ve bad tpi kefeimeye baglanmigtr. Sonn
Kimyasal daar basica kucak caps ve yaksok yong
ener ie burnt. Bu Gzlilere irkte 8, Cve Win
clektronegatfilerindel benzeril cok sayda ve am
gn dgnda kovalent begirolismasey saga. Kovalent
blesige orbitals, px, pyve paren sadece 3 elltron-
i tbe bulunabimes, bora letron eit as olmas
ri Lewis asi ve cok merkedh baglnmayt salayan fave
bzaltierkazande.Oksjene ylksek igs gerbe bet:
gin ozeligi (1.
a
Makale/ Article jm im Ol ial
2.1 Physial Properties of Boron
Sakd boron is very hard and fragile. The appearance of
boron s dll metal ister and not» good conductor of
‘tect. Boron is semiconductor and Ws conduct
“reotes asthe tomporture increases. Semicondting cn
‘Be exaaned as flows At room temperature alactrns ore
tight bound to the coral core andi iff 0 be
come free a5 the temperature increases, becomes fee
‘nd mobies inthe cyst stucture, Even though becase
of augmentation of vation of the ext ope, the Te
Sistance increases, 3t the same tine the conditvy oF
‘material increases 2 the amber of ekectrons become hse
Increases 1
2.2 Chemical Properties of Boron
chomally boron mare closet sium and carbon than
‘aluminium, galfuny nam and thal, tant form
{ovalent bond and molecular compounds sich 23 carbon
‘and scum but ako aferent due t having valence eee
irons one less than the vance oral 1.
The chemical acy of boron dependsan the cyst suc
ture, purty and temperature. only reocts nih the fuorne
{928 a oom temperature and chemically affected by 0)
‘en butin other eves its an nee mater,
Boron reacts lect with inert gs and all nonmetal x
cept He, Te and abo rect easly wth almost al metals
except subgroup meta atthe high temperature,
Chemically cystine boron s inert and resistant 0 bolt
lng Wr and Hl. Only when it grinds ula fine, ly
‘affected by the hot concentrated nite aid,
Hooever, win it heated with an oxidant in basic me-
‘dum, gives chensealconvesion form borate Usual
‘snot found aloe nature, 8 found compounds vith
‘other eements|
{eis aimed hat inorganie chemistry of bron is more ane
‘onal and complated than any ekement inthe periodic
{able ded, In recent year very various structures and
bond types have begun fo be cscovered. The chem be
havior f the boron is detennined by minor damster
‘and high fonization energy. However, due tothe sian
Inelecronegatity of Cand prov Tor age
‘numberof eval compound nasal.
That boron contributes f covalent compounds with the
four oral s x.y, near only thre slactrns gain a
tional properties such as being acceptor electron pair ews
2k) and multicenter boning areas. The high interest to
‘eigen an another pal characteristics of born 1}
3 Boron Products
‘Concentrated boron products
2 Get,
|| MM Makale / Article
+ bor dren
ok at, boraks pants hdr, bocaks deka hia
ibor A sym per borat telrahicrat, sodyum et
sat mane ha, usu bral, bor ks 2.
nyada bor eezerver
sevetnde kin tayrak ake ABD olup, enya re-
inn S113 nna ir pay var. Anca ABD bora
camandirendosrnin cept lnlainda llr
tndan, olen gelecelte bor rezerveinin takenme=
ies le Kary kariods. BU nadenle ABD Kalan bor
ein bi Ks tata rezer an ederekgkan-
3 durdurmutur Turkije’ dek bor rezersinin ta
Bo'dakinden yoleeti, Dany bor rezerdetnin Kalan
Rusya, Sl, Bola, Per, Anti, Sebista da
soak. Dunyada stan toplem 496 mibon to
zewin 375 min ton Tarkiy dedi Dunyada let
tain een bor maden ezervrinin miktaronna
agi) agaidattabloda veri).
+ colemante,
Rafined boron products
Bove a, Borax penta, Borax decahyeat,
baron 48 Soc perborate tevanyaate Sodium Per
borate monohydrate, Borax ankyane, Boron ox (2
4. Boron reserves In the word
Usa where the second resource county fr baron eserves
has share of anost 13% In th world reserves. But, USA
has used boron in various fel of ust fra ong tine
Because of the faced wit the danger of depletion of
Doran inthe near future. 50 USA stopped to removal of
‘the remaining boro reserves by announcing a sates re
Serve The quot ofthe boron reserve in Turkey s higher
than in Americ. Te remaining words Boron reserves are
‘eit in Rusia, Cana, Chile, Bola, Per, Argentina and
Serie 375 milion tons out of 496 millon tons reserves it
the woad are exis in Turkey. The amount ofthe dstnbu-
tion of Boron rezerer operated and estimated inthe world
tegen inthe following table [3
Table 1. The variations of boron reserves in the word (4)
Country "Toa Revew | Toval Reerw
blo 1. Dinyadai bor vezeverinindapimlan Bin on B:0:) | (%B:04)
ie Toplam Toplam Tukey R500 73
Rezerv Reve
(inwon | @%6B:0) | [ABD. OOO e
B03)
rkiye 885 000 73 Rusia aon 2
BD. 80000 65 China FO 38
sya 35000 28
‘Argentina 3000 oF
a 47/000 38
jaatin 000 07 Bolivia 19000 1s
ya 19000 15 Chili 41 000 33
i 41000 33 : saa =
mu 22000 18 :
zakisian | 102 000 82 Kazakhstan [102 000 a
= = Serbia = =
1000 a
1241 000 100 aS 000 o
Toad THAT 000 700_
ah
jan
F a Makale / Article
5-Tarhiy' deh Bor Rezerer
7
“Turkiye dry bor rezernin°872sine sahip olmakla bir
Ite, bu miktan azerindebagka bor maderzrin vagina
da sahip oldugu dusunalmestedi- Yaplan hesoplamalar
Trkiye'detverenin Gran 400 yi edujunu goster-
rmekteir.Ancak dunyadak! pak cok rezervin yak gel
{ke takonecei thin edimetede (ABD 8 i ib ine
[ABD‘de bor gkarabimek icin 400 meteyevaren maden
faalan kaemak gere ken, Tokijede ie topragin 30
metre altnda bore asanabiimettei (5,
Trke'de Bursa, Bales, Eskgeir ve Kitahya'da gens
bor yatalan meveuttr. Taree bor rezerver gag
sk tobi goruimelte,
Tablo 2 Torkiye bor rezererinin made sahalanna
5 Boron Reserves in Turkey
Turkey has 72% of the werl’s boron reserves. Howerer,
sis thought that there Is more then boron mines. The
‘olution: shows thatthe hie of reserves In Turi 400
years. But mary of the world’s reserves are estimated £0
be exhnusted inthe nea ture (sich 988 years for USAL
‘Also even though in USA tis necesary to ig up mines
‘nose 400 metres to remove boon, in Turkey boron can
‘be found 30 meters below the ground 3.
The lage borate deposits are evst in Bursa, Bakes
Eskger and Kita in Turkey. Trkey’s Boron reserves
‘re shown inthe flloning abe
Table 2, Variation of boron rezerves according tothe
min areas in Tokay (6)
gore dagihr (6) — im |
Naat — Teeter | ee cee wp ae
‘fen ces — rasa
Teper eam | ees a]
an Eat [ ole Taser [ana] tee |e ee
Ketel, Das [ Rola ose] fe a+
i ir [Tal goo [36
6. Boe OrinlerininKullarim Alanon 65, Usages Areas of Boron Prodcts
‘nye bor mineral ve ser token sanayi dll
rtoplam bor oka tonapbazinda asada gb ualamak
‘mind
{Cam Sanayi: Tekst cam ly, opti ier, cam serail,
sipeve diger diz cama.
Seramik Sanayi: Emay, sa, porselen boyala,
Nukes Sanayt: Uzay ve Ravacic say, sitanmeye ve
‘unmaya ve ya dayanath malzerle,roket yt atl
alee
‘Asker ve Zs Aral: Zh pla
ektronilletrit ve Bilgisayar Sanayi: CD strate
* de, bigisayar aglannda, sya maya dayant ber opt
kalo, yon ltteer, vakur tpl, elokikkondansator
le onkiynel sora.
lets Arann: Ceptlefonan, movie, eevizyn-
ta
Inaat ve Cimento Sektéende: Mukavemet atc veo
lasyon maize lark.
‘Metal: Paslanmaz ve alain el, strtunmeye ana
ya tas dayan malzeree ehimlee, dk malzeme-
lend kath ads ola, kasi, agrdinclar.
Ener Sektor: Hidrojen tag, gone eneysinin depot
‘as ges pllernde koje ola
(Otomobil Senay: Hava yastkennda, hidoslede, paste
abso, yadlrda ve metal absamlada, ve Ss yam
Seilamak amacyia,
Tek Sektrt: ya dayanl Kumasi, izolasyon malee-
‘elt, sul ip prltma malzerse,
ila ve Kozmetitsanay: Dexenfokt eller, antseptier,
ig macunin
Tip: Osteoporoz tedolrinde, ae hastaliarda, psi
Jateid, kemik geiminde ve manopor ted, bein
“tyth Saptander | ken - October 20147
The boron mineral and compounds-consuming inusties
in the wor can be ited os foons on the bas ofthe
total tonnage of boron exide:
Glass industry: Texte glass ers, opal fibers. glass
Ceramics, Bote and ther flat asses.
Seramic industry: Enamel, gas, porcelain paints.
Nuclear Industry: Space and aviation industry, fiction,
erosion and heat resistant materia rocket ie ace
itary and Armoured Vehicles: Armour plates.
Electronic Electrical and Computer Industry: Co drives,
computer networks, heat and crrsion resistant fiber op-
ti cable, Semiconductor, vacuum tubes, elecrcal on
‘denors,fnetiona fuses
‘Communication Instruments: Mobile phones, modems
televisions
Construction and Cement Sector: Resistance inresing,
Elation material
Metallurgy: Stainless and aloyed tet, feton and core-
sion resstant material soldering, a5 an alive agent
Casting mater blades and abrasives.
Energy Sector: Hydrogen carrey, storing solar eneray, 35
a protective i soar cel.
‘Automotive Industry: Au bags, hydaulie, peste ports,
Tue! ols, metal par, to provide host snd sound nse
Textile Sector: Heat resistant fabri, insulation materia,
artic sk polishing materials
Pharmaceutial and Cosmete Industries: Disinfectants
anus, toothpastes
Mealeal in treatment of esteopersis, aller diseses,
ychiay, bone development, Inthe treatment oF menea
Mf ME BB Makale / Article
nari tedavisind
mya Saney Ban Krnysealann indigenes eetrothe
trier ftasyonladan,banyo crete
risleme ve Beyacitma Sanayk: Tor detrankr, tox be
aver, pera
ra Sehr: Geer, beck bt
Gt Sanayi: Beyazabeoarak
yeu Olarakalyap meme’ ve aaclarda kone
oak Boye ve ver kuutuculannda (7)
trace.
1 Ener hammaddes! olarak bor
yet Romadde olarak bor 3 skis klar, Boranar,
Sroen tay olarak bor ve tatorda yakt olarak dogs
sn llonion bor
1.3 Boranlar
merken hove Kiwvetie ve dniz kurv! 1952 yids
sr mponiarca dolar Racin ir profeye aster. Ben
rokrbonlrdan en a2 2650 daha facia ene veren bor
rojen bles foketiede ve atmosfe st wakarde
st olarak Flaenay baad (8)
1.2 Harojon Tapes Olarak Bor
linen yk ctl od bor idrirden (NaBH) hi
sen eld ecimes esas dajanan bir yt hres! daha
vtenmistic Amerikan Wilenium Cel fmasincs tyerogen
derma ad ere bu ssteme 20dyum bor Ndr yak
ne tei fideajen salma fe gored (9)
ya reside, sodyum bor hia sue eaksio-
tundanbirejen ele dime reatsyons oer:
aH 2H,0->4H, + NABO,
hor hiro yt crs ign elektro eaksnonlen se a6
in
aot BH, +908 ~>80; + 6H,0 + Be
Kata reaksiyon:
be 1 44,0 +20, >B OH
bu reaksyonda yakt dejudan hava okseninden sao
Bor hr yok hctsiin tpl reaksyor Be
NaBH, + 20;-> NalO, + 240
Bor hdr yt ces youn ena kana yk etki
ite br ene dondstirme aes ve Kolay tapnbilen bir
Sn ace ody bor hidrrin (NaBH) sl cet
Fatale temasa geldignde gBeetden sat hidojen zx
yay. Bu hrojen yt hucrsie veya motor ier, Burs
Xaohsjenle erase gacerekyanarve Bu yanma sonucunda
sect nos cha hn son ket
thes slr
6.1.3 Tagt Arasannds Yat Olarak Dogrudan Bor
‘okt des nteminde,sdyum bor hidriran sul eas
nu somucy ede edn sn yak kallanimaka Sz ko
usu yaar imyasalrealiyonu
Neshte 210-244, + NOBO, + 1
pose and inthe treatment of bain cancer.
Chemical Industry: Reduction of some chemical, electro
Iyte process flotation drugs, ath solutions
Uicening and Bleaching Industry: Powder detergents,
power bleaching, polishers
Goricultare Sector: Fertilizers, asactcides or pons
Paper Industry: As bleaching agent
Protective: At 2 protecor n wood materi ond trees,
pints and varies dries (7.
6:1 Boron as Raw Material ofEneray
Baran a raw material for energy is used in three ways:
Boranes, boron as a hydrogen earner and boron cats
rect sed a fue inves:
in 1952, United States ar force ad the nava forces a
{eat huncreds of milins of dos for project. They
hag fo use the Boron hydrogen compounds which pro
vide ot last 30% more eneray than common hydrcar
onsas foe for rackets and atmosphere above arf [8
6.1.2 Boron as a Hylrogen Carrer
1s fuel col which based on producing hydrogen trom
Socium borohydride (NaBH) is ockled to known ft cel
‘Tis aystem that termed hydrogen on demand by Amer
an Mitnium Cell Company provides lean hySrogenSuP-
‘bon the som Borohye fel el 1)
The reaction of hycrogen preduction with soem boro
Ips ond water rtment this uel cel is follows
Nob, 4 2H,0 4H, + NOBO,
‘he electrode reactions in the borohyide fuel cl are a5
follows:
‘Anode reaction; BH, + 60H ~ 60; + 6H,0 + Be
Cathode Reaction: de +4120 + 30,» BOH
The ful supped directly rom air oxygen inthis ree
tion
‘The total reaction in the borohydride ue calls as follows:
Nabi, +20, = NaB0, +240,
‘The borohyehide fue cel that uses intensive energy f 2
Iigh-etfcency energy conversion equipment and tans
portable itd coll easy. When aqueous solution of so
ium borohydride (att) contacts with the cataiyst pure
Ivdrogen ges speeds frm solution. This hyarogen goes
{fol calor engine and bums acting with oxygen. As 2
suitofthiscombustion, lett energy srleased. This
produced energy is moved the vehicle,
6.1.3 Boron as a Ful in The Vehicles
Inthe fuel sustainable proces, the liquid fuel obtaining
‘By reaction of sodium borer with water suse. The
hema reaction ofthe ao as follows
Noah, + 20,0 aH, + NaBO, + heatMakale / Article
oa —
inde, Su inde gbatnen sedyum bor hid (NaBH)
tans ola depotnmatad. Ene retmek in hide
mn ye ered bu kargoma wyglanan katalc-
= inyasareaksiyon Balti Reaksiyonsonucu gz hal
Seibest flan huen yt linden gore eet
cer ee eli. By reskayon sonunda sour bor
1 God meta borat) atk olrak bitkmektedi Sten
ene kaynadyosrak Kullanian hidrojen, sadece inte
ine oetlecesinn, burada hull Katalize eet
rstenig eaman ayiabimeke ve raison kontrol
rake durdurlbameted (10)
alan arestalarsonucunds bocunhidrojenden daha
Coe tae ou raya gst Bor butin ynle-
ge alterna yt sstemlen He nyjestanmsbr Geek
main gree hidoje,almingum, magnesyum abi a
mat yo sstomlrinden stn yon tay konulnds-
tt
ryolth motor sstemlernde tema olarak yak Unite
Piston kl, yak beer antes, safoksjen ele etme
Decleor ve yatma sonrsi cian atk zernd
nm yer alate Neral ben motor Ben
yen yori lduf gb fare yoo dima falc. Ay
ere! prenspl hrojen vey boran olarak tannin
5 rdrojen kang yak sterdeinden de aki,
wotorun Gama Prensiler
ern gene alga prensibsaflastnls borun bel ie
ona a osjen fe yal hicresne ana, pstonun se
frmasasoplanan 100 bar basin anda ekzterik bir
Stsyns ve bunun sonicunds pala piston yukon
relat otrmasine Jaya [1],
da ssktnda yan, pam ézeiiolmayan bor oki
ne bal ir eran Kam haline geile basinca m=
ainda paaraa ve ign yar otra iste
me kon salaraxta [11
bor sole santas bor obs parcalanmas ie Klay
ee edited Saf oksjan se aracin Snne yey
eck gum itlern ayaa See srasnda havadaks
oranda bukinan ak’ ite etrespe ede sce
“(2
stemin ays youn cams bir yapsinasahip BI, (bo-
okt bona Hrokabon br tanks soil
iret ib presienerek kage formuna da get
rota bor ‘antrlenden yn ealastlaak gr do
sl br yo ola kllaiabieked Sistem racn
2 atric lament pi) bese! ve oksen ani
3a artmas saglamabtacr (12)
Jor yok yanma sistem tems emas aaa gelde ve
it.
Sodium borohydie (NaBH) doled n water i stored
{25.0 mixture, When hydrogen is needed to produce en
‘hay, the chemical reaction 1s inated by the catalyst
Vint applied tothe mature. The hydrogen inthe
[phase that flere by reaction is passed inthe fue cell
{produce electric energy. At the end of tis reaction,
Sodium boron salt (Sodium metaborate) Is deposited 3s
temsteHycregen s used an energy source in the system
Vil be procuced coy a8 needed. Therefore, the cataat
ted com be remaved from the soltion aay time and
the reacton canbe stopped in 2 contolble oy 11],
‘Asa result ofreseorches i found thatthe boron be
{er than hyorogen as an energy care. The boron con
pret with othr alematve fel systems wth al spect.
Gutstonding aspects of Boron from the aterative fuel
Stems suchas petrol, hyrogen, aluminium, magnesiom
fre demonstrated 11
fascaly, combustion unt, piston rod, fuel feeding wnt,
‘biaing pure oxygen and feeding units and the waste
procesing unit fter buming are located in boron fueled
Imotor stems, Different aspects of motor are abays
‘Greater hers ft has sor aspects 0 norml gasoline
Ehaine. Besides bese princes are ferent than the
Doon hycogen blending fuel systems defined 35 yar
‘gen oF borane
* operating Principles of Engine
‘The general operating principle of engine is based on
Crothermic rection of purtied boron wth 9 certain pure
‘agg nthe combustion celf under 10 bar pressure pro
ded by compression ofthe piston and as @ result the
piston moved up by exploding
When at room temperature nor-combusibiity and non
twplosion property boron mixed with oxygen under pres
Sure, frexplodes and provides desired thrust nthe intr
tal combustion engine [11
pure boron can be easly obtained by dsintegration of bo
Fon idea solar power station. During movement of the
‘ehicl, pure oxygen wil be obtained by iltation of 2) %
Dover inthe afr with iver fiers thot wl be placed in
front ofthe veil 12.
syste wte ie iguid 810, (bora roksit— bora) haw
ing dense olassy sructre. Hydrocarbon can be depesited
into tank by cooling and aso ean be formed ingot by
presi. Bor can be used by re purified as 2 recycle fel
tthe boron station. The jst provides to Increase fil
tment feed and enygen mature By increasing the vehicle
Speed 2h,
The scheme of boron fuel combustion system i given 2s
follows
eeecoh
CRIS vena omni
se. so pn rt
7.80 Motorunun Avanti
7 even
Sar yok ola yanmayen bir yapead. Delays in
fi etme, kemlanma, stele tutsma fsb okt Bir
‘faze aninda ptlama meydona glee. Ba yonyle
bor sok given br yak Bu zal dpolams ve nak
yin de borin bt ust agar 13)
7.2 Taguma ve Sablama Koay
Bir brim hidrojenin yaptg ig 22 bin bor yapmaktadr
‘ncak borun bie hac a drojein bi ahi
‘an 1de bir Delays ay ata bor irojenden
‘aha az hci kalo Ayea irojenin alm bir tank inde
ogutlorak tlm: gerne Bors ir att tr
fen di, lament pit yapsya bir maka zens yer
aca, Uescuolmadigndan lara fullanisadaeksime:
sce [13
73 Gaz Emisjonunun Olay
foram en Dib aantalrndan bid cove dostu ola
Yanmast sonucu gaz emisyons olmaraktad, Bone olrak
‘endian yogjun cams Bsn yanma sonra ac gkan
‘rerondur bi 222 atinds katiogmaktade Bu atk io™
abon bir tanita tplanbimekte vy proseslenerekKge
Jaki ola llama mimkn elma 1).
£8, Genel Degerlendirme
or trate ve ekonomi agdan nei mineral. un
ya rezevnin demi bis Turkije mas ve bu te
enn ne chide degerendinldis grdemin omer ir ko-
ror (5)
Bor cam, sera, deterjan endsterinden okt okt y=
‘mina kadar coe gens ir lana klanmaktat Bor ve
{rane cinyodagegmiyendust ve teknoloye ship Ok
lero 240 gerd ulagan uc urdnl ie sonar teel i
‘di urumundac (13).
Bu den bay bir meme sah olan mineratin yada
Grime i lke hai Dunya rezervinin 63" Tar
Ue. 810'ona ise ABD rahi Taye tek bapna dann
gn
Makale / Article ne
a
Piston
‘Ser cxygen ter
=
LI
CES contain ipoctn
eran toad
Figure 1. The operating principe of vehicle
7, The Advantages of Boron Engine
31 Securty
‘he baron fuel has an easly non-combustible srt
Therefore, there are no rok of explosion, sparking and te
Ignition. the explosion vll not occur ina cas, Because of
{hat born ss rele ful. Ths property provides an a
arta fr storage and tanspartaon of boron (131,
72 Easiness of Transport and Storage
22 ete boron do the work tha proved by a uit y=
‘iogen but unit volume weight of baron fs one of elven
oft weigh of hydrogen. Hence, the same weight of bo
Fon occupies volume ksthan hydrogen Besides hrogen
‘must be apt na thick tank with cooling whereas boran is
oti the fl tank wil be placed cn a role fo flament
form. ue to nomvolatie for, wil be sed without re
‘ution for year 13.
27.3 The Absonce of Gaseous Emissions
(ne of the biggest advantages of the boron is ature fen
tironment end, The ret of combustion, gas emision
thoes not ecu The dense gly tg led Bora 9 rod
Uetwhih ireland fer comburton and tsois under
[22°C Thi waste hytrocarbon canbe collected na tank of
In pace toe as an ingot fel by processing {14
General Evaluation
Baron i a9 inpestane mineral strategiealy and econo
‘al, An inpertan prt of word reserves iin Turkey 2nd
‘Salaton of these resaner ae an important ise On the
‘end 115,
Boron is used ina wide aeas fom glass, ora detergent
Insty to proton ofthe rocket foe The boron and
predict which has aast 240 kinds of by procs oe the
Imoin input of dusty inthe developing dnd techroogial
‘Counties nthe er (15
‘wo countries dominated to production of the miner
having such reat importance inthe werd. Trkey hes 63
of world eserves and USA has 10% Turkey afloe as the