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UNIFAC MODEL
Since it is development in 1975 by
Abrams and Prauznitz, a number of
different versions of the UNIFAC
group-contribution method for the
estimation of liquid phase activity
coefficients have been developed.
Advantages
What is it?
UNIFAC is a method based on a
group contribution approach for
activity coefficient in liquid phase
of a component i in a solution with
one or more components and is
calculated as the sum of the
contributions of all groups within
the mixture. It depends only on
temperature and composition.
General model equations
Image1.Group-contribution
method.
The main feature of all UNIFAC
method is based on a group
contribution approach where in
activity coefficient in liquid phase
of a component i in solution with
one or more components is
calculated as the sum of the
contributions of all groups within
the mixture.
On the intensives variables, the
UNIFAC method is dependent only
on temperature and composition
but not pressure.
in
the
activity
Some Applications:
Calculate vapour-liquid
equilibria.
L-L equilibria.
Equilibrium Thermodynamics
S-L equilibria.
For estimation of excess
enthalpies.
For determining solubilitys of
gases.
UNIQUAC MODEL
What is it?
The UNIQUAC model or the excess
Gibbs energy, consists in: a
combinatorial, entropic contribution
(accounts the molecules size and
shape effects) and a residual,
enthalpic contribution (accounts for
the energy interaction effects).
Main advantage: it is a good
representation
of
vapour-liquid
equilibrium
and
liquid-liquid
equilibrium and can be obtained for
a large range of non-electrolyte
mixtures.
Applications
Binary systems
Multicomponent systems
Azeotropic systems
Liquid-liquid equilibria
Dilute systems
Self-associating systems
Polymers
Extrapolation
References
1. Kontogeorgis, G. & Gani, R. (2004).
Computer Aided Property
Estimation for Process and Product
Design. November 2, 2015, de
Elsevier B.V Sitio web:
https://books.google.es/books?
id=mE1R5Q-s48C&pg=PA60&dq=what+is+the+
model+unifac&hl=es&sa=X&ved=
0CCUQ6AEwAWoVChMIuZ_D9NryyA
IViHECh1LMApr#v=onepage&q&f=false
2. Behera, M. (2010). VAPOUR LIQUID
EQUILLIBRIUM MODELING USING
UNIFAC GROUP CONTRIBUTION
Equilibrium Thermodynamics
Team members:
Lenia Snchez
A01374086
Jessica Moctezuma
A01168698
Mara Jos Morales
Mariana Muoz
A01373313
Ana Patricia Botello
A01372773
A01373878
Equilibrium thermodynamics
Dr. Yara Almanza
Group:2
November 3, 2015